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101.
    
Trace elements, including rare earth elements (REE), exhibit systematic variations in plutonic rocks from the Captains Bay pluton which is zoned from a narrow gabbroic rim to a core of quartz monzodiorite and granodiorite. The chemical variations parallel those in the associated Aleutian calcalkaline volcanic suite. Concentrations of Rb, Y, Zr and Ba increase as Sr and Ti decrease with progressive differentiation. Intermediate plutonic rocks are slightly enriched in light REE (La/Yb=3.45–9.22), and show increasing light REE fractionation and negative Eu anomalies (Eu/Eu*=1.03–0.584). Two border-zone gabbros have similar REE patterns but are relatively depleted in total REE and have positive Eu anomalies; indicative of their cumulate nature. Initial 87Sr/86Sr ratios in 8 samples (0.70299 to 0.70377) are comparable to those of volcanic rocks throughout the arc and suggest a mantle source for the magmas. Oxygen isotopic ratios indicate that many of the intermediate plutonic rocks have undergone oxygen isotopic exchange with large volumes of meteoric water during the late stages of crystallization; however no trace element or Sr isotopic alteration is evident.Major and trace element variations are consistent with a model of inward fractional crystallization of a parental high-alumina basaltic magma at low pressures (6 kb). Least-squares approximations and trace element fractionation calculations suggest that differentiation in the plutonic suite was initially controlled by the removal of calcic plagioclase, lesser pyroxene, olivine and Fe-Ti oxides but that with increasing differentiation and water fugacity the removal of sub-equal amounts of sodic plagioclase and hornblende with lesser Fe-Ti oxides effectively drove residual liquids toward dacitic compositions. Major and trace element compositions of aplites which intrude the pluton are not adequately explained by fractional crystallization. They may represent partial melts derived from the island arc crust. Similarities in Sr isotopes, chemical compositions and differentiation trends between the plutonic series and some Aleutian volcanic suites indicates that shallow-level fractional crystallization is a viable mechanism for generating the Aleutian calcalkaline rock series.LDGO Contribution no. 2964  相似文献   
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Changes in surface charge of soil particles that accompany mineral transformations during soil formation were measured for a humid tropical chronosequence in Hawaiian basalt ranging in lava flow age from 0.3 to 4100 kiloyears (ky). Parent mineralogy is dominated by glass, olivine, pyroxene, and feldspar, whereas poorly crystalline (PC) weathering products (allophane, microcrystalline gibbsite, ferrihydrite) accumulate in early to intermediate weathering stages (through 400 ky), and crystalline secondary minerals (kaolinite, gibbsite, goethite) are dominant in the oldest (1400 and 4100 ky) soils. Detailed characterization of the solid phase was accomplished with chemical extractions, X-ray diffraction analysis, and molecular spectroscopy (FTIR and 13C MAS NMR). Simultaneous proton titration and background ion adsorption measurements were made on LiCl saturated soils over a range in pH (2-9) and ionic strength (0.001 and 0.01 M LiCl). Dependence of variable surface charge on solution composition reflects the changing nature of mineral-organic interactions over the course of pedogenesis. Points of zero net proton charge (PZNPC) ranged from 3.4 to 6.2 and 2.0 to 5.8 at 0.001 and 0.01 M ionic strength (I), respectively. Intermediate-aged soils containing the highest mass concentration of humified soil organic matter (SOM) and its complexes with PC minerals gave rise to the steepest charging curves (largest pH dependence) and highest PZNPC values. Surface charge properties of these soils most closely reflected their weakly acidic Al and Fe hydroxide constituents, which is consistent with metal hydroxide saturation of organic functional groups, rather than organic coating of mineral surfaces. Charging curves were less steep and PZNPC values were lower for the older soils, consistent with SOM coating of more crystalline goethite, kaolinite, and gibbsite surfaces in a soil system less impacted by labile Al and Fe.  相似文献   
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The impacts of climate change on future river flows are a growing concern. Typically, impacts are simulated by driving hydrological models with climate model ensemble data. The U.K. Climate Projections 2009 (UKCP09) provided probabilistic projections, enabling a risk-based approach to decision-making under climate change. Recently, an update was released—UKCP18—so there is a need for information on how impacts may differ. The probabilistic projections from UKCP18 and UKCP09 are here applied using the change factor method with catchment-based hydrological modelling for 10 catchments across England. Projections of changes in median, mean, high, and low flows are made for the 2050s, using the A1B emissions scenario from UKCP09 and UKCP18 as well as the RCP4.5 and RCP8.5 emissions scenarios from UCKP18. The results show that, in all catchments for all flow measures, the central estimate of change under UKCP18 is similar to that from UKCP09 (A1B emissions). However, the probabilistic uncertainty ranges from UKCP18 are, in all cases, greater than from UKCP09, despite UKCP18 having a smaller ensemble size than UKCP09. Although there are differences between the central estimates of change using UKCP18 RCP4.5, RCP8.5 and A1B emissions, there is considerable overlap in the uncertainty ranges. The results suggest that existing assessments of hydrological impacts remain relevant, though it will be necessary to evaluate sensitive decisions using the latest projections. The analysis will aid development of advice to users of current guidance based on UKCP09 and help make decisions about the prioritization of further hydrological impacts work using UKCP18, which should also apply other products from UKCP18 like the 12-km regional data.  相似文献   
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Subinertial and seasonal variations in the Soya Warm Current (SWC) are investigated using data obtained by high frequency (HF) ocean radars, coastal tide gauges, and a bottom-mounted acoustic Doppler current profiler (ADCP). The HF radars clearly captured the seasonal variations in the surface current fields of the SWC. Almost the same seasonal cycle was repeated in the period from August 2003 to March 2007, although interannual variations were also discernible. In addition to the annual and interannual variations, the SWC exhibited subinertial variations with a period of 5–20 days. The surface transport by the SWC was significantly correlated with the sea level difference between the Sea of Japan and Sea of Okhotsk for both the seasonal and subinertial variations, indicating that the SWC is driven by the sea level difference between the two seas. The generation mechanism of the subinertial variation is discussed using wind data from the European Centre for Medium-range Weather Forecasts (ECMWF) analyses. The subinertial variations in the SWC were significantly correlated with the meridional wind stress component over the region. The subinertial variations in the sea level difference and surface current delay from the meridional wind stress variations by one or two days. Sea level difference through the strait caused by wind-generated coastally trapped waves (CTWs) along the east coast of Sakhalin and west coast of Hokkaido is considered to be a possible mechanism causing the subinertial variations in the SWC.  相似文献   
106.
We show that observable blueshifted radiation can emanate from material freely falling toward compact objects. Using a fully relativistic treatment and considering possible blocking of photon trajectories by a neutron star or black hole, we demonstrate that blueshifts are observable.Supported in part by the National Science Foundation.  相似文献   
107.
Since the U.S. Embassy in Beijing placed an air quality sensor on its roof and began publishing the results on Twitter in 2008, air quality has gained widespread attention on Chinese microblogs. When the Chinese government introduced new air quality standards in 2012, some hailed this as a victory for Chinese microbloggers, signifying the emergence of social media as a democratizing force leading to greater citizen power. Using a representative sample of microblog posts collected from October 2012 to June 2013 on the topic of air pollution, as well as contextual information from a variety of sources, we examine how the government, companies, nongovernmental organizations, and individuals approach the Chinese social media landscape. We find that although microblogs are capable of empowering citizens to advance an environmental cause, social media have also been increasingly employed by the government as a tool for social monitoring and control and by companies as a platform for profiting from air pollution.  相似文献   
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The objective of this study is to assess the climate projections over South America using the Eta-CPTEC regional model driven by four members of an ensemble of the Met Office Hadley Centre Global Coupled climate model HadCM3. The global model ensemble was run over the twenty-first century according to the SRES A1B emissions scenario, but with each member having a different climate sensitivity. The four members selected to drive the Eta-CPTEC model span the sensitivity range in the global model ensemble. The Eta-CPTEC model nested in these lateral boundary conditions was configured with a 40-km grid size and was run over 1961–1990 to represent baseline climate, and 2011–2100 to simulate possible future changes. Results presented here focus on austral summer and winter climate of 2011–2040, 2041–2070 and 2071–2100 periods, for South America and for three major river basins in Brazil. Projections of changes in upper and low-level circulation and the mean sea level pressure (SLP) fields simulate a pattern of weakening of the tropical circulation and strengthening of the subtropical circulation, marked by intensification at the surface of the Chaco Low and the subtropical highs. Strong warming (4–6°C) of continental South America increases the temperature gradient between continental South America and the South Atlantic. This leads to stronger SLP gradients between continent and oceans, and to changes in moisture transport and rainfall. Large rainfall reductions are simulated in Amazonia and Northeast Brazil (reaching up to 40%), and rainfall increases around the northern coast of Peru and Ecuador and in southeastern South America, reaching up to 30% in northern Argentina. All changes are more intense after 2040. The Precipitation–Evaporation (P–E) difference in the A1B downscaled scenario suggest water deficits and river runoff reductions in the eastern Amazon and S?o Francisco Basin, making these regions susceptible to drier conditions and droughts in the future.  相似文献   
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