The interior structure of Mercury and its core sulfur content

Depth-dependent interior structure models of Mercury are calculated for several plausible chemical compositions of the core and of the mantle. For those models, we compute the associated libration amplitude, obliquity, tidal deformation, and tidal changes in the external potential. In particular we study the relation between the interior structure parameters for five different mantle mineralogies and two different temperature profiles together with two extreme crust density values. We investigate the influence of the core light element concentration, temperature, and melting law on core state and inner and outer core size. We show that a sulfur concentration above 10 wt% is unlikely if the temperature at the core-mantle boundary is above 1850 K and the silicate shell at least 240 km thick. The interior models can only have an inner core if the sulfur weight fraction is below 5 wt% for core-mantle boundary temperature in the 1850-2200 K range. Within our modeling hypotheses, we show that with the expected precision on the moment of inertia the core size can be estimated to a precision of about 50 km and the core sulfur concentration with an error of about 2 wt%. This uncertainty can only be reduced when more information on the mantle mineralogy of Mercury becomes available. However, we show that the uncertainty on the core size estimation can be greatly reduced, to about 25 km, if tidal surface displacements and tidal variations in the external potential are considered.     

V473 Lyrae: a Blazhko-effect Cepheid?

The amplitude spectra of the light curves of RR Lyrae Blazhko stars can often be typified by symmetrical triplets. It is shown that the same applies to V473 Lyr. Furthermore, the star is probably a radial pulsator – as is thought to be the case for the RR Lyrae stars – thus ruling out rotational splitting of a purely non-radial mode.     

Characterization of the lithological contact in the shergottite EETA79001—A record of igneous differentiation processes on Mars

Abstract— Elephant Moraine (EET) A79001 is the only Martian meteorite that consists of both an olivine‐phyric shergottite (lithology A) and a basaltic shergottite (lithology B). The presence of these lithologies in one rock has previously been ascribed to mixing processes (either magmatic or impact‐induced). Here we present data regarding phase changes across the contact between the lithologies. These data show that the contact is gradational and suggest that it is a primary igneous feature consistent with crystallization of a single cooling magma. We present a model to establish a petrogenetic connection between an olivine‐phyric and a basaltic shergottite through differentiation. The model involves the shallow or surface emplacement of a magma that contained pre‐eruptive solids (phenocrysts and minor xenocrysts). Subsequent differentiation via crystal settling and in situ crystallization (Langmuir 1989) resulted in a layered sequence of lithology A overlain by lithology B, with gradations in modal abundance of maskelynite (increasing from A to B) and pigeonite/maskelynite (decreasing from A to B), and a gradational change in pattern of pyroxene zonation (zones of magnesian augite separating magnesian and ferroan pigeonite appear and thicken into B) across the contact. A pigeonite phenocryst‐bearing zone near the contact in lithology B appears to be intermediate between lithology A and the bulk of lithology B (which resembles basaltic shergottite Queen Alexandra Range [QUE] 94201). Re‐examination of Sr isotopic compositions in lithology A and across the contact is required to test and constrain the model.     

Principal components in active galactic nuclei variability data and the estimation of the flux contributions from different components

It has been found that the near-infrared flux variations of Seyfert galaxies satisfy relations of the form   F_i ≈α _{i j} +β _{i j} F_j   , where F_i , F_j are the fluxes in filters i and j ; and  α _{i , j} , β _{i , j}   are constants. These relations have been used to estimate the constant contributions of the non-variable underlying galaxies. The paper attempts a formal treatment of the estimation procedure, allowing for the possible presence of a third component, namely non-variable hot dust. In an analysis of a sample of 38 Seyfert galaxies, inclusion of the hot dust component improves the model fit in approximately half the cases. All derived dust temperatures are below 300 K, in the range 540–860 K or above 1300 K. A noteworthy feature is the estimation of confidence intervals for the component contributions: this is achieved by bootstrapping. It is also pointed out that the model implies that such data could be fruitfully analysed in terms of principal components.     

PDRS and Shocks in S106 IR and CEP a East

We present SWS grating scans of pure H2 rotational lines, as well as several infrared fine-structure lines for two embedded Young Stellar Objects, S106 IR and Cep A East. Excitation temperatures and masses were derived from the low-lying pure rotational levels of H2 and are 490 and 740 K and 0.04 and 0.007 M⊙ for S106 and Cep A, respectively. The observations were compared to theoretical models for PDRs and dissociative and non-dissociative shocks. The infrared spectrum of S106 IR is dominated by PDR emission while that of Cep A East has a large shock component. We suggest that the difference between these two objects could reflect an evolutionary trend. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Mesoarchean emergence of modern-style subduction

Well-preserved volcanic sequences span the Paleoarchean to Neoarchean evolution of the Pilbara Craton, in northwestern Australia. This region provides the best physical evidence bearing on the stage of Earth's history when modern-style tectonic processes began. Paleoarchean assemblages in the eastern nucleus of the craton (the 3.51–3.24 Ga Pilbara Supergroup) show few features that can reasonably be interpreted as evidence for modern-style subduction processes. Incompatible trace element-enriched felsic volcanic horizons show geochemical evidence for the interaction between mafic magmas and crust, but this evidence, on its own, can equally well be interpreted in terms of either a subduction-enriched mantle source or local and limited assimilation of felsic crust into the voluminous tholeiitic magmas that dominate the Pilbara Supergroup. Viewed in context within the thick autochthonous and consistently upward-younging Pilbara Supergroup, these felsic units are most likely related to the same plume-dominated processes that formed the basalts that dominate the supergroup. It is very unlikely that modern-style plate tectonic processes played any role in the Paleoarchean evolution of the Pilbara Craton, although some form of non-uniformitarian (e.g. flat) subduction process may have operated.In stark contrast, the Mesoarchean units of the West Pilbara Terrane and the late-tectonic basins that cover that boundary between the West and East Pilbara Terranes, show clear evidence for modern-style convergent margin processes. Igneous rocks in this belt, which flanks the old eastern cratonic nuclei, have enriched geochemical signatures that cannot be accounted for by crustal contamination. This region is also characterised by a linear magmatic and structural fabric, by the presence of lithologically and geochronologically exotic belts, and by the presence of a broad belt of isotopically more juvenile crust. The collective strength of these arguments provides compelling evidence that a modern-style oceanic arc fringed the East Pilbara Terrane at 3.12 Ga and accreted to that terrane by 2.97 Ga. These assemblages mark the minimum age for the birth of modern-style plate subduction process.     

Flood effects on phosphorus immobilisation in a river water filled pit lake—Case study Lake Goitsche (Germany)

Between 1999 and 2002, a former open-cast mine was filled with river water forming the recent Lake Goitsche. During filling initially acid water was neutralised. Phosphorus (P) imported from Mulde River was nearly completely removed from the water column by co-precipitation with iron (Fe) and aluminium (Al) and deposited in the sediment.During extremely high waters of the Mulde River in 2002, a dike breach facilitated a second high import of P into Lake Goitsche with suspended and dissolved matter. The analysis of total phosphorus (TP), however, showed that P again had been eliminated from the water body a few months after the flood event. Sediment investigations before filling with river water, during filling, and after the flood event were used to analyse the process of P immobilisation in a lake with acid mine drainage history.The ratios of Fe to soluble reactive P (SRP) of sediment pore water were up to three orders of magnitudes higher than in natural lakes and can serve as an indicator for potential internal P loading from sediments. The SRP concentrations at the oxic/anoxic boundary were near or below the limit of quantification (< 0.2 μmol/L). Fe and manganese (Mn) redox cycling were responsible for hindering P dissolution from sediment to lake water.Finally it can be stated, that the risk of eutrophication for such a lake seems to be low.     

Modeling approaches and strategies for data-scarce aquifers: example of the Dar es Salaam aquifer in Tanzania

Management of groundwater resources can be improved by using groundwater models to perform risk analyses and to improve development strategies, but a lack of extensive basic data often limits the implementation of sophisticated models. Dar es Salaam in Tanzania is an example of a city where increasing groundwater use in a Pleistocene aquifer is causing groundwater-related problems such as saline intrusion along the coastline, lowering of water-table levels, and contamination of pumping wells. The lack of a water-level monitoring network introduces a problem for basic data collection and model calibration and validation. As a replacement, local water-supply wells were used for measuring groundwater depth, and well-top heights were estimated from a regional digital elevation model to recalculate water depths to hydraulic heads. These were used to draw a regional piezometric map. Hydraulic parameters were estimated from short-time pumping tests in the local wells, but variation in hydraulic conductivity was attributed to uncertainty in well characteristics (information often unavailable) and not to aquifer heterogeneity. A MODFLOW model was calibrated with a homogeneous hydraulic conductivity field and a sensitivity analysis between the conductivity and aquifer recharge showed that average annual recharge will likely be in the range 80–100 mm/year.