Tetrahedral occupancy of ferric iron in (Mg,Fe)O: Implications for point defects in the Earth's lower mantle

We investigated the concentration and site occupation of ferric iron (Fe³⁺) in (Mg,Fe)O to understand the influence of point defects on transport properties such as atomic diffusion, electrical conductivity and viscosity. We conducted Mössbauer spectroscopy of (Mg_0.8Fe_0.2)O single crystals synthesized at temperatures from 1673 to 2273 K and pressures from 5 to 15 GPa with Re–ReO₂ and Mo–MoO₂ oxygen fugacity buffers. The isomer shift of the Mössbauer spectra suggests that Fe³⁺ occupies mostly the tetrahedral site at reduced conditions and both the octahedral and tetrahedral sites at oxidized conditions. We formulate a thermodynamic model of point defect dissolution in (Mg,Fe)O which suggests that unassociated tetrahedral Fe³⁺ is more stable than unassociated octahedral Fe³⁺ at high-pressure and low oxygen fugacity due to the effect of configurational entropy. The pressure dependence of Fe³⁺ concentration indicates a change in the dominant site occupancy of Fe³⁺: (1) Fe³⁺ in the tetrahedral site, (2) Fe³⁺ in the octahedral site, and (3) defect clusters of Fe³⁺ and cation vacancy, in the order of increasing oxygen fugacity and decreasing pressure. This is in reasonable agreement with previously reported experiments on Fe³⁺ concentration, Mg–Fe interdiffusivity and electrical conductivity. We consider it plausible that (Mg,Fe)O accommodates Fe³⁺ in the tetrahedral site down to the lower mantle. Based on our results and available experimental data, we discuss the solubility competition between Fe³⁺ and protons (H⁺), and its implications for transport properties in the lower mantle.     

Chemical composition of Coscinodiscus wailesii and the implication for nutrient ratios in a coastal water, Seto Inland Sea, Japan

Chemical compositions of Coscinodiscus wailesii were determined for four samples of natural cells. Results revealed that the cellular Si:N ratio of C. wailesii cell was 2.4:1.0-5.2:1.0. The impacts of C. wailesii on surrounding coastal water were evaluated from hydrographic observations, in which C. wailesii cell density, nutrients concentrations and temperature were monitored from November 2001 to February 2005 in Harima-Nada, the Seto Inland Sea, Japan. In low temperature periods, from October to December, two peaks of C. wailesii cell density were observed and nutrient concentrations were depleted. The draw-down ratio of Si(OH)(4) and DIN (Si(OH)(4):DIN ratio) in the water column were similar to the cellular Si:N ratio of C. wailesii cells, which have high Si contents. In addition the effects of different Si(OH)(4):DIN ratio were determined for in situ bottle incubation experiments. In the culture experiments, picoplankton (0.2-2.0 microm) which consisted of small flagellates became dominant under low Si(OH)(4):DIN ratios. These results suggested that the sizes distribution shifted to small size and the phytoplankton community was changed to small flagellates after the C. wailesii bloom. These changes would influence predators at higher trophic levels in its coastal ecosystem.     

Species diversity of the genus <Emphasis Type="Italic">Skeletonema</Emphasis> (Bacillariophyceae) in the industrial harbor Dokai Bay,Japan

Seven Skeletonema species were identified at one station in the industrial harbor Dokai Bay, Japan, in October 2007 and then monthly from January 2008 to December 2009 by morphological scanning electron microscopy observations and molecular analyses of mainly the large subunit (LSU) rDNA. We refer to one species identified as S. dohrnii using LSU rDNA, but as S. marinoi using the small subunit (SSU) rDNA and consequently we use the term S. marinoi-dohrnii complex. This is the first time that S. ardens, S. costatum s.s., and S. pseudocostatum have been recorded in Japan and that S. menzelii and S. tropicum have been identified by molecular methods in Japan. The S. marinoi-dohrnii complex was isolated with high frequency all year-round, and S. japonicum was also isolated with high frequency but not so in summer. S. Tropicum was isolated from September to December, but S. ardens and S. costatum s.s. were isolated only when the water temperature exceeded 20°C. S. pseudocostatum bloomed just once, in summer, but S. menzelii was isolated in May and again in October. The continuous year-round occurrence of S. costatum s.l. in the bay is supported by the succession of these seven species. Six of the species, except S. menzelii, were important components of algal blooms in the bay. One to four species of Skeletonema were isolated every month. Monthly species diversity was higher when S. ardens, S. costatum s.s., and S. tropicum that are usually associated with tropical or subtropical waters, were isolated. In general, species diversity of the genus Skeletonema was very high in Dokai Bay.     

Cumulative impact mapping: Advances,relevance and limitations to marine management and conservation,using Canada's Pacific waters as a case study

Analysis of cumulative human impacts in the marine environment is still in its infancy but developing rapidly. In this study, existing approaches were expanded upon, aiming for a realistic consideration of cumulative impacts at a regional scale. Thirty-eight human activities were considered, with each broken down according to stressor types and a range of spatial influences. To add to the policy relevance, existing stressors within and outside of conservation areas were compared. Results indicate the entire continental shelf of Canada's Pacific marine waters is affected by multiple human activities at some level. Commercial fishing, land-based activities and marine transportation accounted for 57.0%, 19.1%, and 17.7% of total cumulative impacts, respectively. Surprisingly, most areas with conservation designations contained higher impact scores than the mean values of their corresponding ecoregions. Despite recent advances in mapping cumulative impacts, many limitations remain. Nonetheless, preliminary analyses such as these can provide information relevant to precautionary management and conservation efforts.     

The comoving-frame equation of radiative transfer in relativistic flows

The comoving-frame equations of radiative transfer and moment equations to accurate terms of all orders inv/c are derived in the modified Lagrangian form. The equations exactly describe the interaction of radiation with matter in a relativistically moving medium in flat or curved spacetime. Two specialized sets of equations are presented: (1) the equation of radiative transfer and moment equations accurate to terms of second order (v ²/c ²), and (2) the transfer equation and moment equations for a radial flow in curved spacetime with the Schwarzschild-type metric.     

W-3参数方程组的数值解法

从Ｗ－３风频模型的期望值及其拟合误差出发,分别用矩法和极值法导出关于Ｗｅｉｂｕｌ参数的两组方程。结合实测风况资料用数值法求解,获得相应的Ｗ－３风频参数,通过几个气象台站的实测资料计算、比较,证明这两种方法给出的参数其拟合精度均高于Ｗ－２模型给出的结果。     

The anoxic water mass in Hiuchi-Nada

Distribution of the anoxic water mass in the eastern part of Hiuchi-Nada was investigated from 1981 to 1983. A cold water mass was found on the bottom of the area concerned in summer, and a second (i.e. lower) thermocline appeared just above the cold water mass. The anoxic water was observed below a second thermocline. The horizontal distribution of the cold water mass coincided with that of the anoxic water mass, and also with a region of high concentration of organic matter in the sediment. These results suggest two important effects of the second thermocline on the generation of the anoxic water mass. Firstly, it prevents supply of dissolved oxygen from the upper to bottom layer of the water column. Secondly, it accelerates settling of particulate material resulting in a large accumulation of organic matter in the bottom water and the sediment which leads to an increase in the rate of oxygen consumption. The net oxygen consumption rate in the bottom layer in this sea was much smaller than that in Mikawa Bay where anoxia occurs at almost the same level as in Hiuchi-Nada. This finding also suggests the important role of the second thermocline.     

Association of picophytoplankton distribution with ENSO events in the equatorial Pacific between 145°E and 160°W

Climatological variability of picophytoplankton populations that consisted of >64% of total chlorophyll a concentrations was investigated in the equatorial Pacific. Flow cytometric analysis was conducted along the equator between 145°E and 160°W during three cruises in November–December 1999, January 2001, and January–February 2002. Those cruises were covering the La Niña (1999, 2001) and the pre-El Niño (2002) periods. According to the sea surface temperature (SST) and nitrate concentrations in the surface water, three regions were distinguished spatially, viz., the warm-water region with >28 °C SST and nitrate depletion (<0.1 μmol kg⁻¹), the upwelling region with <28 °C SST and high nitrate (>4 μmol kg⁻¹) water, and the in-between frontal zone with low nitrate (0.1–4 μmol kg⁻¹). Picophytoplankton identified as the groups of Prochlorococcus, Synechococcus and picoeukaryotes showed a distinct spatial heterogeneity in abundance corresponding to the watermass distribution. Prochlorococcus was most abundant in the warm-water region, especially in the nitrate-depleted water with >150×10³ cells ml⁻¹, Synechococcus in the frontal zone with >15×10³ cells ml⁻¹, and picoeukaryotes in the upwelling region with >8×10³ cells ml⁻¹. The warm-water region extended eastward with eastward shift of the frontal zone and the upwelling region during the pre-El Niño period. On the contrary, these regions distributed westward during the La Niña period. These climatological fluctuations of the watermass significantly influenced the distribution of picophytoplankton populations. The most abundant area of Prochlorococcus and Synechococcus extended eastward and picoeukaryotes developed westward during the pre-El Niño period. The spatial heterogeneity of each picophytoplankton group is discussed here in association with spatial variations in nitrate supply, ambient ammonium concentration, and light field.     

安顺市畜禽养殖碳排放时空差异研究

畜禽养殖是农业碳源之一。根据安顺市畜禽数量,估算2001—2015年安顺市畜禽碳排放量。从畜禽碳排放结构、碳排放变异系数、碳排放密度、碳排放经济强度4个方面对其进行分析。研究结果显示:(1)安顺市2001—2006年的畜禽碳排放量连续增长,由86.91万t增长到113.06万t,2007年下降到84.31万t;2007—2010年缓慢增长;2011—2013年相对平稳;2014—2015年又增长。(2)畜禽碳排放主要来自牛和猪,牛年均碳排放量为70.70万t。(3)安顺市2003—2007年各区县畜禽碳排放绝对差异呈现扩大趋势,2008—2014年差异性呈现减小趋势。(4)西秀区的畜禽碳排放密度最高,平坝县最低;镇宁县的畜禽碳排放经济强度最高;紫云县次之;关岭县最低。安顺市政府部门应该研制并推广畜禽养殖温室气体减排技术,降低畜禽养殖碳排放量。     

Recent Occurrences of Dinophysis fortii (Dinophyceae) in the Okkirai Bay, Sanriku, Northern Japan, and Related Environmental Factors

Occurrence of Dinophysis fortii, a causative organism of diarrhetic shellfish poisoning, in the Okkirai Bay, Sanriku was surveyed in 1995, 1996, 1998 and 1999. In each year, its major occurrence was detected from the late May or early June and continued until the late June or early July. Seawater temperature, salinity and nutrients measurements suggested that inflows of offshore water into the bay played key role on the first major occurrence of D. fortii. With an analysis of continuous temperature data in the Otsuchi Bay which locates north of the Okkirai Bay, this influent was considered to be intermittent inflow of the offshore water by internal tidal waves which propagated from north to south. First occurrence peak of D. fortii was synchronous with phycobilin containing microalgae, synechococcoid cyanobacteria and cryptomonad, in all years. In vivo fluorescence measurement of D. fortii cells in 1995 and 96 showed that the cells in these microalgal-rich water contained more phycobilin pigment than those in the microalgal-poor water. The result may support a hypothesis that D. fortii acquires phycobilin by an uptake of these microalgae. After the first major occurrence in the bay, D. fortii sometimes occurred in rather inshore waters where showed elevated ammonium level possibly due to increased heterotrophic activity. Together with another finding that D. fortii is mixotrophic, it could be assumed that the environment being suited to heterotrophic nutrition also stimulates D. fortii growth in the bay.