全文获取类型
收费全文 | 24829篇 |
免费 | 189篇 |
国内免费 | 918篇 |
学科分类
地球科学 | 25936篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 7篇 |
2019年 | 5篇 |
2018年 | 4768篇 |
2017年 | 4047篇 |
2016年 | 2595篇 |
2015年 | 249篇 |
2014年 | 101篇 |
2013年 | 56篇 |
2012年 | 1004篇 |
2011年 | 2753篇 |
2010年 | 2038篇 |
2009年 | 2336篇 |
2008年 | 1915篇 |
2007年 | 2380篇 |
2006年 | 67篇 |
2005年 | 213篇 |
2004年 | 425篇 |
2003年 | 422篇 |
2002年 | 258篇 |
2001年 | 60篇 |
2000年 | 61篇 |
1999年 | 17篇 |
1998年 | 29篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1985年 | 5篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 23篇 |
1980年 | 21篇 |
1977年 | 2篇 |
1976年 | 8篇 |
1963年 | 2篇 |
1961年 | 1篇 |
1953年 | 1篇 |
1950年 | 1篇 |
1940年 | 1篇 |
1939年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
Helmut Kerndorff Stephan Kühn Thomas Minden Dagmar Orlikowski Thomas Struppe 《Environmental Geology》2008,55(2):291-301
The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater
affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority
called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be
used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of
individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling
and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization
of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing
gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones. 相似文献
52.
Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and 57Fe–58Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ56Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ56Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ57Fe?=?0.534?±?0.010, 2SE). 相似文献
53.
Calcite was synthesized by four methods, and the luminescence decay-time was measured for nine samples before and after heating
hydrothermally in the temperature range 200–400°C. Decay-time data were collected between room temperature and approximately
15 K. The decay time at room temperature is approximately 50 ms, with little difference between a given calcite before and
after hydrothermal treatment. The decay time at 15 K is always greater than at room temperature as the effect of thermal quenching
diminishes. Differences in decay time before and after heating are more apparent at low temperature owing to this reduction
in thermal quenching. The decay time decreased significantly in two samples, and an increase in decay time was observed in
the remaining seven samples following heating. Among the latter group, the change in decay time was insignificant in three
samples. The results are compared with previous data in which it was shown that the effect of heating is to increase the intensity
of luminescence. 相似文献
54.
M. Julleh Jalalur Rahman Rumana Yeasmin Tom McCann 《Journal of the Geological Society of India》2016,88(6):705-710
Mineralogical and chemical investigations (<2μm clay separates) of shale samples from the Neogene-age Surma Group obtained from four wells (Habiganj-11, Shahbazpur-1, Titas-11, Titas-15) in the Bengal basin, Bangladesh, were carried out in order to reveal the clay mineral composition as reservoir exploration and exploitation requires a good understanding of the clay minerals. The samples were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM) and X-Ray fluorescence spectrometry (XRF). Mineralogically, the sub-surface Surma Group shales comprise predominantly quartz, plagioclase, illite, chlorite, kaolinite, with lesser amounts of K-feldspar, dolomite and smectite, and minor to trace amounts of calcite, siderite and pyrite. The chemical composition of the <2 μm clay separates also suggests an illite and chlorite-rich composition. With increasing burial depth, the Surma Group shales are enriched in illite. The gradual decreasing of the smectite clays with depth and ultimate disappearance at greater depths (≥ 3000 m) may have been responsible for the presence of the diagenetic illite. Based on the mineralogical composition it is most likely that the illite-chlorite associations together with quartz and feldspar were predominantly detrital in origin and thus reflect the presence of a rapidly-rising source terrain not subjected to intense weathering. 相似文献
55.
Citizens as sensors: the world of volunteered geography 总被引:62,自引:0,他引:62
Michael F. Goodchild 《GeoJournal》2007,69(4):211-221
In recent months there has been an explosion of interest in using the Web to create, assemble, and disseminate geographic information provided voluntarily by individuals. Sites such as Wikimapia and OpenStreetMap are empowering citizens to create a global patchwork of geographic information, while Google Earth and other virtual globes are encouraging volunteers to develop interesting applications using their own data. I review this phenomenon, and examine associated issues: what drives people to do this, how accurate are the results, will they threaten individual privacy, and how can they augment more conventional sources? I compare this new phenomenon to more traditional citizen science and the role of the amateur in geographic observation. 相似文献
56.
François Farges 《Physics and Chemistry of Minerals》2009,36(8):463-481
Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO4 2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses. 相似文献
57.
Despite a recent increase in the number of vulnerability analyses there has been relatively little discussion of vulnerability
assessment of social–environment system, especially when they face multiple hazards. In this study, we developed an applicable
and convenient method to assess vulnerability of social–environment system at a regional scale. Vulnerability is quantified
by measuring three critical elements (i.e. hazards, sensitivity, and resilience) through some key variables. The results showed
that vulnerability is high in Miaofeng Mountain in Mengtougou District, the hills of Pinggu County and the riparian zones
of the lower courses of the Beiyun and Yongding Rivers; but low in the city of Beijing and the southwestern part of the Fangshan
District. Areas of very high, high, medium, and low-vulnerability account for 6.19, 25.48, 33.06, and 35.27% of the total
area, respectively. The degree of vulnerability decreases in a northwest direction in mountainous areas and declines from
watercourses to riparian zones along a lateral direction in the plain. Some adaptive strategies are also proposed. 相似文献
58.
Mark Anglin Harris 《Environmental Geology》2009,56(8):1517-1522
Several years (7) after incidental lithification by added gypsum, the effect of crushing and phyto-organics on some physical
properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking
up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into <2-mm
particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the
crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of
the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the
controls, as a >3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically
treated samples. The increase in water infiltration by combining crushing with phyto-organic applications was ascribed to
a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized channels and pores. Conversely,
it was concluded that the singular crushing of gypsum-hardened bauxite waste in the waste dumps is potentially wasteful and
ineffective. 相似文献
59.
Samir M. Zaid Oussama A. EL-Badry Adel M. Akarish Mahmoud A. Mohamed 《Arabian Journal of Geosciences》2018,11(7):147
The mineralogy and geochemistry of the Upper Cretaceous Duwi black shales of Nile Valley district, Aswan Governorate, Egypt, have been investigated to identify the source rock characteristics, paleoweathering, and paleoenvironment of the source area. The Duwi Formation consists mainly of phosphorite and black shales and is subdivided into three members. The lower and upper members composed mainly of phosphorite beds intercalated with thin lenses of gray shales, while the middle member is mainly composed of gray shale, cracked, and filled with gypsum. Mineralogically, the Duwi black shales consist mainly of smectite and kaolinite. The non-clay minerals are dominated by quartz, calcite, phosphate, dolomite, feldspar, with little gypsum, anhydrite, iron oxides, and pyrite. Based on the CIA, PIA, and CIW values (average?=?84, 94, 95, respectively), it can be concluded that the litho-components of the studied shales were subjected to intense chemical weathering and reflect warm/humid climatic conditions in the depositional basin. The provenance discrimination diagram indicates that the nature of the source rocks probably was mainly intermediate and mafic igneous sources with subordinate recycled sedimentary rocks (Nubia Formation). Geochemical characteristics indicate that the Duwi black shales in Nile Valley district were deposited under anoxic reducing marine environments. 相似文献
60.
Bristen granite is a body of fine-grained leucogranite occurring in the Gotthard rail base tunnel in the Central Alps. During construction of the tunnel, Bristen granite (Brgr) has been drilled along a 600 m long section. The aplite-granite belongs to the suite of Variscan granitoid intrusions of the Aar massif and contains a variety of accessory minerals typical of highly differentiated granites. Rock forming fluorite, partly enriched in yttrium (Y) and rare earth elements (REE), is intergrown with the late Y- and REE-bearing carbonate mineral synchysite. The granite contains a variety of Ti- and Y-REE-niobates, thorite, and zircon. Compared with the calc-alkaline central Aar granite (cAgr), Bristen granite is strongly depleted in Ti, P, Mg, Sr, and Ba and shows a remarkable enrichment in incompatible elements such as Rb, Th, U, Nb, Y, HREE and F. Bristen granite is the most evolved granitoid rock of the Aar massif. The composition of Brgr is typical of post-collisional reduced (ferroan) A-type granites. The Brgr melt formed in the lower crust and crystallized from a highly differentiated melt at the cotectic point in the quartz-feldspar system close to 100 MPa and 700 °C. The Brgr intruded as a small isolated stock pre-Variscan gneisses with sharply discordant contacts. The primary igneous host of Nb, Ta, Y, U, Th and REE is biotite in addition to minor amounts of allanite, and zircon. The presence of Y-REE-fluorite, synchysite, parisite and Y- and Ti-niobates and other REE-minerals can be related to reaction of igneous biotite and primary fluorite with hydrothermal fluids. The reaction is associated with alpine metamorphism, because Y-bearing fluorite and synchysite have been reported from Alpine fissures. The transformation of primary biotite to chlorite and muscovite released the heavy metal oxides under lower greenschist facies conditions that formed the Alpine diagnostic mineral stilpnomelane at about 300 °C. 相似文献