A re-appraisal of the stratigraphy and volcanology of the Cerro Galán volcanic system,NW Argentina

From detailed fieldwork and biotite ⁴⁰Ar/³⁹Ar dating correlated with paleomagnetic analyses of lithic clasts, we present a revision of the stratigraphy, areal extent and volume estimates of ignimbrites in the Cerro Galán volcanic complex. We find evidence for nine distinct outflow ignimbrites, including two newly identified ignimbrites in the Toconquis Group (the Pitas and Vega Ignimbrites). Toconquis Group Ignimbrites (~5.60–4.51 Ma biotite ages) have been discovered to the southwest and north of the caldera, increasing their spatial extents from previous estimates. Previously thought to be contemporaneous, we distinguish the Real Grande Ignimbrite (4.68 ± 0.07 Ma biotite age) from the Cueva Negra Ignimbrite (3.77 ± 0.08 Ma biotite age). The form and collapse processes of the Cerro Galán caldera are also reassessed. Based on re-interpretation of the margins of the caldera, we find evidence for a fault-bounded trapdoor collapse hinged along a regional N-S fault on the eastern side of the caldera and accommodated on a N-S fault on the western caldera margin. The collapsed area defines a roughly isosceles trapezoid shape elongated E-W and with maximum dimensions 27 × 16 km. The Cerro Galán Ignimbrite (CGI; 2.08 ± 0.02 Ma sanidine age) outflow sheet extends to 40 km in all directions from the inferred structural margins, with a maximum runout distance of ~80 km to the north of the caldera. New deposit volume estimates confirm an increase in eruptive volume through time, wherein the Toconquis Group Ignimbrites increase in volume from the ~10 km³ Lower Merihuaca Ignimbrite to a maximum of ~390 km³ (Dense Rock Equivalent; DRE) with the Real Grande Ignimbrite. The climactic CGI has a revised volume of ~630 km³ (DRE), approximately two thirds of the commonly quoted value.     

Columnar jointing in vapor-phase-altered,non-welded Cerro Galán Ignimbrite,Paycuqui, Argentina

Columnar jointing is thought to occur primarily in lavas and welded pyroclastic flow deposits. However, the non-welded Cerro Galán Ignimbrite at Paycuqui, Argentina, contains well-developed columnar joints that are instead due to high-temperature vapor-phase alteration of the deposit, where devitrification and vapor-phase crystallization have increased the density and cohesion of the upper half of the section. Thermal remanent magnetization analyses of entrained lithic clasts indicate high emplacement temperatures, above 630°C, but the lack of welding textures indicates temperatures below the glass transition temperature. In order to remain below the glass transition at 630°C, the minimum cooling rate prior to deposition was 3.0 × 10⁻³–8.5 × 10⁻²°C/min (depending on the experimental data used for comparison). Alternatively, if the deposit was emplaced above the glass transition temperature, conductive cooling alone was insufficient to prevent welding. Crack patterns (average, 4.5 sides to each polygon) and column diameters (average, 75 cm) are consistent with relatively rapid cooling, where advective heat loss due to vapor fluxing increases cooling over simple conductive heat transfer. The presence of regularly spaced, complex radiating joint patterns is consistent with fumarolic gas rise, where volatiles originated in the valley-confined drainage system below. Joint spacing is a proxy for cooling rates and is controlled by depositional thickness/valley width. We suggest that the formation of joints in high-temperature, non-welded deposits is aided by the presence of underlying external water, where vapor transfer causes crystallization in pore spaces, densifies the deposit, and helps prevent welding.     

Strain-induced magma degassing: insights from simple-shear experiments on bubble bearing melts

Experiments have been performed to determine the effect of deformation on degassing of bubble-bearing melts. Cylindrical specimens of phonolitic composition, initial water content of 1.5 wt.% and 2 vol.% bubbles, have been deformed in simple-shear (torsional configuration) in an internally heated Paterson-type pressure vessel at temperatures of 798–848 K, 100–180 MPa confining pressure and different final strains. Micro-structural analyses of the samples before and after deformation have been performed in two and three dimensions using optical microscopy, a nanotomography machine and synchrotron tomography. The water content of the glasses before and after deformation has been measured using Fourier Transform Infrared Spectroscopy (FTIR). In samples strained up to a total of γ ∼ 2 the bubbles record accurately the total strain, whereas at higher strains (γ ∼ 10) the bubbles become very flattened and elongate in the direction of shear. The residual water content of the glasses remains constant up to a strain of γ ∼ 2 and then decreases to about 0.2 wt.% at γ ∼ 10. Results show that strain enhances bubble coalescence and degassing even at low bubble volume-fractions. Noticeably, deformation produced a strongly water under-saturated melt. This suggests that degassing may occur at great depths in the volcanic conduit and may force the magma to become super-cooled early during ascent to the Earth’s surface potentially contributing to the genesis of obsidian.     

High-temperature vesuvianite: crystal chemistry and surface considerations

A multi-methodical approach has been applied for characterizing the bulk and surface crystal chemical features of a high-temperature vesuvianite crystal from skarns of Mount Somma-Vesuvius Volcano (Naples, Italy). Vesuvianite belongs to the space group P4/nnc with unit cell parameters a = 15.633(1) Å, c = 11.834(1) Å and chemical formula (Ca_18.858 Na_0.028 Ba_0.004 K_0.006 Sr_0.005 □_0.098)_19.000 (Al_8.813 Ti_0.037 Mg_2.954 Mn_0.008 Fe_0.114²⁺ Fe_1.375³⁺ Cr_0.008 B_0.202)_13.511 Si_18.000(O_0.261 F_0.940 OH_7.799)_9.000. Structure refinement, which converges at R = 0.0328, demonstrates a strong positional disorder down the fourfold axes, indicating that the Y1 site is split into two positions (Y1A and Y1B) alternatively occupied. However, because of X4 proximity to Y1B and Y1A, X4 cannot be occupied if Y1B or Y1A are. Overall Y1 occupancy (Y1A + Y1B) reaches approximately 0.5, as common in vesuvianite and occupancy of Y1B site is extremely limited. Moreover, T1 position, limitedly occupied, accommodates the excess of cations generally related to Y position. A small quantity (0.202 apfu) of boron is sited at the T2 site that, like T1, is poorly occupied. The determination of the amount of each element on the (100) vesuvianite surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s, and Ca_2p core levels, evidences that a greater amount of aluminum and a smaller amount of calcium characterize the surface with respect to the bulk. Although both of these features require further investigation, we may consider the Al increase can be related to preferential orientation of Al-rich sites on the (100) plane. Furthermore, the surface structure of vesuvianite suggests that Al, Ca, and Mg cations maintain coordination features at the surface similar to the bulk. Silica, however, while presenting fourfold coordination, shows also a [1]-fold small coordinated component at binding energy 99.85 eV, due to broken Si–O bonds at the surface. The presence of eight- and nine-coordinated Ca cations is suggested by a large XPS feature resulting from the merging of Ca_2p3/2 and Ca_2p1/2 peaks at 348.45 and 352.05 eV, respectively.     

Growth rate and climate responses of Pinus pinea L. in Italian coastal stands over the last century

Sensitivity to climate change and anthropogenic disturbance is a typical feature of Mediterranean forests, which grow under dynamic and manipulated environmental conditions. In this study, we examine stone pine (Pinus pinea L.) along the Tyrrhenian coast of Italy to analyse the tree-growth variability on a temporal scale and to evaluate the radial growth response to climate trends over the last century. The analysis of tree ring widths at the decadal and multidecadal scale, which were standardised to remove the age trend, showed primarily significant downward trends and time periods with lower growth rates. Characterised by a clear decline in tree ring widths, the two periods of 20 years from the mid-1920s and the early 1970s appeared to be the least favourables for tree growth. Precipitation was the main factor driving growth, and the effect was cumulative over consecutive years because of the increase in soil water content. Including the current year of ring formation, correlations between decline in precipitation and tree growth were greatest with 3-year precipitation sums. The shifting influence of winter rainfall on tree ring growth toward not significant values during the last decades, together with the lack of significant correlation between the current year’s precipitation and growth decline from the 1970s, might suggest an increasingly dependence on long periods of water supply to utilise the water content stored due to the previous rainy years. The negative effect on tree-growth decline of summer and early-fall temperatures appeared as a forcing influence related to long-term changes in climate rather than high-frequency climate fluctuations.     

Mixed nonlinear regression for modelling historical temperatures in Central–Southern Italy

This paper has exploited, for Central and Southern Italy (Mediterranean Sub-regional Area), an unprecedented historical dataset as an attempt to model seasonal (winter and summer) air temperatures in pre-instrumental time (back to 1500). Combining information derived from proxy–documentary data and large-scale simulation, a statistical downscaling approach in the form of mixed regression model was developed to adapt larger-scale estimations (regional component) to the sub-regional temperature pattern (local component). It interprets local temperature anomalies by means of monthly based Temperature Anomaly Scaled Index in the range ?5 (very cold conditions in June) to 2 (very warm conditions). The modelled response agrees well with the independent data from the validation sample (Nash–Sutcliffe efficiency coefficient, >0.60). The advantage of the approach is not merely increased accuracy in estimation. Rather, it relies on the ability to extract (and exploit) the right information to replicate coherent temperature series in historical times.     

Geological and archaeological evidence of active faulting on the Martana Fault (Umbria–Marche Apennines,Italy) and its geodynamic implications

This paper examines the morphotectonic and structural–geological characteristics of the Quaternary Martana Fault in the Umbria–Marche Apennines fold‐and‐thrust belt. This structure is more than 30 km long and comprises two segments: a N–NNW‐trending longer segment and a 100°N‐trending segment. After developing as a normal fault in Early Pleistocene times, the N–NNW Martana Fault segment experienced a phase of dextral faulting extending from the Early to Middle Pleistocene boundary until around 0.39 Ma, the absolute age of volcanics erupted in correspondence to releasing bends. The establishment of a stress field with a NE–ENE‐trending σ₃ axis and NW–NNW σ₁ axis in Late Pleistocene to Holocene times resulted in a strong component of sinistral faulting along N–NNW‐trending fault segments and almost pure normal faulting on newly formed NW–SE faults. Fresh fault scarps, the interaction of faulting with drainage systems and displacement of alluvial fan apexes provide evidence of the ongoing activity of this fault. The active left‐lateral kinematic along N–NNW‐trending fault segments is also revealed by the 1.8 m horizontal offset of the E–W‐trending Decumanus road, at the Roman town of Carsulae. We interpret the present‐day kinematics of the Martana Fault as consistent with a model connecting surface structures to the inferred north‐northwest trending lithospheric shear zone marking the western boundary of the Adria Plate. Copyright © 2003 John Wiley & Sons, Ltd.     

Partial melting of ultrahigh-pressure metamorphic rocks at convergent continental margins: Evidences,melt compositions and physical effects

Ultrahigh-pressure(UHP) metamorphic rocks are distinctive products of crustal deep subduction,and are mainly exposed in continental subduction-collision terranes. UHP slices of continental crust are usually involved in multistage exhumation and partial melting, which has obvious influence on the rheological features of the rocks, and thus significantly affect the dynamic behavior of subducted slices. Moreover,partial melting of UHP rocks have significant influence on element mobility and related isotope behavior within continental subduction zones, which is in turn crucial to chemical differentiation of the continental crust and to crust-mantle interaction.Partial melting can occur before, during or after the peak metamorphism of UHP rocks. Post-peak decompression melting has been better constrained by remelting experiments; however, because of multiple stages of decompression, retrogression and deformation, evidence of former melts in UHP rocks is often erased. Field evidence is among the most reliable criteria to infer partial melting. Glass and nanogranitoid inclusions are generally considered conclusive petrographic evidence. The residual assemblages after melt extraction are also significant to indicate partial melting in some cases. Besides field and petrographic evidence, bulk-rock and zircon trace-element geochemical features are also effective tools for recognizing partial melting of UHP rocks. Phase equilibrium modeling is an important petrological tool that is becoming more and more popular in P-T estimation of the evolution of metamorphic rocks; by taking into account the activity model of silicate melt, it can predict when partial melting occurred if the P-T path of a given rock is provided.UHP silicate melt is commonly leucogranitic and peraluminous in composition with high SiO_2,low MgO, FeO, MnO, TiO_2 and CaO, and variable K_2 O and Na_2 O contents. Mineralogy of nanogranites found in UHP rocks mainly consists of plagioclase + K-feldspar + quartz, plagioclase being commonly albite-rich.Trace element pattern of the melt is characterized by significant enrichment of large ion lithophile elements(LILE), depletion of heavy rare earth elements(HREE) and high field strength elements(HFSE),indicating garnet and rutile stability in the residual assemblage. In eclogites, significant Mg-isotope fractionation occurs between garnet and phengite; therefore, Mg isotopes may become an effective indicator for partial melting of eclogites.     

Petrogenesis and geodynamic significance of silicic volcanism in the western Trans-Mexican Volcanic Belt: role of gabbroic cumulates

In the western Trans-Mexican Volcanic Belt voluminous silicic volcanism has been associated with the rifting of the Jalisco block from mainland Mexico. Rhyolitic volcanism started at 7.5 Ma after a major pulse of basaltic volcanism aged 11–8.5 Ma associated with slab detachment. This was followed by a second period, between 4.9 and 2.9 Ma, associated with rhyolitic domes and ignimbrite coexisting with basaltic volcanism. The similarity in rare earth element contents between basalts and rhyolites excludes a simple liquid line of descent. The low Ba and Sr contents and the ferroan character of the rhyolites suggest extensive fractional crystallization. Late Miocene–early Pliocene rhyolite Sr isotope values are only slightly more radiogenic than the basalts, whereas Nd isotope ratios are indistinguishable. We successfully modelled the 7.5–3 Ma silicic magmatism as a result of partial melting of crustal gabbroic complexes that we infer to have formed in the mid-lower crust due to the high-density Fe-enriched composition of the late Miocene basaltic volcanism. Slab rollback since ~7.5 Ma favoured decompression melting and arrival of additional mafic magmas that intruded in the lower crust. These basalts heated and melted the gabbroic complexes forming the silicic magmas, which subsequently underwent assimilation and fractional crystallization processes. The first silicic pulse was emplaced during a period of low tectonic activity. Extensional faulting since the Pliocene favours the eruption of both silicic magma and lesser amount of mafic lavas.     

A new method of identifying an appropriate distance between independent extreme annual rain events for a 5-min time resolution precipitation data network

Theoretical and Applied Climatology - This paper deals with precipitation events, particularly the problem of recognising events individually, of distinguishing one local...