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41.
Stars form in magnetized molecular clouds composed primarily of neutral gas with a trace amount of ions. We present a semi-implicit strategy for incorporating the equations that describe the coupled ion and neutral two-fluid equations, with a full energy equation, into the RIEMANN code that uses a TR-BDF2 algorithm to stably handle the stiffness of the source terms. We demonstrate that the numerical implementation works through the use of a suite of test problems that we catalog here. We show that reproducing the analytic dispersion analysis for the propagation of waves in a two-fluid plasma is an especially strong code test. We also present a two-fluid analogue of the Noh wall-shock problem and demonstrate the performance of the code on the Wardle instability. We also present a novel blast wave test, showing that the results reduce to the single fluid results under strong coupling, yet differing considerably when the coupling is weak. These test problems demonstrate that the numerical implementation can accurately capture the dissipation rate of waves and reproduce the structure of a C-shock. 相似文献
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Chad Paton Jon D. Woodhead Janet M. Hergt David Phillips Simon Shee 《Geostandards and Geoanalytical Research》2007,31(4):321-330
Strontium isotopic composition is a potentially powerful tracer in studies of kimberlitic rocks but the results from even the most carefully collected and stringently prepared bulk-rock samples are still hampered by contamination and alteration effects. Here we describe a LA-MC-ICP-MS technique which can obtain accurate, high precision Sri ratios from 50–150 μm kimberlitic groundmass perovskite without requiring time-consuming mineral separation procedures. Since perovskite is a robust magmatic phase with an extremely low Rb/Sr ratio, the effects of late-stage crustal contamination, post-emplacement alteration and age correction are minimised and results are more representative of primary melt compositions, while additionally preserving powerful grain-scale spatial and textural information. We demonstrate that the adopted protocol overcomes isobaric interferences from Kr+ , Rb+ , Er2+ and Yb2+ , and that Ca dimers and Ca argides do not detectably affect the quality of 87 Sr/86 Sr ratios produced. To illustrate the utility of the technique, contrasting bulk-rock and in situ perovskite results from eleven Proterozoic kimberlites are documented. 相似文献
43.
Countries need to know what species are present within their waters to effectively manage the issue of non-indigenous marine species. Five survey methods are currently employed to detect introduced marine species: the Hewitt and Martin protocols (66% of effort; 73 ports, 12 countries); Rapid Assessment Surveys (7% of effort; 8 regions, 4 countries); the Bishop Museum protocols (7% of effort; 8 ports, 3 countries); the Chilean aquaculture surveys (1% of effort; numerous regions; 1 country); and Passive Sampling protocols (18% of effort; 20 ports, 2 countries). These methods use either quantitative, qualitative, or a mixture of the two sampling techniques and tend to target locations that are potential inoculation sites (i.e., such as ports, marinas and aquaculture facilities). To date, introduced marine species surveys have been implemented in 19 countries and have detected more than 1185 non-indigenous, 735 cryptogenic and 15,315 native species. 相似文献
44.
G. I. Marchuk B. E. Paton G. K. Korotaev V. B. Zalesny 《Izvestiya Atmospheric and Oceanic Physics》2013,49(6):579-591
An analysis is given of the methods of operational oceanography based on measurements derived from satellite data, observations acquired by drifters and passing vessels, and modern simulations of marine and oceanic circulations. In addition, a historical review is conducted of the previous and current research in this field carried out in the Soviet Union, Ukraine, and Russia. A discussion is given of the principles underlying the design of an effective data-computing system (DCS) for solving the problems of operational oceanography and the implementation of the prototype system for the Black Sea within the joint research project of the Russian Academy of Sciences (RAS) and the National Academy of Sciences of Ukraine (NASU) “The Black Sea as an Ocean Simulation Model.” The effectiveness of applying the multicomponent splitting method in the construction of sea circulation models and specialized DCSs with integrated algorithms of variational assimilation of observational data is estimated. The concept of using the Black Sea as a testing site for innovations is developed. The underlying idea of the concept is the similarity of the Black Sea dynamics with processes in the oceans. The numerical Black Sea circulation models used in the project are described, their development areas are discussed, and the requirements to a Black Sea observing system are defined. 相似文献
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Karl R. Atkinson John C. Zarnecki Martin C. Towner Timothy J. Ringrose Axel Hagermann Andrew J. Ball Mark R. Leese Gunter Kargl Mark D. Paton Ralph D. Lorenz Simon F. Green 《Icarus》2010,210(2):843-851
The Huygens probe landed on the then unknown surface of Titan in January 2005. A small, protruding penetrometer, part of the Surface Science Package (SSP), was pushed into the surface material measuring the mechanical resistance of the ground as the probe impacted the landing site. We present laboratory penetrometry into room temperature surface analogue materials using a replica penetrometer to investigate further the nature of Titan’s surface and examine the sensor’s capabilities. The results are then compared to the flight instrument’s signature and suggest the Titan surface substrate material consists of sand-sized particles with a mean grain size ～2 mm. A possible thin 7 mm coating with mechanical properties similar to terrestrial snow may overlie this substrate, although due to the limited data we are unable to detect any further layering or grading within the near-surface material. The unusual weakening with depth of the signature returned from Titan has, to date, only been reproduced using a damp sand target that becomes progressively wetter with depth, and supports the suggestion that the surface may consist of a damp and cohesive material with interstitial liquid contained between its grains. Comparison with terrestrial analogues highlights the unusual nature of the landing site material. 相似文献
47.
Exposure of humans to monomethylmercury (MMHg) occurs primarily through consumption of marine fish, yet there is limited understanding concerning the bioaccumulation and biogeochemistry of MMHg in the biologically productive coastal ocean. We examined the cycling of MMHg in sediments at three locations on the continental shelf of southern New England in September 2003. MMHg in surface sediments is related positively to inorganic Hg (Hg(II) = total Hg − MMHg), the geographical distribution of which is influenced by organic material. Organic matter also largely controls the sediment-water partitioning of Hg species and governs the availability of dissolved Hg(II) for methylation. Potential gross rates of MMHg production, assayed by experimental addition of 200Hg to intact sediment cores, are correlated inversely with the distribution coefficient (KD) of Hg(II) and positively with the concentration of Hg(II), most probably as HgS0, in 0.2-μm filtered pore water of these low-sulfide deposits. Moreover, the efflux of dissolved MMHg to overlying water (i.e., net production at steady state) is correlated with the gross potential rate of MMHg production in surface sediments. These results suggest that the production and efflux of MMHg from coastal marine sediments is limited by Hg(II), loadings of which presumably are principally from atmospheric deposition to this region of the continental shelf. The estimated diffusive flux of MMHg from the shelf sediments averages 9 pmol m−2 d−1. This flux is comparable to that required to sustain the current rate of MMHg accumulation by marine fish, and may be enhanced by the efflux of MMHg from near-shore deposits contaminated more substantially with anthropogenic Hg. Hence, production and subsequent mobilization of MMHg from sediments in the coastal zone may be a major source of MMHg to the ocean and marine biota, including fishes consumed by humans. 相似文献
48.
Chad C. Trout 《Geochimica et cosmochimica acta》2006,70(1):44-55
A model Suwannee fulvic acid (SFA [Leenheer, J.A., 1994. In: Baker, L.A. (Ed.), Chemistry of Dissolved Organic Matter in Rivers, Lakes and Reservoirs. Advances in Chemistry Series, vol. 237. American Chemical Society]) was energy minimized in various deprotonation states using semi-empirical methods. The structures were minimized in the isolated SFA phase and SFA with 60 water molecules to mimic the first solvation sphere. The relative energies of deprotonation were calculated at four carboxylic acid sites with Hartree-Fock (HF/6-31G(d)) and density functional theory (B3LYP/6-31G(d)) methods. Comparisons were made between the theoretical methods and states of solvation. Isolated and solvated models resulted in different relative deprotonation orders. The energy changes calculated for removing a H+ from a given carboxylic acid group as a function of overall model molecule charge are large enough to explain the large variations of carboxyl group pKas in dissolved natural organic matter. Analysis of the SFA structure as a function of molecular charge is also discussed. 相似文献
49.
Chad S. Lane Sally P. Horn Claudia I. Mora Kenneth H. Orvis David B. Finkelstein 《Journal of Paleolimnology》2011,45(3):323-338
Continuous terrestrial records of paleoclimate and paleovegetation that extend to the late Pleistocene are rare for the circum-Caribbean uplands. In this study we analyzed the bulk and compound-specific carbon isotope composition of lake sediments spanning this period from Lago de las Morrenas 1 (LM1), a glacial lake in the highlands of southern Costa Rica, for evidence of climate and vegetation changes that may not have been apparent in previous analyses. The stable carbon isotope ratios of n-alkanes typically derived from terrestrial plants (δ13CC27–C33) indicate an increased abundance of C4 plant taxa during the late Pleistocene and earliest Holocene that may be related to decreased atmospheric carbon dioxide concentrations, increased aridity, or habitat availability. These n-alkane isotope ratios also provide evidence of more arid conditions during the early and late Holocene, and more mesic conditions during the middle Holocene, a pattern prevalent in other paleoclimate records from the region that is thought to be related to millennial-scale dynamics of the intertropical convergence zone (ITCZ). The sensitivity of the LM1 paleorecord to trade wind dynamics provides further support for the role of millennial-scale shifts in ITCZ dynamics in driving neotropical environmental change, and indicates that the effects of ITCZ migration were not limited to the lowlands. 相似文献
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Heather E. Gall Stephen A. Sassman Byron Jenkinson Linda S. Lee Chad T. Jafvert 《水文研究》2014,28(3):1318-1328
Little is known regarding hormone export from tile‐drained agricultural fields despite the widespread presence of tile drains in the Midwestern United States. By intensively measuring water flow rates and hormone concentrations in four subsurface tile drains and three receiving ditches at a working Midwest farm, hormone fluxes and loads from the tile‐drained fields were quantified. Before and during the 17‐month study period (January 2009 – May 2010), the associated farm fields received various animal waste applications (beef, dairy, poultry, sheep, and swine). Hormones monitored included the estrogens17β‐ and 17α‐estradiol, estrone, and estriol; the natural androgens testosterone, and androstenedione; and the synthetic androgens 17β‐ and 17α‐trenbolone, and trendione. Hormone loads measured in the ditches for three drainage areas during the entire 17‐month study period were in ranges of 16–58 mg/ha for total estrogens, 6.8–19 mg/ha for natural androgens, and 4.2–44 mg/ha for synthetic androgens. Because higher hormone concentrations generally occurred during discrete periods of increased flow, high flow rates often were associated with a disproportionately high hormone flux. For example, 80% of total estrogens and natural androgens exported into the ditches occurred during only 9–26% of the study period, coinciding with the most significant storm events. In addition, hormone fluxes were highest during storm events that occurred shortly after animal waste applications. Therefore, to effectively reduce hormone loads exported to downstream aquatic ecosystems in the absence of any application reduction, the short periods during which high‐flow events occur must be targeted. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
