Trace Element and Isotope Geochemistry of the Volcanic Rocks of Bequia, Grenadine Islands, Lesser Antilles Arc: a Study of Subduction Enrichment and Intra-crustal Contamination

Pliocene volcanics on the island of Bequia comprise two interbeddedsuites of basalts and andesites. The isotopically homogeneoussuite (IHS) has a limited range of Sr—Nd—Pb isotopes(⁸⁷Sr/⁸⁶Sr 0.7040–0.7046, ¹⁴³ Nd/¹⁴⁴ Nd 0.5130 and ²⁰⁶Pb/²⁰⁴Pb 19.36–19.51), and mantle-like ¹⁸O values (5.5in clinopyroxene). The isotopically diverse suite (IDS) is characterizedby much wider ranges of radiogenic isotopes (⁸⁷ Sr/⁸⁶Sr 0.7048–0.7077,¹⁴³ Nd/¹⁴⁴ Nd 0.5128–0.5123 and ²⁰⁶ Pb/²⁰⁴ Pb 19.7–20.2),in which all of the Sr and Pb ratios are higher and Nd ratiosare lower than those of the IHS. The IDS is also characterizedby high ¹⁸ O values, up to 7.6 in clinopyroxene. The Sr andPb isotope ratios are too high, and the Nd isotope ratios aretoo low in the IDS for any of these lavas to be derived fromunmodified depleted mantle. Both suites are petrologically very similar and their majorelement compositions and phenocryst contents suggest that theywere formed largely by fractional crystallization of a hydroustholeiitic melt at pressures <3 kbar. The isotopic ratiosand enrichments in large ion lithophile elements (LILE), andto some extent light rare earth elements (LREE), as comparedwith mid-ocean ridge basalts (MORB), of the IHS lavas suggestthat they were derived from a depleted mantle source which hadbeen re-enriched by the addition of 1–4% of a subductioncomponent. This component probably comprised a mixture of dehydrationfluids, and perhaps minor siliceous melts, released from subductingsediments and mafic crust. The extreme isotopic ranges, largeenrichments in incompatible elements, more fractionated LREEpatterns and higher ¹⁸ O values of the IDS lavas are interpretedas resulting from 10–55% assimilation—fractionalcrystallization of sediments, derived from the Guyana Shield,which are present in the arc crust, by IHS type melts. KEY WORDS: trace elements; radiogenic isotopes; arc lavas; Lesser Antilles ^*Corresponding author.     

Distribution of Ferric Iron in some Upper-Mantle Assemblages

The distribution of ferric iron among the phases of upper-mantlerocks, as a function of pressure (P), temperature (T) and bulkcomposition, has been studied using ⁵⁷Fe Mssbauer spectroscopyto determine the Fe³⁺/Fe ratios of mineral separates from 35peridotite and pyroxenite samples. The whole-rock Fe³⁺ complementof a peridotite is typically shared approximately evenly amongthe major anhydrous phases (spinel and/or garnet, orthopyroxeneand clinopyroxene), with the important exception of olivine,which contains negligible Fe³⁺. Whole-rock Fe³⁺ contents areindependent of the T and P of equilibration of the rock, butshow a well-defined simple inverse correlation with the degreeof depletion in a basaltic component. Fe³⁺ in spinel and inboth pyroxenes from the spinel Iherzolite facies shows a positivecorrelation with temperature, presumably owing to the decreasein the modal abundance of spinel. In garnet peridotites, theFe³⁺ in garnet increases markedly with increasing T and P, whereasthat in clinopyroxene remains approximately constant. The complexnature of the partitioning of Fe³⁺ between mantle phases resultsin complicated patterns of the activities of the Fe³⁺ -bearingcomponents, and thus in calculated equilibrium f_O2, which showlittle correlation with whole-rock Fe³⁺ or degree of depletion.Whether Fe³⁺ is taken into account or ignored in calculatingmineral formulae for geothermobarometry can have major effectson the resulting calculated T and P. For Fe-Mg exchange geothermometers,large errors must occur when applied to samples more oxidizedor reduced than the experimental calibrations, whose f_O2 conditionsare largely unknown. Two-pyroxene thermometry is more immuneto this problem, and probably provides the most reliable P—Testimates. Accordingly, the convergence of P—T valuesderived for a given garnet peridotite assemblage may not necessarilybe indicative of mineral equilibrium. The prospects for thecalculation of accurate Fe³⁺ contents from electron microprobeanalyses by assuming stoichiometry are good for spinel, uncertainfor garnet, and distinctly poor for pyroxenes. KEY WORDS: mantle; oxidation; partitioning; peridotite; thermobarometry ^*Corresponding author. Present address: School of Earth and Ocean Sciences, University of Victoria, P.O. Box 1700, Victoria, B.C., V8W 2Y2, Canada     

Winter severity in Europe: The fourteenth century

The fourteenth century is known to include a period of winter cooling in Central and Western Europe, but its timing and magnitude are not clearly established. An attempt to obtain a coherent picture from verified documentary evidence yielded 2133 records from a region covering Central Europe and Northern Italy, mostly originating from the Monumenta Germaniae Historica. Temperatures were assessed using semi-quantitative indices on the basis of proxy information on snow-cover, ice and untimely activity of vegetation. Results: A run of cold winters from 1303 to 1328 was followed by a run of average winters up to 1354. Then winter temperatures were extremely variable up to 1375. For the rest of the century they fluctuated somewhat below the average of the twentieth century. The pattern in the first five decades is compared to that in the Late Maunder Minimum (1675–1715). The possible role of forcing factors (variations in solar output, North Atlantic Deep Water formation) is briefly discussed.     

Photometric investigation of the evolved contact binary system DN Aur

We present here the photometric light curve analyses of the eclipsing binary star DN Aur. The CCD photometry, performed at the Behlen observatory using the 0.76 m automated telescope gave 646 individual data points inV andR bandpass filters. From this data we have determined a new epoch and an orbital period of 0.6168891 days. The published spectral classification is F3.The Wilson-Devinney model was used to derive the photometric solutions. DN Aur is a W UMa type contact binary system. The mass ratio, (q=m ₂/m ₁0.210, where star 2 is eclipsed at the primary minimum) suggests that the system has A-type configuration. The computed light curve has a third light of about 22 percent and a total eclipse in the secondary minimum. A solution with a cool spot on the secondary component is also found. We recommend spectroscopic study of DN Aur even though the light curve analysis show it to be a single line spectroscopic system. Generally contact systems of spectral type F3 have periods ranging from 0.25 to 0.5 days. The longer period of DN Aur suggests that it is an evolved contact system with case A mass transfer.     

Far-infrared contribution to interstellar extinction from graphite whiskers

A mass contribution of graphite whiskers as small as 0.1% to the population of interstellar grains could dramatically change their far-infrared extinction properties. With varying mass fractions of graphite whiskers, and for different size parameters, the infrared extinction could vary from a ^-2 dependence to ⁰, consistent with the requirements of some astronomical observations.     

Motion of test particles in parabolic density distributions

A detailed study of the motion of test-particles [either having a nonzero rest-mass or zero rest-mass] has been carried out for Tolman's type VII solution with vanishing surface density, which is one of the few physically relevant exact solutions of Einstein's field equations for static and spherically symmetric mass distributions.The trapping angles, 0, at which the test-particles escape these configurations are calculated and the trajectories of test-particles are studied in detail. The types of trajectories found for this spacetime geometry are: (1) arc-like trajectories, (2) spiral-like trajectories ending into a circle of constant radius, (3) trajectories with a cusp at the minimum distance, (4) double-bounded trajectories, and (5) double-bounded trajectories with a cusp at the minimum distance. The test-particles following the trajectories of type (1) and type (3) escape the configuration while others are trapped within the structure. Besides the advancement of periastron of the orbits the retrogradation of periastrons are also observed.The stability of the structures is considered by using the variational method (Chandrasekhar, 1964a,b), and its is seen that the structures remain stable at least for a central redshift,z0, as large as 5.09.These studies may distinguish relativistic cluster from a Newtonian one and may find application to the local models of quasi-stellar objects (QSOs).     

Biofluorescence and the extended red emission in astrophysical sources

A broad emission band over the wavelength range 6000–7500 Å in submicron dust in the galaxy and in M82 can be explained by fluorescence phenomena in low-temperature chloroplasts and bacterial pigments. Alternative explanations do not appear to be promising.     

Hydromagnetic Rayleigh problem for a porous wall in slip flow regime

An analysis of the Rayleigh problem in MHD for a porous wall in a slip flow regime is considered. The normal velocity of suction/injection at the wall is assumed to be time dependent. The solution of the problem is obtained in the form of a power series, in terms of known functions. The variations of the velocity field and the skin friction are shown graphically and are followed by a quantitative discussion.Science Update, The Pioneer, India, 21 July 1995 edition     

A model of an exploding,radiating star in general relativity

In a previous paper Adams, Cary and Cohen (1994) presented a model of a supernova. In that paper the equations of General Relativity describing the evolution of a spherically symmetric, radiating star were solved analytically. The evolution of the star was determined by the application of boundary conditions at the center and at the edge. Due to lmitations in the presupernova model, only the very slow inward motion of an unstable, degenerate core could be considered. The solution was also limited by the need to exclude a runaway term, one that increased exponentially with time. Without the exclusion of the runaway, the luminosity would have increased without bound and the mass would have become negative.This paper presents a completely analytic solution to the equations of General Relativity describing the evolution of a Type II supernova. Professor S.E. Woosley kindly gave us data on the physical variables of a 12M ₀ presupernova star. In our model the core collapses within 1 s, leaving a 1.3M ₀ remnant. Shortly afterward 10.6M ₀ is ejected to infinity, and 0.17M ₀ is radiated away in the form of neutrinos. The distance of the edge from the center increases proportionally to the two-thirds power of the time. The luminosity decreases proportionally to the inverse four-thirds power.Although the runaway solution was modified by the exploding rather than a static envelope, it must still be excluded by adjusting initial conditions. Its character is changed from an exponential to a very large power (55) of time. The removal of a degree of freedom by this exclusion leads to physically non-sensical results such as negative luminosity. The inclusion of a term describing motion of the mantle due to neutrino interactions provides the additional degree of freedom necessary for physically reasonable results.     

The GEM project: An international collaboration to survey galactic radiation emission

The GEM (Galactic Emission Mapping) project is an international collaboration established with the aim of surveying the full sky at long wavelengths with a multi-frequency radio telescope. A total of 745 hours of observation at 408 MHz were completed from an Equatorial site in Colombia. The observations cover the celestial band 0 ^h <<24 ^h , and –24° 22<<+35° 37. Preliminary results of this partial survey will be discussed. A review of the instrumental setup and a 10° resolution sky map at 408 MHz is presented.Presented by S. Torres at the UN/ESA Workshop on Basic Space Sciences: From Small Telescopes to Space Missions, Colombo, Sri Lanka 11–14 January 1996