LiDAR-based digital terrain analysis of an area exposed to the risk of lava flow invasion: the Zafferana Etnea territory, Mt. Etna (Italy)

The town of Zafferana Etnea, located on the southeastern slope of Mt. Etna volcano (Italy), has been repeatedly threatened by lava flows in recent centuries. The last serious threat occurred during the 1991–1993 eruption, when the lava front came to a halt only 1.7 km from the centre of town. Morphostructural data derived from light detection and ranging (LiDAR) surveys carried out on Etna in 2005 have enabled us to evaluate the risk of lava invasion in a section (16 km²) of the Zafferana Etnea territory. Qualitative and quantitative results are obtained combining the information derived from LiDAR analysis with geological, morphological and structural data using geographic information systems technology (GIS). The study quantifies in unprecedented detail the areal extent and volume of forested and urban areas and its degree of exposure to different levels of hazard from future lava invasion. Nearly 52% of the urban texture fall into areas of moderate to high risk from lava invasion. Future land use planning should take these findings into account and promote new development preferentially in areas of lower risk.     

Quantification of adamantane in organic media via infrared attenuated total reflection spectroscopy

In the present study, the quantitative determination of the diamondoid compound adamantane in organic solvents via infrared attenuated total reflection (IR-ATR) spectroscopy at unmodified waveguide surfaces was established. Limits of detection (LOD) and quantification (LOQ) of adamantane in dichloromethane, hexane and carbon tetrachloride were determined. Quantitative IR-ATR measurements additionally facilitated the determination of adamantane solubility limit in dichloromethane, hexane and carbon tetrachloride. The developed analytical strategy further enabled the successful detection and quantification of adamantane in crude oil matrices. Consequently, IR-ATR spectroscopy provides a promising strategy for on ship and in situ diamondoid analysis in harsh real world environments.     

Evidence for compressionally induced high subsidence rates in the Kurile Basin (Okhotsk Sea)

A combined volcanological, geochemical, paleo-oceanological, geochronological and geophysical study was undertaken on the Kurile Basin, in order to constrain the origin and evolution of this basin. Very high rates of subsidence were determined for the northeastern floor and margin of the Kurile Basin. Dredged volcanic samples from the Geophysicist Seamount, which were formed under subaerial or shallow water conditions but are presently located at depths in excess of 2300 m, were dated at 0.84±0.06 and 1.07±0.04 Ma with the laser ⁴⁰Ar/³⁹Ar single crystal method, yielding a minimum average subsidence rate of 1.6 mm/year for the northeast basin floor in the Quaternary. Trace element and Sr–Nd–Pb isotope data from the volcanic rocks show evidence for contamination within lower continental crust and/or the subcontinental lithospheric mantle, indicating that the basement presently at 6-km depth is likely to represent thinned continental crust. Average subsidence rates of 0.5–2.0 mm/year were estimated for the northeastern slope of the Kurile Basin during the Pliocene and Quaternary through the determination of the age and paleo-environment (depth) of formation of sediments from a canyon wall. Taken together, the data from the northeastern part of the Kurile Basin indicate that subsidence began in or prior to the Early Pliocene and that subsidence rates have increased in the Quaternary. Similar rates of subsidence have been obtained from published studies on the Sakhalin Shelf and Slope and from volcanoes in the rear of the Kurile Arc. The recent stress field of the Kurile Basin is inferred from the analysis of seismic activity, focal mechanism solutions and from the structure of the sedimentary cover and of the Alaid back-arc volcano. Integration of these results suggests that compression is responsible for the rapid subsidence of the Kurile Basin and that subsidence may be an important step in the transition from basin formation to its destruction. The compression of the Kurile Basin results from squeezing of the Okhotsk Plate between four major plates: the Pacific, North American, Eurasian and Amur. We predict that continued compression could lead to subduction of the Kurile Basin floor beneath Hokkaido and the Kurile Arc in the future and thus to basin closure.     

Photospheric Magnetic Field: Relationship Between North–South Asymmetry and Flux Imbalance

Photospheric magnetic fields were studied using the Kitt Peak synoptic maps for 1976?–?2003. Only strong magnetic fields (B>100 G) of the equatorial region were taken into account. The north–south asymmetry of the magnetic fluxes was considered as well as the imbalance between positive and negative fluxes. The north–south asymmetry displays a regular alternation of the dominant hemisphere during the solar cycle: the northern hemisphere dominated in the ascending phase, the southern one in the descending phase during Solar Cycles 21?–?23. The sign of the imbalance did not change during the 11 years from one polar-field reversal to the next and always coincided with the sign of the Sun’s polar magnetic field in the northern hemisphere. The dominant sign of leading sunspots in one of the hemispheres determines the sign of the magnetic-flux imbalance. The sign of the north–south asymmetry of the magnetic fluxes and the sign of the imbalance of the positive and the negative fluxes are related to the quarter of the 22-year magnetic cycle where the magnetic configuration of the Sun remains constant (from the minimum where the sunspot sign changes according to Hale’s law to the magnetic-field reversal and from the reversal to the minimum). The sign of the north–south asymmetry for the time interval considered was determined by the phase of the 11-year cycle (before or after the reversal); the sign of the imbalance of the positive and the negative fluxes depends on both the phase of the 11-year cycle and on the parity of the solar cycle. The results obtained demonstrate the connection of the magnetic fields in active regions with the Sun’s polar magnetic field in the northern hemisphere.     

Asteroid impact effects on Snowball Earth

Several Snowball Earth periods, in which the Earth has been (almost) totally glaciated, are known from Earth history. Neither the trigger for the initiation, nor the reason for the ending of such phases, are well understood. Here we discuss some mechanical effects of the impact of asteroids 5–10 km in diameter on the Snowball Earth environment. An impact of this scale is the largest impact that is statistically predictable for 10–60 Myr time periods. The impact cratering itself (shock waves, impact crater formation) is not powerful enough to change the natural climate evolution path on Earth. However, the products of impact (mainly—water vapor) can be quickly distributed over a substantial part of the globe, influencing the global circulation (e.g., facilitating cloud formation). It is a question for future studies to confirm if such an event (which is possible statistically during this interval) may or may not have influenced the global climate of the Snowball Earth, and/or contributed to deglaciation.     

Comparison of the classical and the global solutions of the Ideal Resonance Problem

The Ideal Resonance Problem is defined by the Hamiltonian $$F = B(y) + 2\varepsilon A(y) \sin ^2 x,\varepsilon \ll 1.$$ The classical solution of the Problem, expanded in powers of ε, carries the derivativeB′ as a divisor and is, therefore, singular at the zero ofB′, associated with resonance. With α denoting theresonance parameter, defined by $$\alpha \equiv - B'/|4AB''|^{1/2} \mu ,\mu = \varepsilon ^{1/2} ,$$ it is shown here that the classical solution is valid only for $$\alpha ^2 \geqslant 0(1/\mu ).$$ In contrast, the global solution (Garfinkelet al., 1971), expanded in powers ofμ=ε^1/2, removes the classical singularity atB′=0, and is valid for all α. It is also shown here that the classical solution is an asymptotic approximation, for largeα ², of the global solution expanded in powers ofα ^?2. This result leads to simplified expressions for resonancewidth and resonantamplification. The two solutions are compared with regard to their general behavior and their accuracy. It is noted that the global solution represents a perturbed simple pendulum, while the classical solution is the limiting case of a pendulum in a state offast circulation.     

Large,solid particles in the clouds of Venus: Do they exist?

The discovery of large, solid particles in the clouds of Venus is one of the most significant findings of Pioneer Venus because it means that a substantial mass of the clouds is composed of a material other than sulfuric acid. The evidence which suggests that solid particles form a distinctive size mode is reexamined. The mode is defined by a discontinuity between two size ranges of the Pioneer Venus particle size spectrometer. This discontinuity could represent a real size mode. However, it could also be an artifact of the measurement technique. R. G. Knollenberg (1984) discusses several possible instrumental effects which might have caused this discontinuity. It is hypothesized herein that such effects did occur and that the large particles are really the tail of the mode 2 sulfuric acid particle size distribution and are not a separate mode of solid particles. Using such a revised size distribution, it is shown that all of the Pioneer Venus and Venera optical data from the lower clouds can be explained with sulfuric acid droplets without introducing any solid particles. As a by-product of this analysis, it is also found that the upper clouds of Venus must contain a material with a higher refractive index than sulfuric acid. A small quantity of sulfur could account for this observation.     

Scleractinian cold-water corals in the Gulf of Cádiz—First clues about their spatial and temporal distribution

This paper presents the first compilation of information on the spatial distribution of scleractinian cold-water corals in the Gulf of Cádiz based on literature research and own observations (video footage, sediment samples). Scleractinian cold-water corals are widely distributed along the Spanish and Moroccan margins in the Gulf of Cádiz, where they are mainly associated with mud volcanoes, diapiric ridges, steep fault escarpments, and coral mounds. Dendrophyllia cornigera, Dendrophyllia alternata, Eguchipsammia cornucopia, Madrepora oculata and Lophelia pertusa are the most abundant reef-forming species. Today, they are almost solely present as isolated patches of fossil coral and coral rubble. The absence of living scleractinian corals is likely related to a reduced food supply caused by low productivity and diminished tidal effects. In contrast, during the past 48 kyr scleractinian corals were abundant in the Gulf of Cádiz, although their occurrence demonstrates no relationship with main climatic or oceanographic changes. Nevertheless, there exists a conspicuous relationship when the main species are considered separately. Dendrophylliids are associated with periods of relatively stable and warm conditions. The occurrence of L. pertusa mainly clusters within the last glacial when bottom current strength in the Gulf of Cádiz was enhanced and long-term stable conditions existed in terms of temperature. Madrepora oculata shows a higher tolerance to abrupt environmental changes.