Discovery of an albite gneiss from the Ile de Groix (Armorican Massif, France): geochemistry and LA-ICP-MS U–Pb geochronology of its Ordovician protolith

For the first time, an albite orthogneiss has been recognised and dated within the HP–LT blueschist facies metabasites and metapelites of the Ile de Groix. It is characterised by a peraluminous composition, high LILE, Th and U contents, MORB-like HREE abundances and moderate Nb and Y values. A U–Pb age of 480.8?±?4.8?Ma was obtained by LA-ICP-MS dating of zircon and titanite. It is interpreted as the age of the magmatic emplacement during the Early Ordovician. Morphologically different zircon grains yield late Neoproterozoic ages of 546.6–647.4?Ma. Zircon and titanite U–Pb ages indicate that the felsic magmatism from the Ile de Groix is contemporaneous with the acid, pre-orogenic magmatism widely recognised in the internal zones of the Variscan belt, related to the Cambro-Ordovician continental rifting. The magmatic protolith probably inherited a specific chemical composition from a combination of orogenic, back-arc and anorogenic signatures because of partial melting of the Cadomian basement during magma emplacement. Besides, the late Devonian U–Pb age of 366?±?33?Ma obtained for titanite from a blueschist facies metapelite corresponds to the age of the HP–LT peak metamorphism.     

Traveltime parameters in a tilted elliptical anisotropic medium‡

In this paper, we derive analytical expressions for one‐way and two‐way kinematical parameters in elliptical tilted transverse isotropy media. We show that the homogeneous elliptical tilted transverse isotropy models result in hyperbolic moveout with a reflection point sideslip x₀, which can be considered as an additional traveltime parameter for one‐way wave propagation. For homogeneous elliptical tilted transverse isotropy models we show that the inversion of one‐way traveltime parameters suffers from the ambiguity for large tilts. It is shown that the accuracy of the inversion is sensitive to the error in x₀. We also derive and invert the traveltime parameters for a vertically heterogeneous elliptical tilted transverse isotropy model with a tilt gradually changing with depth. The a priori knowledge of parameter δ is very important for inversion. The wrong choise of this parameter results in significant errors in inverted model parameters.     

Noble gases in presolar diamonds III: Implications of ion implantation experiments with synthetic nanodiamonds

Abstract— A series of experiments carried out by Koscheev et al. (1998, 2001, 2004, 2005) showed that the bimodal release of heavy noble gases from meteoritic nanodiamonds can be reproduced by a single implanted component. This paper investigates the implications of this result for interpreting the noble gas compositions of meteoritic nanodiamonds and for their origin and history. If the bimodal release exhibited by meteorite diamonds reflects release of the P3 noble gas component, then the composition inferred for the pure Xe‐HL end member changes slightly, the excesses of heavy krypton isotopes that define Kr‐H become less extreme, evidence appears for a Kr‐L component, and the nucleosynthetic contribution to argon becomes much smaller. After correction for cosmogenic neon inherited from the host meteorites, the neon in presolar diamonds shows evidence for pre‐irradiation, perhaps in interstellar space, and a nucleosynthetic component perhaps consistent with a supernova source. After a similar correction, helium also shows evidence for presolar irradiation and/or a nucleosynthetic component. For the case of presolar irradiation, due to the small size of the diamonds, a large entity must have been irradiated and recoiling product nuclei collected by the nanodiamonds. The high ³He/²¹Ne ratio (?43) calls for a target with a (C + O)/heavier‐element ratio higher than in chondritic abundances. Bulk gas + dust (cosmic abundances) meet this criteria, as would solids enriched in carbonaceous material. The long recoil range of cosmogenic ³He argues against a specific phase. The excess ³He in presolar diamonds may represent trapped cosmic rays rather than cosmogenic ³He produced in the vicinity of the diamond crystals.     

Effect of Decoupling of Lithospheric Plates on the Observed Geoid

A joint effect of weak zones, dividing lithospheric plates, and lateral viscosity variations (LVV) in the whole mantle on the observed geoid is investigated by a new numerical approach. This technique is based on the substantially revised method introduced by Zhang and Christensen (Geophys J Int 114:531–547, 1993) for solving the Navier–Stokes–Poisson equations in the spectral domain with strong LVV. Weak plate boundaries (WPB) are introduced based on an integrated global model of plate boundary deformations GSRM (Kreemer et al. in Geophys J Int 154:8–34, 2003). The effect of WPB on the geoid is significant and reaches ?40 to 70 m with RMS ~20 m. The peaks are observed over large subduction zones in South America and the southwestern Pacific in agreement with previous studies. The positive geoid anomaly in South America could be explained largely by a dynamic effect of decoupling of the Nazca and South American plates. The negative changes of the geoid mostly relate to mid-oceanic ridges. The amplitude of the effect depends on the viscosity contrasts at WPB compared with the plate viscosity until its value reaches the limit of 2.5–3 orders of magnitude. This value might be considered as a level at which the plates are effectively decoupled. The effect of WPB exceeds the effect of LVV in the whole mantle and generally does not correlate with it. However, inclusion of LVV reduces the geoid perturbations due to WPB by about 10 m. Therefore, it is important to consider all factors together. The geoid changes mainly result from changes of the dynamic topography, which are about ?300 to +500 m. The obtained results show that including WPB may significantly improve the reliability of instantaneous global dynamic models.     

Sensitivity of the southern annular mode to greenhouse gas emission scenarios

The leading mode of southern hemisphere (SH) climatic variability, the southern annular mode (SAM), has recently seen a shift towards its positive phase due to stratospheric ozone depletion and increasing greenhouse gas (GHG) concentrations. Here we examine how sensitive the SAM (defined as the leading empirical orthogonal function of SH sea level pressure anomalies) is to future GHG concentrations. We determine its likely evolution for three intergovernmental panel on climate change (IPCC) special report on emission scenarios (SRES) for austral summer and winter, using a multi-model ensemble of IPCC fourth assessment report models which resolve stratospheric ozone recovery. During the period of summer ozone recovery (2000–2050), the SAM index exhibits weakly negative, statistically insignificant trends due to stratospheric ozone recovery which offsets the positive forcing imposed by increasing GHG concentrations. Thereafter, positive SAM index trends occur with magnitudes that show sensitivity to the SRES scenario utilised, and thus future GHG emissions. Trends are determined to be strongest for SRES A2, followed by A1B and B1, respectively. The winter SAM maintains a similar dependency upon GHG as summer, but over the entire twenty-first century and to a greater extent. We also examine the influence of ozone recovery by comparing results to models that exclude stratospheric ozone recovery. Projections are shown to be statistically different from the aforementioned results, highlighting the importance of ozone recovery in governing SAM-evolution. We therefore demonstrate that the future SAM will depend both upon GHG emissions and stratospheric ozone recovery.     

A flow-foliated ignimbrite related to the Åland rapakivi granite in SW Finland

A flow-foliated felsic ignimbrite constitutes the uppermost lithological unit of the 1.58 Gyr anorogenic magmatic rocks in SW Finland. The ignimbrite is derived from an explosive eruption of hot (≅ 950 °C) phenocryst-bearing A-type (rapakivi-type granite magma.
The ignimbrite is close in composition to subvolcanic rapakivi granites that occur in the margins of the kand rapakivi batholith. The subvolcanic granites crystallized under a pressure of ≅ 1 kbar and at temperatures of about 650–700 °C. However, both major and rare earth elements show that the ignimbrite- forming magma was more fractionated than the magma forming the subvolcanic varieties.
Supported by evidence of mafic-felsic magma mingling, it is suggested that injection of hot mafic magma into a shallow magma chamber produced the high temperature of the ignimbrite-forming magma. This injection increased the magmatic and the volatile pressure that caused the eruption of the dry felsic magma.     

Relation between macroseismic intensity and instrumental parameters of strong motions — A statistical approach

One hundred and twenty-eight strong ground motion CALTECH (Earthquakes in the U.S.A., 1940–1971) records of five Californian earthquakes, recorded at ground level and in basements, for which the modified Mercalli macroseismic intensities are known, were statistically processed to calculate 165 wave parameters. Correlation of the peak values of particle acceleration, velocity and displacement, energy, impulse and root-mean-square amplitude of the vibrations, durations of vibrations for certain levels of the peak amplitude, and spectral energies of 10 frequency windows with macroseismic intensity are discussed from the viewpoint of classification of ground-motion records.Paper presented at the 21st General Assembly of the European Seismological Commission held in Sofia 1988.     

Atmospheric and Coupled Model Intercomparison in Terms of Amplitude Phase Characteristics of Surface Air Temperature Annual Cycle

A model intercomparison in terms of surface air temperature annual cycle ampitude-phase characteristics(SAT AC APC)is performed. The models included in the intercomparison belong to two groups:five atmospheric models with prescribed sea surface temperature and sea ice cover and four coupled models forced by the atmospheric abundances of anthropogenic consituents (in total six coupled model simulations). Over land, the models, simulating higher than observed time averaged SAT,also tend to simulate smaller than observed amplitude of its annual and semiannual harmonics and (outside the Tropics laterthan-observed spring and autumn moments. The models with larger(smaller) time averaged amplitudes of annual and semiannual harmonics also tend to simulate larger(smaller)interannual standard deviations. Over the oceans, the coupled models with larger interannual standard deviations of annual mean SAT tend to simulate larger interannual standard deviations of both annual and semiannual SAT harmonics amplitudes. Most model errors are located in the belts 60°-70°N and 60°-70°S and over Antarctica. These errors are larger for those coupled models which do not employ dynamical modules for sea ice.No systematic differences are found in the simulated time averaged fields of the surface air temperature annual cycle characteristics for atmospheric models on one hand and for the coupled models on the other. But the coupled models generally simulate interannual variability of SAT AC APC better than the atmospheric models (which tend to underestimate it). For the coupled models, the results are not very sensitive to the choice of the particular scenario of anthropogenic forcing.There is a strong linear positive relationship between the model simulated time averaged semiannual SAT harmonics amplitude and interannual standard deviation of annual mean SAT.It is stronger over the tropical oceans and is weaker in the extratropics. In the tropical oceanic areas, it is stronger for the coupled than for the atmospheric models.     

Modelling of thermochemical plumes and implications for the origin of the Siberian traps

Thermochemical plumes form at the base of the lower mantle as a consequence of heat flow from the outer core and the presence of local chemical doping that decreases the melting temperature. Theoretical and experimental modelling of thermochemical plumes show that the diameter of a plume conduit remains practically constant during plume ascent. However, when the top of a plume reaches a refractory layer, whose melting temperature is higher than the melt temperature in the plume conduit, a mushroom-shaped plume head develops. Main parameters (melt viscosity, ascent time, ascent velocity, temperature differences in the plume conduit, and thermal power) are presented for a thermochemical plume ascending from the core–mantle boundary. In addition, the following relationships are developed: the pressure distribution in the plume conduit during the ascent of a plume, conditions for eruption-conduit formation, the effect of the P–T conditions and controls on the shape and size of a plume top, heat transfer between a thermochemical plume and the lithosphere (when the plume reaches the bottom of a refractory layer in the lithosphere), and eruption volume versus the time interval t₁ between plume formation and eruption. These relationships are used to determine thermal power and time t₁ for the Tunguska syneclise and the Siberian traps as a whole.

The Siberian and other trap provinces are characterized by giant volumes of lavas and sills formed a very short time period. Data permit a model for superplumes with three stages of formation: early (variable picrites and alkali basalts), main (tholeiite plateau basalts), and final (ultrabasic and alkaline lavas and intrusions). These stages reflect the evolution of a superplume from the ascent of one or several independent plumes, through the formation of thick lenses of mantle melts underplating the lithosphere and, finally, intrusion and extrusion of differentiated mantle melts. Synchronous syenite–granite intrusions and bimodal volcanism abundant in the margins of the Siberian traps are the result of melting of the lower crust at depths of 65–70 km under the effect of plume melts.