Equatorial radius of the Earth: A dynamical determination

An intrresting variation on the familiar method of determining the earth's equatorial radius a_e, from a knowledge of the earth's equatorial gravity is suggested. The value of equatorial radius thus found is 6378,142±5 meters. The associated parameters are GM=3.986005±.000004 × 10²⁰ cm³ sec-⁻² which excludes the relative mass of atmosphere ≅10⁻⁶ ξ GM, the equatorial gravity γ_e 978,030.9 milligals (constrained in this solution by the Potsdam Correction of 13.67 milligals as the Potsdam Correction is more directly, orless indirectly, measurable than the equatorial gravity) and an ellipsoidal flattening of f=1/298.255.     

Uranium (U) concentration and its genetic significance in the phosphorites of the Paleoproterozoic Bijawar Group of the Lalitpur district,Uttar Pradesh,India

The paper presents the uranium (U) concentration and distribution pattern in the Paleoproterozoic phosphorites of Lalitpur district of Uttar Pradesh. The study of thin sections, SEM and XRD reveal that apatite is the essential phosphate mineral while quartz and feldspars are the dominant gangue in the phosphorites of the investigated area. The collophane is observed to be mostly oolitic in form and microspherulitic in texture. The major element geochemistry indicated that the phosphorite samples are rich in P₂O₅, CaO, SiO₂ and Fe₂O₃ whereas depletion of MgO, MnO, K₂O and Al₂O₃ was observed. The CaO/P₂O₅ ratio ranges from 1.13 to 1.46 which is slightly lower than that of cations and anions substituted francolite (1.621) and close to that of carbonate-fluorapatite (1.318). The trace element geochemistry indicates that the phosphorites of Lalitpur have the significant range of U concentration (1.67 to 129.67 μg/g) which is more than that of Th (0.69 to 0.09 μg/g) among the analysed trace elements in the phosphorite samples of the area. The positive correlation of U with P₂O₅, CaO and U/P₂O₅ indicates a close association of U with phosphate minerals like collophane (apatite), whereas negative correlation of U with SiO₂ and Fe₂O₃ may be due to mutual replacement. The antipathetic relationship of U with Ni may be an indication of high oxidizing conditions, whereas sympathetic relationship of U with K₂O points towards higher alkaline conditions of the basin of deposition during phosphatization. The variable concentration of U and its relationship with significant major and trace elements in most of the phosphorite samples lead one to believe that the deposition of these phosphorites might have taken place in highly alkaline medium during fairly oxidizing to weakly reducing environmental conditions of geosynclinal basin.     

Optimization of sample preparation method of total sulphur measurement in mine tailings

A sample preparation method of total sulphur measurement of reactive mine tailings was optimized. The total sulphur was measured by inductively coupled plasma optical emission spectroscopy, and ultrasound technique was used for sample digestion. The optimization process was adopted by a combined approach of experimental design and response surface methodology. The digestion time, temperature and acid-oxidant combination (i.e. effect of H₂O₂ with a fixed amount of acid mixture) were investigated. A two-level and three-factor (2³) full factorial design of experiment was applied to identify the most significant factors, and a central composite design was used to optimize the digestion procedure. KZK-1, a sericite schist, was selected as the certified reference material. The optimum methodology at 95 % confidence level (P < 0.05) was identified to be 10 min of digestion at 77 °C, with a solution of 1 ml HNO₃:1 ml HCl:1.35 ml H₂O₂. This combination resulted in 100 % sulphur recovery. The investigated method was verified by X-ray diffraction analysis. The optimum digestion level was applied to a reactive mine tailings, which achieved satisfactory results with a percentage relative standard deviation < 3 %.     

The geochemistry of uranium occurrences and speciation in groundwater of Chinnar sub basin,South India

An attempt has been made in Chinnar sub basin of Dharmapuri district, South India to isolate the geochemistry of uranium occurrences in groundwater. The geology of the area is mainly of charnockite and granite gneiss. Groundwater samples were collected for two different seasons post and pre monsoon in two different litho units (granite gneiss and charnockite) and analysed for major, minor and uranium concentrations. Higher uranium (18.45 μg L^?1) has been recorded during pre monsoon season in granite gneiss with increasing pH. The saturation index calculation for the groundwater isolated minerals like uaraninite, coffinite, haiweeite and soddyite to be precipitating and uranium oxides like UO_2.25, UO_2.25beta, UO_2.33beta as oversaturated. The Eh-pH diagram attempted represents solubility of uraninite within the pH range of 6.0 to 8.0. The study isolate uranium in groundwater of the study area is controlled by the presence of (U₄O₉) uranium oxide.     

Precipitation variability assessment of northeast China: Songhua River basin

Variability in precipitation is critical for the management of water resources. In this study, the research entropy base concept was applied to investigate spatial and temporal variability of the precipitation during 1964–2013 in the Songhua River basin of Heilongjiang Province in China. Sample entropy was applied on precipitation data on a monthly, seasonally, annually, decade scale and the number of rainy days for each selected station. Intensity entropy and apportionment entropy were used to calculate the variability over individual year and decade, respectively. Subsequently, Spearman’s Rho and Mann–Kendall tests were applied to observe for trends in the precipitation time series. The statistics of sample disorder index showed that the precipitation during February (mean 1.09, max. 1.26 and min. 0.80), April (mean 1.12, max. 1.29 and min. 0.99) and July (mean 1.10, max. 1.20 and min. 0.98) contributed significantly higher than those of other months. Overall, the contribution of the winter season was considerably high with a standard deviation of 0.10. The precipitation variability on decade basis was observed to increase from decade 1964–1973 and 1994–2003 with a mean value of decadal apportionment disorder index 0.023 and 0.053, respectively. In addition, the Mann–Kendall test value (1.90) showed a significant positive trend only at the Shangzhi station.     

Soil responses near Delhi ridge and adjacent regions in Greater Delhi during incidence of a local earthquake

In this study, soil response was carried out for the Greater Delhi region. A folded Proterozoic formation was identified as Delhi ridge, passes through its central part along SSW–NNE direction, and appears to be a main geomorphic feature for the study area. The Delhi ridge is an exposed quartzite rock of about 10–100 m wide and ~25 km long with gentler dipping both toward east and west. We have considered the exposed part as an outcrop side near the ridge axis and the dipping area as rigid base away from the ridge axis for ground motion study during the occurrence of the 25 November 2007 earthquake with magnitude M _L 4.3 (Richter scale) that occurred at Delhi–Haryana State boundary. The degree of shaking was very strong and reported major cracks in the buildings near the epicenter area. We have studied the soil response parameters at the surface level, considering horizontally stratified soil layers above rigid base. The equivalent linear method was used for soil response analysis at 25 sites in Greater Delhi area. The peak amplification factors vary from 3.2 to 5.9 and peak resonance frequency varies from 1.2 to 5.3 Hz. The correlation among the peak amplification factor (A) and frequency (f) was empirically established as A = 0.36f + 3.60. Increasing peak amplification factor was found at sites with increasingly thicker alluvium deposit with lower frequency contains ground motion and vice versa. Seismic zoning map was also reconstructed for peak amplification factors and predominant periods for the study area for the mitigation purposes of earthquake damage. The average shear wave velocity up to 30 m soil depth is also obtained for site classification. The average velocity to 30 m [ $ \overline{{V_{\text{s}} }} (30) $ ] is a widely used parameter for classifying sites for predicting their potentiality to amplify seismic shaking. A lower value [ $ \overline{{V_{\text{s}} }} (30) $ ] thus yields a more conservative estimate of ground motion, which generally increases as $ \overline{{V_{\text{s}} }} (30) $ decreases. Present estimate of $ \overline{{V_{\text{s}} }} (30) $ varies from 315 to 419 m/s. In this study, we have identified two site classes C and D, as per National Earthquake Hazard Reduction Program. The city planner or engineers can directly use these data for site-specific assessment during retrofitting of the existing structure, demolition of the old buildings and design a new structure to avoid major destruction of the buildings due to future earthquake.     

Vulnerability assessments and their planning implications: a case study of the Hutt Valley, New Zealand

An understanding of vulnerability is not only crucial for the survival of the exposed communities to extreme events, but also for their adaptation to climate change. Vulnerability affects community participation in hazard mitigation, influences emergency response and governs adaptive capacity for the changing environmental and hazards characteristics. However, despite increased awareness, assessments and understanding of the processes that produce vulnerability, disaster risks prevail. This raises questions on the effectiveness of vulnerability assessments and their applications for hazard mitigation and adaptation. The literature includes a range of vulnerability assessment methods, wherein frequently the selection of any particular method is governed by the research objectives. On the other hand, hazard mitigation plans and policies even though mention vulnerability, their implementation pays less attention to the variations in its nature and underlying causes. This paper explores possible reasons for such gaps by exploring a case study of the Hutt Valley, New Zealand. It brings out the limitations of different vulnerability assessment methods in representing the local vulnerability and challenges they bring in planning for the vulnerability reduction. It argues that vulnerability assessment based on any particular method, such as deprivation index, principle component analysis, composite vulnerability index with or without weight, may not reveal the actual vulnerability of a place, and therefore, a comprehensive vulnerability assessment is needed.     

Synthesis of biochar from sugarcane filter-cake and its impacts on physiological performance of lettuce (<Emphasis Type="Italic">Lettuce sativa</Emphasis>) grown on cadmium contaminated soil

Soil contamination with cadmium has become major concern all over the world because of its adverse impacts on ecosystem health and agricultural land. Soil amendment with biochar may have varied effects on physical and chemical properties of soil. The objective of the study was to explore the impact of sugarcane filter-cake biochar on physiological performance and growth of lettuce in an aged soil. Four different doses (0, 1.5%, 3%, and 5%) of biochar were used in the soil and conditioned for 1 month. After this, lettuce seedlings were grown in the soil. The results showed that the biochar treatment improved the fresh and dry biomass of leaves and roots as well as plant height while diminished the bioavailability of cadmium from the soil. As compared to control, biochar significantly enhanced the chlorophyll content in lettuce leaves. Due to the biochar amendment, the oxidative stress decreased in lettuce shoots over the control. As compared to control, concentration of cadmium in lettuce significantly decreased after the application of biochar. It was concluded that biochar could mitigate the toxicity of cadmium in lettuce by altering the biochemical and physiological processes in cadmium contaminated soil.     

Geology, Geochemistry and Tectonic Significance of Mafic-ultramafic Rocks of Mesoproterozoic Phulad Ophiolite Suite of South Delhi Fold Belt, NW Indian Shield

A thick sequence of mafic-ultramafic rocks, occurs along a major shear zone (Phulad lineament), running across the length of Aravalli Mountain Range for about 300 kms. It has been suggested, that this sequence may represent a fragment of ophiolite or a rift related metavolcanic suite made up of basalts and fractionated ultramafics. The geological and tectonic significance of the complex is assessed using field relationships, petrography and geochemistry. Structurally, the lowest part of the complex comprises a discontinuous band of plastically deformed harzburgite (mantle component) followed by layered cumulus gabbroic rocks (crustal component). A complex of non-cumulus rocks comprising hornblende schists, gabbros, sheeted dykes and pillowed basalts structurally overlies layered gabbros. Huge bodies of diorite intrude volcanics.

Geochemical classification suggests that all non-cumulus mafic rocks are sub-alkaline basalts except one variety of dykes which shows mildly alkaline character. The sub-alkaline rocks are tholeiite to calc-alkaline with boninite affinity. Tectono-magmatic variation diagrams and MORB normalised patterns suggest a fore arc tectonic regime for the eruption of these rocks.

The mafic rocks of Phulad Ophiolite Suite are zoned across the strike in terms of their distribution from west to east. The hornblende schists and basalts are exposed at the westernmost margin followed by gabbros and dykes. The alkaline dyke occurs at the easternmost part. The rocks of Phulad suite are juxtaposed with shallow water sediments in the east followed by platformal sediments and then continental slope sediments in the further east indicating gradual thickening of the crust from west to east and an eastward subduction. The geochemical interpretation presented in this study, together with discussion of lithological association is used to decipher the tectonic evolution of the Mesoproterozoics of NW Indian shield.