Physicochemical Environment during the Formation of the Mozumi Skarn-type Pb–Zn–Ag Deposit at the Kamioka Mine, Central Japan: A Thermochemical Study

Abstract: The physicochemical environment during the ore formation of the Mozumi skarn-type Pb–Zn–Ag deposit, Kamioka mine, Central Japan is discussed with silicate phase equilibria using calculated phase diagrams. The mineral assemblages, mineral chemistry, and fluid inclusion data are coupled with thermodynamic calculation to estimate the stability fO2–XCO2condition of the mineral assemblages at each ore formation stage. The skarn was approximated by the model system CaO–A12O3–FeO–SiO2–O2–CO2–H2O including grossular-andradite garnet and clinozoisite-epidote solid solutions. The solid solutions are combined into the calculation using "pseudocompound approximation", and real boundary of the mineral assemblages other than simple activity corrected diagram was provided. The diagrams also show isoplethal contour for garnet and epidote.     

Effectiveness of superelastic bars for seismic rehabilitation of clay‐unit masonry walls

This paper presents the results on shaking table tests of half‐scale brick walls performed to investigate the effectiveness of newly developed Cu–Al–Mn superelastic alloy (SEA) bars in retrofitting of historical masonry constructions. Problems associated with conventional steel reinforcing bars lie in degradation of stiffness and strength, or pinching phenomena, under cyclic loading, and presence of large residual cracks in structures during and after intense earthquakes. This paper attempts to resolve the problems by applying newly developed Cu–Al–Mn SEA bars, characterized by large recovery strain, low material cost, and high machinability, as partial replacements for steel bars. Sets of unreinforced, steel reinforced, and SEA‐reinforced specimens are subjected to scaled earthquake excitations in out‐of‐plane direction. Whereas steel‐reinforced specimens showed large residual inclinations, SEA‐reinforced specimens resulted in stable rocking response with slight residual inclinations. Corresponding nonlinear finite element (FE) models are developed to simulate the experimental observations. The FE models are further used to examine the sensitivity of the response with respect to the variations in experimental conditions. Both the experimental and numerical results demonstrate the superiority of Cu–Al–Mn SEA bars to conventional steel reinforcing bars in avoiding pinching phenomena. Copyright © 2012 John Wiley & Sons, Ltd.     

A cross-system analysis of sedimentary organic carbon in the mangrove ecosystems of Xuan Thuy National Park, Vietnam

A cross-system analysis of bulk sediment composition, total organic carbon (TOC), atomic C/N ratio, and carbon isotope composition (δ¹³C) in 82 surface sediment samples from natural and planted mangrove forests, bank and bottom of tidal creeks, tidal flat, and the subtidal habitat was conducted to examine the roles of mangroves in sedimentation and organic carbon (OC) accumulation processes, and to characterize sources of sedimentary OC of the mangrove ecosystem of Xuan Thuy National Park, Vietnam. Sediment grain sizes varied widely from 5.4 to 170.2 μm (mean 71.5 μm), with the fine sediment grain size fraction (< 63 μm) ranging from 11 to 99.3% (mean 72.5%). Bulk sediment composition suggested that mangroves play an important role in trapping fine sediments from river outflows and tidal water by the mechanisms of tidal current attenuation by vegetation and the ability of fine roots to bind sediments. The TOC content ranged from 0.08 to 2.18% (mean 0.78%), and was higher within mangrove forests compared to those of banks and bottoms of tidal creeks, tidal flat, and subtidal sediments. The sedimentary δ¹³C ranged from − 27.7 to − 20.4‰ (mean − 24.1‰), and mirrored the trend observed in TOC variation. The TOC and δ¹³C relationship showed that the factors of microbial remineralization and OC sources controlled the TOC pool of mangrove sediments. The comparison of δ¹³C and C/N ratio of sedimentary OC with those of mangrove and marine phytoplankton sources indicated that the sedimentary OC within mangrove forests and the subtidal habitat was mainly composed of mangrove and marine phytoplankton sources, respectively. The application of a simple mixing model showed that the mangrove contribution to sedimentary OC decreased as follows: natural mangrove forest > planted mangrove forest > tidal flat > creek bank > creek bottom > subtidal habitat.