Progressive metamorphism of the Taitao ophiolite; evidence for axial and off-axis hydrothermal alterations

We estimated metamorphic conditions for the  6 Ma Taitao ophiolite, associated with the Chile triple junction. The metamorphic grade of the ophiolite, estimated from secondary matrix minerals, changes stratigraphically downwards from the zeolite facies, through the prehnite–actinolite facies, greenschist facies and the greenschist–amphibolite transition, to the amphibolite facies. The metamorphic facies series corresponds to the low-pressure type. The metamorphic zone boundaries are subparallel to the internal lithological boundaries of the ophiolite, indicating that the metamorphism was due to axial hydrothermal alteration at a mid-ocean ridge.

Mineral assemblages and the compositions of veins systematically change from quartz-dominated, through epidote-dominated, to prehnite-dominated with increasing depth. Temperatures estimated from the vein assemblages range from  230 °C in the volcanic unit to  380 °C at the bottom of the gabbro unit, systematically  200 °C lower than estimates from the adjoining matrix minerals. The late development of veins and the systematically lower temperatures suggest that the vein-forming alteration was due to off-axis hydrothermal alteration.

Comparison between the Taitao ophiolite with its mid-ocean ridge (MOR) affinity, and other ophiolites and MOR crusts, suggests that the Taitao ophiolite has many hydrothermal alteration features similar to those of MOR crusts. This is consistent with the tectonic history that the Taitao ophiolite was formed at the South Chile ridge system near the South American continent (Anma, R., Armstrong, R., Danhara, T., Orihashi, Y. and Iwano, H., 2006. Zircon sensitive high mass-resolution ion microprobe U–Pb and fission-track ages for gabbros and sheeted dykes of the Taitao ophiolite, Southern Chile, and their tectonic implications. The Island Arc, 15(1): 130–142).     

Temporal and spatial variations in the spawning activity of the micronektonic shrimp,Sergia lucens (hansen) in Suruga Bay,Japan

Temporal and spatial variations in the spawning activity ofSergia lucens were investigated in relation to some environmental conditions of Suruga Bay. The daily egg abundance varied considerably with the coefficient of variation from 81% to 269% in July. The spawning activity was most clearly affected by temperature, but the relationship to lunar period and content of chlorophylla were not obvious. Timing of the July spawning is predictable with increase of the surface temperature to 24°C and strong vertical movements of the 18°C isotherm depth; it is also related to modal length of the shrimp in June. It is suggested that intrusion of cold water at 20–50 m affects reproduction of the shrimps and vertical distribution of eggs and larvae. The shrimp population seemed to relate principally to two spawning grounds,i.e. the head part and the western part of the bay. The timing of spawning is not always synchronous throughout the bay. The spawning is sporadic and the distribution of eggs is patchy. This may reflect a recent decrease in the population of the shrimp due to increased fishing pressure.A part of the present paper is based on the thesis submitted by G. H. B. in partial fulfilment of the requirements for her degree of Master of Science at the Tokyo University of Fisheries in 1986.     

Importance of feeding on regenerable parts of prey for juvenile stone flounder Platichthys bicoloratus in estuarine habitats

Prey availability is one of the most important factors affecting the quality of nursery grounds. Estuaries play an important role as nursery grounds for juvenile stone flounder, but the mechanism behind the consistently high availability of prey has never been examined. This study investigates which prey is mainly selected by juvenile stone flounder (15–55 mm standard length) in the estuary of the Natori River, northern Japan. In a cage experiment, juveniles showed positive selection for the palps of the spionid polychaete Pseudopolydora kempi in March, and for the siphons of the bivalve Nuttallia olivacea in April, May and June in both sandy and muddy-sand habitats. This selective predation showed that sublethal predation on regenerable parts of invertebrates is important for stone flounder. Nuttallia olivacea, the dominant bivalve in the estuary, was more abundant and in better somatic condition in the sandy area in spite of the stronger siphon-cropping pressure by juvenile stone flounder. These results confirm that sublethal predation on highly abundant benthos plays an important role in forming estuarine habitats into areas of high prey availability for juvenile stone flounder, which leads to their high growth rate.     

Metamorphic decarbonation in the Neoproterozoic and its environmental implication

Metamorphic decarbonation reactions and volcanic degassing lead to significant influx of CO₂, a major greenhouse gas, into the ocean-atmosphere system from the solid Earth. Here we present quantitative estimates on CO₂ derived through metamorphic degassing during ultrahigh-temperature (UHT) metamorphism in the Neoproterozoic through the mineralogical and geological analyses of the UHT decarbonation. Our computations show that an extra flux of CO₂ was added to the atmosphere through a Himalayan scale UHT metamorphism to the extent of 6 × 10¹⁶ to 3.0 × 10¹⁸ mol/my, for a duration of 10 my. A calculation of the impact of the extra CO₂ influx to the global mean temperature in the context of carbon cycle and greenhouse effect of CO₂ shows that at the peak influx stage, the steady state temperature would be raised by 4 °C from 15 °C and by 13 °C from 4 °C. Our results have important bearing in evaluating the mechanism of melting and the duration of the Snowball Earth. Our estimate of the maximum degassing rate during UHT metamorphism suggests that the duration of the Marinoan snowball Earth was probably shorter, and the recovery from an ice-covered Earth to ocean-covered Earth was faster than previous estimates.     

Spatial distribution and corresponding determining factors of metal concentrations in surface sediments of Beppu Bay, southwest Japan

This study determined the factors contributing to the spatial distribution of 14 metal concentrations in the surface sediments of Beppu Bay on the basis of comparisons of the organic geochemical properties and environmental parameters through principal component analysis (PCA) and redundancy analysis (RDA). The results of PCA and RDA showed that the concentrations of V, Cr, Co, and As were closely related to the distances between the sampling sites and the Oita River. This indicated that these metals originated from the river's drainage area. The Mn, Cu, Mo, and Cd concentrations were related to the water depth. These results indicated that the Mo, Cd, and Cu deposition processes were controlled by oxygen depletion, and that these elements accumulated in the deeper parts of the bay under anoxic conditions.     

Bioconcentration and biomagnification of polybrominated diphenyl ethers (PBDEs) through lower-trophic-level coastal marine food web

Bivalves, crabs, fishes, seawater, and sediment collected from the inner part of Tokyo Bay, Japan, were measured for 20 polybrominated diphenyl ether (PBDE) and 5 polychlorinated biphenyl (PCB) congeners. To determine the trophic levels of the organisms, carbon and nitrogen stable isotope ratios (δ¹³C and δ¹⁵N) were also measured. Bioconcentration factors of PBDE and PCB congeners increased as the octanol-water partition coefficient (K_ow) rose to log K_ow = 7, above which they decreased again. Biomagnification of PCBs and several PBDE congeners (BDE47, 99, 100, 153 and 154) up the trophic ladder was confirmed by a positive correlation between their concentrations and δ¹⁵N. Other PBDE congeners showed a negative or no correlation, suggesting their biotransformation through metabolism. The more hydrophobic congeners of both PBDEs (Br = 2-6) and PCBs (Cl = 6-9) were biomagnified more. It thus appears that PBDEs are less biomagnified than PCBs.     

Granite subduction: Arc subduction, tectonic erosion and sediment subduction

Continental growth has been episodic, reflecting the episodic nature of mantle dynamics as well as surface dynamics of the Earth, the net result of which is exhibited by the present mantle with two huge reservoirs of TTG rocks, one on the surface continents and the other on the D″ layer on the Core-Mantle Boundary (CMB). During the early half of the Earth history, the felsic continental crust on the surface which formed in an intra-oceanic environment has mostly been subducted into the deep mantle, except in the rare case of parallel arc collision. The growth history of continental crust shows that with its simultaneous formation, a considerable amount must have also been subducted. Such ongoing subduction processes can be seen in the western Pacific region, through tectonic erosion, arc subduction, and sediment-trapped subduction.