华北地块北缘AuAgCuPbZn成矿规律

根据研究区成矿地质背景,分析了地层、构造、岩浆岩等因素对华北地块北缘Au、Ag、Cu、Pb、Zn成矿的控制作用,总结了矿床的时、空分布,共生组合特点,提出了成矿规律.     

盐湖相低熟油脂肪酸的组成与分布特征

对泌阳凹陷碱性盐湖相、舞阳凹陷盐湖相、襄城凹陷膏盐湖相、南阳凹陷淡水湖相低熟油脂肪酸组成和分布特征进行了分析与研究。结果表明这些不同盐湖相的低熟原油的脂肪酸为丰度不同的饱和正构酸、不饱和正构酸、少量异构酸、类异戊二烯酸及脂肪酸乙酯系列化合物。脂肪酸的组成和分布反映了原始有机质的来源。     

Remote-sensing inversion model of surface water suspended sediment concentration based on in situ measured spectrum in Hangzhou Bay, China

Suspended sediment concentration (SSC) is an important parameter for monitoring coastal water quality. Suspended particles are also the main optically active substances for ocean color remote sensing. It is important to study the surface reflectance spectra features of coastal turbid water, as it can be the basis for establishing more accurate remote-sensing inversion models. In this study, Hangzhou Bay, China, was selected as the study area. Two in situ measurement and sampling stations in the estuary of the Qiantang River which flows into Hangzhou Bay were set up separately. Above-water spectrum observation method, which the NASA recommended, was adopted to measure the reflection spectrum of turbid waters. Surface water samples were simultaneously collected to obtain the corresponding SSC data. The results showed that the total suspended particle concentrations in the Hangzhou Bay were typically high, and the inorganic suspended particle concentrations were far greater than the phytoplankton concentrations, which averages 705?mg/L and 1.16?mg/m³. The SSC at two sampling stations both showed significant temporal variability, particularly appearing short-period rapid fluctuations accompanying the tidal cycle. The measured surface water reflectance spectra all showed typical curve characteristics of high turbid water, and as the SSC increased, the corresponding reflectivity of surface water also increased. The increments at different wavelengths were variational, with two reflectance peaks appearing at 650?C700-nm and near the 800-nm wavelength of spectral curves, respectively. The first derivative of spectral curves showed that the first reflectance peak location appeared to be a ??red shift?? phenomenon with the SSC increasing. The correlation coefficients between the SSC of surface water and the remote-sensing reflectance according to moderate resolution imaging spectra-radiometer (MODIS) channels?? central wavelength were different significantly, which were larger at MODIS long-wavelength channels (>650?nm) and smaller at MODIS short-wavelength channels (400?C550?nm). The value of determination coefficient R ² was 0.82 when the reflectance ratio of MODIS band 2 to band 1 was selected as the SSC sensitive bands combination and exponential regression analysis was employed. Therefore, the reflectance ratio of MODIS band 2 to band 1 can be adopted as the main band combination for establishing surface water SSC remote-sensing inversion model in the Hangzhou Bay.     

长白山望天鹅火山双峰式火山岩的成因演化

望天鹅火山活动从早到晚分为三期：①长白期以粗面玄武岩为主,少量碱性玄武岩和玄武质粗安岩;②望天鹅期又分早晚两个亚期,早期玄武质粗安岩和粗面岩,晚期碱性流纹岩;③红头山期碱性流纹岩。望天鹅火山岩的岩石学、ＲＥＥ、不相容元素和Ｎｄ、Ｓｒ、Ｐｂ同位素（１４３Ｎｄ／１４４Ｎｄ、８７Ｓｒ／８６Ｓｒ、２０６Ｐｂ／２０４Ｐｂ分别变化于０．５１２５６７～０．５１２６４２、０．７０５１９８～０．７１６７４２和１７．４３４～１７．９３４）,揭示了岩浆源区明显受洋壳的俯冲和壳幔混合混染,三期火山岩具有共同的岩浆源区和紧密的成因演化关系,分离结晶作用控制了岩浆的演化过程。原始碱性系列玄武质岩浆经橄榄石、辉石的结晶分异,向粗面玄武岩演化;粗面玄武岩经斜长石强烈的结晶分离作用,还有辉石、钛铁氧化物和磷灰石的分离结晶作用形成具显著Ｅｕ、Ｓｒ、Ｂａ、Ｔｉ、Ｐ负异常的碱性流纹岩,导致本区火山岩缺失中性（ＳｉＯ２＝５７％～６３％）的安山岩和粗安岩,呈现双峰式火山岩组合的特点。     

综合物探技术在小盘岭公路隧道选线中的应用

利用综合物探技术,查明岩体风化情况、围岩分类以及构造带分布,进而为公路隧道的选线提供足够的信息,具有重要的意义。采用先进的电阻率成像技术和高分辨率浅层地震勘探方法,在小盘岭公路选线时,取得了很好的应用效果。     

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

超高压变质岩矿物中的显微构造缺陷:来自TEM和FTIR研究的证据

超高压变质矿物的某些显微构造缺陷可能指示了岩石短暂和快速抬升过程。文中报道了中国大别山双河地区超高压硬玉石英岩矿物显微构造缺陷的透射电镜(TEM)和Fourier变换红外光谱(FTIR)的研究结果。用TEM研究方法,在硬玉石英岩中硬玉包裹体内发现了亚微米级天然蒙钠长石(MA,C2/m)、高钠长石(HA,C)和低钠长石(LA,C)三种多形变体。表明岩石在折返过程经历过高温变质作用(>930℃),以及退变质过程的快速冷却;在石英包裹体内发现了纳米级柯石英和石盐子矿物,提供了柯石英转变为石英以及峰期变质条件下高盐流体存在的证据。"名义上无水矿物"(NAMs)的结构水(OH/H2O)是以缺陷形式赋存于矿物结构中。FTIR分析结果显示硬玉、石榴石、金红石和石英中结构水的平均含量分别为1000×10-6、(900~1600)×10-6、>2000×10-6和<4×10-6,硬玉石英岩全岩含水量为(490~600)×10-6,表明在高压-超高压变质作用过程中,地壳或原岩中的水可以通过这些NAMs携带到地球深部。该类显微构造缺陷可能是大陆碰撞造山带在高应变速率下的局部弱化和深部断层作用的结果。     

中国锑矿资源潜力及成矿预测

锑矿是中国的优势矿产之一.地质大调查开展以来,尤其是西部大开发战略找矿政策实施以来,中国西部新发现了一批大中型锑矿.西藏、新疆锑矿资源优势的逐渐显现,打破了原来以湖南、广西、贵州等东部省份为主的分布格局.本文结合全国重要矿产潜力评价成果,通过广泛查阅资料,综合分析地层、构造、岩浆岩等成矿条件,在全国范围内划分了11个锑矿成矿远景区,并分析了主要成矿远景区的成矿特征和找矿潜力.同时还对其他远景区进行了简单评述,提出找矿建议.     

中国东北部陆缘内生金矿床成因类型、成矿时代及地球动力学背景

中国东北部陆缘是我国内生金矿床较为发育的地区之一,以成矿作用复杂、蕴藏丰富的金资源量倍受国内外地质学家关注。通过对该区内生金矿的地质和成矿年代的系统研究,初步将该区内生金矿床划分为中温热液金矿床、接触交代-热液金矿床、斑岩型/类斑岩型金铜矿床和浅成低温热液金矿床4种主要成因类型和3个重要成矿期（170～160 Ma、130～110 Ma和110～90 Ma）。结合同位素地球化学特征,进一步确定中温热液金矿床的成矿物质主要来自下地壳源,成矿作用与中生代燕山早期古太平洋板块俯冲作用引发的中国东部大陆边缘岩石圈减薄及拆沉的动力学过程密切相关;接触交代-热液金矿床的成矿物质来源于年轻地壳,成矿作用与古太平洋板块俯冲引起的岩石圈减薄拆沉的伸展构造背景下的岩浆接触交代作用更为密切;而斑岩型/类斑岩型金铜矿床和浅成低温热液金矿床的成矿物质来源为壳幔混合源,其成矿发生在古太平洋板块向亚洲大陆正北向俯冲转入Izanagi Farallon板块西向俯冲的构造转换期。     

不同氧化度碱性水钠锰矿氧化As(Ⅲ)和Cr(Ⅲ) 的动力学特性

用批量法研究了Mn平均氧化度分别为4.02、3.85和3.70的碱性水钠锰矿对As(Ⅲ)和Cr(Ⅲ)氧化的动力学特性。结果表明,碱性水钠锰矿氧化As(Ⅲ)和Cr(Ⅲ)先经历准一级动力学反应阶段,随后表观速率常数(k_obs)逐渐减小至趋近零,达到反应平衡,k_obs逐渐减小除了逆反应影响外,还与产物在矿物表面不断积累,钝化反应位点有关。初始反应阶段k_obs随氧化度增加而增大,氧化As(Ⅲ)的k_obs分别为: 0.095 1、0.039 6和0.007 1 min^-1;氧化Cr(Ⅲ)的k_obs分别为0.034 2、0.017 8和0.014 8 min^-1。氧化As(Ⅲ)的初始反应阶段生成的Mn(Ⅱ)基本保留在矿物表面,对反应位点钝化大,使k_obs减小速度快。而Cr(Ⅲ) 氧化初始阶段,Mn(Ⅱ)释放明显滞后于Cr(Ⅵ)释放,但随反应进行逐渐增加,与Cr(Ⅵ)释放量比值接近于反应计量比。故Cr(Ⅲ) 氧化生成Mn(Ⅱ)对位点的钝化远小于As(Ⅲ)氧化,其初始反应阶段后k_obs减小速度较慢,且氧化度越高,保持一级动力学的初始反应阶段越长,k_obs减小越慢。因此,水钠锰矿的Mn氧化度越高,氧化As(Ⅲ)和Cr(Ⅲ)的反应速率越快,As(Ⅲ)和Cr(Ⅲ)在碱性水钠锰矿表面氧化产物的释放行为是影响其反应动力学特性的重要因素。