黑龙江杂岩蓝片岩—云母片岩矿物成分及变质作用P-T条件

黑龙江构造混杂岩中保留着一套曾遭受过中高压变质作用的岩石,其代表性岩石为:蓝片岩-云母片岩;蓝闪石、铁蓝闪石和多硅白云母(单位结构中Si=3.37～3.46>3.30)等具有中高压性质的典型变质矿物在岩石中平衡共生.蓝片岩-云母片岩组合至少经历了早期和晚期两阶段变质,早期为绿帘蓝片岩相,变质温压条件为T=320～460℃,P=7.8×108～11×108Pa.晚期为高绿片岩相,出现富镁绿泥石(XMg=0.565～0.646)交代早期钠质角闪石和多硅白云母等高压变质矿物现象,变质温度升高而压力有所降低,由石榴石云母片岩所限定的高绿片岩相变质条件为T=536～598℃,P=6.8×108～9.5×108Pa,属中温和中高压变质.     

Carbon isotopic thermometry calibrated by dolomite-calcite solvus temperatures

The temperature dependence of carbon isotopic fractionations between calcite and graphite, and between dolomite and graphite are calibrated by the calcite-dolomite solvus geothermometry using marbles collected from the contact metamorphic aureole in the Kasuga area, central Japan. The carbon isotopic fractionations (Δ¹³C_Cc-Gr and Δ¹³C_DoGr) systematically decrease with increasing metamorphic temperature. The concordant relationships between the fractionations and solvus temperatures are approximately linear with T^?2 over the temperature range. 400° to 680°C: Δ¹³C_CcGr (%.) = 5.6 × 10⁶ × T^?2 (K) ? 2.4 Δ¹³C_DoGr (%.) = 5.9 × 10⁶ × T^?2 (K) ? 1.9 These systematic relationships between fractionation and temperature suggest that carbon isotopic equilibria between carbonates and graphite were attained in many cases. The equation for the calcite-graphite system has a slope steeper than Bottinga's (1969) results. It is, however, in good agreement with that of Valley and O'Neil (1981) in the temperature range from 600° to 800°C.Because of the relatively high sensitivity to temperature, these isotopic geothermometers are useful for determining the temperatures in moderate- to high-grade metamorphosed carbonate rocks.