Large seasonal changes in the recharge of seawater in a subterranean estuary revealed by a radon tracer

Activities of radon (²²²Rn) in groundwater were continuously monitored in a saline aquifer from September 2010 to July 2011. The activities of ²²²Rn ranged from 200 to 4300 Bq m^?3, with a large seasonal variation. Because the activity of ²²²Rn in seawater is low, ²²²Rn in saline groundwater must be produced in the aquifer from radium (²²⁶Ra) in rocks and sediments. The ²²²Rn activities were higher in the warm‐dry seasons (September–November 2010 and April–May 2011) when the saline aquifer was stable. In contrast, the lowest ²²²Rn activities were observed in the cold‐dry season (December 2010 and January–March 2011), because of the effective exchange between groundwater and seawater. In addition, sudden decreases of ²²²Rn activities coincided with episodic drops in groundwater temperatures. These results reveal that lower seawater temperature in winter may result in density‐driven seawater intrusion. During the wet season (June–July 2011), ²²²Rn activities were more clearly affected by semi‐monthly and diurnal tidal pumping, showing higher ²²²Rn activities during low and spring tides. Such a tidal effect was not clearly observed during the warm‐dry and cold‐dry seasons. This result implies that the residence time of SGD in coastal zones is significantly affected by seasonal changes in driving forces such as tidal pumping and seawater intrusion. Copyright © 2016 John Wiley & Sons, Ltd.     

An ENSO stability analysis. Part I: results from a hybrid coupled model

In this study, we use the Bjerknes stability (BJ) index as a tool to investigate overall El Niño-Southern Oscillation (ENSO) stability in a hybrid-coupled model (HCM) with various atmosphere and ocean background states. This HCM shows that ENSO growth rates as measured by the BJ index and linear growth rates estimated directly with a time series of the Niño 3.4 indices from the coupled model simulations exhibit similar dependence on background states, coupling strength, and thermodynamic damping intensity. That is, the BJ index and linear growth rates increase with a decrease in the intensity of the background wind, an increase in coupling strength, or a decrease in the intensity of thermodynamic damping, although the BJ index tends to overestimate the growth rate. A detailed analysis of the components of the BJ index formula suggests the importance of model climatological background states and oceanic dynamic parameters in determining ENSO stability. We conclude that the BJ index may serve as a useful tool for qualitatively evaluating the overall ENSO stability in coupled models or in observations without a detailed eigen-analysis that is difficult to perform in models more complex than relatively simple models.     

Optimization of As(V) adsorption on Fe-RH-MCM-41-immobilized GAC using Box–Behnken Design: Effects of pH,loadings, and initial concentrations

This work focused on the removal from water of arsenate in the 100 to 500 μg/L range using Fe-RH-MCM-41 immobilized on GAC by a colloidal impregnation method. A Response Surface Method (RSM) based on the Box–Behnken Design (BBD) was used to evaluate the effects of pH, adsorbent loading, and initial arsenate concentrations. The thermal stability of Fe-RH-MCM-41/GAC was greater than 460 °C because Fe-RH-MCM-41 and epoxy resin covered the GAC, preventing GAC weight loss. The rate and capacity for arsenate adsorption on Fe-RH-MCM-41/GAC were higher than for GAC. The effects of pH, adsorbent loading, and initial arsenate concentration showed significant effects on efficiency, in terms of percent arsenate removal. Significant interaction occurred as positive effects between arsenate and arsenate concentrations, and pH and arsenate concentrations, and as negative effects between pH and pH, adsorbent loading and adsorbent loading, and adsorbent loading and arsenate concentrations.     

Cloud cover retrieved from skyviewer: A validation with human observations

Cloud cover information is used alongside weather forecasts in various fields of research; however, ground observation of cloud cover is conducted by human observers, a method that is subjective and has low temporal and spatial resolutions. To address these problems, we have developed an improved algorithm to calculate cloud cover using sky image data obtained with Skyviewer equipment. The algorithm uses a variable threshold for the Red Blue Ratio (RBR), determined from the frequency distribution of the Green Blue Ratio (GBR), to calculate cloud cover more accurately than existing algorithms. To verify the accuracy of the algorithm, we conducted daily, monthly, seasonal, and yearly statistical analyses of human observations of cloud cover, obtained every hour from 0800 to 1700 Local Standard Time (LST) for the entirety of 2012 at the Gangwon Regional Meteorological Administration (GRMA), Korea. A case study compared daily images taken at 1200 LST in each season with pixel images of cloud cover calculated by our improved algorithm. The selected cases yielded a high correlation coefficient of 0.93 with the GRMA data. A monthly case study showed low root mean square errors (RMSEs) and high correlation coefficients (Rs) for December (RMSE = 1.64 tenths and R = 0.92) and August (RMSE = 1.43 tenths and R = 0.91). In addition, seasonal cases yielded a high correlation of 0.9 and 87% consistency within ± 2 tenths for winter and a correlation of 0.83 and 82% consistency for summer, when cases of cloud-free or overcast conditions are frequent. Annual analyses showed that the bias of GRMA and Skyviewer cloud cover data for 2012 was -0.36 tenth, and the RMSE was 2.12 tenths, with the GRMA data showing more cloud cover. Considering that the GRMA and Skyviewer data were gathered at different spatial locations, GRMA and Skyviewer data were well correlated (R = 0.87) and showed a consistency of 80% in their cloud cover data (consistent within ± 2 tenths).     

Mechanism of Kelvin and Rossby waves during ENSO events

Summary ?The fields of sea-level height anomaly (SLHA) and surface zonal wind anomaly (SZWA) have been analyzed to investigate the typical evolution of spatial patterns during El Ni?o-Southern Oscillation (ENSO) events. Sea surface temperature (SST) changes during ENSO events are represented as an irregular interplay of two dominant modes, low-frequency mode and biennial mode. Cyclostationary principal component (PC) time series of the former variables are regressed onto the PC time series of the two dominant SSTA modes to find the spatial patterns of SLHA and SZWA consistent with the two SSTA modes. The two regressed patterns of SLHA explain a large portion of SLHA total variability. The reconstruction of SLHA using only the two components reasonably depicts major ENSO events. Although the low-frequency component of SST variability is much larger than the biennial component, the former does not induce strong Kelvin and Rossby waves. The biennial mode induces much stronger dynamical ocean response than the low-frequency mode. Further decomposition of the SLHA modes into Kelvin and Rossby components shows how these two types of equatorial waves evolve during typical ENSO events. The propagation and reflection of these waves are clearly portrayed in the regressed patterns leading to a better understanding of the wave mechanism in the tropical Pacific associated with ENSO. A close examination suggests that the delayed action oscillator hypothesis is generally consistent with the analysis results reported here. Rossby wave development in the central Pacific in the initiation stage of ENSO and the subsequent reflection of Kelvin waves at the western boundary seems to be an important mechanism for further development of ENSO. The development of Kelvin waves forced by the surface wind in the far-western Pacific cannot be ruled out as a possible mechanism for the growth of ENSO. While Kelvin waves in the far-western Pacific serve as an intiation mechanism of ENSO, they also cause the termination of existing ENSO condition in the central and eastern Pacific, thereby leading to a biennial oscillation over the tropical Pacific. The Kelvin waves from the western Pacific erode the thermocline structure in the central Pacific preventing further devlopment of ENSO and ultimately terminating it. It should be emphasized that this wave mechanism is clear and active only in the biennial mode. Received August 15, 2001; revised March 6, 2002     

Assessment of immune parameters of manila clam <Emphasis Type="Italic">Ruditapes philippinarum</Emphasis> in different physiological conditions using flow cytometry

Cellular and humoral immune parameters are often used as biomarkers to trace environmental and physiological stresses in marine bivalves. In this study, we compared various immune parameters of Manila clams (Ruditapes philippinarum) under normal conditions and under a high level of desiccation, using flow cytometry. The immune parameters analyzed included, total hemocyte count, hemocyte mortality, hemocyte DNA damage, reactive oxygen species (ROS) production, and phagocytosis activity. Total hemocyte count, hemocyte DNA damage, and hemocyte mortality were significantly elevated among clams under high desiccation stress, while phagocytosis activity and spontaneous ROS production were significantly lower compared to those parameters of the control clams (p<0.05). These data suggest that the immune parameters analyzed in this study well reflect the physiological status of clams.     

Integration of air pollution data collected by mobile sensors and ground-based stations to derive a spatiotemporal air pollution profile of a city

ABSTRACT

Air pollution has become a serious environmental problem causing severe consequences in our ecology, climate, health, and urban development. Effective and efficient monitoring and mitigation of air pollution require a comprehensive understanding of the air pollution process through a reliable database carrying important information about the spatiotemporal variations of air pollutant concentrations at various spatial and temporal scales. Traditional analysis suffers from the severe insufficiency of data collected by only a few stations. In this study, we propose a rigorous framework for the integration of air pollutant concentration data coming from the ground-based stations, which are spatially sparse but temporally dense, and mobile sensors, which are spatially dense but temporally sparse. Based on the integrated database which is relatively dense in space and time, we then estimate air pollutant concentrations for given location and time by applying a two-step local regression model to the data. This study advances the frontier of basic research in air pollution monitoring via the integration of station and mobile sensors and sets up the stage for further research on other spatiotemporal problems involving multi-source and multi-scale information.     

Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea)

After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure.     

U–Pb zircon ages and Sr-Nd-Pb isotopic compositions for Permian–Jurassic plutons in the Ogcheon belt and Ryeongnam massif, Korea: Tectonic implications and correlation with the China Qinling–Dabie belt and the Japan Hida belt

Abstract The Ogcheon fold belt and the Ryeongnam massif in the Korean Peninsula are made up of Precambrian igneous and sedimentary rocks that have been metamorphosed, tectonically deformed and extensively intruded by mafic to felsic plutonic rocks of Permian to Jurassic age. In the present study, we report seven new U–Pb zircon ages and Sr‐Nd‐Pb isotopic data for Permian to Jurassic plutons in the Ogcheon belt and the Ryeongnam massif. In the Ogcheon belt, these are: the Cheongsan porphyritic granite (217 ± 3.1 My), the Baegrog foliated granodiorite (206.4 ± 3.6 My), the Sani granite (178.8 ± 2.9 My) and the Yeonggwang foliated granite (173.0 ± 1.7 My). For the Ryeongnam massif, we report on the Yeongdeog foliated granodiorite (252.2 ± 2.9 My), the Sancheong gabbro (203.8 ± 3.3 My) and the Baegseogri foliated granodiorite (177.8 ± 2.4 My). All of these ages are lower concordia intercepts; the upper concordia intercepts indicate derivation from a Precambrian protolith. Sr, Nd and Pb isotopes also reveal that much of the Permian–Jurassic (252–173 Ma) plutonism in Korea was generated by recycling of Precambrian rocks. These new ages, together with other published zircon ages indicate that the plutonism in the Ogcheon fold belt is coeval with that in the Ryeongnam massif, but based on the Sr‐Nd‐Pb isotopic evidence, they are not cogenetic. In addition, zircon ages provide information on the movement along the Honam shear zone, which cuts across the whole Korean Peninsula and along most of its length provides the boundary between the Ogcheon fold belt and the Ryeongnam massif. It has a prolonged history of movement and deformation and appears to have been active from the Precambrian through to the Mesozoic, from before 1924 Ma to at least 180 Ma. The Permian–Jurassic igneous and tectonic activity in Korea is a manifestation of the more extensive orogenic activities that affected the East Asian continent at that time. In China, ultra high‐pressure rocks of the Qinling–Dabie belt formed between 210 and 230 Ma as result of the collision between the South China block and the North China block. In central Japan, corresponding plutonic activity is dated as 175 to 231 Ma. The absence of ultra high‐pressure rocks in Korea and Japan precludes a simple extension of the Qinling–Dabie belt eastwards; however, the effects of the continental collision eastwards are apparent from the igneous and tectonic activity.