Brans-Dicke cosmology,II

We discuss the implications of the Brans-Dicke scalar-tensor theory for cosmology with particular emphasis on the primordial element abundances that would obtain. Two general classes of models are found. Models of one class expand through the nuclear burning stage slightly more rapidly than the general relativistic case: models of the other class may expand at any rate whatsoever. The first class of models yeilds primordial abundances of D, He³ and He⁴ in agreement with their general relativistic values if the present mass density is low. High-density cosmologies, however, would produce too much He⁴. The second class of models yields element abundances which are far too high unless the expansion rate was quite large: in this case no He⁴ at all is produced. Finally, we determine the rate of change of the constant of gravitationG at the present epoch. For all but a very small class of models is negative at the present epoch. Models with positive values of at the present epoch produce no primordial He⁴ whatsoever, and have ages significantly lower than the corresponding general relativistic ages.     

Morphology of lunar craters: A test of lunar erosional models

This paper is a test of published theoretical and experimental studies of crater erosion by micrometeorite bombardment which predict systematic variations in the morphology of lunar craters as a function of crater diameter and crater age. Numerical, ranking-type degradation classifications indicate that the craters on Mare Imbrium and Mare Tranquillitatus confirm these predictions by showing a systematic increase in degradation with decreasing diameter for craters smaller than a few kilometers in diameter but larger than the equilibrium diameter, and by showing fixed proportions of fresh, moderately degraded and very degraded craters under equilibrium conditions. Furthermore, the relative ages of the two mare surfaces may be determined using a diameter/mean-degradation-number curve. These determinations of relative age and process of crater erosion are both essentially independent of the traditionally studied crater diameter/frequency relationships. Morphologies of terra craters near Mare Humorum suggest a young, non-equilibrium crater population superposed on a perimordial population with about equilibrium proportions of fresh, moderately degraded and very degraded craters. The primordial population has been modified by pre-Imbrian or early Imbrian deposition of blanketing deposits. A comparative study of several crater degradation classifications indicates that all are essentially interchangeable.     

Scattering in the Atmosphere of Venus. I. Line profiles and curves of growth for isotropic scattering

We have computed line profiles and curves of growth for both reflected and transmitted radiation for typical lines in CO₂ bands (in the photographic infrared) which occur in the spectrum of Venus. In our model the pressure variation with altitude was considered and the base of the cloud deck was set at the 2 bar level. The temperature was held constant at 250K and a Voigt profile was used for the lineshape. We also assumed that the scale height of the cloud particles was equal to the scale height of the gas. The calculations were made for four values of the scattering optical thickness (τ_c = 0.1, 1.0, 10, and 100) using a continuum single scattering albedo $\text{ω}{}_{\mathrm{<mtext>c</mtext>}}\text{= 0.9975}$ (which gives a Bond albedo of 0.896 for τ_c = 100, the value observed for Venus at these wavelengths). Curves of growth are also presented for reflected radiation which has been averaged over the visible disk for three values of the Venus phase angle (0, 86, and 166°).     

Winkler's method overestimates dissolved oxygen in seawater: Iodate interference and its oceanographic implications

Dissolved oxygen in seawater has been determined by using the Winkler's reaction scheme for decades. An interference in this reaction scheme that has been heretofore overlooked is the presence of naturally occurring iodate in seawater. Each mole of iodate can result in an apparent presence of 1.5 mol of dissolved oxygen. At the concentrations of iodate in the surface and deep open ocean, it can lead to an overestimation of 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 of oxygen in these waters respectively. In coastal and inshore waters, the effect is less predictable as the concentration of iodate is more variable. The solubility of oxygen in seawater was likely overestimated in data sources that were based on the Winkler's reaction scheme for the determination of oxygen. The solubility equation of García and Gordon [Garcia H.E., Gordon, L.I., 1992. Oxygen solubility in seawater: Better fitting equations. Limnol. Oceanogr. 37, 1307–1312] derived from the results of Benson and Krause [Benson, F.B., Krause, D. Jr., 1984. The concentration and isotopic fractionation of oxygen dissolved in freshwater and seawater in equilibrium with the atmosphere. Limnol. Oceanogr. 29, 620–632] is free from this source of error and is recommended for general use. By neglecting the presence of iodate, the average global super-saturation of oxygen in the surface oceans and the corresponding efflux of oxygen to the atmosphere both have been overestimated by about 8%. Regionally, in areas where the degree of super-saturation or under-saturation of oxygen in the surface water is small, such as in the tropical oceans, the net air–sea exchange flux can be grossly under- or overestimated. Even the estimated direction of the exchange can be reversed. Furthermore, the presence of iodate can lead to an overestimation of the saturation anomaly of oxygen in the upper ocean attributed to biological production by 0.23 ± 0.07%. AOU may have been underestimated by 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 in the surface mixed layer and deep water, while preformed phosphate and preformed nitrate may have been overestimated by 0.004 ± 0.001 and 0.06 ± 0.02 μmol kg^− 1 in the surface mixed layer, and 0.005 ± 0.0004 and 0.073 ± 0.006 μmol kg^− 1 in the deep water. These are small but not negligible corrections, especially in areas where the values of these parameters are small. At the increasing level of sophistication in the interpretation of oxygen data, this source of error should now be taken into account. Nevertheless, in order to avoid confusion, an internationally accepted standard needs to be adopted before these corrections can be applied.     

Characterization and molecular analysis of hepatic microsomal UDP-glucuronosyltransferases in the marine fish, Pleuronectes platessa

Here we report the results of the first molecular enzymological study of fish UDP-glucuronosyltransferase (UDPGT). UDPGT activities of plaice liver microsomes were greatest for planar phenols and there was low but measurable conjugation of bilirubin, testosterone and androsterone. A highly purified preparation was isolated which possessed activities towards 1-naphthol, bilirubin and testosterone, containing several molecular weight species of M_r 52–56 kDa. On immunoblot analysis these proteins cross-reacted with a polyspecific anti-rat UDPGT antibody, suggesting that a number of plaice UDPGT isoforms with epitopes in common with the corresponding rat enzymes had been purified.     

Holocene sedimentation of a wave-dominated barrierisland shoreline: Cape Lookout, North Carolina

The sedimentary record of 130 km of microtidal (0.9 m tidal range) high wave energy (1.5 m average wave height) barrier island shoreline of the Cape Lookout cuspate foreland has been evaluated through examination of 3136 m of subsurface samples from closely spaced drill holes. Holocene sedimentation and coastal evolution has been a function of five major depositional processes: (1) eustatic sea-level rise and barrier-shoreline transgression; (2) lateral tidal inlet migration and reworking of barrier island deposits; (3) shoreface sedimentation and local barrier progradation; (4) storm washover deposition with infilling of shallow lagoons; and (5) flood-tidal delta sedimentation in back-barrier environments.

Twenty-five radiocarbon dates of subsurface peat and shell material from the Cape Lookout area are the basis for a late Holocene sea-level curve. From 9000 to 4000 B.P. eustatic sea level rose rapidly, resulting in landward migration of both barrier limbs of the cuspate foreland. A decline in the rate of sea-level rise since 4000 B.P. resulted in relative shoreline stabilization and deposition of contrasting coastal sedimentary sequences. The higher energy, storm-dominated northeast barrier limb (Core and Portsmouth Banks) has migrated landward producing a transgressive sequence of coarse-grained, horizontally bedded washover sands overlying burrowed to laminated back-barrier and lagoonal silty sands. Locally, ephemeral tidal inlets have reworked the transgressive barrier sequence depositing fining-upward spit platform and channel-fill sequences of cross-bedded, pebble gravel to fine sand and shell. Shoreface sedimentation along a portion of the lower energy, northwest barrier limb (Bogue Banks) has resulted in shoreline progradation and deposition of a coarsening-up sequence of burrowed to cross-bedded and laminated, fine-grained shoreface and foreshore sands. In contrast, the adjacent barrier island (Shackleford Banks) consists almost totally of inlet-fill sediments deposited by lateral tidal inlet migration. Holocene sediments in the shallow lagoons behind the barriers are 5–8 m thick fining-up sequences of interbedded burrowed, rooted and laminated flood-tidal delta, salt marsh, and washover sands, silts and clays.

While barrier island sequences are generally 10 m in thickness, inlet-fill sequences may be as much as 25 m thick and comprise an average of 35% of the Holocene sedimentary deposits. Tidal inlet-fill, back-barrier (including flood-tidal delta) and shoreface deposits are the most highly preservable facies in the wave-dominated barrier-shoreline setting. In the Cape Lookout cuspate foreland, these three facies account for over 80% of the sedimentary deposits preserved beneath the barriers. Foreshore, spit platform and overwash facies account for the remaining 20%.     

Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay

A combination of CTD casts, discrete bottle sampling and in situ voltammetric microelectrode profiling was used to examine changing redox conditions in the water column at a single station south of the Bay Bridge in the upper Chesapeake Bay in late July/early August, 2002–2005. Short-term (2–4 h) fluctuations in the oxic/suboxic/anoxic interface were documented using in situ voltammetric solid-state electrodes. Profiles of dissolved oxygen and sulfide revealed tidally-driven vertical fluctuations of several meters in the depth and thickness of the suboxic zone. Bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ also varied over the tidal cycle by approximately an order of magnitude. These data indicate that redox species concentrations at this site varied more due to physical processes than biogeochemical processes. Based on analysis of ADCP data, tidal currents at this station were strongly polarized, with the principal axis of tidal currents aligned with the mainstem channel. Together with the chemical data, the ADCP analysis suggests tidal flushing of anoxic bottom waters with suboxic water from north of the site. The present study is thus unique because while most previous studies have focused on processes across relatively stable redox interfaces, our data clearly demonstrate the influence of rapidly changing physical mixing processes on water column redox chemistry.Also noted during the study were interannual differences in maximum bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺. In 2003, for example, heavy spring rains resulted in severe hypoxia/anoxia in June and early July. While reported storm-induced mixing in late July/early August 2003 partially alleviated the low-oxygen conditions, bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ were still much higher than in the previous year. The latter implies that the response time of the microbial community inhabiting the suboxic/anoxic bottom waters to changing redox conditions is slow compared to the time scale of episodic mixing events. Bottom water concentrations of the redox-sensitive chemical species should thus be useful as a tracer to infer prior hypoxic/anoxic conditions not apparent from ambient oxygen levels at the time of sampling.     

U.S. Minerals Management Service (MMS) Prelease Geological and Geophysical (G & G) Data Acquisition: A 20-Year Retrospective, 1976-1996

Since 1976, the Minerals Management Service (MMS) has administered its prelease geological and geophysical (G & G) data acquisition program through Title 30, Part 251, of the Code of Federal Regulations, which govern permitting, acquisitions, and data release. Leading indicators of offshore oil and gas activity are the number of permits issued to industry, associated mileage, and expenditures. Over the last 20 years, permit activity has indicated that most of the oil and gas surveying has been in the Gulf of Mexico, where 80 % of all permits have been issued, followed by Alaska (10 %), the Pacific (7 %), and the Atlantic (3 %). These statistics correlate with the dominant position of the central and western Gulf of Mexico areas in oil and gas activity. More than 95 % of all permits were issued for geophysical exploration, mostly for two-dimensional (2-D) common-depth-point (CDP) seismic data. However, over the last 10 years, permits for three-dimensional (3-D) seismic data have averaged 25 % of all geophysical permits and, by 1996, made up approximately half of all geophysical permits offshore-wide. Between 1976 and the early 1990s, industry shot approximately 500,000 linemiles of 2-D CDP data each year on the Outer Continental Shelf (OCS). Of that total, MMS acquired approximately50,000 line-miles annually. In the 1990s, parallel with industry, MMS increased its acquisition of 3-D seismic data in concert with the development and use of interactive workstations. The majority of 2-D and 3-D data have been acquired in the Gulf of Mexico by a ratio of 2:1 over Alaska, the next largest data inventory. With regard to MMS expenditures for G & G data, from 1976 through the 1980s, Alaska, having more offshore area than the other three regions combined, had the largest portion. However, in the 1900s, the vast majority of expenditures have been in the Gulf of Mexico. Over the years, permit totals, mileage acquired, and expenditures for data reflect trends of oil and gas pricing, limitations of offshore moratoria, and a shift of industry emphasis to foreign theaters.