低硼氢氧化镁的制备及热分解动力学参数

本文以水合氯化镁、工业氨水为原料制备出了低硼含量的纯度 >99%的氢氧化镁和氧化镁。利用差热 -热重 (DTA- TG)、X-射线衍射 (XRD)、透射电子显微镜 (TEM)等手段 ,对氢氧化镁的热稳定性、相结构、表观状态以及脱水动力学参数进行了分析。结果为 :氢氧化镁以束状纤维和片状粉末共存 ,在 6 2 3K基本完成脱水反应生成氧化镁 ,其脱水反应的表观活化能 E为135 .4 k J· mol-1,指前因子 A为 5 .15× 10 10 ,反应级数 n为 1.10     

Geochemistry of trace elements and Sr-Nd isotopes of foraminifera shell from the Okinawa Trough

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Clogging of saturated porous media by silt‐sized suspended solids under varying physical conditions during managed aquifer recharge

Managed aquifer recharge is an effective method for utilizing excess flood flows, but clogging of porous media is a limiting factor in the implementation of this water storage technique. In recent years, much research on the physical clogging of porous media during artificial recharge has been conducted. However, the understanding of clogging due to silt‐sized suspended solids (SS) is still inadequate, especially under varying physical conditions. Here, we subjected sand columns to controlled rates of flow and SS suspensions to investigate the influence of media size, SS size, SS concentration, and flow velocity on the clogging of porous media by silt‐sized SS. The results show that the diameter ratio of SS particles to sand grains is the dominant factor influencing the position of physical clogging. As pore velocity increased, the mobility of silt‐sized SS was enhanced and retention in the porous media decreased noticeably. The spatial retention profiles in the porous media were found to vary greatly at different flow velocities. The SS concentration of the infiltrating suspension also dramatically influenced the mobility and deposition of silt‐sized SS particles, such that high concentrations accelerated the clogging process. As the different physical factors changed, the breakthrough curves and retention profiles of silt‐sized SS particles changed obviously and the mechanisms of retention differed. On the whole, clogging position is mainly determined by particle size ratio, but clogging rate is dominated by a variety of factors including particle size ratio, SS concentration, and flow velocity.     

太湖水体氮、磷浓度演变趋势(1985-2015年)

分析了太湖水体氮、磷浓度1985-2015年的演变趋势.结果表明,近30年来,全太湖水体氮、磷指标总体呈先恶化、后好转的波动变化趋势.总氮（TN）浓度年均值在1.79～3.63 mg/L之间,30年平均值为2.62±0.03 mg/L,总磷（TP）浓度年均值在0.04～0.15 mg/L之间,30年平均值为0.086±0.001 mg/L,1996年全太湖TN （3.84 mg/L）和TP （0.15 mg/L）浓度年均值均达历史峰值.氮、磷逐月浓度变化情况显示,TN浓度呈明显季节性变化规律,最高值集中出现在3、4月,概率分别为67%和33%,最低值则分布在8、9、10、11月,概率分别为18%、41%、29%和12%,而TP浓度则没有明显的季节性变化规律.太湖各湖区水体氮、磷浓度变化空间异质性明显,西部水域和北部水域变化幅度大于东部水域、南部水域和湖心区.太湖水体氮、磷浓度的长期变化趋势显然和流域经济发展及各项环保管理措施的实施密切相关,同时也受到重大水情变化的影响.此外,在相对封闭的局部湖湾水体可以通过水利调度等综合治理措施短时期内改善氮、磷指标,但大太湖水质的改善任重而道远.     

港珠澳跨海工程沉管隧道三维地震反应分析

以港珠澳大桥沉管隧道为工程研究背景,考虑管节接头GINA止水带的橡胶材料特性、场地的初始地应力平衡以及上覆动水压力作用等,分析了水平及竖向地震作用下沉管隧道三维动力反应。结果表明:动水压力对隧道结构的竖向及水平方向的动力响应均有一定影响,尤其是对隧道结构的竖向反应影响较水平方向更加明显,最大可达70%;隧道接头GINA止水带竖向剪切变形较水平纵向的拉伸变形及水平横向剪切变形明显偏大,尤其两侧止水带竖向剪切变形较大;混凝土隧道管节上顶板及边墙较管节底部更易受到明显的拉应力。     

Dynamic interaction of bridge–train system under non‐uniform seismic ground motion

The probability that an earthquake occurs when a train is running over a bridge in earthquake‐prone regions is much higher than before, for high‐speed railway lines are rapidly developed to connect major cities worldwide. This paper presents a finite element method‐based framework for dynamic analysis of coupled bridge–train systems under non‐uniform seismic ground motion, in which rail–wheel interactions and possible separations between wheels and rails are taken into consideration. The governing equations of motion of the coupled bridge–train system are established in an absolute coordinate system. Without considering the decomposition of seismic responses into pseudo‐static and inertia‐dynamic components, the equations of motion of the coupled system are formed in terms of displacement seismic ground motions. The mode superposition method is applied to the bridge structure to make the problem manageable while the Newmark‐β method with an iterative computation scheme is used to find the best solution for the problem concerned. Eight high‐speed trains running over a multi‐span steel truss‐arch bridge subject to earthquakes are taken as a case study. The results from the case study demonstrate that the spatial variation of seismic ground motion affects dynamic responses of the bridge–train system. The ignorance of pseudo‐static component when using acceleration seismic ground motions as input may underestimate seismic responses of the bridge–train system. The probability of separation between wheels and rails becomes higher with increasing train speed. Copyright © 2011 John Wiley & Sons, Ltd.     

水工建筑物强震动加速度记录的分析处理

从工程应用角度详细介绍水工强震动加速度记录正确处理分析的方法与原理.主要介绍了震源的评估原理,强震动加速度记录预处理过程中单位换算、奇异点剔除、基线校正、滤波除噪等步骤的方法原理,后处理分析中一次、二次积分、谱分析原理.阐述了利用强震动加速度记录进行震害快速评估原理.文中以二滩拱坝强震监测台阵监测到的一次强震加速度记录的处理过程为例,以图表形式直接明了地强调指出了强震动加速度记录处理中容易发生错误的过程,并提出相应的处理方法.     

大庆地震台网近震震级偏差分析与校正

选取大庆地震台网2002-2009年近震报告资料,以《黑龙江省地震目录》给出的震级为标准,进行震级偏差统计.按地区分段校正后,震级精度明显提高.     

川滇地区活动地块现今地壳形变特征

位于青藏高原东南缘的川滇菱形块体的地壳运动主要以鲜水河、安宁河、则木河、小江、红河、澜沧江、龙门山等深大断裂的强烈构造活动为特征,新生代以来受青藏高原物质向东侧流动及阿萨姆顶点楔入的作用,使该地区构造活动复杂,地震活动强烈而频繁,是研究地壳形变与地震的有利地区之一.但由于形变观测资料时空分布的制约,以前很多学者对川滇地区活动断裂的GPS形变研究主要以大尺度为主,主要反映川滇块体的整体运动特征,而对于利用GPS研究各个块体间的相互作用及其对边界带的活动构造的作用缺少深入的分析,本文正是基于1998～2002年间该地区200多GPS点位的三期GPS复测资料(网络工程和973项目),将川滇地区分为9个次级活动块体,计算了各个活动块体的欧拉旋转矢量和主要活动断裂的运动速度,并分析了该地区的应变场特征和地震危险性.结果表明川滇地区活动块体的运动有以下特点:     

地震重现时间间隔概率分布函数选择的必要条件

地震重现时间间隔的分布规律研究对于短期和中长期地震预测、地震灾害预防和救援有着重要的理论和实际意义,如果能够确定地震重现时间间隔的概率密度函数(probability density function-pdf),则在统计学的意义上,能够对地震再次发生的概率进行评估和预测.在地震重现时间间隔的pdf研究中,一个核心问题是如何判断某个pdf是否能够有效地描述地震重现时间间隔分布特征.作者提出利用特征地震重现时间间隔数据的变化系数(COV)与其偏度(S),变化系数与其峰度(K)的相关关系对所选择的pdf的适用性进行判别.研究表明,常用的一些概率密度函数(对数正态分布、gamma分布、Weibull分布和指数分布)并不合适作为描述特征地震的重现时间间隔分布的数学模型.