Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay

A combination of CTD casts, discrete bottle sampling and in situ voltammetric microelectrode profiling was used to examine changing redox conditions in the water column at a single station south of the Bay Bridge in the upper Chesapeake Bay in late July/early August, 2002–2005. Short-term (2–4 h) fluctuations in the oxic/suboxic/anoxic interface were documented using in situ voltammetric solid-state electrodes. Profiles of dissolved oxygen and sulfide revealed tidally-driven vertical fluctuations of several meters in the depth and thickness of the suboxic zone. Bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ also varied over the tidal cycle by approximately an order of magnitude. These data indicate that redox species concentrations at this site varied more due to physical processes than biogeochemical processes. Based on analysis of ADCP data, tidal currents at this station were strongly polarized, with the principal axis of tidal currents aligned with the mainstem channel. Together with the chemical data, the ADCP analysis suggests tidal flushing of anoxic bottom waters with suboxic water from north of the site. The present study is thus unique because while most previous studies have focused on processes across relatively stable redox interfaces, our data clearly demonstrate the influence of rapidly changing physical mixing processes on water column redox chemistry.Also noted during the study were interannual differences in maximum bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺. In 2003, for example, heavy spring rains resulted in severe hypoxia/anoxia in June and early July. While reported storm-induced mixing in late July/early August 2003 partially alleviated the low-oxygen conditions, bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ were still much higher than in the previous year. The latter implies that the response time of the microbial community inhabiting the suboxic/anoxic bottom waters to changing redox conditions is slow compared to the time scale of episodic mixing events. Bottom water concentrations of the redox-sensitive chemical species should thus be useful as a tracer to infer prior hypoxic/anoxic conditions not apparent from ambient oxygen levels at the time of sampling.     

Unsteady hydromechanics of a steering podded propeller unit

Unsteady forces, torques and bending moments were predicted for a model podded propulsor unit at various azimuth angles. Predictions in time history include propeller shaft thrust, propulsor unit thrust, normal forces to the propeller shaft bearing, total forces acting on the propulsor unit, propeller shaft torque, blade spindle torque, in-plane and out-of-plane bending moments, and propulsor unit stock shaft torque and bending moments. Analysis was performed for averaged forces and their fluctuations as well. A time-domain unsteady multi-body panel method code, PROPELLA, was further developed for this prediction work. Predictions were compared with a set of time averaged in-house experimental data for a puller-type podded propulsor configuration in the first quadrant operation. Unsteady fluctuations of forces were predicted numerically. Analysis was made for the bending moment on propeller blades, shaft and the propulsor unit stock shaft for azimuth angles from 0° to 45°. It indicates that the magnitude and fluctuation of the forces are significant and they are essential for structural strength and design optimization. The predicted bending moment and global forces on the propulsor unit provide some useful data for ship maneuvering motion and simulation in off-design conditions.     

The Daily Erosion Project – daily estimates of water runoff,soil detachment,and erosion

Water runoff and sediment transport from agricultural uplands are substantial threats to water quality and sustained crop production. To improve soil and water resources, farmers, conservationists, and policy‐makers must understand how landforms, soil types, farming practices, and rainfall interact with water runoff and soil erosion processes. To that end, the Iowa Daily Erosion Project (IDEP) was designed and implemented in 2003 to inventory these factors across Iowa in the United States. IDEP utilized the Water Erosion Prediction Project (WEPP) soil erosion model along with radar‐derived precipitation data and government‐provided slope, soil, and management information to produce daily estimates of soil erosion and runoff at the township scale (93 km² [36 mi²]). Improved national databases and evolving remote sensing technology now permit the derivation of slope, soil, and field‐level management inputs for WEPP. These remotely sensed parameters, along with more detailed meteorological data, now drive daily WEPP hillslope soil erosion and water runoff estimates at the small watershed scale, approximately 90 km² (35 mi²), across sections of multiple Midwest states. The revisions constitute a substantial improvement as more realistic field conditions are reflected, more detailed weather data are utilized, hill slope sampling density is an order of magnitude greater, and results are aggregated based on surface hydrology enabling further watershed research and analysis. Considering these improvements and the expansion of the project beyond Iowa it was renamed the Daily Erosion Project (DEP). Statistical and comparative evaluations of soil erosion simulations indicate that the sampling density is adequate and the results are defendable. The modeling framework developed is readily adaptable to other regions given suitable inputs. © 2017 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Groundwater Development Stress: Global‐Scale Indices Compared to Regional Modeling

The increased availability of global datasets and technologies such as global hydrologic models and the Gravity Recovery and Climate Experiment (GRACE) satellites have resulted in a growing number of global‐scale assessments of water availability using simple indices of water stress. Developed initially for surface water, such indices are increasingly used to evaluate global groundwater resources. We compare indices of groundwater development stress for three major agricultural areas of the United States to information available from regional water budgets developed from detailed groundwater modeling. These comparisons illustrate the potential value of regional‐scale analyses to supplement global hydrological models and GRACE analyses of groundwater depletion. Regional‐scale analyses allow assessments of water stress that better account for scale effects, the dynamics of groundwater flow systems, the complexities of irrigated agricultural systems, and the laws, regulations, engineering, and socioeconomic factors that govern groundwater use. Strategic use of regional‐scale models with global‐scale analyses would greatly enhance knowledge of the global groundwater depletion problem.     

A regime shift in sediment export from a coastal watershed during a record wet winter,California: Implications for landscape response to hydroclimatic extremes

Small, steep watersheds are prolific sediment sources from which sediment flux is highly sensitive to climatic changes. Storm intensity and frequency are widely expected to increase during the 21st century, and so assessing the response of small, steep watersheds to extreme rainfall is essential to understanding landscape response to climate change. During record winter rainfall in 2016–2017, the San Lorenzo River, coastal California, had nine flow peaks representing 2–10‐year flood magnitudes. By the third flood, fluvial suspended sediment showed a regime shift to greater and coarser sediment supply, coincident with numerous landslides in the watershed. Even with no singular catastrophic flood, these flows exported more than half as much sediment as had a 100‐year flood 35 years earlier, substantially enlarging the nearshore delta. Annual sediment load in 2017 was an order of magnitude greater than during an average‐rainfall year, and 500‐fold greater than in a recent drought. These anomalous sediment inputs are critical to the coastal littoral system, delivering enough sediment, sometimes over only a few days, to maintain beaches for several years. Future projections of megadroughts punctuated by major atmospheric‐river storm activity suggest that interannual sediment‐yield variations will become more extreme than today in the western USA, with potential consequences for coastal management, ecosystems, and water‐storage capacity. The occurrence of two years with major sediment export over the past 35 years that were not associated with extremes of the El Niño Southern Oscillation or Pacific Decadal Oscillation suggests caution in interpreting climatic signals from marine sedimentary deposits derived from small, steep, coastal watersheds, to avoid misinterpreting the frequencies of those cycles. Published 2018. This article is a U.S. Government work and is in the public domain in the USA.     

Progressive failure of sheeted rock slopes: the 2009–2010 Rhombus Wall rock falls in Yosemite Valley,California, USA

Progressive rock‐fall failures in natural rock slopes are common in many environments, but often elude detailed quantitative documentation and analysis. Here we present high‐resolution photography, video, and laser scanning data that document spatial and temporal patterns of a 15‐month‐long sequence of at least 14 rock falls from the Rhombus Wall, a sheeted granitic cliff in Yosemite Valley, California. The rock‐fall sequence began on 26 August 2009 with a small failure at the tip of an overhanging rock slab. Several hours later, a series of five rock falls totaling 736 m³ progressed upward along a sheeting joint behind the overhanging slab. Over the next 3 weeks, audible cracking occurred on the Rhombus Wall, suggesting crack propagation, while visual monitoring revealed opening of a sheeting joint adjacent to the previous failure surface. On 14 September 2009 a 110 m³ slab detached along this sheeting joint. Additional rock falls between 30 August and 20 November 2010, totaling 187 m³, radiated outward from the initial failure area along cliff (sub)parallel sheeting joints. We suggest that these progressive failures might have been related to stress redistributions accompanying propagation of sheeting joints behind the cliff face. Mechanical analyses indicate that tensile stresses should occur perpendicular to the cliff face and open sheeting joints, and that sheeting joints should propagate parallel to a cliff face from areas of stress concentrations. The analyses also account for how sheeting joints can propagate to lengths many times greater than their depths behind cliff faces. We posit that as a region of failure spreads across a cliff face, stress concentrations along its margin will spread with it, promoting further crack propagation and rock falls. Published in 2012. This article is a US Government work and is in the public domain in the USA.     

Surveying Upstate NY Well Water for Pesticide Contamination: Cayuga and Orange Counties

Private wells in Cayuga and Orange counties in New York were sampled to determine the occurrence of pesticide contamination of groundwater in areas where significant pesticide use coincides with shallow or otherwise vulnerable groundwater. Well selection was based on local groundwater knowledge, risk modeling, aerial photo assessments, and pesticide application database mapping. Single timepoint samples from 40 wells in each county were subjected to 93‐compound chromatographic scans. All samples were nondetects (reporting limits ≤1 μg/L), thus no wells from either county exceeded any of 15 state groundwater standards or guidance values. More sensitive enzyme‐linked immunosorbent assays (ELISA) found two wells with quantifiable atrazine in each county (0.1–0.3 μg/L), one well with quantifiable diazinon (0.1 μg/L) in Orange County, and one well with quantifiable alachlor (0.2 μg/L) in Cayuga County. Trace detections (<0.1 μg/L) in Cayuga County included atrazine (five wells), metolachlor (six wells), and alachlor (one well), including three wells with multiple detections. All 12 Cayuga County wells with ELISA detections had either corn/grain or corn/forage rotations as primary surrounding land uses (although 20 other wells with the same land uses had no detections) and all quantified detections and most trace detections occurred in wells up to 9‐m deep. Orange County trace (<0.1 μg/L) ELISA detections (atrazine three wells, diazinon one well, and metolachlor five wells) and quantified detections were only generally associated with agricultural land uses. Finding acceptable drinking water quality in areas of vulnerable groundwater suggests that water quality in less vulnerable areas will also be good.     

Key Design Elements of Building Pressure Cycling for Evaluating Vapor Intrusion—A Literature Review

Building pressure cycling (BPC) is becoming an increasingly important tool for studying vapor intrusion. BPC has been used to distinguish subslab and indoor sources of vapor intrusion as well as to define reasonable worst case volatile organic compound mass discharge into a structure. Analyses have been performed both semi-quantitatively with concentration trends and quantitatively with more rigorous flux calculation and source attribution methods. This paper reviews and compares the protocols and outcomes from multiple published applications of this technology to define the key variables that control performance. Common lessons learned are identified, including those that help define the range of building size and type to which BPC is applicable. Differences in test protocols are discussed, recognizing that the complexity of the test protocol required depends on the particular objectives of each project. Research gaps are identified and tabulated for future validation studies and applications.     

Cadmium release caused by the die-back of the saltmarsh cord grass Spartina anglica in Poole Harbour (UK)

As in many other areas, the perennial cord grass Spartina anglica C.E. Hubbard has been extremely successful at colonising the English and Irish south coasts, but it is dying back for reasons that are not completely understood. The present study considers the relationship between die-back and metal concentrations in estuarine sediment. No obvious impact of the metal contamination on the S. anglica growth/die-back could be detected in the study zone, Poole Harbour, although the die-back did seem to have substantially influenced the metal concentrations in the sediments of the estuary. Based on core profiles, the remaining patches of S. anglica still retain elevated concentrations and the overall cadmium concentrations in the sediments have risen since 1925. However, considerable quantities of the cadmium stored in the sediment by S. anglica appear to have been washed out rapidly in the die-back zones. Should serious erosion of the saltmarsh occur, triggered for example by sea-level rise, then sudden and high levels of cadmium release may cause harmful effects to marine biota.     

The Regional Ocean Modeling System (ROMS) 4-dimensional variational data assimilation systems: Part II - Performance and application to the California Current System

The Regional Ocean Modeling System (ROMS) 4-dimensional variational (4D-Var) data assimilation systems have been systematically applied to the mesoscale circulation environment of the California Current to demonstrate the performance and practical utility of the various components of ROMS 4D-Var. In particular, we present a comparison of three approaches to 4D-Var, namely: the primal formulation of the incremental strong constraint approach; the dual formulation “physical-space statistical analysis system”; and the dual formulation indirect representer approach. In agreement with theoretical considerations all three approaches converge to the same ocean circulation estimate when using the same observations and prior information. However, the rate of convergence of the dual formulation was found to be inferior to that of the primal formulation. Other aspects of the 4D-Var performance that relate to the use of multiple outer-loops, preconditioning, and the weak constraint are also explored. A systematic evaluation of the impact of the various components of the 4D-Var control vector (i.e. the initial conditions, surface forcing and open boundary conditions) is also presented. It is shown that correcting for uncertainties in the model initial conditions exerts the largest influence on the ability of the model to fit the available observations. Various important diagnostics of 4D-Var are also examined, including estimates of the posterior error, the information content of the observation array, and innovation-based consistency checks on the prior error assumptions. Using these diagnostic tools, we find that more than 90% of the observations assimilated into the model provide redundant information. This is a symptom of the large percentage of satellite data that are used and to some extent the nature of the data processing employed. This is the second in a series of three papers describing the ROMS 4D-Var systems.