273.15 到 308.15 K下二元体系（LiCl-H2O 和 MgCl2-H2O）和三元体系（LiCl-MgCl2-H2O）的体积性质研究

用高精度振动管在 273.15 至 308.15 K 的温度范围内以 5 K 的间隔对两个二元系统（LiCl-H2O 和 MgCl2-H2O）和三元系统（LiCl-MgCl2-H2O）的密度进行了实验测定密度计。基于 Vogel-Fulcher-Tamman (VFT) 方程,对 LiCl(aq) 和 MgCl2(aq) 密度与温度和摩尔浓度的相关方程的系数进行了参数化。 Young的理想混合规则被成功地应用于基于相关的二元解性质关联三元系统的密度。根据二元和三元体系的体积特性数据,根据 Pitzer 离子相互作用理论,得到 Pitzer 单盐参数和混合离子相互作用参数。在本工作中确定了三元体系在恒定离子强度下的混合体积 (ΔVm)。     

砒砂岩区地貌形态三维分形特征量化及空间变异

针对现有地貌形态三维分形模型结构存在的不足,构建一个新的地貌形态三维分形维数测算模型。基于该模型对砒砂岩区274个小流域的地貌形态三维分形维数进行计算并分析其空间变异规律。研究表明：① 基于该模型计算的分形维数能更准确地反映地貌形态复杂度信息;② 砒砂岩区小流域地貌形态三维分形维数介于1.683 6~1.948 6之间;③ 地貌形态三维分形维数整体上覆土砒砂岩区（均值为1.765 9）<裸露砒砂岩强度侵蚀区（均值为1.785 4）和剧烈侵蚀区（均值为1.774 8）<覆沙砒砂岩区（均值为1.796 6）。由于地表覆盖物、砒砂岩裸露程度和土壤侵蚀机理的差异而形成的不同地貌特征是该区地貌形态分形特征空间变异的主要原因。     

深圳农民工集聚空间的演变特征及影响机制

以2000年、2010年人口普查数据和2008年珠江三角洲外来农民工问卷调查为基础数据,以街道为单元,运用数理统计分析和GIS空间技术揭示深圳农民工集聚空间演变特征及其影响机制。研究发现：① 深圳农民工以青年为主体,具有受教育水平高、职业转型模式多样、留城意愿较低和社会空间分异度较高等特征。② 农民工规模呈现西北部最高、中部其次、沿海最低的地带性分布规律,农民工高密度地区主要分布在工业集中区和城市中心区;热点区（高聚集区）集中在西部和北部的宝安区和龙华新区,冷点区（低聚集区）则分布在南部的中心城区,与传统制造业布局相一致。③ 农民工空间演化格局相对稳定,全市农民工分布重心逐步向西北偏移;全市农民工集中度略有上升,热点区基本稳定,冷点区有所扩大;农民工人口密度高值由“1个高中心+1个外围中心”逐步演变为“1个高中心+2个外围中心”;农民工空间变化差异较大,增长演变类型呈多样化。④ 深圳农民工分布的时空演变特征与常住人口存在较为明显的差异。⑤ 农民工集聚空间的分布演变受住房因素、就业机会、交通条件、社会网络、城市规划共同影响。     

Degrading river network due to urbanization in Yangtze River Delta

Evolution of river systems under the background of human activities has been a heated topic among geographers and hydrologists. Spatial and temporal variations of river systems during the 1960s–2010s in the Yangtze River Delta (YRD) were investigated based on streams derived from the topographic maps in the 1960s, 1980s and 2010s. A list of indices, drainage density (Dd), water surface ratio (WSR), ratio of area to length of main streams (R), evolution coefficient of tributaries (K) and box dimension (D), were classified into three types (quantitative, structural, and complex indices) and used to quantify the variations of stream structure. Results showed that: (1) quantitative indices (Dd, WSR) presented decreasing trend in the past 50 years, and Dd in Wuchengxiyu, Hangjiahu and Yindongnan have decreased most, about 20%. Structurally, the Qinhuai River basin was characterized by significant upward R, and K value in Hangjiahu went down dramatically by 46.8% during the 1960s–2010s. Decreasing tendency in D was found dominating across the YRD, and decreasing magnitude in Wuchengxiyu and Hangjiahu peaks for 7.8% and 6.5%, respectively in the YRD. (2) Urbanization affected the spatial pattern of river system, and areas with high level of urbanization exhibited least Dd (2.18 km/km²), WSR (6.52%), K (2.64) and D (1.42), compared to moderate and low levels of urbanization. (3) Urbanization also affected the evolution of stream system. In the past 50 years, areas with high level of urbanization showed compelling decreasing tendency in quantitative (27.2% and 19.3%) and complex indices (4.9%) and trend of enlarging of main rivers (4.5% and 7.9% in periods of the 1960s–1980s and the 1980s–2010s). In the recent 30 years, areas with low level of urbanization were detected with significant downward trend in Dd and K. (4) Expanding of urban land, construction of hydraulic engineering and irrigation and water conservancy activities were the main means which degraded the river system in the YRD.     

Construction and progress of Chinese terrestrial ecosystem carbon,nitrogen and water fluxes coordinated observation

Eddy Covariance technique (EC) achieves the direct measurement on ecosystem carbon, nitrogen and water fluxes, and it provides scientific data for accurately assessing ecosystem functions in mitigating global climate change. This paper briefly reviewed the construction and development of Chinese terrestrial ecosystem flux observation and research network (ChinaFLUX), and systematically introduced the design principle and technology of the terrestrial ecosystem carbon, nitrogen and water fluxes coordinated observation system of ChinaFLUX. In addition, this paper summarized the main progress of ChinaFLUX in the ecosystem carbon, nitrogen and water exchange and environmental controlling mechanisms, the spatial pattern of carbon, nitrogen and water fluxes and biogeographical mechanisms, and the regional terrestrial ecosystem carbon budget assessment. Finally, the prospects and emphases of the terrestrial ecosystem carbon, nitrogen and water fluxes coordinated observation of ChinaFLUX are put forward to provide theoretical references for the development of flux observation and research in China.     

Progress in China’s sustainable development research: Contribution of Chinese geographers

Sustainable development has always been a hotspot in Chinese geographical research. Herein, we conduct a systematic statistical analysis of the contribution of Chinese geographers to sustainable development research using bibliometric methods. Based on the review of a vast amount of literature, we identify the main research teams, research funding sources, journals, and key research fields. The findings are as follows: (1) the resources and environmental institutes of the Chinese Academy of Sciences have a significant influence on sustainable development research; (2) China’s central government foundations (the National Natural Science Foundation of China and National Social Sciences Fund) are the main research funding sources; (3) most of the highly cited articles are published in journals sponsored by the Geographical Society of China; and (4) sustainable development theory and its research areas are being constantly enriched and perfected. Based on the statistics of keywords, the theory, research methods, research regional scales, and key research areas are summarized and expounded.     

Extracting urban areas in China using DMSP/OLS nighttime light data integrated with biophysical composition information

DMSP/OLS nighttime light (NTL) image is a widely used data source for urbanization studies. Although OLS NTL data are able to map nighttime luminosity, the identification accuracy of distribution of urban areas (UAD) is limited by the overestimation of the lit areas resulting from the coarse spatial resolution. In view of geographical condition, we integrate NTL with Biophysical Composition Index (BCI) and propose a new spectral index, the BCI Assisted NTL Index (BANI) to capture UAD. Comparisons between BANI approach and NDVI-assisted SVM classification are carried out using UAD extracted from Landsat TM/ETM+ data as reference. Results show that BANI is capable of improving the accuracy of UAD extraction using NTL data. The average overall accuracy (OA) and Kappa coefficient of sample cities increased from 88.53% to 95.10% and from 0.56 to 0.84, respectively. Moreover, with regard to cities with more mixed land covers, the accuracy of extraction results is high and the improvement is obvious. For other cities, the accuracy also increased to varying degrees. Hence, BANI approach could achieve better UAD extraction results compared with NDVI-assisted SVM method, suggesting that the proposed method is a reliable alternative method for a large-scale urbanization study in China’s mainland.     

中国交通CO2排放时空格局演变及其影响因素——基于2000~2012年30个省（市）面板数据的分析

通过构建交通CO₂排放模型对2000~2012年中国30个省（市）的交通CO₂排放时空演变特征进行了分析。并采取“由大到小”逐步回归的建模方式,在传统的固定效应模型（面板数据模型）基础上引入时间固定效应,构建了双向固定效应模型对中国交通CO₂排放的社会经济、城市形态、交通发展等方面的影响因素进行研究。结果表明：2000~2012年期间,中国交通CO₂排放总量和人均交通CO₂排放量分别以9.29%和8.69%的年均增速增长,前者的区域差异呈先增后减趋势,后者的区域差异则首先呈周期性波动,而后一直保持减少趋势。人均GDP和城镇居民家庭人均可支配收入对人均交通CO₂排放具有显著的正向效应,表明社会经济发展和居民收入水平提高是交通CO₂排放增长的主要驱动因素。城市人口密度对交通CO₂排放亦具有显著的正向效应,这意味着未来中国应加强对城市人口密度的规划控制,以避免因人口过度集聚而额外增加产生交通CO₂排放。公共交通发展水平对交通CO₂排放增长具有显著的负向效应,但小汽车拥有率对交通CO₂排放的影响并不显著。     

湖北郧县辽瓦店黄土剖面风化特征及其对气候变化的响应

对湖北郧县辽瓦店剖面的沉积学特征及磁化率、粒度、Rb、Sr含量等理化指标进行了研究。结果表明:辽瓦店剖面自下而上具有马兰黄土(L₁)-过渡层(L_t)-古土壤(S₀)-全新世黄土(L₀)-表土(TS)地层序列;不同地层单元的风化成壤差异明显,其成壤强弱顺序为古土壤S₀成壤最强、全新世黄土L₀和过渡层L_t次之、马兰黄土L₁最弱。成壤强弱的变化揭示出该区晚更新世末期(11 500 a BP以前)气候干冷,全新世早期(11 500~8 500 a BP)气候处于晚更新世干冷向全新世中期暖湿的过渡阶段,全新世中期(8 500~3 100 a BP)气候最为温暖湿润,全新世晚期(3 100 a BP以来)气候转为干冷且逐渐恶化的变化过程。     

常量元素氧化物含量及其比值揭示的中晚全新世以来玛曲高原的环境演变

对玛曲高原具有代表性的黄土-古土壤-风成砂剖面(OL剖面)常量元素氧化物含量及其比值的地球化学特征分析表明:(1)常量元素氧化物总含量为91.93%且SiO₂(67.93%) >Al₂O₃(11.2%) >Fe₂O₃(3.97%) >CaO(3.76%)>K₂O(2.16%) >Na₂O(1.81%) >MgO(1.1%);(2)玛曲高原处于较弱的脱Ca、Na初级风化阶段,并伴有碳酸盐的淋失;(3)玛曲高原的气候经历了冷干-凉润-温湿-凉干的冷暖旋回。依据常量元素氧化物含量及其比值揭示的环境特征并结合¹⁴C测年将玛曲高原中晚全新世以来的环境演变划分为4.6 ka BP以前的风沙活动强烈期、4.6～4.3 ka BP的风沙活动较弱期、4.3～0.3 ka BP的固结成壤期和0.3 ka BP至今的风沙活动增强期4个阶段。