Structure of the Fram Strait branch of the boundary current in the Eurasian Basin of the Arctic Ocean

Recent mooring-based observations at several locations along the continental slope of the Arctic Ocean's Eurasian Basin showed a transformation of the Boundary Current (BC) from a mostly barotropic flow in Fram Strait to a jet-like baroclinic current northeast of Svalbard, and the reemergence of the barotropic structure of the flow in the eastern Eurasian Basin. This transformation is accompanied by a weakening of the flow from ～24 cm/s in Fram Strait to ～5 cm/s at the Lomonosov Ridge. The maximum of the baroclinic component of the BC at an intermediate depth (～200–370 m) is associated with the Atlantic Water core. The depth range of the baroclinic current maximum is controlled by cross-slope density gradients above and below the baroclinic velocity maximum as follows from the geostrophic balance of forces. According to the model simulations, the BC splits into shallow and deep branches in the proximity of Svalbard due to a divergence of isobaths, confirming topographically-controlled BC behavior. The shallow branch is located at a shelf break with a typical bottom depth of ～200 m and current speed of up to ～24 cm/s. The discussed results, which provide insight on some basic aspects of the dynamics of the BC (the major oceanic heat source for the Arctic Ocean), may be of importance for understanding of the ocean's role in shaping the arctic climate system state.     

Structural evolutions of an obsidian and its fused glass by shock-wave compression

Shock-recovery experiments for obsidian and its fused glass have been carried out with pressure up to 35 GPa. Structural evolution accompanying the shock compression was investigated using X-ray diffraction technique, Raman and infrared spectroscopy. The densities of obsidian and its fused glass increased with applied shock pressure up to 25 GPa. Densification reached a maximum of 4.7 and 3.6% for obsidian and its fused glass, respectively. The densification mechanism is attributed to reduction of the T–O–T angle, and changes in ring statistics in the structure. Density reduction observed at greater than 25 GPa of applied shock pressure is due to partial annealing of the high-density glass structures brought by high post-shock residual temperature. The density of fused glass is almost equal to its original value at 35 GPa while the shocked obsidian has a slightly lower value than its original value. Amorphization of crystallites present in the obsidian due to shock compression is probably the cause of the density decrease. The structural evolution observed in shock-compressed obsidian and its fused glass can be explained by densification resulting from average T–O–T angle reduction and increase of small rings, and subsequent structural relaxation by high post-shock temperature at applied shock compression above 25 GPa.     

Hydrochemical and isotopic evidence of recharge,apparent age,and flow direction of groundwater in Mayo Tsanaga River Basin,Cameroon: bearings on contamination

Unplanned exploitation of groundwater constitutes emerging water-related threats to MayoTsanaga River Basin. Shallow groundwater from crystalline and detrital sediment aquifers, together with rain, dams, springs, and rivers were chemically and isotopically investigated to appraise its evolution, recharge source and mechanisms, flow direction, and age which were used to evaluate the groundwater susceptibility to contamination and the basin’s stage of salinization. The groundwater which is Ca–Na–HCO₃ type is a chemically evolved equivalent of surface waters and rain water with Ca–Mg–Cl–SO₄ chemistry. The monsoon rain recharged the groundwater preferentially at an average rate of 74 mm/year, while surface waters recharge upon evaporation. Altitude effect of rain and springs show a similar variation of −0.4‰ for δ¹⁸O/100 m, but the springs which were recharged at 452, 679, and 773 m asl show enrichment of δ¹⁸O through evaporation by 0.8‰ corresponding to 3% of water loss during recharge. The groundwater which shows both local and regional flow regimes gets older towards the basins` margin with coeval enrichment in F⁻ and depletion in NO₃ ⁻. Incidentally, younger groundwaters are susceptible to anthropogenic contamination and older groundwaters are sinks of lithologenic fluoride. The basins salinization is still at an early stage.     

On the Complete System of Integrals in Celestial Mechanics

A partially translative one-parameter continuous transformation group is derived, and used in order to get the system of integrals of celestial mechanics.     

Organizations and the interior characteristics of winter monsoon clouds by dual-polarization Doppler radar observation in Hokuriku, Japan

To understand the characteristics of winter monsoon clouds, dual-polarization Doppler radar observations were carried out at Mihama, Hokuriku, Japan. A series of organized disturbances associated with the passage of a cyclonic circulation was analyzed. The following scenario was proposed. Environmental circumstances, for example, temperature and wind profiles, surface heat and moisture fluxes, etc., determine the organizational style of mesoscale convections. This organization regulates the convection interior flow pattern including the location and intensity of updrafts. Subsequently, it influences interior microphysical properties, for example, the types of precipitation particles, their growth and distributions, their electrification, etc. In this paper, an observational example following this scenario is presented.     

Symmetropy of earthquake patterns: asymmetry and rotation in a disordered seismic source

We demonstrate that the idea of symmetropy can be used for quantification of earthquake patterns. The symmetropy can be considered as a measure of asymmetry. A pattern is richer in asymmetry when the symmetropy is smaller. The specific results of its applications are obtained as follows. In a discrete model of a seismic source with self-organized criticality, the spatial patterns of earthquakes during critical states and sub-critical states are distinguished by the behaviour of the symmetropy: sub-critical patterns show that the symmetropy is approximately a constant but this has various values during critical states. The critical patterns show asymmetric property without any asymmetric force from the outside and without asymmetric intracellular rule. We show that the emergence of asymmetric patterns is a generic feature of dynamic ruptures in our model. Such a generic asymmetry results from the model which is an inherently discrete system consisting of finite-sized cells. These cells may represent geometrical disordered fault zones. We further discuss rotational motions that generate seismic rotational waves. In micromorphic continuum theory, such rotations are attributed to dynamic ruptures in disordered systems. We note that the concept of disorder in this theory is expressed by a set of finite-sized microstructures and is consistent with the concept of disorder modelled in the present study. Thus, we suggest that the spatially asymmetric patterns of earthquakes might be related to the rotational motions, because both come from dynamic ruptures in a discrete fault zone without a well-defined continuum limit.     

High pressure infrared spectra of diaplectic anorthite glass

Samples of synthetic diaplectic anorthite glass (38 GPa shock pressure), thermal glass and synthetic anorthite crystals were investigated using infrared spectral methods at one atmosphere and high pressures (near 4 GPa). Band positions and pressure derivatives for the Si-O asymmetric modes in the region 1,300–900 cm^?1 indicate that the diaplectic glass has more structural similarities with the crystalline material than with thermal glass even though the overall infrared spectral characteristics suggest a glassy state.     

Predominant hosting lead(II) in ternary mixtures of heavy metal ions by a novel of diethylaminomethyl-calix[4]resorcinarene

Heavy metal ions from single and ternary systems of Pb(II), Cu(II), and Ni(II) adsorbed by calix[4]resorcinarenes in water–chloroform extraction were studied. Comparison was made of calix[4]resorcinarenes, 2,8,14,20-tetraundecyl calix[4]resorcinarene-4,6,10,12,16,18,22,24-octol, and diethylaminomethyl-calix[4]resorcinarene, 5,11,17,23-tetra(diethylaminomethyl)-2,8,14,20- tetraundecylcalix[4]resorcinarene-4,6,10,12,16,18,22,24-octol, for predominant extraction of their ions from the ternary mixture of aqueous solution at different pH in a water layer. The hosting of Pb(II) by the diethylaminomethyl-calix[4]resorcinarene occurred efficiently at pH 6–7. The hosting of Pb(II), Cu(II), and Ni(II) ions for the ternary aqueous mixture was applied to the Langmuir isotherm. Adsorption was studied using nuclear magnetic resonance spectroscopy in a water–deuterium chloroform extraction system. Results showed that as the heavy metal ions were included into the host cavity, the observation of shifted peaks of water molecules from downfield to higher field was visible in the nuclear magnetic resonance spectra, meaning that water molecules were included with heavy metal ion into the host cavity. The spectra also showed that the diethylamino group expressed formation of the coordination complex between the diethylaminomethyl-calix[4]resorcinarene and Pb(II) for the purpose of predominant hosting of Pb(II).     

Formative conditions and sedimentary structures of sandy 3D antidunes: an application of the gravel step‐pool model to fine‐grained sand in an experimental flume

Antidunes and their sedimentary structures can be useful in reconstructing paleo‐hydraulic conditions, especially for large discharge events. However, three‐dimensional (3D) antidunes in sand‐sized sediments have not yet been studied extensively, as compared to either two‐dimensional (2D) antidunes or antidunes in gravel‐sized sediments. In this study, we estimated formative conditions of gravel step‐pool morphologies and applied them to the formation of 3D antidunes over a sand bed. Formative conditions are expressed in terms of a relationship between the water discharge per unit width and the bed slope. Flume experiments demonstrated that 3D mound‐like antidune configurations and their associated internal sedimentary structures could be preserved. Internal sedimentary structures were characterized by shallow lens‐like structures whose bases were erosional. Although gently‐dipping concave‐upward lamination was dominant, convex‐upward lamination was occasionally observed. The dimensions of lenticular lamina‐sets can be used to estimate antidune geometry. Thus if 3D antidunes can be interpreted in the stratigraphic record, it is possible to estimate the paleo‐hydraulic parameters such as water discharge and bed slope more precisely than previously. Copyright © 2010 John Wiley & Sons, Ltd.     

Vertical heat transfer based on direct microstructure measurements in the ice-free Pacific-side Arctic Ocean: the role and impact of the Pacific water intrusion

This study quantifies diapycnal mixing and vertical heat transfer in the Pacific side of the Arctic Ocean, where sea-ice cover has disappeared between July and September in the last few decades. We conducted microstructure measurements in the open water region around the Canada Basin from late summer to fall in 2009 and 2010 using R/V Mirai. In the study domain, the dissipation rate of turbulent kinetic energy, ε, is typically as low level as O(10^?10) W kg^?1, resulting in vertical heat diffusivity of O(10^?7) m² s^?1, which is close to the molecular diffusivity of heat, suggesting comparatively little predominance of mechanical turbulent mixing. An exception is the case at the Barrow Canyon, where the strong baroclinic throughflow generates substantial vertical mixing, producing ε > O(10^?7) W kg^?1, because of the shear flow instability. Meanwhile, in the confluence region, where the warm/salty Pacific water and the cold/fresh Arctic basin water encounter, the micro-temperature profiles revealed a localized enhancement in vertical diffusivity of heat, reaching O(10^?5) m² s^?1 or greater. In this region, an intrusion of warm Pacific water creates a horizontally interleaved structure, where the double-diffusive mixing facilitates vertical heat transfer between the intruding Pacific water and the surrounding basin waters.