Pilot-scale field model tests for detecting landfill leachate intrusion into the subsurface using a grid-net electrical conductivity measurement system

The grid-net electrical conductivity measurement system for detecting exact locations of landfill leachate intrusion in the subsurface was developed in this study. Laboratory and pilot-scale field model tests were performed to evaluate the direct application of a grid-net electrical conductivity measurement system for the detection of landfill leachate. A significant increase in electrical conductivity of soil was observed by adding landfill leachate. This can be explained as an increase in electrical conductivity of pore fluid due to an increase in leachate constituents as charge carriers. In pilot-scale field model tests, leachate intrusion locations were accurately identified at the initial stage of landfill leachate release by the grid-net electrical conductivity measurement system. The electrical conductivity of the subsurface before leachate injection lay within a small range of 24.8–43.0 S/cm. The electrical conductivity values in detected points were approximately ten times more than the conductivity values of the subsurface without landfill leachate intrusion. The results in this study indicate that the grid-net electrical conductivity measurement method has a possible application for detecting locations of landfill leachate intrusion into the subsurface at the initial stage, and thus has great potential in monitoring leachate leakage at waste landfills.     

Evaluation of multiphase flotation models in grid turbulence via Particle Image Velocimetry

Industrial processes involving multi-phase flows such as flotation require understanding of the relationships between bubbles, solid particles and the flow. Modern experimental tools are employed in this effort to measure with great accuracy the basic features of the motion of all three phases in turbulent flow. We employed a unique Digital Particle Image Velocimeter (DPIV) that can record with great accuracy and kHz temporal resolution, velocity vectors of all three phases, namely the fluid, the solid particles and the air bubbles. The interaction of these three phases was studied in homogeneous isotropic turbulence generated by cylindrical grids. Particles and bubbles were released into the turbulence and the motions of the three phases were monitored. The experimental results obtained in the present work were compared with the predictions of the models published in the literature.     

The collectorless flotation of chalcopyrite ores using sodium sulfide

The collectorless flotation process has been tested on six different chalcopyrite ores while monitoring the potentials ($\text{E}{}_{\mathrm{<mtext>h</mtext>}}$) of the pulp. The results show that collectorless flotation is effective only under oxidizing conditions. In addition, the flotation requires that the chalcopyrite surface be relatively free of hydrophilic oxidation products, which can be accomplished by treating the ore pulp with sodium sulfide (Na₂S). On the basis of these findings, methods of improving the collectorless flotation process are discussed.     

Postglacial marine environmental changes in Maxwell Bay, King George Island, West Antarctica

Sediment textural properties and total organic carbon (TOC) contents of three sediment cores from Maxwell Bay, King George Island, West Antarctica, record changes in Holocene glaciomarine sedimentary environments. The lower sedimentary unit is mostly composed of TOC-poor diamictons, indicating advanced coastal glacier margins and rapid iceberg discharge in proximal glaciomarine settings with limited productivity and meltwater supply. Fine-grained, TOC-rich sediments in the upper lithologic unit suggest more open water and warm conditions, leading to enhanced biological productivity due to increased nutrient-rich meltwater supply into the bay. The relationship between TOC and total sulfur (TS) indicates that the additional sulfur within the sediment has not originated from in situ pyrite formation under the reducing condition, but rather may be attributed to the detrital supply of sand-sized pyrite from the hydrothermal-origin, quartz-pyrite rocks widely distributed in King George Island. The evolution of bottom-water hydrography after deglaciation was recorded in the benthic foraminiferal stable-isotopic composition, corroborated by the TOC and lithologic changes. The ع⁸O values indicate that bottom-water in Maxwell Bay was probably mixed gradually with intruding ¹⁸O-rich seawater from Bransfield Strait. In addition, the ع³C values reflect a spatial variability in the carbon isotope distribution in Maxwell Bay, depending on marine productivity as well as terrestrial carbon fluxes by meltwater discharge. The distinct lithologic transition, dated to approximately 8000 yr BP (uncorrected) and characterized by textural and geochemical contrasts, highlights the postglacial environmental change by a major coastal glacier retreat in Maxwell Bay.     

Investigating the Effects of Different LED Wavelengths on Aggregation and Swimming Behavior of Chub Mackerel (Scomber japonicus)

Ocean Science Journal - Efficient fish aggregation systems are essential for catching chub mackerel (Scomber japonicus), which is a major target of purse seine fisheries in South Korea. To aid the...     

Stabilization of arsenic-contaminated mine tailings using natural and calcined oyster shells

Natural oyster shells (NOS) and calcined oyster shells (COS) were used to immobilize arsenic (As) from contaminated mine tailings. In addition, a blend of Portland cement (PC)/cement kiln dust (CKD) was used as a stabilizing agent. The Korean Standard Test (KST) method (1 N HCl extraction) was used to evaluate the effectiveness of the treatment. The experimental results showed that COS effectively immobilized As in treated mine tailings. Specifically, an As concentration less than 1 mg L⁻¹ was obtained following COS treatment at 25 and 30 wt%. However, all the samples subjected to NOS treatments failed the Korean warning standard of 1.2 mg L⁻¹ after 28 days of curing. All of the COS-PC treatments were successful meeting the Korean warning standard after 7 days of curing. However, the PC-only treatment failed to meet the Korean warning standard. Similarly, the CKD-only treatment was failed to meet the Korean warning standard after 7 days of curing. However, the COS-CKD treatment showed that when the COS content was greater than 20 wt%, less than 1 mg L⁻¹ of As leachability was obtained. Scanning electron microscopy–energy dispersive X-ray spectroscopy (SEM–EDX) showed needle-like and torpedo-like Ca–As phases in the COS-treated samples suggesting that As was strongly associated with Ca and O. X-ray absorption near edge structure (XANES) analyses confirmed that As(V) was prevalent in the tailings and that there were no changes in As speciation following NOS or COS treatment.     

Interbed Modeling to Predict Wellbore Damage for Big Hill Strategic Petroleum Reserve

Oil leaks were found in wellbores of Caverns 105 and 109 at the Big Hill Strategic Petroleum Reserve site. According to the field observations, two instances of casing damage occurred at the depth of the interbed between the caprock bottom and salt top. A three-dimensional finite element model, which allows each cavern to be configured individually, was constructed to investigate horizontal and vertical displacements in each well as it crosses the various interbeds. The model contains interfaces between each lithology and a shear zone (fault) to examine the interbed behavior in a realistic manner. This analysis results indicate that the casings of Caverns 105 and 109 failed, respectively, from shear stress that exceeded the casing shear strength due to the horizontal movement of the salt top relative to the caprock and tensile stress due to the downward movement of the salt top from the caprock. The wellbores of Caverns 114 and 104, located at the far end of the field and near the fault, respectively, are predicted to fail by shear stress in the near future. The wellbores of inmost Caverns 107 and 108 are predicted to fail by tensile stress in the near future. The salt top subsides because the volumes of caverns in the salt dome decrease with time due to salt creep closure, while the caprock does not subside at the same rate as the salt top because the caprock is thick and stiff. This discrepancy yields deformation of the well.