Numerical analysis of canister movements in an engineered barrier system

The mid-term safety of deep geological nuclear waste repositories is based in part on the presence of a buffer, the main role of which is to isolate the environment from radionuclides. A design evaluation of such a repository is necessary to assess the potential vertical canister movement inside the drift that could reduce the buffer efficiency. A thermo-hydro-mechanical (THM) simulation is performed in a vertical cross-section of the drift. The THM couplings are described, and their influences on the mid-term (300 years) response of the engineered barrier system (EBS) are revealed. This study uses an advanced constitutive model to simulate the THM processes that occur in a specific EBS design case. The near-field simulations of the nuclear waste canister are performed in a two-dimensional finite element configuration that considers the effect of gravity. The focus of this study is on the mechanical behaviour of the buffer, which consists of two different forms of bentonite. Such an approach allows realistic consideration of the effect of the wetting and drying of the buffer material in non-isothermal conditions. Due to a specific design that includes bentonite blocks and pellets, the canister is observed to heave slightly during the re-saturation period, which extends up to 100 years.     

Morphological controls on the dynamics of carbonate landscapes under a mediterranean climate

The influence of the morphological setting on the denudation of carbonate landscapes and the respective contributions of mechanical and chemical weathering processes are still debated. We have addressed these questions by measuring ³⁶Cl concentrations in 40 samples from the Luberon mountain, SE France, to constrain the denudation of various landscape elements. We observe a clear contrast between the local denudation rates from the flat summit surface, clustered around 30 mm/ka, and the basin‐average denudation rates across the flanks, ranging from 100 to 200 mm/ka. This difference highlights the transient evolution of the range, whose topography is still adjusting to previous uplift events. Such a pattern also suggests that carbonate dissolution is not the only driver of denudation in this setting, which appears to be significantly controlled by slope‐dependent processes.     

Comparison of tropical cyclogenesis indices on seasonal to interannual timescales

This paper evaluates the performances of four cyclogenesis indices against observed tropical cyclone genesis on a global scale over the period 1979–2001. These indices are: the Genesis Potential Index; the Yearly Genesis Parameter; the Modified Yearly Convective Genesis Potential Index; and the Tippett et al. Index (J Clim, 2011), hereafter referred to as TCS. Choosing ERA40, NCEP2, NCEP or JRA25 reanalysis to calculate these indices can yield regional differences but overall does not change the main conclusions arising from this study. By contrast, differences between indices are large and vary depending on the regions and on the timescales considered. All indices except the TCS show an equatorward bias in mean cyclogenesis, especially in the northern hemisphere where this bias can reach 5°. Mean simulated genesis numbers for all indices exhibit large regional discrepancies, which can commonly reach up to ±50%. For the seasonal timescales on which the indices are historically fitted, performances also vary widely in terms of amplitude although in general they all reproduce the cyclogenesis seasonality adequately. At the seasonal scale, the TCS seems to be the best fitted index overall. The most striking feature at interannual scales is the inability of all indices to reproduce the observed cyclogenesis amplitude. The indices also lack the ability to reproduce the general interannual phase variability, but they do, however, acceptably reproduce the phase variability linked to El Ni?o/Southern Oscillation (ENSO)—a major driver of tropical cyclones interannual variations. In terms of cyclogenesis mechanisms that can be inferred from the analysis of the index terms, there are wide variations from one index to another at seasonal and interannual timescales and caution is advised when using these terms from one index only. They do, however, show a very good coherence at ENSO scale thus inspiring confidence in the mechanism interpretations that can be obtained by the use of any index. Finally, part of the gap between the observed and simulated cyclogenesis amplitudes may be attributable to stochastic processes, which cannot be inferred from environmental indices that only represent a potential for cyclogenesis.     

Surface chemistry and reactivity of plant phytoliths in aqueous solutions

In order to better understand the reactivity of plant phytoliths in soil solutions, we determined the solubility, surface properties (electrophoretic mobilities and surface charge) and dissolution kinetics of phytoliths extracted from fresh biomass of representative plant species (larch tree and elm, horsetail, fern, and four grasses) containing significant amount of biogenic silica. The solubility product of larch, horsetail, elm and fern phytoliths is close to that of amorphous silica and soil bamboo phytoliths. Electrophoretic measurements yield isoelectric point pH_IEP = 0.9, 1.1, 2.0 and 2.2 for four grasses, elm, larch and horsetail phytoliths respectively, which is very close to that of quartz or amorphous silica. Surface acid–base titrations allowed generation of a 2-pK surface complexation model (SCM) for larch, elm and horsetail phytoliths. Phytoliths dissolution rates, measured in mixed-flow reactors at far from equilibrium conditions at 1 ≤ pH ≤ 8, were found to be very similar among the species, and close to those of soil bamboo phytoliths. Mechanistic treatment of all plant phytoliths dissolution rates provided three-parameters equation sufficient to describe phytoliths reactivity in aqueous solutions:$R(\text{mol}/{\text{cm}}^2/\text{s})=6?{10}^{?16}?a_{\text{H+}}+5.0?{10}^{?18}+3.5?{10}^{?13}?a_{\text{OH}?}^{0.33}$Alternatively, the dissolution rate dependence on pH can be modeled within the concept of surface coordination theory assuming the rate proportional to concentration of > SiOH₂⁺, > SiOH⁰ and > SiO^? species. In the range of Al concentration from 20 to 5000 ppm in the phytoliths, we have not observed any correlation between their Al content and solubility, surface acid–base properties and dissolution kinetics.It follows from the results of this study that phytoliths dissolution rates exhibit a minimum at pH ～ 3. Mass-normalized dissolution rates are similar among all four types of plant species studied and these rates are an order of magnitude higher than those of typical soil clay minerals. The minimal half life time of larch and horsetail phytoliths in the interstitial soil solution ranges from 10–12 years at pH = 2–3 to < 1 year at pH above 6, comparable with mean residence time of phytoliths in soil from natural observations.     

Nonlinear Formulation of the Bulk Surface Stress over Breaking Waves: Feedback Mechanisms from Air-flow Separation

Historically, our understanding of the air-sea surface stress has been derived from engineering studies of turbulent flows over flat solid surfaces, and more recently, over rigid complex geometries. Over the ocean however, the presence of a free, deformable, moving surface gives rise to a more complicated drag formulation. In fact, within the constant-stress turbulent atmospheric boundary layer over the ocean, the total air-sea stress not only includes the traditional turbulent and viscous components but also incorporates surface-wave effects such as wave growth or decay, air-flow separation, and surface separation in the form of sea-spray droplets. Because each individual stress component depends on and alters the sea state, a simple linear addition of all stress components is too simplistic. In this paper we present a model of the air-sea surface stress that incorporates air-flow separation and its effects on the other stress components, such as a reduction of the surface viscous stress in the separated region as suggested by recent measurements. Naturally, the inclusion of these effects leads to a non-linear stress formulation. This model, which uses a variable normalized dissipation rate of breaking waves and normalized length of the separation bubble, reproduces the observed features of the drag coefficient from low to high wind speeds despite extrapolating empirical wave spectra and breaking wave statistics beyond known limits. The model shows the saturation of the drag coefficient at high wind speeds for both field and laboratory fetches, suggesting that air-flow separation over ocean waves and its accompanying effects may play a significant role in the physics of the air-sea stress, at least at high wind speeds.     

Multi-imaging and Bayesian estimation for photon counting with EMCCDs

A multi-imaging strategy is proposed and experimentally tested to improve the accuracy of photon counting with an electron multiplying CCD (EMCCD), by taking into account the random nature of its on-chip gain and the possibility of multiple photodetection events on one pixel. This strategy is based on Bayesian estimation on each image, with a priori information given by the sum of the images. The method works even for images with large dynamic range, with more improvement in the low light level areas. In these areas, two thirds of the variance added by the EMCCD in a conventional imaging mode are removed, making the physical photon noise predominant in the detected image.     

Upper-mantle flow beneath French Polynesia from shear wave splitting

Upper-mantle flow beneath the South Pacific is investigated by analysing shear wave splitting parameters at eight permanent long-period and broad-band seismic stations and 10 broad-band stations deployed in French Polynesia from 2001 to 2005 in the framework of the Polynesian Lithosphere and Upper Mantle Experiment (PLUME). Despite the small number of events and the rather poor backazimuthal coverage due to the geographical distribution of the natural seismicity, upper-mantle seismic anisotropy has been detected at all stations except at Tahiti where two permanent stations with 15 yr of data show an apparent isotropy. The median value of fast polarization azimuths (N67.5°W) is parallel to the present Pacific absolute plate motion direction in French Polynesia (APM: N67°W). This suggests that the observed SKS fast polarization directions result mainly from olivine crystal preferred orientations produced by deformation in the sublithospheric mantle due to viscous entrainment by the moving Pacific Plate and preserved in the lithosphere as the plate cools. However, analysis of individual measurements highlights variations of splitting parameters with event backazimuth that imply an actual upper-mantle structure more complex than a single anisotropic layer with horizontal fast axis. A forward approach shows that a two-layer structure of anisotropy beneath French Polynesia better explains the splitting observations than a single anisotropic layer. Second-order variations in the measurements may also indicate the presence of small-scale lateral heterogeneities. The influence of plumes or fracture zones within the studied area does not appear to dominate the large-scale anisotropy pattern but may explain these second-order splitting variations across the network.     

Relative current effect on short wave growth

Ocean Dynamics - Short waves growth is characterized by nonlinear and dynamic processes that couple ocean and atmosphere. Ocean surface currents can have a strong impact on short wave steepness and...     

Reinterpretation of an archaeological pebble culture from the Middle Mekong River valley,Cambodia

In 1963, E. Saurin and J.‐P. Carbonnel discovered the Sre Sbov site on an alluvial terrace of the Mekong River in central Cambodia. Saurin described a lithic typology dating to the Lower/Middle Pleistocene from this site. Although the original lithic assemblage has been lost, this typology has been used continuously as a reference by Southeast Asian prehistorians. In 2007, a Khmer–French team conducted excavations at Sre Sbov that yielded numerous pebbles and cobbles showing apparently convincing handmade removals, as Saurin had previously described. However, an in‐depth study of this assemblage, combined with a geological survey of the area, led to the conclusion that the stones were, in fact, of natural origin, and that for this reason their typology should be disregarded. Using satellite imagery and geological surveys, we explain how such a misinterpretation may have occurred and define a “buffer zone,” corresponding to the maximal extent of the proto‐Mekong River, where fluvially reworked pebbles and cobbles resembling artifacts may be recovered. © 2009 Wiley Periodicals, Inc.