Effect of catalyst combination on growth of single-walled carbon nanotubes

A new effective catalysts combination of iron — nickel for alcohol CVD technique was found. This catalyst catalyzed well as well as the typical catalyst of iron — cobalt catalysts, but gave a different diameter distribution. Calculating their electrical density of states under the assumption of their solid lattice structures, the result was fairly consistent with experimental results. The number of electrical states near Fermi level that is considered to be important for catalytic reaction is enough and the DOS of iron – nickel catalyst was quite similar to that of cobalt unlike manganese – copper catalyst. Consequently, a blend of catalysts that has a similar DOS to cobalt and has enough states near the Fermi level can be a good catalyst for alcohol CVD.     

Structural Investigation of the Binding of 5‐Substituted Swainsonine Analogues to Golgi α‐Mannosidase II

Golgi α‐mannosidase II (GMII) is a key enzyme in the N‐glycosylation pathway and is a potential target for cancer chemotherapy. The natural product swainsonine is a potent inhibitor of GMII. In this paper we characterize the binding of 5α‐substituted swainsonine analogues to the soluble catalytic domain of Drosophila GMII by X‐ray crystallography. These inhibitors enjoy an advantage over previously reported GMII inhibitors in that they did not significantly decrease the inhibitory potential of the swainsonine head‐group. The phenyl groups of these analogues occupy a portion of the binding site not previously seen to be populated with either substrate analogues or other inhibitors and they form novel hydrophobic interactions. They displace a well‐organized water cluster, but the presence of a C(10) carbonyl allows the reestablishment of important hydrogen bonds. Already approximately tenfold more active against the Golgi enzyme than the lysosomal enzyme, these inhibitors offer the potential of being extended into the N‐acetylglucosamine binding site of GMII for the creation of even more potent and selective GMII inhibitors.     

Application of microalgae hydrolysate as a fermentation medium for microbial production of 2-pyrone 4,6-dicarboxylic acid

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Wheel/rail contact dynamics in turnout negotiations with combined nodal and non-conformal contact approach

In railroad turnouts, geometries of tongue and crossing rails are very complex and their shapes are changing along the track. Therefore, wheels are subjected to not only tread and flange contacts, but also the back-of-flange and top-of-flange contacts in the case of spring switches of tram vehicles. For this reason, one needs to deal with significant jumps in contact points for solving wheel/rail contact problems in turnout, and an accurate prediction of jumps in contact points is one of the most important issues that need to be carefully handled in the dynamic simulation of vehicle/turnout interactions. In this investigation, a numerical procedure that can be used for solving such a complex wheel/rail contact problem in turnout is proposed. In particular, a combined nodal and non-conformal contact approach is developed such that significant jumps in contact points are detected using the nodal search, while the exact location of contact point is then determined with continuous surface parameterizations using non-conformal contact equations. With this combined nodal and non-conformal contact approach for the contact geometry analysis of vehicle/turnout interactions, multiple look-up contact tables can be generated in an efficient way without losing accuracy. Since detailed contact search is performed off-line to obtain look-up contact tables, significant changes in contact points in turnout can be efficiently predicted on-line with tabular data to be interpolated in a standard way. Several numerical examples are presented in order to demonstrate the use of the numerical procedure developed in this investigation.     

A study of suppression of vapor explosions by adding inversely soluble polymers

The mechanism of the suppression of vapor explosions by adding inversely soluble polymers in water is studied. Vapor explosion experiments and quench experiment are conducted using a silver test piece. Polymetric solution (polyethylene oxide), of concentrations from 0 to 500 wppm, whose normalized viscosity (by water) varies from 1.00 to 2.00, is used. No vapor explosion is observed in the aqueous polymer solution at a concentration higher than 200 wppm. Quench experiments using the silver test piece submerged in the polymer solution and water are performed in order to examine the stability of film boiling. The suppression of the vapor film collapse is attributed to the precipitation of polyethylene as a gel around the vapor film. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 31(4): 297–306, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10037     

Microporous activated carbons from used coffee grounds for application to electric double‐layer capacitors

Electrochemical double‐layer capacitors (EDLCs) are devices that store enormous amounts of charge electrostatically when a potential is applied between electrodes of very high surface area (typically made of porous carbon) and an electrolyte. Wider commercialization of this technology has been held back by the lack of ultralow‐cost electrode materials. We demonstrate that used coffee grounds can be processed to form low‐cost electrodes. The surface and electrochemical characteristics of microporous activated carbons from used coffee grounds (CGCs) were measured. First, optimal times and temperatures for carbonization and activation were identified on the basis of Brunauer–Emmett–Teller (BET) surface area, pore volume, and pore size distribution. Second, CGCs were used as polarized electrodes in EDLCs, whose capacitances were evaluated using cyclic voltammetry. The results show that carbonization for 1 h at 600 °C with a heating rate of 300 °C/h, followed by CO₂ activation for 2 h at 1000 °C, affords the highest BET surface area (1867 m²/g) compared to other works. The produced CGCs have many micropores of less than 2 nm across, which contribute to the formation of an electric double layer. Capacitors made using these CGCs show the highest capacitance (103 F/g) in 0.8 M (C₂H₅)₄NBF₄/PC as an organic electrolyte, which is much higher than the ∼80 F/g typically used in organic‐electrolyte‐based commercial EDLCs, suggesting that coffee grounds are a useful electrode material. © 2014 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

AC side harmonic and phenomena accompanying DC-injection of utility-interactive PV system

The experiments investigated phenomena related to direct contact between the DC output of a PV array and the AC power from the utility grid. The results show that the DC power flows through the distribution transformers (DC-injection) saturating their magnetic circuits. The saturation of magnetic circuits makes peak currents, incorporating a large portion of even harmonics, flow through the high-voltage side of the distribution transformer, adding the level of harmonic distortion of its exciting current. With the increase of injecting DC-current to the utility grid, peak currents at the primary side of distribution transformer increases the most, and even among the same effective (rms) values, the increase of primary side current is larger than that of the secondary side current.     

Development of a numerical cancellous bone model for finite-difference time-domain simulations of ultrasound propagation

The trabecular frame in cancellous bone has numerous porous spaces of various sizes and shapes. Their continual arrangement changes with position in the bone. Assuming that the complicated pore space is the aggregation of spherical pores, in this study, the trabecular structure was analyzed using a three-dimensional (3-D) X-ray microcomputed tomography (muCT) image. Analysis involved a 3-D cancellous bone model developed for numerical simulations of ultrasound propagation. In this model, the trabecular structure was simplified by regularly arranging spherical pores in a solid bone. Using a viscoelastic, finite-difference, time-domain (FDTD) method with the simplified cancellous bone model, ultrasound pulse waveforms propagating through cancellous bone were simulated in two cases of the propagations parallel and perpendicular to the main trabecular orientation. The porosity dependences of the propagation properties, attenuation, and propagation speed were derived from the simulated waveforms. Comparisons with simulated results using the realistic cancellous bone model reconstructed from a 3-D muCT image, assisted to further validate this simplified model.