Conducting carbon/polymer composites as a catalyst support for proton exchange membrane fuel cells

Carbon/poly(3,4‐ethylene dioxythiophene) (C/PEDOT) composites are synthesized by in situ chemical oxidative polymerization of EDOT monomer on carbon black in order to decrease carbon corrosion that occurred in carbon‐supported catalysts used in proton exchange membrane fuel cell. The effects of different dopants including polystyrene sulfonic acid, p‐toluenesulfonic acid and camphorsulfonic acid with the addition of ethylene glycol or dimethyl sulfoxide on the properties of the composites are investigated. The synthesized composites are characterized by X‐ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, surface area analysis and scanning electron microscope. Electrical conductivity is determined by using the four‐point probe technique. Electrochemical oxidation characteristics of the synthesized C/PEDOT composites are investigated by cyclic voltammetry by applying 1.2 V for 24 h. The composite prepared at 25 °C with p‐toluenesulfonic acid and ethylene glycol shows the best carbon corrosion resistance. Platinum‐supported catalyst by using this composite was prepared using microwave irradiation technique, and it was seen that the prepared catalyst did not significantly lose its hydrogen oxidation and oxygen reduction reaction activities after electrochemical oxidation. Copyright © 2013 John Wiley & Sons, Ltd.     

Estimation of ground pressures on a shielded TBM in tunneling through squeezing ground and its possibility of jamming

Bulletin of Engineering Geology and the Environment - Single- and double-shield tunnel boring machines are being increasingly considered for use in rock tunneling projects. However, one of the main...     

Investigation of engineering properties for usability of Lefke stone (Osmaneli/Bilecik) as building stone

Lefke stone is a sandstone that has been widely used in mosques, madrasas, churches, and houses as building stone. The geological features and engineering properties of Lefke stone outcropped in the southern part of Osmaneli/Bilecik were investigated in field and laboratory studies. Samples acquired during the fieldwork were tested to determine the physical, mechanical, durability, and hygrothermal properties in the laboratory. The mean physico-mechanical properties of Lefke stone yielded apparent density of 2.38 g/cm³, specific gravity of 2.68 g/cm³, total porosity of 11.26%, 2.93% water absorption by weight, uniaxial compressive strength of 94 MPa, flexure strength of 11.45 MPa, a 3.90 MPa point load strength, 4.5–5 Mohs hardness, and field Schmidt hammer rebound value of 36. According to durability tests, Lefke stone is resistant to CaCl₂ salt mist but has low resistance to SO₂ aging. Salt crystals placed in the discontinuities of the rock caused slight crack growth. The stone’s resistance to crystallization of sodium sulphate salt is low, and an increase in the volume of salts crystallized in the rock results in low corner strengths. A capillary water-absorption value of 0.0016 kg/m².h places Lefke stone into the category of very low water absorption capacity and permeability. The water vapor diffusion resistance factor (μ) less than 1 indicates that the sandstone has high breathability. Its performance in historical buildings, field observations, and values obtained through laboratory tests confirm that Lefke sandstone can be used as a building stone.

     

The effect of slightly warm temperature on work performance and comfort in open‐plan offices – a laboratory study

The aim of the study was to determine the effect of a temperature of 29°C on performance in tasks involving different cognitive demands and to assess the effect on perceived performance, subjective workload, thermal comfort, perceived working conditions, cognitive fatigue, and somatic symptoms in a laboratory with realistic office environment. A comparison was made with a temperature of 23°C. Performance was measured on the basis of six different tasks that reflect different stages of cognitive performance. Thirty‐three students participated in the experiment. The exposure time was 3.5 h in both thermal conditions. Performance was negatively affected by slightly warm temperature in the N‐back working memory task. Temperature had no effect on performance in other tasks focusing on psychomotor, working memory, attention, or long‐term memory capabilities. Temperature had no effect on perceived performance. However, slightly warm temperature caused concentration difficulties. Throat symptoms were found to increase over time at 29°C, but no temporal change was seen at 23°C. No effect of temperature on other symptoms was found. As expected, the differences in thermal comfort were significant. Women perceived a temperature of 23°C colder than men.     

Proximate composition and fatty acid profiles of common pufferfish species in the Mediterranean Sea

The effects of season and gender on the proximate composition and fatty acid profiles of the most widespread pufferfish species in the Mediterranean Sea (Lagocephalus sceleratus, Lagocephalus spadiceus, Lagocephalus suezensis and Torquigener flavimaculosus) caught in Mersin Bay, in the north-eastern Mediterranean during four seasons were investigated. The results showed that the crude protein, lipid, moisture and ash level in pufferfish were in the range of 18.7%–21.7%, 0.61%–1.93%, 76.1%–78.6% and 1.08%–1.87%, respectively. All of the pufferfish had significant levels of polyunsaturated fatty acid (PUFA). However, the consumption of L. sceleratus, L. suezensis and T. flavimaculosus may be risky due to the possibility of having tetrodotoxin in their muscles. Nevertheless, L. spadiceus is a pufferfish species that is popularly consumed in East Asian countries, and is of nutritional interest and commercial potential in the Mediterranean region as well so its proximate composition and fatty acid profile are of interest.