全文获取类型
收费全文 | 15059篇 |
免费 | 1470篇 |
国内免费 | 1637篇 |
学科分类
数理化 | 18166篇 |
出版年
2024年 | 158篇 |
2023年 | 370篇 |
2022年 | 554篇 |
2021年 | 377篇 |
2020年 | 207篇 |
2019年 | 221篇 |
2018年 | 255篇 |
2017年 | 214篇 |
2016年 | 237篇 |
2015年 | 239篇 |
2014年 | 394篇 |
2013年 | 285篇 |
2012年 | 1445篇 |
2011年 | 1904篇 |
2010年 | 469篇 |
2009年 | 337篇 |
2008年 | 1215篇 |
2007年 | 1217篇 |
2006年 | 1134篇 |
2005年 | 1011篇 |
2004年 | 752篇 |
2003年 | 547篇 |
2002年 | 469篇 |
2001年 | 349篇 |
2000年 | 377篇 |
1999年 | 326篇 |
1998年 | 264篇 |
1997年 | 271篇 |
1996年 | 241篇 |
1995年 | 239篇 |
1994年 | 263篇 |
1993年 | 261篇 |
1992年 | 208篇 |
1991年 | 189篇 |
1990年 | 183篇 |
1989年 | 203篇 |
1988年 | 112篇 |
1987年 | 98篇 |
1986年 | 95篇 |
1985年 | 80篇 |
1984年 | 67篇 |
1983年 | 69篇 |
1982年 | 46篇 |
1981年 | 51篇 |
1980年 | 33篇 |
1979年 | 16篇 |
1978年 | 13篇 |
1974年 | 11篇 |
1965年 | 17篇 |
1963年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
1.
Jing-Yi Xie Hui-Ying Zhao Yi-Wen Dong Yang Wu Da-Peng Liu Yong-Ming Chai Bin Dong 《结构化学》2022,(7):59-64
The heterojunction interfacial modulation of FeP is an effective strategy to regulate the intrinsic activity and stability, which is a major challenge to promote the industrial application of FeP-based electrocatalysts. Herein, hollow Fe4C/FeP box with heterojunction interface and carbon armor is successfully synthesized, which can expose numerous active sites and protect catalyst from corrosion. Electrochemical measurements show that Fe4C/FeP exhibits excellent hydrogen ev... 相似文献
3.
Let p ∈ [1, ∞), q ∈ [1, ∞), α∈ R, and s be a non-negative integer. Inspired by the space JNp introduced by John and Nirenberg(1961) and the space B introduced by Bourgain et al.(2015), we introduce a special John-Nirenberg-Campanato space JNcon(p,q,s) over Rn or a given cube of R;with finite side length via congruent subcubes, which are of some amalgam features. The limit space of such spaces as p →∞ is just the Campanato space which coincides with the space BMO(the space of functions with bounded mean oscillations)when α = 0. Moreover, a vanishing subspace of this new space is introduced, and its equivalent characterization is established as well, which is a counterpart of the known characterization for the classical space VMO(the space of functions with vanishing mean oscillations) over Rn or a given cube of Rn with finite side length.Furthermore, some VMO-H1-BMO-type results for this new space are also obtained, which are based on the aforementioned vanishing subspaces and the Hardy-type space defined via congruent cubes in this article. The geometrical properties of both the Euclidean space via its dyadic system and congruent cubes play a key role in the proofs of all these results. 相似文献
4.
根据教育部颁布的《普通高中物理课程标准(2017年版)》,在上海市物理教育教学基地(上海高校“立德树人”人文社会科学重点研究基地)的大力支持下,由上海市教育委员会组织编写的上海高中物理非统编教材进行了正式使用前的试教试用活动,此教材是在上海高中物理“二期课改”教材的基础上全面改写而成的.单元教学设计已成为当前教学设计的焦点问题,以《物理·必修》(第三册)静电场单元为例,详细阐述了“教学问题链”的设计理念,希望与广大一线教师交流试教试用的心得与反思,推动新课改课堂转型. 相似文献
5.
Xiangwen Kong Fang Yu Shengtong Niu Fan Gong Shuang Yang Jinggong Liu Benlong Luo Xinqiang Fang 《中国化学快报》2022,33(6):2997-3002
Copper-catalyzed divergent annulations between α-diketones and alkynyl α-diketones have been achieved, delivering a series of highly functionalized and biologically important cis-hexahydro-2Hcyclopenta[b]furan(HCPF) and 2-hydroxydihydrofuran-3(2H)-one(HDFO) products with high levels of stereoselectivity under identical conditions. The protocol features the use of earth-abundant copper catalyst, mild conditions, shortening synthetic routes in constructing different molecular frameworks, and reduc... 相似文献
6.
Yi Yang Jinsong Wu Bei Cheng Liuyang Zhang Ahmed Abdullah Al-Ghamdi Swelm Wageh Youji Li 《结构化学》2022,(6):6-23
Single-atom catalysts have high catalytic activity due to their unique quantum size effects and optimal atom utilization. Herein, visiblelight-responsive photocatalysts were designed by coupling Cd S with graphene quantum dots(GQDs) and platinum single atoms(Pt SAs). GQDs and Pt SAs were successively loaded on ultrathin Cd S nanosheets through freeze-drying and in-situ photocatalytic reduction. The synergistic effect between Pt SAs and GQDs results in superior photocatalytic activity with a hydr... 相似文献
7.
针对惯性约束聚变实验中多诊断系统在有限空间同时作业引发碰撞风险的问题,设计了基于碰撞目标检测和空间距离测算方法的空间干涉检测与预警系统,分析了真空靶室特定环境下不同实现方法的适用条件和可行性。实验室条件下模拟验证结果表明,基于结构光深度图像获取方法可获得较好的碰撞距离测量精度,在靶室半径探测距离内空间测距误差不大于3cm,为靶室空间干涉检测与预警提供了一种可行的解决方案。 相似文献
8.
Sensitivity improvement of aluminum-based far-ultraviolet nearly guided-wave surface plasmon resonance sensor 下载免费PDF全文
An aluminum (Al) based nearly guided-wave surface plasmon resonance (NGWSPR) sensor is investigated in the far-ultraviolet (FUV) region. By simultaneously optimizing the thickness of Al and dielectric films, the sensitivity of the optimized Al-based FUV-NGWSPR sensor increases from 183°/RIU to 309°/RIU, and its figure of merit rises from 26.47 RIU-1 to 32.59 RIU-1 when the refractive index of dielectric increases from 2 to 5. Compared with a traditional FUV-SPR sensor without dielectric, the optimized FUV-NGWSPR sensor can realize simultaneous improvement of sensitivity and figure of merit. In addition, the FUV-NGWSPR sensor with realistic materials (diamond, Ta2O5, and GaN) is also investigated, and 137.84%, 52.70%, and 41.89% sensitivity improvements are achieved respectively. This work proposes a method for performance improvement of FUV-SPR sensors by exciting nearly guided-wave, and could be helpful for the high-performance SPR sensor in the short-wavelength region. 相似文献
9.
Hongjun Yue Huixin Chen Chen Zhao Zhiming Zheng Ke Zhou Qjaobao Zhang Guiming Zhong Can-Zhong Lu Yong Yang 《Journal of Energy Chemistry》2021,(2):347-353,I0012
Current studies of cathodes for potassium batteries(PBs) mainly focus on the intercalation-type materials.The conversion-type materials that possess much higher theoretical capacities are rarely discussed in previous literatures.In this work,carbon fluoride(CF_x) is reported as a high capacity conversion-type cathode for PBs for the first time.The material delivers a remarkable discharge capacity of>250 mAh g-1 with mid-voltage of 2.6 V at 20 mA g-1.Moreover,a highly reversible capacity of around 95 mAh g-1 is achieved at 125 mA g-1 and maintained for 900 cycles,demonstrating its excellent cycling stability.The mechanism of this highly reversible conversion reaction is further investigated by nuclear magnetic resonance spectra,X-ray diffraction,and transmission electron microscopy studies.According to the analyses,the C-F bond in the cycled material is different from that in the pristine state,which presents relatively higher reversibility.This finding offers important insights for further improving the performance of the CF_x.This work not only demonstrates the CF_x as a high performance cathode for PBs,but also paves a new avenue of exploring conversion-type cathodes for high energy density PBs. 相似文献
10.
Two new homosecoiridoids, named loniaceticiridoside (1) and lonimalondialiridoside (2), were isolated from an aqueous extract of the flower buds of Lonicera japonica. Their structures including the absolute configuration were determined by extensive spectroscopic studies, especially by 2D NMR and CD data analysis. A proposed biosynthetic pathway and preliminary investigations of the biological activity of compounds 1 and 2 are also discussed. 相似文献