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1.
Valentina I. Simagina Pavel A. Storozhenko Olga V. Netskina Oksana V. Komova Galina V. Odegova Yury V. Larichev Arcady V. Ishchenko Anna M. Ozerova 《Catalysis Today》2008,138(3-4):253
Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (γ-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts. 相似文献
2.
Tkachenko Yurii G. Britun Yurchenko Djema Z. Ochkas Larisa F. Bovkun Galina A. 《Powder Metallurgy and Metal Ceramics》2004,43(1-2):99-104
The influence which the composition of powder mixtures, the treatment conditions which the mixtures are subjected to, and the conditions under which the hot-pressed composite materials B4C – (5-10 mass%) calcium-silicon are fabricated exert on the structure, nature of failure, and mechanical properties of these materials is investigated. Optimum properties are possessed by material containing 10 mass% of addition. It is shown that the structure, morphology, and dispersivity, as well as the nature of the distribution of the components that are added to the composite material (secondary phase) vary as the temperature of hot pressing changes. Maximal mechanical characteristics of the composite material (σbend = 560 MPa, K 1c = 4.7 MPa·m1/2, HV = 37 GPa) are attained at hot-pressing temperatures in the range 2000-2100°C. 相似文献
3.
A. Andreev L. Prahov M. Gabrovska A. Eliyas V. Ivanova 《Applied catalysis. B, Environmental》1996,8(4):365-373
The catalytic activity of a wide range of transition metal oxides in oxidation of sulphide ions by air in aqueous medium was studied. Some specific features of the reaction mechanism on some of the studied oxides were considered. The transition metal oxides are promising catalysts for practical application. Some of these oxides will allow the preparation of catalysts possessing activity comparable to that of the cobalt phthalocyanine based catalysts, popular in industrial practice. 相似文献
4.
5.
I. V. Shcherbatenko E. P. Ivanova V. I. Surikov 《Chemical and Petroleum Engineering》2007,43(5-6):335-342
A method is proposed for calculating the optimum density of lattice of blades of screw pump impeller that ensures, for a given
cavitation margin (inlet pressure), the first critical condition on the partial cavitation characteristic of the pump. The
equations obtained can be used also to calculate the permissible cavitation margin of screw centrifugal and screw mixed-flow
pumps as well as of stand-alone screw impeller, provided the geometric and operating conditions of the screw are given.
__________
Translated from Khimicheskoe i Neftegazovoe Mashinostroenie, No. 6, pp. 29–33, June, 2007. 相似文献
6.
E. A. Ivanova D. F. Kasatkin L. A. Akishina E. V. Nepomnyashchaya 《Chemistry and Technology of Fuels and Oils》1992,28(5):241-243
Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, pp. 2–3, May, 1992. 相似文献
7.
8.
N. I. Ivanova V. V. Kharitonov V. E. Ivanov 《Journal of Engineering Physics and Thermophysics》1992,63(2):766-768
Optimum conditions for cementing prepared roofing paper are determined and an installation for laying prepared roofing paper as a hydroinsulating roofing carpet is designed.Gomel Polytechnic Institute. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 63, No. 2, pp. 151–153, August, 1992. 相似文献
9.
The main problems in estimating the uncertainty due to the presence of impurities in the material: the absence in the documents of a unique definition of the quantity being measured – the fixed point temperature, the lack of agreed methods of realizing the fixed points and the insufficient justification of the equations used for the estimate, are analyzed. The results of a measurement of the melting point of gallium are presented, which differ in the conditions in which they were realized – with one and two liquid-solid interfaces and different solidification conditions, are presented. The reasons for the considerable difference between the values of the temperatures obtained in these experiments are discussed. 相似文献
10.
A model is developed in which the theory of deterministic chaos for the interface layer is used to treat both homophase and heterophase fluctuations of density (volume) and the fluctuations of pressure, whose duration increases as the critical point is approached. This approach, based on the transition from continuous differential equations to mappings, leads to a number of important consequences in theoretical analysis of high-temperature processes of evaporation and condensation, including the loss of information on the initial conditions, the alternation, and the presence of branching points on bifurcation diagrams. 相似文献