全文获取类型
收费全文 | 960篇 |
免费 | 13篇 |
国内免费 | 2篇 |
学科分类
数理化 | 975篇 |
出版年
2021年 | 9篇 |
2020年 | 10篇 |
2019年 | 9篇 |
2018年 | 11篇 |
2017年 | 9篇 |
2016年 | 9篇 |
2015年 | 12篇 |
2014年 | 11篇 |
2013年 | 26篇 |
2012年 | 40篇 |
2011年 | 35篇 |
2010年 | 27篇 |
2009年 | 25篇 |
2008年 | 37篇 |
2007年 | 41篇 |
2006年 | 50篇 |
2005年 | 55篇 |
2004年 | 38篇 |
2003年 | 26篇 |
2002年 | 24篇 |
2001年 | 22篇 |
2000年 | 24篇 |
1999年 | 17篇 |
1998年 | 13篇 |
1997年 | 8篇 |
1996年 | 18篇 |
1995年 | 15篇 |
1994年 | 11篇 |
1993年 | 11篇 |
1992年 | 19篇 |
1991年 | 18篇 |
1990年 | 22篇 |
1989年 | 9篇 |
1988年 | 13篇 |
1987年 | 10篇 |
1986年 | 11篇 |
1985年 | 13篇 |
1984年 | 20篇 |
1982年 | 18篇 |
1981年 | 20篇 |
1980年 | 12篇 |
1979年 | 17篇 |
1978年 | 12篇 |
1977年 | 9篇 |
1976年 | 9篇 |
1975年 | 8篇 |
1974年 | 18篇 |
1973年 | 18篇 |
1972年 | 9篇 |
1970年 | 8篇 |
排序方式: 共有975条查询结果,搜索用时 0 毫秒
1.
Arsenic speciation analysis in marine samples was performed using ion chromatography (IC) with inductively coupled plasma mass spectrometry (ICP‐MS) detection. The separation of eight arsenic species, viz. arsenite, monomethyl arsonic acid, dimethylarsinic acid, arsenate, arsenobetaine, tetramethylarsine oxide, arsenocholine and tetramethylarsonium ion was achieved on a Dionex AS4A (weaker anion exchange column) by using a nitric acid pH gradient eluent (pH 3.3 to 1.3). The entire separation was accomplished in 12 min. The detection limits for the eight arsenic species by IC–ICP‐MS were in the range 0.03–1.6 µ g l?1, based on 3σ of the blank response (n = 6). The repeatability and day‐to‐day reproducibility were calculated to be less than 10% (residual standard deviation) for all eight species. The method was validated by analyzing a certified reference material (DORM‐2, dogfish muscle) and then successfully applied to several marine samples, e.g. oyster, fish muscle, shrimp and marine algae. The low power microwave digestion was employed for the extraction of arsenic from seafood products. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
2.
Copper(II) is determined by non-extractive spectrophotometry as a complex of butylene dithiocarbamate formed in situ by reaction between carbon disulfide and pyrrolidine in aqueous Triton X-100 medium. This method is similar to that with butylene dithiocarbamate as starting material in the sense of simplicity, sensitivity, precision and accuracy. Pyrrolidine is the best of seven secondary amines tested in this way for copper determinations. 相似文献
3.
4.
Y. Sakaiguchi T. Shikata H. Urakami A. Tamura H. Hirata 《Colloid and polymer science》1987,265(8):750-753
Some cationic surfactants such as cetyltrimethylammonium bromide (CTAB) show a very spectacular viscoelasticity in solution, in even very diluted states, with some aromatic substances added, such as salicylic acid. Formerly, the authors established that the remarkable solution behaviour was the result of the entanglement of such enormously elongated giant micelles, based on recognition of the existence of large aggregates, through direct observation of them as substantial images under the electron microscope.In this report, we further confirm the relation between micelle length and solution viscoelasticity after arbitrarily obtaining different size aggregates by altering the media pH, or by admixing shorter chain length surfactants than CTAB, which alone did not induce viscoelasticity. 相似文献
5.
Six alkaloids have been isolated from the fruits of the plant Daphniphyllaceae. Two of them are new alkaloids, namely methyl homodaphniphyllate (1) and daphnilactone-B (2). The structure of the former was deduced by chemical transformation from daphniphylline (3). The structure of daphnilactone-B was estimated by the exhaustive spectral analysis as well as by chemical evidences, and finally determined by an X-ray crystallographic analysis of the free base. 相似文献
6.
Rikuhei Tanikaga Yoshimasa MatsumotoMaki Sakaguchi Yohei KoyamaKentaro Ono 《Tetrahedron letters》2003,44(35):6781-6783
Lipase-mediated acetylations of trans- and cis-2-substituted cyclohexanols gave the corresponding (1R)-cyclohexyl acetates and (1S)-cyclohexanols in high yields and ee, but c-4-tert-butyl-c-2-ethenyl-r-1-cyclohexanol was unreactive owing to the steric interaction between the axial OH group and the axial H atoms at the 3- and 5-positions. In the cis-isomer the OH group occupies an equatorial position to bind to the lipase, and less bulky axial alkenyl and alkynyl groups might not so much prevent acetylations than an alkyl group. 相似文献
7.
From a biogenetic point of view, a great variety of related alkaloids isolated from the plant Daphniphyllaceae are related to one another by bond formation or fission. Thus, daphnialcohol acetate (6), a derivative of the degradation products of daphniphylline (1), was subjected to von Braun degradation followed by acid-catalyzed recyclization to give an isomer (8) of daphnialcohol, which has a new type of nitrogen heterocyclic skeleton. Furthermore, daphnilactone-B (3) was converted into a daphniphylline-type compound (19) via a plausible intermediate (21). 相似文献
8.
The complete structure of palytoxin (1) was elucidated by us in 1982.1 Our continuous interests in palytoxin led us to examine minor constituents of Okinawan Palythoa tuberculosa. In this paper, we describe successful isolation and structural elucidation of four minor toxins, which were named homopalytoxin (2), bishomopalytoxin (3), neopalytoxin (4) and deoxypalytoxin (5). 相似文献
9.
10.
Yoshimasa Fukazawa Satoshi Harada Akira Inai Toshiya Okajima 《Tetrahedron letters》1993,34(52):8493-8496
The title compound (2) has been synthesized, the structure and the physical properties of which are investigated by X-ray, spectroscopic analyses, and MO calculations. There exists charge transfer (CT) interaction between the tropylium ion and the facing phenyl ring. From the pKR+ value of 2, it can be clear that the cation 2 is stabilized by the CT interaction. In spite of the presence of bond weakening σ-π orbital mixing, the cation 2 withstands retro[4+4]type bond cleavage, which is quite interesting when compared to a facile cleavage for the congener with anthracene photodimer type structure. 相似文献