全文获取类型
收费全文 | 17376篇 |
免费 | 2834篇 |
国内免费 | 2368篇 |
学科分类
数理化 | 22578篇 |
出版年
2024年 | 62篇 |
2023年 | 363篇 |
2022年 | 678篇 |
2021年 | 799篇 |
2020年 | 854篇 |
2019年 | 833篇 |
2018年 | 712篇 |
2017年 | 689篇 |
2016年 | 918篇 |
2015年 | 962篇 |
2014年 | 1169篇 |
2013年 | 1566篇 |
2012年 | 1683篇 |
2011年 | 1717篇 |
2010年 | 1216篇 |
2009年 | 1102篇 |
2008年 | 1293篇 |
2007年 | 1044篇 |
2006年 | 925篇 |
2005年 | 744篇 |
2004年 | 594篇 |
2003年 | 450篇 |
2002年 | 379篇 |
2001年 | 283篇 |
2000年 | 225篇 |
1999年 | 220篇 |
1998年 | 158篇 |
1997年 | 121篇 |
1996年 | 132篇 |
1995年 | 97篇 |
1994年 | 94篇 |
1993年 | 81篇 |
1992年 | 60篇 |
1991年 | 60篇 |
1990年 | 36篇 |
1989年 | 39篇 |
1988年 | 24篇 |
1987年 | 21篇 |
1986年 | 37篇 |
1985年 | 27篇 |
1984年 | 14篇 |
1983年 | 20篇 |
1982年 | 15篇 |
1981年 | 11篇 |
1979年 | 6篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1973年 | 4篇 |
1957年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
HIRFL–CSR加速器中束流与真空中剩余气体的碰撞损失 总被引:1,自引:1,他引:0
研究了重离子加速器中束流与真空中剩余气体的碰撞损失过程和碰撞截面,在依据大量实验数据的基础上,提出了一组计算离子一原子的电荷交换截面的经验公式.以兰州重离子加速器HDRFL及冷却储存环CSR为例,给出了依据碰撞截面的公式计算束流在加速器真空中的传输效率的方法,并计算了在不同真空度下HIRFL的ECR源轴向注入束运线、注入器SFC、前束运线、主加速器SSC和后束运线等不同加速阶段及CSR的传输效率,并提出合理的真空度要求.HIRFL的真空分布测量和束流的损失测量证明了该计算方法的可靠性. 相似文献
2.
3.
Werner Leißner 《Results in Mathematics》1991,20(1-2):530-537
4.
Catalytic properties of silica-supported heteropolyacids (HPA) in a mechanical mixture with reduced Me-Ce oxides (Me = Ni,
Pd) in n-hexane isomerization are studied. The role of each component of the mixed oxides (Ce and, typically, Ni and Pd) and their
optimum content has been illuminated: cerium is not only beneficial for eliminating or preventing coke deposition but is also
effective for maintaining the Keggin structure of the highly-organized HPA during the reaction and probably allows a better
dispersion of the second metal species. Nickel and palladium, present as Ni0 and Pd0, reinforce the activation of the alkane, which is difficult to obtain by means of a direct attack by an acid, and, thus,
enhance noticeably the activity of the catalyst. The best mechanical mixtures are obtained with 30–70 wt % NiCeO-HPW/SiO2 and 50–50 wt % Pd0.1CeO-HPW/SiO2. These mixtures have the highest efficiency for a Ni/(Ni + W) atomic ratio of 0.66 and a Pd/(Pd + W) ratio of 0.40, respectively.
Finally, the conversion of n-hexane is in the order HPW > HSiW > HBW, which seems to be consistent with the order of their acid strength as per the literature,
but the isomerization selectivity appears to be slightly higher on HSiW.
Published in Russian in Kinetika i Kataliz, 2006, Vol. 47, No. 1, pp. 24–28.
The text was submitted by the authors in English. 相似文献
5.
6.
BP神经网络在上海住宅市场需求预测中的应用 总被引:5,自引:0,他引:5
人工神经网络是近期发展最快的人工智能领域研究成果之一 ,本文在介绍 BP神经网络的有关原理的基础上 ,建立了一个上海住宅市场的 BP神经网络模型 ,并通过该模型对上海住宅市场的需求进行了预测和分析 .分析结果表明人工神经网络方法在住宅市场需求预测中的应用是可行的并且是有效的 . 相似文献
7.
Stable aminoxyls and an iminoxyl were observed by spin trapping and EPR techniques during the nitration of coumarins containing a hydroxy group by nitric oxide. The trapped free radicals are deduced to be the resonance stabilized phenoxy-like radicals. The mechanisms for the nitrations are suggested. 相似文献
8.
Richard Kotek Kyeong Pang Ben Schmidt Alan Tonelli 《Journal of Polymer Science.Polymer Physics》2004,42(23):4247-4254
Poly(ethylene isophthalate) (PEI) was synthesized for this research with essentially a condensation polymerization of isophthalic acid and ethylene glycol catalyzed by zinc acetate and antimony trioxide. Several samples were obtained, and their characteristics were observed and compared with poly(ethylene terephthalate) (PET). The synthesized PEI samples were chemically identified by 1H NMR. Thermal analysis with differential scanning calorimetry (DSC) yielded results that indicate the samples were primarily amorphous, with a glass‐transition temperature of 55–60 °C. Molecular weights of these PEI samples were also obtained through intrinsic viscosity measurements (Mark–Houwink equation). Molecular weights varied with conditions of the polymerization, and the highest molecular weight achieved was 21,000 g/mol. Finally, the diffusion coefficient, solubility, and permeability of CO2 gas in PEI were measured and found to be substantially lower than in PET, as anticipated from their isomeric chemical structures. This is because in PET the phenyl rings are substituted in the para (1,4) positions, which allows for their facile flipping, effectively permitting gases to pass through. However, the meta‐substituted phenyl rings in PEI do not permit such ring flipping, and thus PEI may be more suitable for barrier applications. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4247–4254, 2004 相似文献
9.
Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products. 相似文献
10.