共查询到19条相似文献,搜索用时 546 毫秒
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在CO2激光功率为50—300W、扫描速度为20mm/s、激光散光斑为20mm照射条件下 ,诱导非 晶Fe735Cu1Nb3Si135B9带中发生结构重组,产生定量纳米α-F e(Si)晶相形成双相组织结构材料. 利用穆斯堡尔谱研究了非晶Fe735C u1Nb3Si135B9合金激光纳米化的 超精细结构. 实验结果表明,激光诱导非晶 Fe735Cu1Nb3Si135B 9纳米化后,其超精细磁场的分布随 着激光功率变 化由单峰向双峰变化,在高功率辐照时, 出现了双峰分布,并且峰位向高场移动. 高激光 功率辐照非晶Fe735Cu1Nb3Si135 sub>B9合金纳米晶化相有四种超精细结 构,即2个超精细磁场较小的初晶相和2个超精细磁场较大的纳米晶化相. 其中超精细磁场较 大(17—25MA/m)的α-Fe(Si)相为DO3结构.
关键词:
激光
纳米晶α-Fe(Si)
735Cu1Nb< sub>3Si135B9')" href="#">非晶Fe735Cu1Nb< sub>3Si135B9
超精细结构
超精细磁场 相似文献
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对非晶合金Fe78Si9B13进行了超短脉冲电流处理,实现了晶化时α-Fe(Si)单相结构析出.可以认为,脉冲电流作用时,电子运动与非晶中空位型结构缺陷间的周期性排斥效应促进了类金属原子从非晶结构单元中析出,使Fe(Si)原子局部富集,导致基体金属相在较低温度下优先成核.而在空位的定向迁移的同时,将伴随B原子的扩散,则B原子局域富集,Fe-B化合物的形核析出就要受到这两个因素的抑制
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用转靶X射线源及弯晶EXAFS谱仪测定了Fe80B20及Fe80Si6B14金属玻璃中铁的X射线K吸收谱。由EXAFS谱确定了两种金属玻璃的近邻结构参量。此外,通过测定XANES谱并与纯铁及其有关的化合物Fe2B,FeB中铁的XANES比较发现:吸收边能量、“白线”结构等均出现一些变化,表明两种金属玻璃的近邻原子Fe-B,Fe-Si以及Fe-Fe之间的相互作用比铁与硼所形成的稳定化合物中要强,这对于决定金属玻璃的短程序结构具有重要的作用。
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本工作用X射线散射技术研究了金属一类金属玻璃合金Pd77Si16.5Ag6.59,Co42.9Ni27.3Fe7.8Si8B14和Co50.7Ni19.5Fe7.8Si6B16的结构。求出了它们的干涉函数I(s)和原子径向分布函数RDF(r),并由此获得了有关结构信息的原子平均距离、最近邻配位数和短程有序畴半径。此外,对这些合金的RDF(r)第一峰作了高斯分布拟合,求得了比较好的拟合方程,并用近似方法估算了其中金属-金属原子间的配位数。
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Study of structural and magnetic properties of Fe_(80)P-_9B_(11) amorphous alloy by ab initio molecular dynamic simulation 下载免费PDF全文
The structural and magnetic properties of Fe_(80)P_9B_(11) amorphous alloy are investigated through ab initio molecular dynamic simulation. The structure evolution of Fe_(80)P_9B_(11) amorphous alloy can be described in the framework of topological fluctuation theory, and the fluctuation of atomic hydrostatic stress gradually decreases upon cooling. The left sub peak of the second peak of Fe–B partial pair distribution functions(PDFs) becomes pronounced below the glass transition temperature, which may be the major reason why B promotes the glass formation ability significantly. The magnetization mainly originates from Fe 3d states, while small contribution results from metalloid elements P and B. This work may be helpful for developing Fe-based metallic glasses with both high saturation flux density and glass formation ability. 相似文献
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The variations of induced magnetic anisotropy with annealing and measuring temperatures in metallic glasses (Fe1 − xCox)78Si10B12 have been measured. It was found that Ku (T) was proportional to Mns (T) for T below 200°C, and the index n varied with the cobalt content x and annealing conditions, not being smaller than 3. To the predictions of the existing pair-ordering and single-ion theories, the above results are anomalous. By considering the distributions of exchange integrals and activation energies in metallic glasses, this anomalous behaviour could be explained properly. 相似文献
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近年来, 基于非晶合金名义弹性区的流变力学行为探索其结构及形变机理是非晶合金领域研究的热点之一. 本文根据非晶合金结构不均匀性的特征, 提出能够比拟树状分形网络结构的分数阶微分流变模型研究非晶合金的黏弹性行为. 通过室温纳米压痕实验, 对三种不同泊松比和玻璃化转变温度的非晶合金的黏弹性变形行为进行了研究. 实验结果表明: 在表观弹性区, 非晶合金的变形表现出与加载速率相关的线性黏弹性性质. 根据Riemann-Liouville分数阶微积分定义, 分别由分数阶微分及整数阶Kelvin模型对实验结果进行了分析. 分析结果表明, 相对于整数阶流变模型, 分数阶微分流变模型能更精细地表征材料的黏弹性变形特征; 在流变模型参数中, 黏性系数ηA和分数阶次α反映出材料的流变特性和流动趋势, 流变参数与玻璃转变温度、泊松比之间具有较好的相关性, 上述相关性有助于从微观结构角度理解材料塑性与泊松比的关联. 相似文献
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E. Trk 《Journal of magnetism and magnetic materials》1979,10(2-3):303-306
The temperature dependence of Young's modulus of three metallic glasses, Fe32Ni36Cr14P12B6, Fe40Ni40P14B6 and Fe40Ni38Mo4B18 was measured. In the magnetically saturated state no appreciable change in slope below Tc, i.e. no Invar- like effects are observed in the elastic constants. 相似文献
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Mihaela Valeanu G. Filoti V. Kuncser Felicia Tolea B. Popescu A. Galatanu G. Schinteie A.D. Jianu I. Mitelea D. Schinle C.M. Craciunescu 《Journal of magnetism and magnetic materials》2008,320(14):e164-e167
Four Fe–Mn–Si alloys, Fe62Mn32Si6, Fe62Mn20Si5Cr8Ni5, Fe62Mn16Si5Cr12Ni5 and Fe65Mn9Si7Cr10Ni9, were obtained by the melt-spinning method. The samples were structurally, magnetic and shape memory effect (SME) investigated, both “as quenched” and thermally treated. The Mn-rich compositions show different phase, magnetic behavior and SME in comparison with Mn-poor compositions. The thermal treatments generate transformation between the two existing majority phases ( and γ), related magnetization and SME behavior. The features are derived from the corroboration of structural, magnetic interaction and magnitude of SME data. 相似文献
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R. B. da Silva A. M. H. de Andrade A. M. Severino A. D. C. Viegas R. L. Sommer 《Physica B: Condensed Matter》2002,320(1-4):156-158
In this work, results on the giant magnetoimpedance (GMI) of a glass-covered amorphous microwires with nominal compositions Co70.4Fe4.6Si15B10 and Fe77.5Si7.5B15 are presented. The impedance Z=R+iX has been investigated as function of frequency (up to 1.8 GHz) and magnetic field (up to ±400 Oe), using a HP4396B impedance analyzer and an appropriate coaxial microwave cavity. The effects of the thermal treatments (Joule heating, from 20 mA up to 100 mA for 10 min) for anisotropy induction and, as a consequence, for GMI effect have been investigated. 相似文献
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G.L. Whittle A. Calka A.P. Radliński B. Luther-Davies 《Journal of magnetism and magnetic materials》1985,50(3):278-286
We present the results of picosecond laser annealing of as-quenched Fe85B15 and Fe82B18 metallic glasses. The influence of the laser radiation on the surface and bulk properties are studied using CrK X-ray diffraction and transmission Mössbauer spectroscopy. The X-ray data show that the amorphous nature of the surface of the samples can be improved with laser treatment. The mat (cooling) surfaces of the ribbons appear to be more affected by the laser treatment, and show a higher stability. The Mössbauer data reveal that laser annealing of ribbon surfaces also affects the bulk properties of these materials due to induced stresses from the surface layer. The magnetic properties of these materials can be modified by laser annealing. 相似文献