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采用激光熔覆技术,在基体45#钢板上熔覆了含Nb的双相不锈钢涂层。采用扫描电子显微镜(SEM)和能谱分析仪(EDS)对涂层的微观组织和元素组成进行了表征分析,测试了涂层沿深度方向上的显微硬度,在20℃条件下进行了UMT摩擦磨损试验,并在3.5 wt.%的NaCl水溶液中进行电化学测试。结果表明:在双相不锈钢合金粉中添加Nb进行激光熔覆,所制备的熔覆层中碳化物由Cr和Nb的碳化物组成,同时Cr含量显著降低;熔覆层中添加Nb后,其硬度和耐磨性比未添加Nb的熔覆层有显著提高,Nb含量为1.4%的时候效果最好;随着Nb含量的增大,自腐蚀电位逐渐增大,自腐蚀电流密度逐渐降低,说明Nb含量越高熔覆层的耐蚀性越好。综上所述,当熔覆层中Nb含量为1.4%的时候,其耐磨性和耐蚀性最好。 相似文献
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针对现有煤矿液压支架表面激光熔覆层抗腐蚀性差、裂纹敏感性高的问题,通过提高合金成分中Ni元素含量,添加Nb元素及控制C元素含量的方法,以期提高熔覆层抗腐蚀性并降低裂纹敏感性。本文通过扫描电镜、EDS等测试方法对成分改进前后的熔覆层组织结构进行了分析,并对200h盐雾腐蚀后的熔覆层组织结构及腐蚀机理进行了分析探讨。结果表明,Ni含量的提高使得熔覆层内残余奥氏体含量增加,从而增加熔覆层韧性,有效降低裂纹敏感性;添加Nb元素及控制C元素后,有效控制了Cr_(23)C_6的形成,提高熔覆层抗腐蚀性。 相似文献
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采用激光熔覆技术在40 Cr Ni Mo基材上制备了TiC增强双相不锈钢复合熔覆层,熔覆层物相主要由奥氏体、马氏体、M7C3型碳化物和TiC组成。其中M7C3型碳化物主要包括Fe7C3、Cr7C3或者(Fe、Cr)7C3三种,TiC按尺寸可分为熔解后析出的微米级TiC以及粗大的未熔TiC颗粒。析出的TiC颗粒为方块状,随着TiC添加量增加,呈花瓣状长大。未熔TiC颗粒与基材形成了扩散界面,具有很好的界面结合性。当加入30 wt.%TiC时,熔覆层具有最好的耐磨性,硬度可达55.26 HRC,磨损体积为2.54×10-2 mm3,耐磨性是基材的3.37倍。 相似文献
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本文研究了热作模具钢4Cr5MoV1Si在热变形过程中碳化物的动态析出行为。TEM分析认为,动态析出的碳化物主要为Mo2C和VC。碳化物的定量分析表明;随着固溶于基体中碳化物形成元素含量的降低,动态析出的碳化物减少。 相似文献
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The effects of CeO2 on microstructure and corrosion resistance of TiC-VC reinforced Fe-based laser cladding layers were investigated. The results showed that carbides presented in cladding layers were TiVC2 and VC. A small quantity of CeC appeared with 2.0 wt.% CeO2 addition. The amount of lamellar pearlite increased while the amount of residual austenite decreased with increasing CeO2 addition. The corrosion resistance of cladding layers increased firstly and then decreased with the addition of CeO2 increasing. The EIS spectrum of the cladding layer without CeO2 was composed of an inductive arc at low frequency and a capacitive arc at high frequency. The cladding layer with 0.5 wt.% CeO2 addition showed the best corrosion resistance, and then the inductive arc at low frequency transformed into a capacitive arc. 相似文献
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采用等离子熔覆(PTA)在Q235上制备出含有细小碳化铌的Fe-Cr-B-C-Nb熔覆层,设计了B含量分别为0,2.2%,3.2%,4.0%的四组合金,通过SEM,XRD,MLS-225型湿式橡胶轮磨粒磨损试验机,自制落锤冲击试验机研究了B含量对Fe-Cr-B-C-Nb熔覆层组织与性能的影响.结果表明B含量对熔覆层组织与性能有显著的影响,随B含量的增加,合金硬度不断增加,耐磨性逐渐增加,合金的耐冲击性逐渐变差,当B含量为2.2%时,合金具有良好的综合性能. 相似文献
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The effect of carbide morphology and matrix structure on abrasion resistance of cast alloyed steel with 2.57% C, 16.2% Cr and 0.78% Mo was studied in the as‐cast and heat treated conditions. Samples were austenitized at three different temperatures of 980, 1050 and 1250 °C for 15 minutes and followed by tempering at 540 °C for 3 hours. The austenitizing temperature of 980 °C revealed fully martensitic structure with little amount of retained austenite, while at 1050 °C the matrix was austenitic with massive amount of coarse secondary carbides. The austenitic matrix with very fine secondary carbides was developed at 1250 °C. The maximum abrasion resistance was obtained at 1050 °C due to the highest structure hardness and existence of both eutectic and secondary carbides in larger size than the formed groove by the abrasive particles during the wear test. On the other hand, the as‐cast pearlitic structure showed high wear rate by an applied load of up to 0.2 bar, followed by very rapid increase in wear rate with higher applied loads. It could be considered that the austenitizing temperature of 1050 °C showed better combination of abrasion resistance and toughness in comparison with other heat treatment cycles. 相似文献