共查询到19条相似文献,搜索用时 203 毫秒
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硫增感AgBrI T颗粒乳剂光电子行为研究 总被引:3,自引:1,他引:3
利用微波相敏技术,获得了硫增感AgBrI T颗粒乳剂中自由光电子和束缚光电子时间衰减信号,分析了光电子衰减时间、电子陷阱效应、光电子寿命、有效陷阱深度及束缚电子转移时间与增感时间的关系,获得了最佳的增感时间、衰减时间、电子陷阱效应、光电子寿命、有效陷阱深度和转移时间数值, 相似文献
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采用微波辅助水热法制备了NiGa_2O_4纳米粉体。用X射线衍射光谱、扫描电子显微镜、透射电子显微镜和X射线光电子能谱等研究了反应温度、时间和沉淀pH对NiGa_2O_4的相组成以及气敏性能的影响。结果表明:微波水热下,180℃反应2 h合成晶型较好的NiGa_2O_4粉体。在pH为10、180℃反应2 h合成的NiGa_2O_4于室温下对三甲胺有较高的响应和较好选择性。对10×10~(-6)(mL/m~3)三甲胺响应值达到3.5,响应时间约为75 s,恢复时间约为45 s;最低检测限为1×10~(-6),响应值约为1.8。 相似文献
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应用常规感光测定法、电镜法、介电损耗仪和微波光导仪研究了Pb~(2+)对卤化银乳剂微晶的掺杂效应。结果表明:Pb~(2+)使乳剂的感光度降低,灰雾明显升高,而反差变化不大。由电子显微镜照片表明,Pb~(2+)对乳剂微晶大小和形状影响不大,但是离子电导和微波光导数据显示出,Pb~(2+)的掺杂使离子电导率降低0.15个对数单位,电子电导成倍降低。上述结果暗示:Pb~(2+)对照相性能的影响不是由于乳剂微晶大小和形状的变化,可能由以下两个原因引起:(1)Pb~(2+)起了深的电子陷阱作用,使光电子徙动路程缩短,影响潜影的形成效率,(2)Pb~(2+)(或PbBr_2)成为复合中心,加速光电子与空穴的复合,催化显影过程。 相似文献
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硫增感AgBr I T颗粒乳剂光电子行为研究 总被引:1,自引:1,他引:1
本文利用微波吸收相敏检测技术,同时获得了硫增感AgBrIT颗粒乳剂,在不同增感条件下自由光电子和浅俘获光电子的时间衰减曲线,分析了不同的硫增感产物的陷阱效应.结果表明:开始时,增感产物起电子陷阱作用,至45min时,浅电子陷阱作用最佳.如增感时间进一步增加,硫增感产物将变为深电子陷阱.本文还讨论了浅电子陷阱中浅俘获光电子衰减时间与阱深的依存关系. 相似文献
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针对煤矿井下低压供电系统相敏短路保护技术的现状,对比了几种常用相敏保护装置的类型、保护方式及技术特点,展望了矿井智能化配电系统的发展趋势,对相敏短路保护器的选用具有参考价值。 相似文献
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We have synthesized several nitrobenzanthrones (NBAs) and investigated their structures in solution using NMR spectroscopy. In our study, however, low solubility of NBAs in organic solvents always became a serious problem and led to NMR spectra with low signal-to-noise ratios. To solve this problem, we adopted a new method of conventional coherence transfer pathway selection using pulsed field-gradients. The double-pulsed field-gradient spin echo (DPFGSE) sequence was used for selecting natural-abundance carbon-13 isotopomers by using a bilinear rotation decoupling (BIRD) sequence and a so-called gradient-BIRD pulse for the excitation sculpting technique. We performed NMR measurements on 3,9-dinitro-7 H -benz[ d,e ]anthracene-7-one (compound 1), 3,9,11-trinitro-7 H -benz[ d,e ]anthracene-7-one (compound 2), and 2-nitro-7 H -benz[ d,e ]anthracene-7-one (compound 3) by this method and obtained spectra of high quality. Combining the results from phase-sensitive 2D NOESY, HOHAHA, and DPFGSE-HMQC, DPFGSE-HMQC TOCSY, and phase-sensitive FG-HMBC permitted us to complete NMR assignments. It was confirmed that the present method enables us to improve the sensitivity and to assign the NMR signal readily, even for compounds with low solubility. 相似文献
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为了优化环保高强力再生橡胶的微波辐射工艺,本文首先对微波再生原料进行预处理,然后选择合理的微波辐射方法,在微波再生过程中确定了适宜的加料顺序,在微波再生后确定了再生橡胶的冷却工艺,还确定了再生过程中的最佳工艺条件微波辐射时间、温度和功率。通过优化微波辐射工艺获得的环保型高强力再生橡胶,胶片表面光洁、质地均匀,适合压延、压出工艺。实验结果表明再生胶的拉伸强度和扯断伸长率能分别达到18.74MPa和443.00%。 相似文献
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《Drying Technology》2013,31(8):2063-2079
A new drying method of combined superheated steam and microwave drying is being proposed. The drying rates of sintered glass beads in combined superheated steam and microwave drying are experimentally and theoretically investigated. Drying experiments have been carried out in a waveguide where a standing wave is formed to uniformly heat a small sample. Concerning drying rate curves in combined superheated steam and microwave drying, a distinct constant rate period has been observed. For the falling rate period, high drying rates have been observed. For both periods, the drying rates in combined superheated steam and microwave drying are higher than those in superheated steam alone. Also, in comparison with the results of combined nitrogen and microwave drying, the normalized drying rates in combined superheated steam and microwave drying are higher than those at less than the critical moisture content in combined nitrogen and microwave drying. Moreover, theoretical drying rates for the falling rate period (predicted by a modified receding evaporation front model) in combined superheated steam and microwave drying, are in good agreement with the observed drying rates. The combined superheated steam and microwave drying method can attain higher drying rates under mild external conditions. 相似文献
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研究了微波对松香与丙烯酸发生Diels-Alder加成反应的促进作用,并通过FT-IR、紫外和HPLC对产物进行分析,确认主要产物即为目标产物。结果表明,微波可有效地加速反应。在35 g松香,7.2 mL丙烯酸加成反应体系中,微波辐照下常压反应90 min,或在密闭压力罐中反应 5 min,反应基本完成。产物的酸值远高于常规加热反应8 h所得产物。常规加热法制备丙烯酸松香时,增加反应时间、升高反应温度均有利于产物酸值的提高。而微波加热反应体系,加压体系中最佳微波功率是640 W,较高的功率和更长的反应时间反而导致产物酸值降低。 相似文献
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The effect of intense electromagnetic fields, generated inside a multimode microwave applicators, on the crystallization of calcium carbonate polymorphs starting from calcium bicarbonate solutions has been investigated. The identification and quantitative analysis of the calcium carbonate polymorphs has been made by X-ray diffraction using Rietveld-Reference Intensity Ratio (RIR) method. Scanning Electron Microscopy analysis has also been performed to study the morphology of calcium carbonate samples. Crystallization tests have been conducted at atmospheric pressure while adjusting microwave power to maintain solution temperature between 80 °C and 90 °C. For the sake of comparison, calcium carbonate powders have also been prepared using conventional heating either in a oven or on a hot plate with a magnetic stirrer. The experiments conducted using microwave radiation gave in a high percentage yield of aragonite (99%) which has been favoured by increasing microwave exposure times. Low microwave exposure times, on the other hand, favours vaterite formation which crystallized in an unusual flower-like morphology. 相似文献
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To demonstrate the potential of microwave drying in the ceramic industry, microwave demolding of tableware product by a continuous microwave belt drier has been investigated. This study focuses on the investigation of the effects of the irradiation time, sample size, microwave power and location of magnetron on overall drying kinetics. The results show that microwave drying has several advantages over the conventional method such as shorter processing time, volumetric dissipation of energy throughout a product, high energy efficiency, reduced amount of mold usage, and offering product quality. Further quantitative validation of experimental data could be very useful, especially in providing information for processing high-performance microwave drying for developing the ceramic industry in Thailand. 相似文献