Acid mine drainage biogeochemistry at Iron Mountain,California

The Richmond Mine at Iron Mountain, Shasta County, California, USA provides an excellent opportunity to study the chemical and biological controls on acid mine drainage (AMD) generation in situ, and to identify key factors controlling solution chemistry. Here we integrate four years of field-based geochemical data with 16S rRNA gene clone libraries and rRNA probe-based studies of microbial population structure, cultivation-based metabolic experiments, arsenopyrite surface colonization experiments, and results of intermediate sulfur species kinetics experiments to describe the Richmond Mine AMD system. Extremely acidic effluent (pH between 0.5 and 0.9) resulting from oxidation of approximately 1 × 10⁵ to 2 × 10⁵ moles pyrite/day contains up to 24 g/1 Fe, several g/1 Zn and hundreds of mg/l Cu. Geochemical conditions change markedly over time, and are reflected in changes in microbial populations. Molecular analyses of 232 small subunit ribosomal RNA (16S rRNA) gene sequences from six sites during a sampling time when lower temperature (<32°C), higher pH (>0.8) conditions predominated show the dominance of Fe-oxidizing prokaryotes such as Ferroplasma and Leptospirillum in the primary drainage communities. Leptospirillum group III accounts for the majority of Leptospirillum sequences, which we attribute to anomalous physical and geochemical regimes at that time. A couple of sites peripheral to the main drainage, "Red Pool" and a pyrite "Slump," were even higher in pH (>1) and the community compositions reflected this change in geochemical conditions. Several novel lineages were identified within the archaeal Thermoplasmatales order associated with the pyrite slump, and the Red Pool (pH 1.4) contained the only population of Acidithiobacillus. Relatively small populations of Sulfobacillus spp. and Acidithiobacillus caldus may metabolize elemental sulfur as an intermediate species in the oxidation of pyritic sulfide to sulfate. Experiments show that elemental sulfur which forms on pyrite surfaces is resistant to most oxidants; its solublization by unattached cells may indicate involvement of a microbially derived electron shuttle. The detachment of thiosulfate (S₂O₃^2-) as a leaving group in pyrite oxidation should result in the formation and persistence of tetrathionate in low pH ferric iron-rich AMD solutions. However, tetrathionate is not observed. Although a S₂O₃^2--like species may form as a surface-bound intermediate, data suggest that Fe³⁺ oxidizes the majority of sulfur to sulfate on the surface of pyrite. This may explain why microorganisms that can utilize intermediate sulfur species are scarce compared to Fe-oxidizing taxa at the Richmond Mine site.

     

A glacial chronology for the Fish Creek drainage of Boulder Mountain, Utah, USA

Boulder Mountain, located in South Central Utah, is one of several mountain ranges on the Colorado Plateau that was glaciated during the late Pleistocene. Using ³He exposure-age dating (corrected for non-cosmogenic ³He with shielded samples), we determined ³He exposure-ages for boulders from the most well-preserved moraines in the Fish Creek drainage of Boulder Mountain. ³He exposure-ages indicate a last glacial maximum (LGM) advance ∼23,100 ± 1300 to 20,000 ± 1400 yr ago and a later and smaller advance ∼16,800 ± 500 to 15,200 ± 500 yr ago. This chronology is very similar to other cosmogenic glacial chronologies from the Western U.S. and suggests that the timing of glacial advance and retreat on the Colorado Plateau was generally in phase with the rest of the Western U.S. during the late Pleistocene.     

Iron deposition as acidic groundwater encounters carbonates in the alluvium of Pinal Creek,Arizona, U.S.A.

In a column experiment, acidic groundwater from Pinal Creek Arizona, a Cu mining area, was eluted through a composited alluvial sample obtained from a core that had been removed from a well downgradient of the acidic groundwater. The minerals present in typical grains and flakes in the alluvium before and after the elution were determined by X-ray diffraction (XRD), scanning electron microscopy, and energy dispersive multichannel analyses (EDX). The concentrations of Fe, Ti, Mn, Si, Al, Na, Ca, K, Mg and S in these grains and flakes and in their microcrystalline surface coatings were measured by EDX.In addition to magnetite, hematite, and Fe-Ti oxides, Fe was most concentrated in micas (especially biotite-like flakes) and in the microcrystalline coatings. The measured elements in these microcrystalline coatings were primarily K, Fe, Al, and Si. The microcrystalline coatings on the mica flakes also contained Mg. The approximate l:3 Mg:Si atomic ratios (ARs)_of the biotite-life flake both before and after the elution would suggest that the Fe deposited during the elution had not substituted for Mg in these flakes. As a result of the elution, assuming no loss of Si, the averaged recorded Fe:Si AR of the microcrystalline coatings increased from (0.46 to 0.58):3.00.Iron deposition on the typical grains and flakes may relate to the presence of Fe in the particle on which it is deposited or to the presence of Fe in the microcrystalline surface coatings before elution. The data here are not sufficient for a statistical evaluation, but elution caused the following trends: (l) The Fe:Si AR increased in the (K,Fe,Al,Si)-microcrystalline surface coatings; (2) For the mica flakes, there was more than a 2-fold increase in the Fe:Si AR for the microcrystalline surface coatings of the Fe-rich biotite-like flakes but no measurable increase of the Fe:Si AR for the microcrystalline surface coatings of the muscovite-like flakes that contained 3–5 times less Fe; (3) Also for the biotite-like flakes, the increase in Fe:Si AR was greater in the flakes that had a higher Fe:Si AR; (4) The Fe deposition on the Fe-rich microcrystalline surface coatings of the feldspar was much greater than on the Fe-poor, beige quartz and feldspar grains that, prior to elution, had only CaS0₄ microcrystalline coatings; and (5) No Fe was deposited on Fe-poor grains with no microcrystalline surface coating.     

Geochemical controls on ground water composition at the Cripple Creek Mining District,Cripple Creek,Colorado

A combined approach involving evaluations of historical information, compositional trends, site mineralogy, and forward and inverse geochemical modeling was used to assess the effects of Au mining on ground water quality at the Cripple Creek Mining District. The District is located in a Tertiary volcanic diatreme complex surrounded by Precambrian granite. Historically, mining activity was underground whereas present-day mining occurs in surface mines. Between 1896 and 1941, a series of tunnels was excavated to drain the underground mining areas. The Carlton Tunnel, located about 900–950 m below the surface, is the primary ground water drain for the mining areas. Ground water flowing from the Carlton Tunnel has historically been of good quality. The geochemical processes controlling the quality of the Carlton Tunnel water were the focus of this study. Mineralogical and acid/base accounting data indicate that the diatreme is zoned vertically from an oxidized condition with acidic paste-pH, acidic ground water, and elevated metal concentrations near the surface to an alkaline condition with high pH, elevated SO₄, and low metal concentrations at depth. The average travel time of water from the surface to the Carlton Tunnel is estimated to be at least 25a based on ³H determinations. Forward geochemical modeling results indicate that this travel time is sufficient for ground water to reach equilibrium with calcite, gypsum, and fluorite by the time it exits through the Carlton Tunnel. Equilibrium processes have effectively fixed the pH, alkalinity, and SO₄ in the Carlton Tunnel water to near-constant levels for at least 24–70a based on comparisons to historically reported water compositions. Inverse geochemical modeling results indicate that there is sufficient neutralization capacity at depth in the diatreme to maintain the current good quality of the ground water flowing from the Carlton Tunnel for the forseeable future, assuming no significant changes in hydrogeochemical conditions.     

Stratigraphic and structural controls on groundwater salinity variations in the Poso Creek Oil Field,Kern County,California, USA

Hydrogeology Journal - Groundwater total dissolved solids (TDS) distribution was mapped with a three-dimensional (3D) model, and it was found that TDS variability is largely controlled by...     

Multiple paleosols of the late Albian Boulder Creek Formation, British Columbia, Canada

Fifteen lithified paleosols, closely spaced in vertical sequence, occur in the top 90 m of the late Albian Boulder Creek Formation in the foothills of northeastern British Columbia, Canada. The paleosols have well-developed profiles 0·5 to 1·5 m thick, including A, B and C horizons. The paleosols are characterized by their grey colour, cutans, vertical roots, peds, spherulitic siderite and absence of sedimentary structures. The paleosols formed during a period when one or more basin wide unconformities occurred as a result of either eustatic sea level fluctuations or local tectonic events. These unconformities represent the terrestrial record of a lowered base level which caused valley incision and decreased rates of sedimentation on the incised flood plain. The climate was humid to subhumid. Overall, the environment in which these soils developed was of low relief and subject to little erosion. The water table was high for part of the year but there is also evidence of periodic drying and oxidation of organic debris. Cumulatively, the paleosols in this interval may represent 150000 yr of non-deposition.     

Geochemical evolution of groundwater in the Maneadero coastal aquifer during a dry year in Baja California, Mexico

Water pumped from 25 shallow wells (<31 m) in the Maneadero unconfined coastal aquifer was studied geochemically in order to determine the short-term compositional variability of the aquifer due to seawater intrusion during a drier than normal year (Fall 2001 to Fall 2002). The groundwater was commonly found to be mixed with seawater, with TDS concentrations in November 2002 ranging from 0.99 to 9.46 g l^–1, having an intermediate Na⁺Cl^– to Ca²⁺Cl^– water-type. Rapid recharge events of short duration, after low and short rainfall events during the study period, are suggested from short-term fluctuations in water quality. Seawater intrusion is progressing faster in the central and southern coastal sections of the aquifer and has recently affected the quality of the sites pumping water to the nearby city of Ensenada. Only one of the wells used for the Ensenada water supply had a TDS concentration lower than the 1.0 g l^–1 official limit. Low flow rates and high residence times of water are inferred to be the cause for high alkalinity in the east-central section of the aquifer. High NO₃ in the east-central aquifer indicates that any NO₃ infiltration due to fertilizer use was only slightly dispersed. After a short rainfall season during winter 2001, a significant decrease was seen for the previously most enriched site. However, concentrations above the 10 mg l^–1 official limit persisted in 2002, affecting one well for urban supply (15.9 mg l^–1). The water from this well is nevertheless mixed with better-quality water from other wells before being distributed through the citys piping system.

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Resumen Se estudió la geoquímica de aguas bombeadas por medio de 25 pozos no muy profundos (<31 m) en el acuifero costero no confinado de Maneadero con el objetivo de determinar la variación de la composición en el corto plazo en el acuifero por la intrusión de agua de mar durante un año más seco de lo normal (otoño 2001 a otoño 2002). Se observó que comúnmente las aguas subterráneas estaban mezcladas con agua de mar, con concentraciones de sólidos totales disveltos (STD) de entre 0.99--9.46 g l^–1 y un tipo de agua intermedia Na⁺Cl^– to Ca²⁺Cl^–. A partir de las fluctuaciones en la calidad del agua en el corto plazo se puede inferir que se dan eventos de recarga rápida de poca duración después de eventos de poca lluvia de poca duración y poco volumen durante el periodo de estudio. La intrusión de agua de mar está progresando más rápido en el centro y sur del acuifero costero y ha afectado recientemente la calidad de los sitios de bombeo de agua para la ciudad de Ensenada. Solamente uno de los pozos usados para el abastamiento de Ensenada tiene un STD por debajo del límite oficial de 1.0 g l^–1. Se presume que las razones lentas de flujo y los tiempos de residencia largos del agua son la causa de la alta alcalinidad en el centro-este del acuifero. Una concentración alta de NO₃ en el este-centro del acuifero indica que cualquier infiltración de NO₃ por aplicación de fertilizantes ha sido poco dispersad. Después de poca lluvia en el invierno de 2001, se observó una disminución importante en la zona previamente más enriquecida. Sin embargo, concentraciones sobre el límite oficial de 10 mg l^–1 continuaron en 2002, afectando a un pozo para suministro de agua urbana (15.9 mg l^–1). El agua extraída de este pozo es mezclada con agua de mejor calidad y se distribuye por el sistema urbano de suministro de agua.

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Résumé Leau de pompage de 25 puits peu profonds (<31 m) situés dans laquifère côtier non-confiné de Maneadero a été étudiée dans le but de déterminer la variation géochimique à court terme qui résulte de lintrusion deau de mer lors dune année plus sèche quà lhabitude (automne 2001 à automne 2002). Leau souterraine est souvent retrouvée mélangée avec de leau de mer, avec des concentrations en résidus solides dissous (RSD) qui sétalent entre 0.99 et 9.46 g l^–1 pour novembre 2002, avec un type intermédiaire en Na⁺Cl^– jusquà Ca²⁺Cl^–. Les processus suggérés pour les fluctuations rapides de la qualité de leau sont des événements de recharge de courte duré suite à de faibles et brèves périodes de précipitations. Lintrusion deau de mer progresse plus rapidement dans les parties centrales et sud de laquifère côtier où la qualité de leau pompée vers la ville de Ensenada a récemment été affectée. Un seul des puits utilisés par la ville de Ensenada pour lapprovisionnement en eau potable a une concentration en RSD sous la limite officielle permise de 1.0 g l^–1. Le temps de résidence élevé et le faible taux découlement de leau souterraine sont présumés être la cause de lalcalinité élevée dans la partie centrale-est de laquifère. La concentration élevée en NO₃ dans cette partie de laquifère indique que la totalité de linfiltration de NO₃ dû à lutilisation de fertilisants ne sest que très peu dispersée. Suite à une courte saison des pluies à lhiver 2001, une diminution substantielle a été notée au site qui était le plus enrichi avant la saison des pluies. Malgré tout, des concentrations dépassant la limite officielle permise de 10 mg l^–1 ont persisté, affectant un puits utilisé pour lapprovisionnement urbain (15.9 mg l^–1). Leau provenant de ce puits est toutefois mélangée avec de leau de meilleure qualité provenant dautres puits avant dêtre distribuée par laqueduc municipal.

     

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

     

重庆金佛山泉水地球化学特征及其空间分布意义

2006年7月和9月在重庆金佛山地区选取22个地下水出露的泉点.对泉水的地球化学性质进行详细调查。利用野外和实验室测量手段得到了主要阴离子和阳离子浓度与物理化学参数。分析得知:研究区泉水的水化学类型为Ca-HCO_3和Ca、Mg-HCO_3;结合地质和地貌背景把它们分为6个泉群,分别讨论各泉群的空间分布意义;估算泉水方解石(SI_C)、白云石(SI_D)和石膏(SI_G)的饱和指数,即可反映地层岩性、地形和地下水的运移时间对水质的影响,该区地下水基本上是来自大气降水的下渗.没有深部含水层的上升混合.这些泉水的地球化学特征以及它们的空间分布规律能够很好地反映区内地质状况.该研究可以为金佛山地区地下水资源的调查和环境保护提供基础数据。     

Saline groundwater seepage zones and their impact on soil and water resources in the Spicers Creek catchment,central west,New South Wales,Australia

Saline seepage zone development and hence dryland salinity is a major environmental problem which many arid to semiarid landscapes in Australia are experiencing. Due to the geological complexity of the regional aquifer system and the heterogeneous nature of the local groundwater system, each groundwater seepage zone in the Spicers Creek catchment, central west, New South Wales, Australia possesses different mechanisms which control its development. Saline seepage zones have formed adjacent to a fault zone, and two experimental sites were established through these groundwater discharge zones to understand geochemical processes which have led to the development of soil sodicity, gully erosion and the flushing of salts into the surface water systems. Seepage zone groundwaters contain a distinctive geochemical signature with elevated concentrations of Na, Cl, HCO₃, Ca, Sr, B, As and Li. The mixing of deep saline groundwaters together with ion exchange processes lead to a distinctive seepage zone groundwater chemistry being developed. Altering the landscape features within this rural groundwater system has developed water toxicity for crops, soil sodicity leading to land degradation, and waterlogging problems.     

Geohydrological models and earthquake effects at Yucca Mountain, Nevada

 Yucca Mountain, the proposed site for the high-level nuclear waste repository, is located just south of where the present water table begins a sharp rise in elevation. This large hydraulic gradient is a regional feature that extends for over 100 km. Yucca Mountain and its vicinity are underlain by faulted and fractured tuffs with hydraulic conductivities controlled by flow through the fractures. Close to and parallel with the region of large hydraulic gradient, and surrounding the core of the Timber Mountain Caldera, there is a 10- to 20-km-wide zone containing few faults and thus, most likely, few open fractures. Consequently, this zone should have a relatively low hydraulic conductivity, and this inference is supported by the available conductivity measurements in wells near the large hydraulic gradient. Also, slug injection tests indicate significantly higher pressures for fracture opening in wells located near the large hydraulic gradient compared to the opening pressures in wells further to the south, hence implying that lower extensional stresses prevail to the north with consequently fewer open fractures there. Analytical and numerical modeling shows that such a boundary between media of high and low conductivity can produce the observed, large hydraulic gradient, with the high conductivity medium having a lower elevation than the water table. Further, as fractures can close due to tectonic activity, the conductivity of the Yucca Mountain tuffs can be reduced to a value near that for the hydraulic barrier due to strain release by a moderate earthquake. Under these conditions, simulations show that the elevation of the steady-state water table could rise between 150 and 250 m at the repository site. This elevation rise is due to the projected shift in the location of the large hydraulic gradient to the south in response to a moderate earthquake, near magnitude 6, along one of the major normal faults adjacent to Yucca Mountain. As the proposed repository would only be 200–400 m above the present water table, this predicted rise in the water table indicates a potential hazard involving water intrusion. Received: 7 June 1996 / Accepted: 19 November 1996     

贵州赫章铁矿山泥盆系地层地球化学特征及其与晚古生代裂陷作用关系

对贵州赫章铁矿山地区泥盆系地层、构造和晚古生代裂陷槽的特征进行研究,用分析地层地球化学特征论述泥盆系各地层与裂陷槽之间的关系。通过对泥盆纪地层岩性、(La/Yb)N值和Ce/Ce*值等稀土元素特征值的分析认为各地层的形成受到了裂陷槽的控制,也反映出裂陷槽的详细变化过程。     

Electrical methods of detecting contaminated groundwater at the stringfellow waste disposal site,riverside county,California

At the Stringfellow Class I waste-disposal site near Riverside, California, the influence of variations in groundwater chemistry and saturation on electrical measurements made from the surface was tested Spontaneous potential, D C electrical sounding, dipole-dipole resistivity profiles, and mise-a-la-masse measurements were employed to investigate the sub-surface migration of the acidic fluids deposited in this site between 1956 and 1972 Mise-a-la-masse exploration conducted at the downstream edge of the site detected a major anomaly which, on excavation, proved to be the signature of a previously unsuspected leak from the surface disposal ponds on the site Downstream from the site, a dipole-dipole profile and electrical soundings correlate well with electrical conductivity of groundwater obtained from monitoring wells This study demonstrates that geophysical methods may be used to search for and map leaks from toxic chemical waste dumps     

Geochemical characteristics of crustal anatexis during the formation of migmatite at the Southern Sierra Nevada,California

We provide data on the geochemical and isotopic consequences of nonmodal partial melting of a thick Jurassic pelite unit at mid-crustal levels that produced a migmatite complex in conjunction with the intrusion of part of the southern Sierra Nevada batholith at ca. 100 Ma. Field relations suggest that this pelitic migmatite formed and then abruptly solidified prior to substantial mobilization and escape of its melt products. Hence, this area yields insights into potential mid-crustal level contributions of crustal components into Cordilleran-type batholiths. Major and trace-element analyses in addition to field and petrographic data demonstrate that leucosomes are products of partial melting of the pelitic protolith host. Compared with the metapelites, leucosomes have higher Sr and lower Sm concentrations and lower Rb/Sr ratios. The initial ⁸⁷Sr/⁸⁶Sr ratios of leucosomes range from 0.7124 to 0.7247, similar to those of the metapelite protoliths (0.7125–0.7221). However, the leucosomes have a much wider range of initial ε_Nd values, which range from −6.0 to −11.0, as compared to −8.7 to −11.3 for the metapelites. Sr and Nd isotopic compositions of the leucosomes, migmatites, and metapelites suggest disequilibrium partial melting of the metapelite protolith. Based on their Sr, Nd, and other trace-element characteristics, two groups of leucosomes have been identified. Group A leucosomes have relatively high Rb, Pb, Ba, and K₂O contents, Rb/Sr ratios (0.15<Rb/Sr<1.0), and initial ε_Nd values. Group B leucosomes have relatively low Rb, Pb, Ba, and K₂O contents, Rb/Sr ratios (<0.15), and initial ε_Nd values. The low Rb concentrations and Rb/Sr ratios of the group B leucosomes together suggest that partial melting was dominated by water-saturated or H₂O-fluxed melting of quartz + feldspar assemblage with minor involvement of muscovite. Breakdown of quartz and plagioclase with minor contributions from muscovite resulted in low Rb/Sr ratios characterizing both group A and group B leucosomes. In contrast, group A leucosomes have greater contributions from K-feldspar, which is suggested by: (1) their relatively high K concentrations, (2) positive or slightly negative Eu anomalies, and (3) correlation of their Pb and Ba concentrations with K₂O contents. It is also shown that accessory minerals have played a critical role in regulating the partitioning of key trace elements such as Sm, Nd, Nb, and V between melt products and residues during migmatization. The various degrees of parent/daughter fractionations in the Rb–Sr and Sm–Nd isotopic systems as a consequence of nonmodal crustal anatexis would render melt products with distinct isotopic signatures, which could profoundly influence the products of subsequent mixing events. This is not only important for geochemical patterns of intracrustal differentiation, but also a potentially important process in generating crustal-scale as well as individual pluton-scale isotopic heterogeneities.     

Zonal Distribution of Variations in Structural State of Alkali Feldspar within the Rader Creek Pluton, Boulder Batholith, Montana

The granodioritic Rader Creek pluton of the composite Boulderbatholith contains microperthitic alkali feldspar of bulk compositionOr₆₅ to Or₈₆ with a structurally variable potassic phase. Completecell parameters, 2V measurements, and bulk composition are givenfor 11 feldspar samples. The 131 and 131 reflections for theseand 58 additional samples show the following structural typesin the potassic phase: orthoclase only; orthoclase with subordinatemaximum or near-maximum microcline (obliquity = 0.75–1.00);orthoclase with subordinate intermediate microcline (obliquity= 0.64–0.71); and intermediate microcline (obliquity =0.56–0.77) with subordinate orthoclase. Within the plutondifferent feldspar structural types occur in zones whose boundariesare approximately parallel to contacts with younger intrusiverocks cutting the Rader Creek pluton but are, in places, nearlyperpendicular to zonation within the pluton defined by rockcomposition. In general, the orthoclase zone is closest to thecontact with younger intrusives; the intermediate microclinezone is the most distant. Bulk compositions of alkali feldsparare more potassic in the orthoclase zone than elsewhere. Thedata suggest a complex history for the alkali feldspar, involvingat least two stages: 1. Exsolution and partial inversion oforthoclase to intermediate microcline during cooling of theRader Creek pluton; 2. Transformation of the intermediate-microclineassemblage to orthoclase during reheating of the pluton at thetime of intrusion of younger plutons of the batholith. The transitionalstage in this transformation is characterized by orthoclaseco-existing with subordinate microcline, whose obliquity usuallyapproaches that of maximum microcline.     

Wash-out processes of evaporitic sulfate salts in the Tinto river: Hydrogeochemical evolution and environmental impact

This work deals with the wash-out processes of evaporitic salts in the Tinto river in October 2005, with the arrival of the first rainfall after the summer. In order to monitor water levels and electrical conductivity, a datalogger was set up in the river, while sampling was performed by a portable autosampler. Thirty-two samples were selected for analysis for a wide range of elements by ICP-AES. Three different flood events, with a maximum discharge of 8.1 m³/s, were monitored. River waters suffered from a dilution effect at the beginning of the first event, recording a concentration decrease of most elements, just before the wash-out of soluble salts precipitated during the summer took place. Wash-out processes provoked a sharp increase in most element concentrations coinciding with an intense decrease in Na and Sr. After the first event, there was strong enrichment of As, and to a lesser extent in Fe, Cr and Pb, due probably to the redissolution/transformation of Fe oxyhydroxysulfates. During the third event, evaporitic sulfate salts were depleted from riverbanks ending wash-out processes, and a decrease in most element concentrations was observed. Barium exhibited different behaviour to the rest of elements owing to the solubility control exerted by barite. Lead also showed a different pattern throughout the study period, its concentration decreasing due probably to its great affinity for coprecipitate on jarosite-group minerals, and increasing when schwertmannite precipitation is thermodynamically favoured. In October 2005, the Tinto river carried around 8100 t SO₄, 1300 t Fe, 400 t Al, 100 t Zn and Cu, etc., highlighting the importance of wash-out processes of soluble salts in the Ría de Huelva ecosystem and metal fluxes into the Atlantic Ocean.     

Hydrochemical evolution and variation of groundwater and its environmental impact at Sohag, Egypt

Groundwater resources of Sohag, Egypt are currently threatened by contamination from agricultural and urbanization activities. Groundwater in Sohag area has a special significance where it is the second source for fresh water used for agricultural, domestic, and industrial purposes. Due to growing population, agriculture expansion, and urbanization, groundwater quality assessment needs more attention to cope with the increasing water demand in this arid zones and limited water resources. The aim of this paper is to address the integrated role of geochemical processes, agriculture and urbanization in evolution of groundwater composition, and their impact on groundwater quality to help in management and protection of groundwater resources of study area using geochemical modeling techniques and geographical information systems. Spatial variation of groundwater hydrochemical properties, rock–water interaction, ion exchange, and assessment of groundwater quality were investigated. Results indicated that groundwater properties are varied spatially and its evolution in the study area is generally controlled by the prevailed geochemical processes represented by leaching, dissolution, and precipitation of salts and minerals, ion exchange, in addition to human activities represented by agriculture and urbanization as well as climatic and poor drainage conditions. Management alternatives should be followed in the study area to avoid degradation of groundwater quality and provide sustainable development.     

北大别山仙桥中生代酸性火山岩地球化学特征、锆石U-Pb年龄及其成矿构造背景

东秦岭-北大别山构造-岩浆演化是热点研究问题,关于该带火山岩喷发时限存在较大的争议,其岩石成因和成岩构造环境尚不清楚。对北大别山西段仙桥膨润土矿床英安岩进行锆石U-Pb同位素测年和岩石地球化学研究,结果表明,仙桥酸性火山岩具有高钾(3.96%~5.01%)、富碱(K2O+Na2O介于7.97%~8.96%之间)、弱过铝质(A/CNK为1.0~1.15)等特点,属高钾钙碱性-钾玄岩系列火山岩。岩石轻稀土元素富集,重稀土元素亏损明显,负Eu异常不明显,Nb、Ta亏损明显,且具有高Nb/Ta、(La/Yb)N、Sr/Y值,表现为典型的埃达克质岩石地球化学特征。LA-ICP-MS锆石U-Pb同位素定年测得,仙桥成矿岩石英安岩喷发年龄为133±1 Ma,与邻区双桥膨润土、皇城山银矿床陈棚组火山岩的年龄一致。研究认为,仙桥火山岩具有埃达克岩的特征,由增厚下地壳物质部分熔融形成,产生于中生代后碰撞构造环境,在133 Ma左右,北大别山仙桥地区还未发生大规模的拆沉减薄的岩浆活动。     

Petrology of the Caribou Mountain Pluton, Klamath Mountains, California

The Caribou Mountain pluton is a small trondhjemitic body thatintruded semipelitic schist of the Stuart Fork terrane in lateMiddle Jurassic to Early Cretaceous time. Its emplacement followedthe intrusion of an adjoining body of hornblende quartz dioritecalled the Middle Fork pluton and the mode of its emplacementwas as an asymmetric ballooning diapir (Davis, 1963), as shownby concentric foliation, radial late-stage dikes, foliated enclaves,and folded blocks of schlieren-banded tonalite. Coarse-grainedhornblende-bearing trondhjemite is the dominant rock type inthe Caribou Mountain pluton, and it is called the ‘maintrondhjemite’. It was followed by medium-grained ‘latetrondhjemite’ and by late-stage trondhjemitic and granodioriticdikes. All the trondhjemitic rock types are characterized bylow alkali contents, high light rare earth elements, low initial⁸⁷Sr/⁸⁶Sr, and low ¹⁸O. However, the late trondhjemite has higherNa₂O and a higher initial ⁸⁷Sr/⁸⁶Sr value than the main trondhjemite,and the two units cannot be related by fractional crystallization.The late granodioritic dikes are richer in Ba, Rb, Y, and Scthan the late trondhjemite and probably reflect assimilationof Stuart Fork metasedimentary rocks by late-stage trondhjemiticmagma. Mafic enclaves in the main trondhjemite contain xenocrysts ofquartz and plagioclase derived from the host by magma mixing.The enclaves have K₂O, Ba, and Rb contents similar to, or higherthan those of the host rocks. Their rare earth element (REE)patterns display strong middle REE enrichment caused by accumulationof hornblende, probably as the result of filter pressing. The main trondhjemite cannot be derived from Middle Fork magmabecause the initial ⁸⁷Sr/⁸⁶Sr of the Middle Fork pluton is lowerthan that of the trondhjemite. The absence of parental maficmagmas of appropriate composition suggests that the CaribouMountain trondhjemitic magmas formed by partial melting of anamphibolitic source rock compositionally similar to low-K tholeiite.     

Structure and Petrology of the Alpine-type Peridotite at Burro Mountain, California, U.S.A.

The alpine-type peridotite at Burro Mountain is a partiallyserpentinized harzburgite-dunite body approximately 2 km indiameter. It lies in a chaotic mélange derived from theFranciscan Formation (Upper Jurassic to Upper Cretaceous) ofthe southern Coast Ranges of California. The peridotite is boundedon the east by a vertical fault in the Nacimiento fault zonethat brings sedimentary rocks of Taliaferro's (1943b) AsuncionGroup (Upper Cretaceous) into contact with the peridotite. Theperidotite appears to be one of a number of tectonic lenses,having a wide range in size, that make up the mélange.These lenses include metagraywacke, metachert, greenstone, amphibolite,and blueschist, as well as ultramafic rocks, and represent awide range of pressure-temperature environments. The outer shell of the peridotite is a sheared serpentinitezone 10–15 m thick. The peridotite was tectonically emplacedat its present level as a cold solid mass and had little effecton the mineral assemblages of the Franciscan Formation. Localdevelopment of lawsonite and aragonite in shear zones may berelated to the peridotite emplacement. Foliated harzburgite forms approximately 60 per cent of theperidotite. It is a lithologically uniform rock that has anolivine: orthopyroxene ratio of approximately 75:25. Accessoryclinopyroxene and chromian spinel generally make up less than5 per cent of the harzburgite. Dunite, composed of olivine,accessory chromian spinel (< 5 per cent), and trace amountsof pyroxene, makes up approximately 40 per cent of the peridotiteand occurs as dikes, sills, and irregular bodies in the harzburgite. Olivine and pyroxene show small but significant compositionalvariations and chromian spinel shows a large range in the cationratio Cr/(Cr+Al+ Fe³⁺). The compositional variations in theseminerals are related to original differences in bulk chemicalcomposition. The following compositional ranges were determinedfor minerals in the harzburgite: olivine, Fo_91.1–Fo_91.4;orthopyroxene, En_89.8–En_91.1; clinopyroxene, Ca_47.0Mg_50.0Fe_3.0–Ca_48.7Mg_48.2Fe_3.1;chromian spinel, Cr/(Cr+Al+Fe³⁺) 0.37–0.55. The pyroxeneshave a range in A1₂O₃ content of 1.3–3.0 wt per cent.Olivine from dunite ranges from Fo₉₁ to Fo_{92 7} and the chromianspinel has a range in the Cr/(Cr+Al+Fe³⁺) ratio of 0.30–0.75.Although all the dunites are lithologically similar, three distincttypes are recognized on the basis of composition of coexistingolivine and chromian spinel. Structural relations between thethree types of dunite suggest three periods of emplacement (possiblyoverlapping) of dunite into harzburgite. The evidence indicatesthat the dunite, and probably also the harzburgite crystallizedfrom an ultramafic magma, probably in the upper mantle. After the magmatic episode and crystallization, the peridotitewas subjected to a deep-seated plastic deformation and recrystallization.The first phase of the deformation produced a pervasive, planarstructural element (S₁) that crosscuts many harzburgite-dunitecontacts. It is probable that some of the dunite sills wereemplaced during this deformation. The foliation, S₁, is definedby layers of different orthopyroxene content in harzburgite,and by discontinuous layers of chromian spinel in dunite. Flowor slip along S₁ produced slip folds in harzburgite—dunitecontacts with axial planes parallel to S₁. At a later stage,isoclinal folds developed in S₁, and the present olivine microfabricwas probably formed by recrystallization in the stress fieldthat produced the isoclinal folding. In the olivine microfabric,X tends to be perpendicular to the axial planes (S₂) of theisoclinal folds and Y and Z tend to form double maxima in S₂approximately 90° apart. Mg–Fe²⁺ distribution betweencoexisting mineral pairs yields a calculated temperature offormation of approximately 1200 °C. Although this temperatureis only a nominal value, it indicates that the mineral pairsequilibrated at a significantly high temperature. In view ofthe deformation and recrystallization, the calculated temperaturepossibly represents subsolidus re-equilibration of the mineralsduring this event. The deformation and recrystallization probablyoccurred shortly after crystallization while the peridotitewas still at a high temperature. A later deep-seated deformation produced small scattered kinkfolds in S₁ that tend to disrupt the major olivine microfabric.The kink folding was accompanied or followed by the developmentof kink bands in olivine that reflect intragranular glidingon the system T = [Okl], t = [100]. The kink bands probablyformed at a minimum temperature of 1000 °C. Following the deep-seated deformation, which probably took placein the mantle, the peridotite mass was tectonically detachedand moved upward to its present level in the crust. Cleavages,joints, and faults provided channels for water to pervade theperidotite and allow alteration of the primary minerals.