超高压榴辉岩金红石中高场强元素变化的控制因素及其地球动力学意义

利用LA-ICP-MS对CCSD-MH超高压榴辉岩中金红石进行了详细的原位微区微量元素组成分析.金红石中高场强元素Nb和Ta含量主要受全岩Nb、Ta和TiO₂含量控制, Zr、Hf含量比较稳定基本不受全岩含量影响.粒间金红石中, 同一颗粒金红石核部Zr含量系统高于边部, 而边部则出现了明显的Pb和Sr富集特征.CCSD-MH榴辉岩中金红石与全岩的Nb/Ta比值呈现明显的不一致性.全岩Nb/Ta比值明显低于金红石且与全岩TiO₂含量负相关, 而金红石的Nb/Ta比值与全岩Nb、Ta含量和Nb/Ta比值没有明显的相关关系.金红石和全岩之间非完全耦合的Nb/Ta组成表明, 金红石并非形成于原岩的结晶过程中而是在超高压变质作用过程中形成, 尽管金红石是榴辉岩中Nb、Ta含量的主要载体矿物, 但金红石的Nb/Ta比值并不一定能完全代表全岩的特征, 而与全岩Nb、Ta和TiO₂的含量有关.粒间金红石核部Zr含量所记录的温度与粒径之间具有明显的正相关性, 反映金红石中的Zr在其形成后没有封闭.粒间金红石所表现出的明显的边部富集Pb和Sr的特征, 反映了后期流体活动对金红石组成的影响.这些研究结果为金红石中Zr在高温下的扩散作用和后期流体活动的影响提供了重要证据, 这可能是利用金红石Zr含量地质温度计计算的苏鲁-大别榴辉岩变质温度(598~827℃) 偏低的主要原因.      

西藏松多地区超基性岩地球化学特征及对松多古特提斯洋演化的启示

唐加-松多古特提斯缝合带的提出改变了地学界对青藏高原古特提斯演化格局的认识。为进一步约束唐加-松多古特提斯缝合带中蛇绿岩的岩石成因及类型, 以松多地区的超基性岩为研究对象, 对其进行了岩石学和全岩地球化学研究。结果显示, 松多地区超基性岩与原始地幔相比具有较高的MgO和TFe2O3含量, 以及较低的Al2O3和TiO2含量。样品稀土元素总含量介于4.04×10-6~9.31×10-6之间, 大部分低于原始地幔值。稀土元素配分曲线呈较宽缓的"U"型, 轻稀土元素较富集。微量元素分布形式与全球深海橄榄岩的微量元素分布形式基本一致, 具有明显的Th、Nb负异常, 大部分样品具有轻微的Zr、Hf负异常。定量模拟估算表明, 研究区超基性岩主要为尖晶石二辉橄榄岩地幔批式熔融后的难熔残留体, 熔融程度大于25%, 并具一定程度石榴子石相熔融的特征, 未受到后期岩石-熔体反应的改造, 其原岩应为亏损的深海橄榄岩。结合区域研究成果, 松多地区超基性岩可能形成于大洋中脊(MOR)环境, 为典型的大洋中脊玄武岩(MORB)型蛇绿岩端元之一。     

Ultramafic Blocks in Sumdo Region, Lhasa Block, Eastern Tibet Plateau: An Ophiolite Unit

Recently, an over 100 kin long MORB-type eclogite belt of Permian was discovered in the Sumdo (松多) region of the Lhasa block, Tibet. A critical question thus is: what is the tectonic setting of the eclogite belt and is it related to an unrecognized suture in the region? Further investigations show that there are some mafic and ultramafic rocks spatially associated with the eclogite belt in the region. Three ultramafic massifs were recognized in the Sumdo region, and called the Luomaling (罗马岭),Gongbupala (贡布爬拉) and Qiazhasumdo (卡扎松多) massifs. All the massifs are fault-contacted with greenschist (Chasagang (岔萨岗) Formation) or muscovite-quartz schist (Mabuku (马布库) Formation), and individuals are about 100 m×50 m in size extending in EW as the regional structure. All the ultramafic rocks have been entirely serpentinized, and the Gongbupala massif has been selected for study in geochemistry. Eleven chemical analyses of the rocks from the Gongbupala massif show a narrow range in contents: SiO2(35.97-40.63) wt.%, MgO (37.02-38.60) wt.%, TiO2(0.01-0.08) wt.%, Al2O3 (0.80-1.64) wt.%, (Na2O+K2O) less than 0.1 wt.%, with high volatile contents (H2O+CO2) (11.24-14.91) wt.%. After recalculation without H2O+CO2, the mean values are SiO2 45.24 wt.%, MgO 43.54 wt.%, FeOT(7.45-9.97) wt.% (8.55 wt.% in average), (MgO+FeOT) 52.09 wt.%, Mg# (100×Mg/(Mg+Fe*), where Fe* represents total Fe)=89.42-90.08, (m+f)/Si ((atomicity Mg+atomicity Fe) /atomicity Si)=1.53-1.75 (1.59 in average), respectively. The mean M/F (atomicity Mg/atomicity Fe) ratio of the rocks is 9.05, which is classified as magnesium enriched-type of ultramafic rocks. The compositional features, depleted in K, Na, Ca, Al and Ti and enriched in Mg#, indicate the characteristics of peridotite originated from a depleted mantle. The rocks have low ∑ REE with (1.60-2.68)×10-6 similar to those of the primitive mantle. The chondrite-normalized REE patterns of all samples show slightly enrichment in LREE, with (Ce/Yb)N 1.03-2.46, but a little depleted in HREE. Most samples show a slight negative anomaly in Eu, a feature In REE from a relic mantle and common features In highly serpentinized ultramafic rocks in the Yarlung-Zangbo (雅鲁藏布) ophiolite and the Bangong (班公)-Nnjiang (怒江)ophiolite in Tibet. The primitive mantle-normalized spiderdiagram of trace elements for Gongbupala ultramafic rocks yields uniform distributed pattern. They are relatively enriched in Rb, Ba, La, P element (LHSE) and depleted in Sin, Ti, Y, Yb element (HFSE), a feature of metasomatic mantle peridotite. The geochemical features of the rocks suggest that the protofith of Gongbupala serpentinite in Sumdo region is harzburgite, a typical depleted mantle rock, and may represent a dismembered ophiolite unit in the region.     

拉萨地块松多高压变质带不同类型榴辉岩的变质演化过程及其限定方法探讨

拉萨地块中东部松多高压变质带是揭示拉萨地体形成与演化过程的重要研究对象。松多变质带记录了古特提斯洋的俯冲和闭合过程。前人对松多地区出露的榴辉岩及围岩开展了大量的岩石学工作,但变质峰期温压条件没有得到很好的限定,温压分布范围较广,且变质演化过程仍存争议。笔者等总结了松多变质带不同地区榴辉岩的岩石学和矿物学特征,汇总了不同计算方法得到的温压条件。通过对比发现,松多高压变质带内榴辉岩的峰期温压条件处于465~880℃,2.5~3.9 GPa的范围,其宽泛的峰期温压条件是由于不同计算方法和折返机制造成的。与传统矿物对温压计相比,变质相平衡模拟方法更适合低温榴辉岩的峰期温压条件及变质过程的限定。     

拉萨地块松多高压变质带不同类型榴辉岩的变质演化过程及其限定方法探讨

拉萨地块中东部松多高压变质带是揭示拉萨地体形成与演化过程的重要研究对象。松多变质带记录了古特提斯洋的俯冲和闭合过程。前人对松多地区出露的榴辉岩及围岩开展了大量的岩石学工作,但变质峰期温压条件没有得到很好的限定,温压分布范围较广,且变质演化过程仍存争议。笔者等总结了松多变质带不同地区榴辉岩的岩石学和矿物学特征,汇总了不同计算方法得到的温压条件。通过对比发现,松多高压变质带内榴辉岩的峰期温压条件处于465~880℃,2.5~3.9 GPa的范围,其宽泛的峰期温压条件是由于不同计算方法和折返机制造成的。与传统矿物对温压计相比,变质相平衡模拟方法更适合低温榴辉岩的峰期温压条件及变质过程的限定。     

金红石和榍石Zr温度计在新疆西南天山榴辉岩中的应用

应用LA-ICP-MS方法对新疆西南天山高压-超高压变质带中的榴辉岩及其高压脉体中的金红石和榍石进行了Zr含量的检测和Zr温度计的计算。榴辉岩中位于石榴石幔部且与绿辉石共生的金红石包体Zr含量都集中于10~20μg/g;而基质金红石的Zr含量为30~50μg/g,高于包体金红石。榍石均为金红石退变质的产物,且各样品间的榍石Zr含量较均一,都集中在3~5μg/g之间。脉体金红石Zr含量则与榴辉岩中基质金红石的Zr含量相当甚至偏高一些,为30~60μg/g。金红石和榍石的Zr温度计研究也表明,榴辉岩石榴石中的金红石包体生长于压力峰期阶段,温压条件为480~540℃、2.7~3.0 GPa;基质金红石随温度增加达到退变质再平衡,记录了温度峰期的条件,约530~590℃、2.4~2.7 GPa;榴辉岩中高压脉体中的金红石则生长于退变质榴辉岩相阶段,金红石Zr温度计给出结果为540~580℃、1.5~2.1 GPa,记录了近等温降压的过程;榴辉岩中的榍石在1.0 GPa左右达到平衡,榍石Zr温度计给出的温度为540~560℃,记录了进一步的近等温降压的过程。根据以上4个阶段的分析结果,得出一个较完整的顺时针p-T轨迹,且与相平衡模拟所限定的p-T轨迹相一致。金红石的Zr含量可以作为压力的指示,表明压力校正在金红石Zr温度计中起到了重要作用。在对金红石和榍石Zr温度计进行应用时,要结合细致的岩相学观察,综合考虑压力、活度、扩散速率、退变质作用和流体影响等方面的因素,才能得到比较精确的温压估算结果和pT轨迹。     

Trace Elements of Multi-stage Minerals and Titanite U-Pb Dating for the Gneisses from Liansan Island, Sulu UHPM Belt

Gneisses with anatectic characteristics from the Liansan island in the Sulu UHPM (ultra-high pressure metamorphic) belt were studied for petrography, titanite U-Pb dating and mineral geochemistry. Three origins of garnets are distinguished: metamorphic garnet, peritectic garnet and anatectic garnet, which are formed in the stages of peak metamorphism, retrograde anatexis and melt crystallization, respectively. The euhedral titanite has a high content of REE and high Th/U ratios, which is interpreted as indicating that it was newly-formed from an anatectic melt. The LA-ICP-MS titanite U-Pb dating yields 214–217 Ma ages for the titanite (melt) crystallization. The distribution of trace elements varies in response to the different host minerals at different stages. At the peak metamorphic stage, Y and HREE are mainly hosted by garnet, Ba and Rb by phengite, Sr, Nb, Ta, Pb, Th, U and LREE by allanite and Y, U and HREE by zircon. During partial melting, Y, Pb, Th, U and REE are released into the melt, which causes a dramatic decline of these element contents in the retrograde minerals. Finally, titanite absorbs most of the Nb, U, LREE and HREE from the melt. Therefore, the different stages of metamorphism have different mineral assemblages, which host different trace elements.     

西藏松多地区早侏罗世变质辉长岩的成因及其构造意义

冈底斯岩浆岩带中东部松多地区新发现的变质辉长岩对于讨论松多古特提斯洋演化历史具有重要约束意义。在详细野外地质调查基础上,本文报道了松多变质辉长岩的LA-ICP-MS锆石U-Pb年龄、锆石Hf同位素成分分析和全岩地球化学组成,并探讨了岩石的成因及其对松多古特提斯洋构造演化的启示。结果表明,松多变质辉长岩原岩形成于195±6Ma～202±2Ma之间; Si O2含量为45. 56%～53. 69%,MgO含量较高为6. 04%～11. 75%,Mg#为66～77;高Cr(209×10-6～746×10-6)和Ni(80×10-6～234×10-6)含量。该岩石富集轻稀土元素,平滑右倾的稀土配分模式介于E-MORB和OIB之间;富集大离子亲石元素和Nb、Ta等高场强元素;具有较低的(La/Yb)N=2. 06～4. 81、(La/Sm)N=1. 50～2. 48、(Gd/Yb)N=1. 21～1. 67和(Ce/Y)N2。锆石εHf(t)值为-1. 9～3. 9,具相对古老Hf模式年龄(988～1361Ma)。综合对区域地质、年代学、岩石地球化学以及锆石Hf同位素等资料的全面分析,认为松多早侏罗世变质辉长岩原岩的岩浆可能起源于下地壳改造的亏损岩石圈地幔的部分熔融,形成于松多古特提斯洋壳板片断离事件所引发岩石圈减薄的伸展构造背景。     

青海省都兰县艾日克汗森地区榴辉岩地球化学特征及其地质意义

青海省都兰县艾日克汗森地区的榴辉岩位于都兰北榴辉岩带西北方向约12 km,是最新发现的较大规模榴辉岩产地。此榴辉岩为柴北缘高压-超高压变质带的一部分,大部分退变质程度较高。锆石U-Pb年龄为（435±4）Ma,代表了此榴辉岩峰期变质年龄;该榴辉岩SiO2含量为48.36%~49.22%,（Na2O+K2O）含量为3.28%~3.65%,Na2O含量均大于K2O;原岩为基性玄武岩,为亚碱性拉斑玄武岩系列,构造环境为大洋中脊玄武岩环境。榴辉岩稀土配分曲线表现为右倾型模式,弱富集轻稀土元素,亏损重稀土元素,（La/Sm）N=1.70~2.34,（La/Yb）N=1.18~2.54,属于幔源E-MORB型。微量元素表现为强烈亏损Th、P、Zr等高场强元素,富集Rb、Ba等大离子亲石元素。指示了柴北缘晚奥陶世到早志留世时期柴达木陆块与欧龙布鲁克微陆块的深俯冲与碰撞造山背景。     

榴辉岩类捕虏体的地球化学特征及其构造意义——来自徐淮地区中生代侵入杂岩中的信息

利用X-荧光光谱和ICPMS测试了徐淮地区中生代侵入杂岩中榴辉岩类捕虏体的组成.主量元素为: SiO₂的含量为40.88%~47.82%, TiO₂为0.78%~2.00%, Al₂O₃为11.72%~16.08%, FeO (全铁) 为12.77%~20.29%, MgO为5.23%~11.47%, CaO为7.80%~13.11%, Na2O为0.30%~2.09%, K₂O为0.13%~0.69%.榴辉岩类捕虏体具有较低的稀土元素丰度(Σ_REE= (34.26~115.51) ×10-6), 且具有明显的Nb、P、Zr和Ti的负异常.捕虏体的I(Sr) 和ε(Nd, t) 值分别为0.7042~0.7085和-5.77~2.99 (L-4为-13.05).上述特征暗示本区榴辉岩类捕虏体的原岩具有岛弧拉斑玄武岩的特征.榴辉岩类捕虏体Nd的模式年龄和其中锆石SHRIMPUPb年龄显示它们应属于华北克拉通的基底物质.华北克拉通基底物质发生的榴辉岩相变质作用暗示中生代早期华北克拉通东部曾存在一次重要的陆壳加厚过程, 这应与扬子克拉通沿北西或北西西方向深俯冲于华北克拉通之下有关.      

Origins of Xenolithic Eclogites and Pyroxenites from the Central Slave Craton, Canada

Major- and trace-element and Sr–Nd–Hf isotopic compositionsof garnet and clinopyroxene in kimberlite-borne eclogite andpyroxenite xenoliths were used to establish their origins andevolution in the subcontinental lithospheric mantle beneaththe central Slave Craton, Canada. The majority of eclogitescan be assigned to three groups (high-Mg, high-Ca or low-Mgeclogites) that have distinct trace-element patterns. Althoughpost-formation metasomatism involving high field strength element(HFSE) and light rare earth element (LREE) addition has partiallyobscured the primary compositional features of the high-Mg andhigh-Ca eclogites, trace-element features, such as unfractionatedmiddle REE (MREE) to heavy REE (HREE) patterns suggestive ofgarnet-free residues and low Zr/Sm consistent with plagioclaseaccumulation, could indicate a subduction origin from a broadlygabbroic protolith. In this scenario, the low REE and smallpositive Eu anomalies of the high-Mg eclogites suggest moreprimitive, plagioclase-rich protoliths, whereas the high-Caeclogites are proposed to have more evolved protoliths withhigher (normative) clinopyroxene/plagioclase ratios plus trappedmelt, consistent with their lower Mg-numbers, higher REE andabsence of Eu anomalies. In contrast, the subchondritic Zr/Hfand positive slope in the HREE of the low-Mg eclogites are similarto Archaean second-stage melts and point to a previously depletedsource for their precursors. Low ratios of fluid-mobile to lessfluid-mobile elements and of LREE to HREE are consistent withdehydration and partial melt loss for some eclogites. The trace-elementcharacteristics of the different eclogite types translate intolower _Nd for high-Mg eclogites than for low-Mg eclogites. Withinthe low-Mg group, samples that show evidence for metasomaticenrichment in LREE and HFSE have lower _Nd and _Hf than a samplethat was apparently not enriched, pointing to long-term evolutionat their respective parent–daughter ratios. Garnet andclinopyroxene in pyroxenites show different major-element relationshipsfrom those in eclogites, such as an opposite CaO–Na₂Otrend and the presence of a CaO–Cr₂O₃ trend, independentof whether or not opx is part of the assemblage. Therefore,these two rock types are probably not related by fractionationprocesses. The presence of opx in about half of the samplesprecludes direct crystallization from eclogite-derived melts.They probably formed from hybridized melts that reacted withthe peridotitic mantle. KEY WORDS: eclogites; pyroxenite xenoliths; mantle xenoliths; eclogite trace elements; eclogite Sr isotopes; eclogite Hf isotopes; eclogite Nd isotopes     

Geochemical Characteristics and Implications of Eclogite Gravels from Mesozoic Strata at the Northern Margin of Dabie Orogenic Belt

The eclogite gravels, which were found in the Mesozoic Fenghuangtai and Maotanchang formations on the northern margin of the Dabie orogenic belt, are rich in K2O(1.21%),∑REE (278μg/g) ,and LILE(such as Rb, Ba, K, Th, etc.) , with high (La/Yb)N ratios(14.4),on the basis of the analyses of major elements, rare-earth elements (REE) and trace elements. Their enrichment in LILE, notable Nb-Ta depletion through, and depletion in HFSE relative to REE in comparison with the primitive mantle and N-MORB indicate that the protoliths of the eclogite gravels were formed in an island-arc setting. According to the Th-Hf-Ta discrimination diagram, the protoliths of the eclogite gravels are characterized by volcanic arc basalts.Trace element data indicate that the subducted marine sediments were assimilated in the magma chamber, resulting in the enrichment of LILE in the protoliths. Therefore, the protoliths of the eclogite gravels are considered to have been formed in an inland-arc setting, indicating that there had developed a paleo-inland arc before Triassic collision between the North and South China blocks in the Dabie orogenic belt. There is a marked difference between the eclogite gravels and the eclogites developed along the Dabie orngenic belt, solely based on their geochemical data,especially REE. Therefore, the eclogite gravels may not be derived from eclogite terrains preserved in the Dabie orogenic belt.     

大别-苏鲁超高压变质带榴辉岩部分熔融的证据——微量元素和铅同位素

俯冲玄武质洋壳的部分熔融作用是一种重要的大陆生长作用，但是陆壳物质在俯冲过程中能否发生部分熔融缺少直接的证据。笔者利用已有的微量元素分配系数，讨论了岛弧玄武岩在脱水和部分熔融2种过程中微量元素行为和铅同位素演化的差异。Pb在2种过程中都属于不相容元素，但在脱水过程中其不相容性明显高于Rb、Ba、Th、U，而在熔融过程中则低于上述元素，在ω(Rb)/ω(Pb)-ω(Rb)、ω（Ba)/ω(Pb)-ω(Ba)、ω（Th)/ω(Pb)-ω(Th)、ω（U）／ω(Pb)-ω(U)相关图上2种过程的演化方向差别明显。此外，Pb和Th、U的相容性的差异也使得石榴石和绿辉石的单矿物铅同位素在2种过程中明显不同。在此基础上，结合大别－苏鲁榴辉岩的实测数据，认为大别－苏鲁榴辉岩可能部分是岛弧玄武岩部分熔融后的残余体，部分为单纯脱水的产物。大陆玄武质岩石在俯冲过程中也可能发生部分熔融作用。     

大别造山带北缘中生代地层中榴辉岩砾石地球化学特征及构造意义

大别造山带北缘中生代地层凤凰台组和毛坦厂组中榴辉岩砾石的主元素、稀土元素以及微量元素具有如下特征，主元素中K2O富集(1．2l％)，高∑REE(278μg／g)，高(La／Yb)N(14．4)和大离子亲石元素(LILE，如Rb、Ba、K和Th等)富集。LILE明显富集，显著的Nb-Ta负异常槽，以及与原始地幔、N型大洋中脊玄武岩(N-MORB)相比，一些高场强元素(HFSE)相对于REE亏损，这些都支持榴辉岩砾石原岩的岛弧环境成因。在Th-Hf-Ta判别图上，榴辉岩砾石原岩属于火山弧玄武岩。推测原岩物质成分来源于地幔楔，在俯冲过程中并可能被海底沉积物所混染，所以富集了LILE。因此，榴辉岩砾石原岩可能形成于火山岛弧构造背景，同时也表明大别碰撞造山带在三叠纪陆-陆碰撞之前存在古岛弧发育阶段。根据地球化学特征特别是与稀土元素的比较，榴辉岩砾石与目前在大别造山带发现的榴辉岩有明显差别，因此后者可能不是前者的源区岩石。     

西藏拉萨地块MORB型榴辉岩的岩石地球化学特征

松多榴辉岩的SiO2、Al2O3含量分别为45.3%～50.6%、12.93%～14.27%,K2O Na2O为1.3%～2.8%,TFeO/MgO为1.11～2.02,CaO为10.4%～14.47%,K2O<0.3%,Na2O为0.97%～2.47%。总体上具有玄武质或辉长质岩石的成分特征,属于钙碱性系列,具有MORB的特征,表明其原岩来自大洋环境。松多榴辉岩大多数样品的稀土元素配分模式显示轻稀土元素亏损,无明显的Eu异常,重稀土元素平坦。微量元素蛛网图均显示从Zr到Yb属于平坦型,基本上未发生分馏。松多榴辉岩的LaN/YbN比值为0.19～0.56,LaN/CeN为0.75～0.81,LaN/SmN为0.37～0.81,三者均小于1;Hf/Th除了石英榴辉岩中的06Y-344样品为6.81外,其他样品为11.10～33.97,均大于8;Ce/Nb为2.72～19.02,均大于2;Th/Yb为0.01～0.10,均小于或等于0.1,也说明其原岩具有典型MORB的特征。锆石SHRIMPU-Pb定年获得松多榴辉岩的变质年龄为261Ma±5.3Ma,推测其原岩可能为古特提斯洋盆的残留。     

西藏拉萨地体榴辉岩的地球化学特征和Sm-Nd、Rb-Sr同位素组成及其地质意义

最近在青藏高原拉萨地体新发现了一条榴辉岩带,该榴辉岩带位于冈底斯岩浆岛弧带的北缘。对该带榴辉岩的岩石地球化学特征及SmNd、RbSr同位素组成研究表明： ① 该带榴辉岩的原岩主要是一套低钾的大洋拉斑系列玄武岩,其原岩类似于典型的NMORB,源于亏损地幔; ② 该带榴辉岩样品 （87Sr/86Sr）i＝0.70335~0.70457,变化范围较大,且与εNd（t）值及微量元素特征均没有好的对应关系,可能是由于该套岩石形成于大洋环境,形成后遭受了海水的蚀变作用;（3）该带榴辉岩全岩的SmNd等时线年龄为305.5±50Ma （2σ）,（143Nd/144Nd）i＝0.5126±0.00007 （2σ）,表明该带榴辉岩可能形成于早石炭－晚二叠世,在这一时期冈底斯北缘可能存在古特提斯洋盆及古特提斯洋盆深俯冲作用。     

江苏东海榴辉岩向斜长角闪岩转化的研究

东海榴辉岩曾被俯冲到上地幔，而后又折返回地表，经历了宽广的温度、压力、应力、流体条件等变化范围，形成了大量矿物反应结构，为研究岩石矿物反应提供了很好的素材。本文选取东海地区一个保留从初始榴辉岩到斜长角闪岩完整退变质序列的榴辉岩体作为研究对象，通过详细的显微结构观察、矿物成分分析、成分空间分析、成分迁移估算，揭示了东海榴辉岩向斜长角闪岩的转化过程。该过程可划分为两个阶段：早期为替代绿辉石的后成合晶形成阶段，通过绿辉石内部端元组分间的反应实现，反应产物之一的Fe^2 与金红石结合形成钛铁矿，Ca、Mg被排出到绿辉石体系之外。晚期退变为流体的渗滤交代作用，表现为石榴子石被角闪石部分取代、后成合晶的角闪石化，以及黝帘石、白云母的形成。退变质的最后阶段为石榴子石被绿帘石 角闪石 赤铁矿完全替代。榴辉岩转化成含帘石的斜长角闪岩。     

青藏高原拉萨地块松多榴辉岩的锆石SHRIMP U-Pb年龄及锆石中的包裹体

拉萨地块榴辉岩样品中的锆石SHRIMP U-Pb年龄值为(242.4±15.2)～(291.9±12.8)Ma,平均261.7Ma±5.3Ma。所有锆石均含有大量的包裹体,主要分布在锆石核部。最常见的矿物包裹体是石榴子石,其次为石英、磷灰石、金红石和绿辉石,可见角闪石、榍石、多硅白云母和钠长石。包裹体具3种组合:榴辉岩相(Grt Omp Rt Phe)、角闪岩相(Amp Spn Ab)和不确定相(Qtz Ap)。锆石中的矿物包裹体与岩石中对应矿物的成分相同。包裹体集中在锆石核部和榴辉岩相矿物的大量出现表明锆石生长发生于变质峰期或峰期之后不久。锆石的Th/U比值均很低,具变质成因锆石的典型特征。区域地质资料对比表明,榴辉岩的原岩可能形成于石炭纪—二叠纪早期,是古特提斯洋盆裂解的产物。     

东昆仑夏日哈木退变质榴辉岩地球化学、年代学特征及其地质意义

本文对东昆仑夏日哈木退变质榴辉岩开展岩石地球化学和年代学研究,探讨其原岩性质和构造背景。岩石SiO₂含量为46.77%~49.31%,Al₂O₃含量为13.6%~14.6%,TiO₂含量为0.93%~2.29%,全碱（K₂O+Na₂O）含量为1.61%~2.66%,原岩属亚碱性玄武岩系列中的拉斑玄武岩。（La/Yb）_N=0.98~1.63,（La/Sm）_N=0.98~1.41,δEu=1.10~1.28,稀土元素球粒陨石标准化图呈弱Eu正异常的右倾型,岩石相对富集大离子亲石元素Rb、Ba和不相容元素U,相对亏损高场强元素Zr、Hf,Hf/Th=0.59~0.97,Th/Yb=0.13~0.27,显示其原岩具E-MORB特征。退变质榴辉岩的锆石Th/U比值为0.002~0.091,为变质成因锆石,其锆石SIMS U-Pb年龄为414.2 ±7.3 Ma,代表了退变质榴辉岩的峰变质年龄,结合区域地质背景,认为该岩石形成于早泥盆世早期由碰撞作用向碰撞后伸展作用转换的构造环境。