隐钾锰矿40Ar/39Ar定年及锰矿脉生长速率:以云南巴夜次生氧化锰矿为例

对氧化锰矿床的年代学研究不仅可以直接限定锰矿床次生富集成矿的时间及锰氧化物的生长速率,而且可为区域构造隆升、地貌形成过程和古气候演变等重大地质事件提供关键的年代学信息.本文报道云贵高原典型次生氧化锰矿-巴夜锰矿的高精度40Ar/39Ar定年数据,并根据40Ar/39Ar年龄计算了锰矿脉的生长速率.研究对象选自两条氧化锰矿脉(脉宽3～6cm),其中A脉与含锰岩系即中元古界锰铝榴石片岩的片理平行,产状平缓,而B脉则与锰铝榴石片岩的片理垂直,产状近于直立.矿相学观察、粉晶X-射线衍射、扫描电子显微镜-能谱分析和电子探针成分分析结果表明,上述两条矿脉均主要由隐钾锰矿组成,矿物结晶程度较高,具有针状和纤维状的良好晶形,K2O含量为0.96%～4.70%.激光阶段加热40Ar/39Ar同位素分析结果表明,A脉的形成时间为(1.35±0.05)～(1.16±0.04)Ma(坪年龄,2σ;n=14);根据样品的空间分布和坪年龄计算出其生长速率为115～153mm/Ma.B脉的年龄略微年轻,介于(1.23±0.05)～(1.01±0.09)Ma(坪年龄,2σ;n=7),计算的生长速率为34～67mm/Ma.A脉和B脉生长速率的差异反映氧化锰矿的生长与流体体系的压力大小有关.世界上其他地区氧化锰矿中锰结核的生长速率一般为0.3～9mm/Ma,比巴夜矿区氧化锰矿脉的生长速率低1～2个数量级,说明氧化锰矿的生长机制是控制其生长速率的重要因素:巴夜矿区的氧化锰矿脉由风化溶液中四价锰离子的直接沉淀而形成并充填在裂隙中,矿脉自脉壁向中心生长,而其他地区用于生长速率计算的样品均为环带状锰结核,受控于氧化锰的自催化氧化作用或锰-铁氧化物之间的催化氧化,锰氧化物自结核中心向外生长.隐钾锰矿的40Ar/39Ar定年结果还表明,更新世时期云贵高原以温暖潮湿的古气候为主,并经历了显著的构造抬升.     

下扬子天目山盆地火山岩锆石LA-ICP-MS定年及地质意义

天目山盆地是下扬子江南隆起带保存较完整的中生代火山盆地,中生代火山岩系岩性自下而上主要为流纹岩-英安岩-安山岩。对盆地内黄尖组下段流纹岩和英安岩分别进行了锆石 LA-ICP MS定年,分别获得了133．6±1．5 Ma（MSWD＝0．73）和135．0±2．1 Ma（MSWD＝0．78）的锆石U-Pb年龄,指示天目山盆地黄尖组火山岩时代为早白垩世。天目山盆地火山活动起始时间和长江中下游地区晚中生代火山活动基本一致,说明江南隆起带和长江中下游地区在早白垩世均处于强烈拉张环境。     

几种全岩样品40Ar-39Ar年龄谱的探讨

探讨了玄武岩、辉绿岩和断层泥中粘土矿物3种全岩样品在40Ar-39Ar分析中的某些问题。利用快中子照射过程中不同矿物发生不均匀Ar丟失的模式解释了玄武岩40Ar-39Ar全熔年龄与K-Ar年龄间的差异。对辉绿岩样品的40Ar-39Ar分析确定了辉绿岩脉的侵入时代,并说明该地区其它辉绿岩样品K-Ar年龄的离散是受后期变质作用的影响。对于断层泥中粘土矿物,快中子照射中39Ar的反冲丢失导致<1μm粒级部分的40Ar-39Ar全熔年龄偏高。<1μm和2～10μm粒级样品的40Ar-39Ar年龄谱中,低温区较低的阶段年龄可能是断层后期较强烈活动的结果。     

Intercalibration of international and domestic ~(40)Ar/~(39)Ar dating standards

40Ar/39Ar method is a high precision dating means, of which the age is obtained by contrasting the un- known sample with those of standards. Usually the age of standard is determined by K-Ar method in which the 38Ar spike should be added for measurement. However, the absolute concentration of 38Ar spike is measured through the calibrated standards in turn, al- though occasionally the concentration of 38Ar spike is determined by other dating methods, such as Rb-Sr, U-Pb methods, which is kn…     

40Ar/39Ar isotopic ages of Qitianling granite and their geologic implications

This paper has reported the first application of 40Ar/39Ar dating to orthoclase from Qitianling granite. The resultant plateau ages yielded by three orthoclase specimens 2KL-17, 99LQ-2 and 2KL-31 (Note: The last one was taken from the part of granite which had been attributed to Cailing super-unit of the Indosinian Period by the former researchers) collected from the said granite are (139.57±2.79) Ma, (140.55±2.81) Ma and (144.91±2.90) Ma respectively. The above-mentioned ages represent the closed 40Ar/39Ar age of the orthoclase. The consistency in age dating results, the similarity in geochemical characteristics and rock textures, and the NW-SE orientation of orthoclase phenocrysts almost throughout the granite, provide evidence for the intimate relationship between the Furong super-unit and the Cailing super-unit that form the main part of the granite, suggesting that they are products of comagmatic conjugate differentiation during the Late Jurassic. This paper also makes a comparison between the Qitianling granite and the Qianlishan granite.     

(40)~Ar/(39)~Ar chronology and geochemistry of high-K volcanic rocks in the Mangkang basin, Tibet

Our two newly obtained high-quality 40Ar/39Ar ages suggest that the high-K volcanic rocks of the Lawuxiang Formation in the Mangkang basin, Tibet were formed at 33.5±0.2 Ma. The tracing of elemental and Pb-Sr-Nd isotopic geochemistry indicates that they were derived from an EM2 enriched mantle in continental subduction caused by transpression. Their evidently negative anomalies in HFSEs such as Nb and Ta make clear that there is an input of continental material into the mantle source. The high-K rocks at 33.5±0.2 Ma in the Mangkang basin may temporally, spatially and compositionally compare with the early one of two-pulse high-K rocks in eastern Tibet distinguished by Wang J. H. et al., implying that they were formed in the same tectonic setting.     

The~(40)Ar/~(39)Ar geochronology constraint and geological significance of mylonites in Shangyi-Chicheng fault belt on the north of North China Craton

The Shangyi-Chicheng fault belt extending along the south boundary of the Inner Mongolia axis on the north of the North China Craton was formed in the Middle Proterozoic. This fault has special geological significance1) in the evolution of the North China…     

~(40)Ar/~(39)Ar geochronology of the Faku tectonites:Implications for the tectonothermal evolution of the Faku block,northern Liaoning

As for the metamorphic rock series distributed on the “Faku Faulted Convex (FFC)”[1] of the northern Liaoning, the earliest geologic investigation divided it into the Langzishan, Dashiqiao and Gaixian forma-tions1) and considered it to be equivalent to the Liaohe Group in the eastern Liaoning, whereas Liaoning Bu-reau of Geology and Mineral Resources (LBGMR) included it into the Lower Proterozoic basement[1]. Recent 1︰50000 scale geological mapping2) reveals that this deformed and …     

Post-caldera activity in the Alban Hills volcanic district (Italy): 40Ar/39Ar geochronology and insights into magma evolution

We present 24 ⁴⁰Ar/³⁹Ar ages for the youngest volcanic products from the Alban Hills volcanic district (Rome). Combined with petrological data on these products, we have attempted to define the chronology of the most recent phase of activity and to investigate the magma evolution of this volcanic district. The early, mainly explosive activity of the Alban Hills spanned the interval from 561±1 to 351±3 ka. After approximately 50-kyr of dormancy, a mainly effusive phase of activity took place, accompanied by the strombolian activity of a small central edifice (Monte delle Faete). This second phase of activity spanned the interval 308±2 to 250±1 ka. After another dormancy period of approximately 50-kyr, a new, hydromagmatic phase of activity started at 200 ka at several centers located to the southwest of the Monte delle Faete edifice. After an initial recurrence period of approximately 50-kyr, which also characterized this new phase of activity, the longest dormancy period (approximately 80-kyr) in the history of the volcanic district preceded the start of the activity of the Albano and Giuturna centers at 70±1 ka. Results of our study suggest a quasi-continuous magmatic activity feeding hydromagmatic centers with a new acme of volcanism since around 70 ka. Based on data presented in this paper, we argue that the Alban Hills should not be considered an extinct volcanic district and a detailed re-assessment of the volcanic hazard for the area of Rome is in order. Published online: 4 April 2003 Editorial responsibility: J. Donnelly-Nolan     

40Ar/39Ar geochronology and exhumation of mylonitized metamorphic complex in Changle-Nanao ductile shear zone

New⁴⁰Ar/³⁹Ar plateau ages from rocks of Changle-Nanao ductile shear zone are 107.9 Ma(Mus), 108.2 Ma(Bi), 107.1 Ma(Bi), 109.2 Ma(Hb) and 117.9 Ma(Bi) respectively, which are concordant with their isochron ages and record the formation age of the ductile shear zone. The similarity and apparent overlap of the cooling ages with respective closure temperatures of 5 minerals document initial rapid uplift during 107–118 Ma following the collision between the Min-Tai microcontinent and the Min-Zhe Mesozoic volcanic arc. The⁴⁰Ar/³⁹ Ar plateau ages, K-Ar date of K-feldspar and other geochronologic information suggest that the exhumation rate of the ductile shear zone is about 0.18–1.12 mm/a in the range of 107–70 Ma, which is mainly influenced by tectonic extension.     

~(40)Ar/~(39)Ar dating of shear deformation of the Xianshuihe fault zone in west Sichuan and its tectonic significance

TheNW-SEstrikingXianshuihefaultzoneslicesthesoutheasternTibetanPlateauandconnectssoutheastwardwiththeAnninghe-Zemuhe-Xiaojiangfaultzone,whichformahuge,activesinistralstrike-slipfaultzone(fig.1).ThisfaultzoneisanimportantseismicfaultineastTibet[1-5].EarthquakegeologystudiesandoffsetpatternsofyounggeologicalfeatureshaveshownthatlateQuaternarysinistralsliprateoftheXianshuihefaultzonereaches13mm/a[1,2].TheXianshuhefaultzoneconsistsoftwomainbranches,theDaofufaultbranchinthewestandtheXianshuih…     

表生明矾石族矿物40Ar/39Ar年代学概述

近年来,激光40Ar/39Ar法成功测定了硫化物矿床氧化带中表生明矾石族矿物(明矾石和黄钾铁矾)的年龄,表明这类矿物适用于 40Ar/39Ar法定年。激光熔样方法引入40Ar/39Ar定年,不仅减少了样品的用量,同时也降低了系统的空白本底水平; 利用阶段加热法得到的年龄谱图,不仅可以有效识别原生矿物的混染和多世代矿物的存在,还可以检测样品中的过剩、继承Ar。虽然风化矿物定年还存在一些潜在的问题,但是只要有科学的采样和合理的分析流程,并结合其他检测手段,就可以获得有意义的风化年龄。这为研究新生代以来化学风化、氧化带形成时间和古气候提供了新的方法。