西藏尕尔穷铜金矿床岩体地球化学特征

对班公湖-怒江缝合带西段尕尔穷中型铜金矿岩体进行了野外地质调查、岩相学研究及全岩地球化学分析.石英闪长岩和花岗斑岩均富集Rb,Ba,Th,U等大离子亲石元素,亏损Nb,Ta,Zr,Hf等高场强元素;Rb/Sr远大于1,具负铌和弱负铕异常,轻重稀土分馏不明显,花岗斑岩明显亏损Sr和Ti元素.研究认为,石英闪长岩为岛弧环境...     

西藏尕尔穷铜矿床金银矿物特征及赋存状态

西藏尕尔穷铜矿床位于班公湖-怒江成矿带西侧,是成矿带中重要且具有代表性的矽卡岩型铜矿床。由于对矿石的研究程度较低,制约了成矿作用、矿床成因的深入研究,限制了矿床进一步的综合开发利用。通过野外地质调查采样,利用显微镜鉴定、扫描电镜观察、X射线能谱仪及电子探针成分分析测试、矿物晶体化学式计算等手段和方法,对矿石成分、金银的赋存状态及主要载金矿物的特征进行研究。结果表明,成矿过程经历了岩浆热液成矿期和表生风化期,岩浆热液期是金的主要成矿期。金银主要以互化物的形式产出,以粒间金、包体金为主,裂隙金和薄膜金其次。载金矿物主要为铁氧化物、铁铜硫化物及石英等脉石矿物。矿床成因类型为岩浆热液接触交代成因的矽卡岩型铜金矿床。     

Re-Os dating of gold-bearing arsenopyrite of the Maoling gold deposit,Liaoning Province,Northeast China and its geological significance

The Maoling gold deposit, one of the large gold deposits in eastern Liaoning Province, NE China, is an arsenopyrite-disseminated gold deposit with a resource of approximately 25 t Au and an average Au grade of 3.2 g/t. Six arsenopyrites closely related to Au mineralization of the Maoling gold deposit are dated by Re-Os technique and define a Re-Os isochron with an age of 2316±140 Ma, which suggests that the deposit was formed in the Paleoproterozoic era rather than in the Indosinian period as some early researchers suggested. High initial ^187Os/^188Os ratio of 1.32±0.48 indicates a crustal derivation of the ore-forming material of the deposit, which may be derived from rocks of the Gaixian formation of the Liaohe Group. Furthermore,the result also implies that the age of the Gaixian Formation in the Maoling district is older than 2316±140 Ma.     

西藏甲玛铜多金属矿有用元素空间分布特征及地质意义

为了查明西藏甲玛多金属矿主要矿体有用元素在不同海拔高度的三维空间分布规律,通过钻孔和探槽取样,利用原子吸收法和等离子体原子发射光谱法测试了21 911个化学样品,然后利用等值线图法,得到了6种有用元素在矿体内部的三维空间分布。结果表明:Au、Ag、Cu元素矿体底部有一个高值中心,随着高度增加,高值范围以此中心逐渐向外扩散,并以4.5km海拔高度为界,以下呈较明显的环形扩散,以上呈较明显的线形扩散。Mo元素在矿体底部有2个富集中心,随着高度增加,Mo的分布范围较Cu更大,但是大体上仍表现出环形向外扩散的特征。Pb和Zn的分布规律与其他4种元素完全不同,主要分布于海拔高度>4.5km区域,并且分布范围小。结合元素地球化学特征及岩浆热液成矿特点,可以判断甲玛主矿体的底部存在一个含矿中心,为岩浆热液上升中心,由底向上,呈环状向外扩散,在矿体上部受线性构造影响,呈近似带状分布。该矿床有用元素空间分布具有典型的岩浆热液型矿床分布特征。     

Indosinian isotope ages of plutons and deposits in southwestern Miaoershan-Yuechengling,northeastern Guangxi and implications on Indosinian mineralization in South China

The Miaoershan-Yuechengling complex pluton is the largest granitoid complex in the western Nanling metallogenic belt with a surface exposure of >3000 km2.The complex pluton is composed of an early stage granitoid batholith and late stage small intrusions.The early stage batholith contains mainly medium-grained porphyritic mica granite and porphyritic monzonite granite,whereas the late stage intrusions are composed of muscovite granite porphyry and muscovite monzonitic granite.There are many W-Sn-Mo-Pb-Zn-Cu ores in the contact zone between the batholith and strata,forming an ore-rich belt around the batholith.Based on zircon LA-ICP-MS U-Pb ages,the southwestern part of the early stage batholith formed at 228.7 ± 4.1 Ma(MSWD = 2.49),with slightly earlier magmatic activity at 243.0 ± 5.8 Ma(MSWD = 2.62).The Yuntoujie muscovite granite was associated with W-Mo mineralization and has a zircon LA-ICP-MS U-Pb age of 216.8 ± 4.9 Ma(MSWD = 1.44).The Re-Os isochron age of molybdenite from the Yuntoujie W-Mo ore was 216.8 ± 7.5 Ma(MSWD = 11.3).Our new isotope data suggest that the late stage intrusive stocks from the southwestern Miaoershan-Yuechengling batholith were closely associated with W-Mo mineralization from the Indosinian period.These new results together with previous isotope data,suggest that South China underwent not only the well-known Yanshanian mineralization event,but also a widespread Indosinian metallogenic event during the Mesozoic period.Therefore,South China has a greater potential for Indosinian mineralization than previously thought such that more attention should be given to the Indosinian ore prospecting in South China.     

Re-Os dating of Mo-bearing black shale of the Laoyaling deposit,Tongling, Anhui Province,China

Laoyaling is a typical stratiform deposit in the Tongling district and the molybdenum orebody is hosted by black shale of the Dalong Formation of the Upper Permian system. Eight black shale samples from the Laoyaling Mo orebody were dated by Re-Os technique using ICP-MS, which give an isochron age of 234.2±7.3 Ma with an initial 187Os/188Os ratio of 1.37±0.39. The apparent Re-Os age is a few million years younger than the depositional age of the Late Permian. The young isochron age may be caused by the later hydrothermal disturbance or mass fractionation during ICP-MS measurement. However, the obtained isochron age is close to the depositional age and far earlier than those of the Late Yanshanian intrusions. It suggests that the Mo ore of the Laoyaling deposit is sedimentary in origin and not related to the Late Yanshanian magmatism. Black shales of the Upper Permian are distributed widely in the Mid-Lower Yangtze region, our result is important for understanding the ore-forming processes in the regio     

豫西栾川中鱼库锌(铅)矿床闪锌矿Rb-Sr年龄及其地质意义

中鱼库矽卡岩型锌(铅)矿床位于华北陆块南缘河南省西部栾川Mo-W-Pb-Zn-Ag多金属矿集区南部,矿体呈层状-似层状赋存于新元古界栾川群三川组碎屑岩、碳酸盐岩地层中.因缺乏精确的成矿年代学研究,对该矿床成因的争议较大.本文在矿床地质背景和岩石矿物学研究的基础上,对13件矿石样品中的闪锌矿进行Rb-Sr同位素年代学研究.闪锌矿87 Rb/86 Sr和87 Sr/86 Sr同位素比值分别集中在0.802～18.98和0.713 359～0.748 684,二者具有良好的线性关系;其等时线年龄为(136.4士0.8) Ma (2σ,MSWD=3.6),(87 St/86 Sr)t=0.711 913士0.000 074.Rb-Sr同位素年龄反映该矿床形成于早白垩世,稍晚于研究区内的斑岩-矽卡岩型Mo-W矿床(146士2 MaB.P.),与区内最后一阶段花岗质岩浆活动(142～136MaB.P.)有关,属于栾川Mo-W-Pb-Zn-Ag多金属成矿系统.结合区域资料,认为该矿床形成于中生代陆-陆碰撞过程中由挤压向伸展转变的阶段,或碰撞后造山的局部伸展背景.     

Re-Os isotope dating of pyrite from the footwall mineralization zone of the Xinqiao deposit,Tongling, Anhui Province: Geochronological evidence for submarine exhalative sedimentation

The Xinqiao deposit is located in the Tongling area,Anhui Province.This deposit is dominantly composed of stratiform sulfide orebodies,which are restricted to the transitional zone from clastic rocks to carbonates at the base of the Late Carboniferous Huanglong Formation.There are discordant veinlets or networks of mineralization in the footwall rocks below the stratiform sulfide orebodies.The underlying discordant mineralization zones coexist with conformable stratiform sulfide orebodies,which are considered to be the most representative features of massive sulfide deposits formed by submarine exhalative sedimentation.This study reports a pyrite 187Re-187Os isotopic age of 319±13 Ma(MSWD=16) for the footwall mineralization zone.This isochron age is consistent with the interval of strata hosting the conformable stratiform sulfide orebody,and provides direct geochronological evidence for Carboniferous exhalative sedimentary mineralization.     

西藏马攸木金矿床地质特征及成因初探

马攸木金矿床是西藏最近发现的首例大型独立岩金矿床.该文着重介绍了马攸木岩金矿床的矿体形态、矿石结构构造和矿石物质组分、金矿物的一般特征,并将马攸木金矿床的形成分为热液期、风化期和沉积期,其中与岩金矿形成有关的热液期至少可分为三个矿化阶段.论述了岩金矿床的流体包裹体特征、S和Pb同位素特征及Ar同位素年龄.初步认为该矿床属与地热活动有关的浅成中低温热液矿床.     

西藏甲玛铜多金属矿夕卡岩特征及成因意义

甲玛铜多金属矿为西藏冈底斯成矿带中段的超大型矿床.通过研究矿床夕卡岩岩石学特征、岩石化学特征、稀土元素和微量元素地球化学特征,显示夕卡岩主要受早白垩世林布宗组角岩、板岩和晚侏罗世多底沟组大理岩之间的层间构造带所控制,主要呈层状、似层状产出,夕卡岩由上至下具有夕卡岩角岩-石榴子石夕卡岩-硅灰石夕卡岩-夕卡岩化大理岩的分带...