Study of a solar powered solid adsorption–desiccant cooling system used for grain storage

A hybrid solar cooling system, which combines the technologies of rotary desiccant dehumidification and solid adsorption refrigeration, has been proposed for cooling grain. The key components of the system are a rotary desiccant wheel and a solar adsorption collector. The former is used for dehumidification and the later acts as both an adsorption unit and a solar collector. The heating load from sunshine can thus be reduced to a greater extent since the solar adsorption collector is placed on the roof of the grain depot. Compared with the solid adsorption refrigeration system alone, the new hybrid system performs better. Under typical conditions, the coefficient of performance of the system is >0.4 and the outlet temperature is <20°C. It is believed that the system can be used widely in the regions with abundant solar resources due to such advantages as environmental protection, energy saving and low operation costs. Additionally, some parameters, for example, ambient conditions, the effectiveness of the heat exchanger and evaporative cooler, mass air-flow rate, etc., which affect system performance, are also analyzed.     

Modelling and performance study of a continuous adsorption refrigeration system driven by parabolic trough solar collector

This article suggests a numerical study of a continuous adsorption refrigeration system consisting of two adsorbent beds and powered by parabolic trough solar collector (PTC). Activated carbon as adsorbent and ammonia as refrigerant are selected. A predictive model accounting for heat balance in the solar collector components and instantaneous heat and mass transfer in adsorbent bed is presented. The validity of the theoretical model has been tested by comparison with experimental data of the temperature evolution within the adsorber during isosteric heating phase. A good agreement is obtained. The system performance is assessed in terms of specific cooling power (SCP), refrigeration cycle COP (COP_cycle) and solar coefficient of performance (COP_s), which were evaluated by a cycle simulation computer program. The temperature, pressure and adsorbed mass profiles in the two adsorbers have been shown. The influences of some important operating and design parameters on the system performance have been analyzed.The study has put in evidence the ability of such a system to achieve a promising performance and to overcome the intermittence of the adsorption refrigeration systems driven by solar energy. Under the climatic conditions of daily solar radiation being about 14 MJ per 0.8 m² (17.5 MJ/m²) and operating conditions of evaporating temperature, T_ev = 0 °C, condensing temperature, T_con = 30 °C and heat source temperature of 100 °C, the results indicate that the system could achieve a SCP of the order of 104 W/kg, a refrigeration cycle COP of 0.43, and it could produce a daily useful cooling of 2515 kJ per 0.8 m² of collector area, while its gross solar COP could reach 0.18.     

Exergy analysis of solar assisted double effect absorption refrigeration system

Exergy or the available energy is based on the second law of thermodynamics and goes back to Maxwell and Gibbs. It is the exergy content and not the energy content, that truly represents the potential of the substance to cause change. Exergy is the only rational basis for evaluating the system performance. The aim of this project is to study in detail the exergy variation in the solar assisted absorption system. The influence of the cycle parameters are analysed on the basis of first law and second law effectiveness and the results indicated various ways of improving system performance by better design. Also a better quality of the evaporator has more effect on the system performance than the better quality of other components. It was shown that second law analysis quantitatively visualizes losses within a system and gives clear trends for optimization.     

太阳能双喷射式制冷系统性能计算分析

建立了双喷射式制冷系统的物理模型和数学模型,计算了太阳能双喷射式制冷系统中气体喷射器和气-液喷射器的性能参数、系统性能参数随制冷剂和工况的变化。结果表明,在给定的发生温度、蒸发温度、冷凝温度范围内,气体喷射器的喷射系数和系统COP均随发生温度和蒸发温度的升高而增大,随冷凝温度的增大而减小。气-液喷射器的喷射系数则随发生温度的升高而减小,除水外,均随冷凝温度的升高而减小。     

Development of a novel hydrate-based refrigeration system: A preliminary overview

This paper gives a preliminary overview of our attempt at developing a hydrate-based refrigeration system based on a novel conceptual design. The system forms a closed cycle, which is more or less analogous to the conventional vapor-compression refrigeration cycle. The cycle of present interest is performed by a multiphase refrigerant, which is typically a mixture of one or two hydrate-forming substances and water. The refrigerant is required to form a hydrate at a temperature as high as 30 °C or above, desirably under a modest pressure, such that the heat released by the exothermic hydrate formation can be efficiently removed by an environmental fluid such as the atmospheric air, groundwater or river water. The hydrate slurry thus formed is depressurized to dissociate at a lower temperature, typically 5–9 °C, thereby absorbing heat from a space to be refrigerated. To confirm the feasibility of the above conceptual design of the hydrate-based refrigeration system, a thermodynamic analysis of the system and a simulation of its operation have been performed. Also a laboratory-scale refrigerator based on the above design was constructed and tested. The paper summarizes the results of these efforts to show the potential advantages of the hydrate-based refrigeration system over conventional ones and to give the prospects of our refrigeration-system development.     

Evaluation of a combined ejector–vapour-compression refrigeration system

A new refrigeration cycle based on the combination of an ejector cycle with a vapour compression cycle is described. This integration maximizes the performance of the conventional ejector cycles and provides high COP for refrigeration. The analyses show that the new cycle has a significant increase in system performance over the conventional systems, its COP values are competitive to the absorption machines. If the system is powered by waste heat and the cost of its supply can be neglected, the COP values will be much higher. The system performance can be further improved if dual refrigerants are used and the dual refrigerants giving high performance are identified. © 1998 John Wiley & Sons, Ltd.     

Suggested solution concentration for an energy-efficient refrigeration system combined with condensation heat-driven liquid desiccant cycle

This paper presents a hybrid energy-efficient refrigeration system enhanced by liquid desiccant evaporative cooling technology for subcooling the refrigerant, where the liquid desiccant cycle is driven by the exhausted heat from the condenser and three commonly used liquid desiccants: LiCl, LiBr and CaCl₂ aqueous solutions are considered here. The solution concentration for the proposed hybrid energy-efficient refrigeration system should be determined and optimized carefully for better performance. Sensitive study of solution concentration involved in the hybrid system is conducted at different condensation temperature. The results indicates that under standard working condition (i.e., condensing temperature is 50 °C), the optimum solution concentration is 0.31 for LiCl aqueous solution, 0.45 for LiBr aqueous solution and 0.42 for CaCl₂ aqueous solution, while the maximum COPs are nearly same. When the condensing temperature is 45 °C, the optimum solution concentration should be set at 0.27 for LiCl aqueous solution, and 0.41 for LiBr aqueous solution and 0.37 for CaCl₂ aqueous solution, while condensing temperature is 55 °C, it is 0.35 for LiCl aqueous solution, 0.49 for LiBr aqueous solution and 0.45 for CaCl₂ aqueous solution. The simple fitting formulas are obtained, and performance improvement potential is discussed.     

Performance assessment of a liquid‐phase separation refrigeration cycle

Absorption refrigeration cycles are alternatives to conventional vapor‐compression cycles in which the energy required for refrigeration is provided by heat instead of mechanical work. In this paper, a novel refrigeration cycle utilizing the immiscible liquid‐phase separation behavior is simulated and analyzed using Aspen simulator. The two conjugate liquids adopted in this work are triethylamine (solute) and water (solvent). This binary system has a low critical solution temperature of 18 °C. The thermophysical properties of the binary mixture are generated using the universal functional activity coefficient (UNIFAC) and the nonrandom two‐liquid (NRTL) models. The phase splitting phenomenon at the generator temperature is predicted by both models. However, in comparison with the available experimental data for the same binary mixture, NRTL model gives better predictions for the flow rates and compositions of the material streams. Heat duties of the evaporator, absorber, and generator and the power consumption of the solution pump have been calculated using UNIFAC and NRTL models. The cycle COP that plays a major role in determining the cycle economical viability has been predicted for different operating conditions using the two models. Simulation results show that, for a waste heat reservoir at 60 °C and using NRTL model, the COP is about 2.0. Second law analysis conducted for all cycle components of the cycle shows that about 42% of the total exergy destructed occurs in the generator. Finally, the liquid‐phase separation refrigeration cycle is predicted to be a promising cycle in the near future because of hardware and energy savings. Copyright © 2011 John Wiley & Sons, Ltd.     

新型太阳能吸收式制冷循环的性能分析

在两级溴化锂吸收式制冷循环的基础上,提出了一种由太阳能驱动的新型吸收式制冷循环,并对其进行性能分析。通过大量计算,分析结果表明,在现有太阳能集热器所能提供的热水温度范围内,新型太阳能吸收式制冷循环有较高的热力系数。该循环系统的中间压力、中间浓度对系统的热力系数和热源可利用温差有较大影响。     

Simulation of an adsorption solar cooling system

A more realistic theoretical simulation model for a tubular solar adsorption refrigerating system using activated carbon-methanol (AC/M) pair has been introduced. The mathematical model represents the heat and mass transfer inside the adsorption bed, the condenser, and the evaporator. The simulation technique takes into account the variations of ambient temperature and solar radiation along the day. Furthermore, the local pressure, and local thermal conductivity variations in space and time inside the tubular reactor are investigated as well. A C++ computer program is written to solve the proposed numerical model using the finite difference method. The developed program covers the operations of all the system components along the cycle time. The performance of the tubular reactor, the condenser, and the evaporator has been discussed. Time allocation chart and switching operations for the solar refrigeration system processes are illustrated as well. The case studied has a 1 m² surface area solar flat plate collector integrated with a 20 stainless steel tubes containing the AC/M pair and each tube has a 5 cm outer diameter. In addition, the condenser pressure is set to 54.2 kpa. It has been found that, the solar coefficient of performance and the specific cooling power of the system are 0.211 and 2.326 respectively. In addition, the pressure distribution inside the adsorption bed has been found nearly uniform and varying only with time. Furthermore, the AC/M thermal conductivity is shown to be constant in both space and time.     

Parametric analysis for a new combined power and ejector–absorption refrigeration cycle

A new combined power and ejector–absorption refrigeration cycle is proposed, which combines the Rankine cycle and the ejector–absorption refrigeration cycle, and could produce both power output and refrigeration output simultaneously. This combined cycle, which originates from the cycle proposed by authors previously, introduces an ejector between the rectifier and the condenser, and provides a performance improvement without greatly increasing the complexity of the system. A parametric analysis is conducted to evaluate the effects of the key thermodynamic parameters on the cycle performance. It is shown that heat source temperature, condenser temperature, evaporator temperature, turbine inlet pressure, turbine inlet temperature, and basic solution ammonia concentration have significant effects on the net power output, refrigeration output and exergy efficiency of the combined cycle. It is evident that the ejector can improve the performance of the combined cycle proposed by authors previously.     

Performance characteristics of a two-stage irreversible combined refrigeration system at maximum coefficient of performance

A general cycle model of a two-stage combined refrigeration system is established and used for analizing the influence of multi-irreversibilities, such as finite rate heat transfer, heat leak between the heat reservoirs and internal dissipation of the working fluid, on the performance of the refrigeration system. The coefficient of performance is taken as an objective function for optimization. The maximum coefficient of performance is calculated, and other corresponding performance parameters, such as the temperatures of the working fluid in the isothermal processes, the optimal distribution of the heat transfer areas and the power input of the refrigeration system, are determined. The results obtained here are more general than those obtained from a two-stage endoreversible combined refrigeration system and can guide the optimal design and operation of real combined refrigerator systems.     

Theoretical study of a solar powered absorption/MED combined system

In this article, a theoretical study is presented for a solar powered combined system comprising a LiBr---H₂O absorption cooling machine and a multiple-effect distillator (MED). The MED has 8 VTE of the falling film type, and it replaces the condenser in conventional absorption machines. Steam released at the generator pressure is supplied to the effect which matches its conditions, and the condensate follows its usual route towards the evaporator of an A/C unit. Thus, the MED is powered by the waste heat of the absorption machine which improves the overall gain and the thermodynamic characteristics significantly.

Governing equations for the combined system are given and are numerically solved. Medium parabolic concentrators are used to power the system, and a transient simulation for the combined arrangement is presented.

Results are given for a typical design summer day in Jeddah, Saudi Arabia, for a range of firing temperatures 150–190°C with a storage temperature amplitude of 10–20°C over a daily working period of 12 h. For a given cooling load of 100 ton refrigeration, the system can produce up to 40m³ of fresh water at a specific collector area of 12.41. H₂O plus 0.03 TR/m². The overall COP_o reaches 1.44, which is more than twice that of a conventional absorption machine at the same temperature levels.     

Maximum equivalent efficiency and power output of a PEM fuel cell/refrigeration cycle hybrid system

With the help of the current models of proton exchange membrane (PEM) fuel cells and three-heat-source refrigeration cycles, the general model of a PEM fuel cell/refrigeration cycle hybrid system is originally established, so that the waste heat produced in the PEM fuel cell may be availably utilized. Based on the theory of electrochemistry and non-equilibrium thermodynamics, expressions for the efficiency and power output of the PEM fuel cell, the coefficient of performance and cooling rate of the refrigeration cycle, and the equivalent efficiency and power output of the hybrid system are derived. The curves of the equivalent efficiency and power output of the hybrid system varying with the electric current density and the equivalent power output versus efficiency curves are represented through numerical calculation. The general performance characteristics of the hybrid system are discussed. The optimal operation regions of some parameters in the hybrid system are determined. The advantages of the hybrid system are revealed.     

Performance analysis of a waste‐heat‐powered thermodynamic cycle for multieffect refrigeration

A multieffect refrigeration system that is based on a waste‐heat‐driven organic Rankine cycle that could produce refrigeration output of different magnitudes at different levels of temperature is presented. The proposed system is integration of combined ejector–absorption refrigeration cycle and ejector expansion Joule–Thomson (EJT) cooling cycle that can meet the requirements of air‐conditioning, refrigeration, and cryogenic cooling simultaneously at the expense of industrial waste heat. The variation of the parameters that affect the system performance such as industrial waste heat temperature, refrigerant turbine inlet pressure, and the evaporator temperature of ejector refrigeration cycle (ERC) and EJT cycles was examined, respectively. It was found that refrigeration output and thermal efficiency of the multieffect cycle decrease considerably with the increase in industrial waste heat temperature, while its exergy efficiency varies marginally. A thermal efficiency value of 22.5% and exergy efficiency value of 8.6% were obtained at an industrial waste heat temperature of 210°C, a turbine inlet pressure of 1.3 MPa, and ejector evaporator temperature of 268 K. Both refrigeration output and thermal efficiency increase with the increase in turbine inlet pressure and ERC evaporator temperature. Change in EJT cycle evaporator temperature shows a little impact on both thermal and exergy efficiency values of the multieffect cycle. Analysis of the results clearly shows that the proposed cycle has an effective potential for cooling production through exploitation of lost energy from the industry. Copyright © 2014 John Wiley & Sons, Ltd.     

An investigation of the solar powered absorption refrigeration system with advanced energy storage technology

This paper presented a new solar powered absorption refrigeration (SPAR) system with advanced energy storage technology. The advanced energy storage technology referred to the Variable Mass Energy Transformation and Storage (VMETS) technology. The VMETS technology helped to balance the inconsistency between the solar radiation and the air conditioning (AC) load. The aqueous lithium bromide (H₂O-LiBr) was used as the working fluid in the system. The energy collected from the solar radiation was first transformed into the chemical potential of the working fluid and stored in the system. Then the chemical potential was transformed into thermal energy by absorption refrigeration when AC was demanded. In the paper, the working principle and the flow of the SPAR system were explained and the dynamic models for numerical simulation were developed. The numerical simulation results can be used to investigate the behavior of the system, including the temperature and concentration of the working fluid, the mass and energy in the storage tanks, the heat loads of heat exchanger devices and so on. An example was given in the paper. In the example, the system was used in a subtropical city like Shanghai in China and its operating conditions were set as a typical summer day: the outdoor temperature varied between 29.5 °C and 38 °C, the maximum AC load was 15.1 kW and the total AC capacity was 166.1 kW h (598.0 MJ). The simulation results indicated that the coefficient of performance (COP) of the system was 0.7525 or 0.7555 when the condenser was cooled by cooling air or by cooling water respectively and the storage density (SD) was about 368.5 MJ/m³. As a result, the required solar collection area was 66 m² (cooling air) or 62 m² (cooling water) respectively. The study paves the road for system design and operation control in the future.     

Adsorption refrigeration—An efficient way to make good use of waste heat and solar energy

This paper presents the achievements gained in solid sorption refrigeration prototypes since the end of the l970s, when interest in sorption systems was renewed. The applications included are ice making and air conditioning. The latter includes not only cooling and heating, but also dehumidification by desiccant systems. The prototypes presented were designed to use waste heat or solar energy as the main heat source. The waste heat could be from diesel engines or from power plants, in combined cooling, heating and power systems (CCHP). The current technology of adsorption solar-powered icemakers allows a daily ice production of between 4 and 7 kg m⁻² of solar collector, with a solar coefficient of performance (COP) between 0.10 and 0.16. The silica gel–water chillers studied can be powered by hot water warmer than 55 °C. The COP is usually around 0.2–0.6, and in some commercially produced machines, it can be up to 0.7. The utilization of such chillers in CCHP systems, hospitals, buildings and grain depots are discussed. Despite their advantages, solid sorption systems still present some drawbacks such as low specific cooling power (SCP) and COP. Thus, some techniques to overcome these problems are also contemplated, together with the perspectives for their broad commercialisation. Among these techniques, a special attention was devoted to innovative adsorbent materials, to advanced cycles and to heat pipes, which are suitable devices not only to improve the heat transfer but also can help to avoid corrosion in the adsorbers. Recent experiments performed by the research group of the authors with machines that employ composite adsorbent material and heat pipes showed that it is possible to achieve a SCP of 770 W kg⁻¹ of salt and COP of 0.39 at evaporation temperatures of −20 °C and generation temperature of 115 °C.     

The use of a novel algorithm to analyse a sequential storage problem in a refrigeration plant

The minimum-cost operating strategy for an idealized refrigeration plant having cogeneration capacity was previously analysed using a linear programming model. It is shown here that the addition of chilled-water storage can reduce energy costs by substantially altering the optimum operating strategy. A novel algorithm that uses a sequence of linear programming optimizations to analyse the dynamic behaviour of a store, is discussed. The method avoids approximations inherent in usual dynamic programming techniques, gives useful insights into the problem structure, and offers significant savings in computational time. The economic advantages of storing chilled water in the model plant are discussed, and a target figure for store capital cost is derived.     

The novel use of phase change materials in refrigeration plant. Part 2: Dynamic simulation model for the combined system

A dynamic mathematical model for coupling the refrigeration system and PCMs has been developed in this paper. Overall the model consists of the following basic components: a compressor, a condenser, an expansion valve, an evaporator cooler and a PCM heat exchanger. The model developed here, is based on a lumped-parameter method. The condenser and evaporator were treated as storage tanks at different states, which have a superheat region, a two-phase region and a sub-cooled region. In the single-phase region the parameters are considered homogeneous whereas in the two-phase region, the intensive properties are considered as in thermal equilibrium. The compressor model is considered as an adiabatic process; an isentropic efficiency is employed in this process. The expansion process in the thermostatic expansion valve is considered as an isenthalpic process. The PCM is treated as a one-dimensional heat transfer model. The mathematical simulation in this study predicts the refrigerant states and dynamic coefficient of performance in the system with respect to time. The dynamic validation shows good agreement with the test result.