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1.
阳离子型微乳液对显色剂1—(2—吡啶偶氮)—2—萘酚的增溶作用 总被引:5,自引:0,他引:5
以光度法研究了阳离子型微乳液对显色剂1-(2-吡啶偶氮)-2-萘酚(PAN)的增溶作用,通过测定PAN在阳离子型CTMAB/n-C5H11OH/n-C9H20微乳液中的“胶束位”n和结合常数K,并与相同表面活性剂胶束体系比较,探讨了微乳液对显色剂PAN的增溶作用。 相似文献
2.
二烷基磷(膦)酸钠盐萃取体系的相行为 总被引:4,自引:0,他引:4
用二烷基磷(膦)酸钠盐NaA作为阴离子表面活性剂,测定了NaA-醇-油-水体系W/O型微乳液中水的增溶量,用类三元相 图单相微乳区,测定了NaDTMPP-HDTMPP-煤油-水(含Na2SO4)体系相的变化,并讨论了溶剂、醇、温度、含盐量等对相行为的影响。 相似文献
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维生素C在CTAB/n—C5H11OH/H2O体系中的增稳作用 总被引:4,自引:0,他引:4
在CTAB/n-C5H11OH/H2O体系中,维生素C存在于O/W、W/O液滴的内侧,C5H11OH则存在于液滴的外侧,阻碍渗透进入膜相中的水与维生素C的接触,从而在幅芳降低了维生素C在水体系中的氧化程度,提高了其稳定性,O/W、W/O微乳液对维生素C分子艇的机理亦从层状液晶对其增稳作用中得到证明。 相似文献
4.
混合微乳液的增敏作用研究:Cd(Ⅱ)—5—Br—PADAP的分光光度测定 总被引:2,自引:0,他引:2
研究了在O/W混合微乳液SDS-OP/nC4H9OH/n-C7H16/H2O介质中,Cd(Ⅱ)-5-Br-PADAP的显色反应。结果表明显色反应的灵敏度较单一的SDS微乳液,单一的OP的微乳液,混合SDS-OP胶束的介质中,具有更好的增敏作用和稳定性,Cd浓度在0-5μg/100mL范围内符合比尔定律。方法用于废水和环境水样中微量Cd的测定,结果满意。 相似文献
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微乳液增敏作用机理探讨:显色剂在微乳液中的分配系数 总被引:13,自引:0,他引:13
与胶束体系比较,显色剂PNA和CAS在油/水(O/W)微乳液中具有更大的分配系数,这表明O/W微乳液比胶束体系具有更好的增敏作用是因为O/W微乳液对显色剂PAN和CAS具有更好的增溶与富集作用所致。 相似文献
6.
醇的链长对微乳状液形成的影响 总被引:6,自引:0,他引:6
本文研究了醇对非离子型表面活性剂AEO9[C12H25O(C2H4O)9OH]、正庚烷、水体系形成微乳液的影响。通过四组分的拟三元相图,得到各体系的微乳区。结果表明,当醇的链长不同时,体系的微乳区的类型及面积均不同。其中,丁醇体系的微乳区面积最大,它比Bansal-Shah-O'connel相关方程的结果少一个碳原子。 相似文献
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W/O微乳液体系稳定条件的研究 总被引:10,自引:0,他引:10
研究表明[1~4] ,一个好的微乳液体系要求具有稳定范围宽阔 ,对pH值和温度的变化不敏感等特点。本文研究目的是为了寻找一个适合制备所需功能氧化物粒子的微乳液体系 ,考察研究Tx 6~C4H9OH/c C6H1 2 /H2 O体系W/O微乳液在不同条件下能稳定存在的组成范围以及温度和不同pH值对该稳定组成区域的影响。1 实验部分1 1 实验试剂本实验以Tx 6(烷基聚氧乙烯酚醚 )为表面活性剂 ,C4H9OH(正丁醇 )为助表面活性剂 ,c C6H1 2(环己烷 )为油相。除Tx 6由上海高桥石化三厂提供外 ,其它试剂均为分析纯。1 2 实验内容在 2… 相似文献
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SDBS/正辛烷/正丁醇/盐水体系中相微乳液微观结构的研究 总被引:1,自引:0,他引:1
利用冷冻蚀刻电镜、FT-IR、ESR和NMR方法研究了SDBS/n-C4H9OH/n-C8H18盐水体系中相微乳液微观结构。四种方法均表现随着体系含盐度的增加,中相微乳液微观结构经历了从O/W型到B.C型,再到W/O型的转变。 相似文献
11.
Urea is found to show the hydrotrope action when the aqueous solubility of surfactant CTAB is enhanced while it will show the hydrotrope-solubilization action when the solubilized amount of n-C5H11OH in O/W microemulsion and that of water in W/O microemulsion are increased. The mechanism of the hydrotrope-sotubilization action of urea is in fact the increase of the stability of W/O and O/W microemulsion and structural transition from the lamellar liquid crystal phase to the bicontinuous structure. 相似文献
12.
《Colloids and surfaces. A, Physicochemical and engineering aspects》2002,196(2-3):223-234
Penicillin potassium salt (penicillin-K) is found to show hydrotrope action, which can increase the solubility of cationic surfactant CTAB in water. Penicillin-K also shows hydrotrope-solubilization action, which makes the W/O and O/W microemulsion more stable and increases the solubilized amount of n-C5H11OH in O/W microemulsion and that of water in W/O microemulsion for CTAB/n-C5H11OH/H2O system. However, in this system, the presence of penicillin-K can decrease the stability of the lamellar liquid crystal phase due to its structure change to bicontinuous, which are proved by the mechanism of its hydrotrope-solubilization action. 相似文献
13.
Cephanone is found to show the hydrotrope and hydrotrope-solubilization action in CTAB/n-C5H11OH/H2O system. Cephanone can increase the solubilities of cationic surfactant CTAB or
n-C5H11OH in water and water in
n-C5H11OH. It can also increase the solubilization amount of
n-C5H11OH in O/W microemulsion and that of water in W/O microemulsion, which makes the two regions of O/W and W/O microemulsion larger, and even linked together. The mechanism of the hydrotrope-solubilization action of cephanone is related to the location of cephanone in the palisade of microemulsion which causes the stability of O/W and W/O microemulsion to be enhanced and that of lamellar liquid crystal to be reduced. Therefore, the mechanism of hydrotrope-solubilization is the structural transition from lamellar liquid crystal to the bicontinuous structure. 相似文献
14.
Urea can enhance the aqueous solubility of surfactant CTAB (hexadecyltrimethylammonium bromide) when it shows the hydrotrope action. It will show the hydrotrope‐solubilization action when the solubilized amount of n‐C5H11OH in O/W microemulsion and that of water in W/O microemulsion are increased. The mechanism of the hydrotrope‐solubilization action of urea is the increase of the stability of W/O and O/W microemulsion and structural transition from the lamellar liquid crystalline phase to the bicontinuous structure. 相似文献
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Horseradish peroxidase (HRP) in cationic water-in-oil (W/O) microemulsions has always been ignored in reverse micellar enzymology, mainly because cationic surfactants are inhibitors of enzyme peroxidase. In the present study, for the first time, we have successfully introduced the cationic W/O microemulsion as an attractive host for efficient HRP activity. To this notion, much improved activity of HRP was observed in the W/O microemulsion of cetyltrimethylammonium bromide (CTAB) with an increase in n-hexanol concentration and W0 ([water]/[surfactant]), presumably due to the increased interfacial area of the microemulsions. In support of our above observation, six surfactants were synthesized with an increased headgroup size where the methyl groups of CTAB were subsequently replaced by the n-propyl and 2-hydroxyethyl groups, respectively, to prepare mono-, di-, and tripropylated/hydroxyethylated n-hexadecylammonium bromide. The peroxidase activity enhanced with headgroup size and also followed an overall trend similar to that found in the case of CTAB. Possibly, the reduced positive charge density at the augmented interfacial area by means of increase, either in headgroup size, cosurfactant concentration, and/or W0, is not capable of inactivating HRP. Also, the larger space at the interface may facilitate easier solubilization of the enzyme and increase the local concentration of enzyme and substrate, leading to the higher activity of HRP. The best activity was obtained with surfactant N-hexadecyl-N,N,N-tripropylammonium bromide, the highest ever found in any cationic W/O microemulsions, being almost 3 times higher than that found in water. Strikingly, this observed highest activity is comparable with that observed in an anionic bis(2-ethylhexyl)sulfosuccinate sodium salt (AOT)-based system, the best W/O microemulsions used for HRP. 相似文献
17.
在十六烷基三甲基溴化铵(CTAB)或十八胺(C18NH2)/正庚烷/乙醇/HAuCl4.4H2O W/O型微乳液体系中,利用简单的加热手段通过乙醇还原法制备了具有不同形貌和尺寸的憎水性金纳米材料。由CTAB或C18NH2稳定的金纳米颗粒运用紫外可见光谱(UV-vis)、透射电镜(TEM)和X射线衍射(XRD)等分别进行了表征和分析。用混合表面活性剂(CTAB/C18NH2)替代单一表面活性剂(CTAB)可以削弱CTAB对金纳米晶体生长的导向作用并提高粒子的单分散性。 相似文献
18.
The effects of vitamin C are determined in the oil-in-water(0/ W) and water-in-oil(W/ 0) microemulsion regions of CTAB/ pentanol/ p-xylene/ H20 system. The addition of Vc joins the O/ W and W/ O areas in the phase diagram and expands the bicontinous region by reducing the lamellar liquid crystal one. The results show that the “ coupling action” of Vc is in fact a structural transition from lamellar crystal to isotropic phase with W/ O, O/ W and bicontinous structure. 相似文献
19.
《Journal of Dispersion Science and Technology》2013,34(6):763-769
Abstract The hydrolysis of cephanone in water, cetyl trimethyl ammonium bromide (CTAB) micelle, and CTAB/n‐C5H11OH/H2O O/W microemulsion was studied through UV‐VIS absorption spectroscopy. The mechanism of the hydrolysis and the effects of both the acidity of the media and the composition of O/W microemulsion on the hydrolysis were studied. The results show that the hydrolysis rate of cephanone increases with the acidity. Compared with water, CTAB micelle and CTAB/n‐C5H11OH/H2O O/W microemulsion suppress this hydrolysis. The inhibition of the hydrolysis of cephanone by CTAB micelle and CTAB/n‐C5H11OH/H2O O/W microemulsion is related to the location of cephanone in the interphases of CTAB micelles and CTAB/n‐C5H11OH/H2O O/W microemulsion droplets. 相似文献