Mg-Gd-Y-Mn耐热镁合金的压缩变形行为研究

采用Gleeble-1500热模拟机对Mg-Gd-Y-Mn稀土镁合金在温度为300～500℃、应变速率为0.001～1.0s-1、最大变形程度为60%的条件下,进行恒应变速率高温压缩模拟实验研究.分析了实验合金高温变形时流变应力与应变速率及变形温度之间的关系以及组织变化,计算了表观激活能及相应的应力指数,为选择这种合金的热变形加工条件提供了实验依据.结果表明:合金的稳态流变应力随应变速率的增大而增大,在恒应变速率条件下,合金的真应力水平随温度的升高而降低;在给定的变形条件下,计算得出的表观激活能和应力指数分别为200kJ·mol-1和5.1.根据实验分析,合金的热加工宜在400～500℃温度范围内进行.     

Mg-Gd-Y-Zr镁合金热压缩流变应力的研究

采用恒应变速率高温压缩模拟实验，对Mg-Gd-Y-Zr镁合金在应变速率为0．001～1．0s^-1、变形温度为150～500℃条件下的流变应力行为进行了研究，计算了变形激活能及相应的应力指数，建立了峰值流变应力方程。结果表明：在恒温条件下，合金的流变应力随应变速率的增大而增大；在恒应变速率条件下，合金的流变应力随温度的升高而降低；在350-500℃，0．001～1．s^-1的变形条件下，变形激活能和应力指数分别为2215kJ／mol和368；流变应力方程计算出的峰值应力与真实值基本吻合。     

Mg-Nd-Zn-Zr稀土镁合金的热变形行为

采用GLEEBLE-1500热模拟机对Mg-Nd-Zn-Zr稀土镁合金在温度为250～450.℃、应变速率为0.002～0.100.s-1、最大变形程度为60%的条件下, 进行高温压缩模拟实验研究. 分析了实验合金在高温变形时的流变应力和应变速率及变形温度之间的关系, 计算了变形激活能和应力指数, 并研究了在热压缩过程中组织的变化, 为确定该稀土镁合金的挤压温度提供了实验依据. 结果表明: 合金的峰值流变应力随应变速率的增大而增加, 随温度的升高而降低; 合金的变形激活能在300～400.℃内变化不大, 而在400～450.℃时增加很大; 根据实验分析认为该稀土镁合金挤压温度定在350～400.℃左右为宜; 在350.℃左右顺利挤出的实验合金有很好的力学性能: σb=275.5.MPa, δ=13.5%.     

Mg-11.21Gd-2.26Y-0.44Zr稀土镁合金热变形行为

采用差热分析、金相显微镜等手段,分析了Mg-11.21Gd-2.26Y-0.44Zr稀土镁合金的微观组织,结果发现,在温度530℃均匀化热处理4h,可使大部分合金元素固溶。采用Gleeble3800热模拟实验机,在温度为320℃～480℃、应变速率为0.001s-1～0.1s-1、最大变形程度为60%的条件下,对该镁合金进行热压缩实验,结果表现,材料流变应力行为和显微组织受到变形温度和变形速率的严重影响;合金的流动应力可以采用Sellars方程形式描述;计算出的变形激活能为225.67kJ.mol-1。     

铸态Mg-7Gd-5Y-1.2Nd-Zr镁合金热变形行为研究

针对Mg-7Gd-5Y-1.2Nd-Zr镁合金,研究了其铸态显微组织以及在Gleeble-1500D热模拟机上单向压缩的力学行为。变形速率为0.002~1s-1,变形温度为573~723K,下压量为60%。铸态Mg-7Gd-5Y-1.2Nd-Zr合金组织由α-Mg基体和网状的共晶构成;变形温度和变形速率对合金的峰值应力有明显的影响,在相同温度条件下,峰值应力随变形速率的增加而升高,在相同的应变速率条件下,峰值应力随变温度的升高而降低;高温条件下的共晶组织的软化也是合金变形抗力下降的重要原因;应变速率为0.1s-1时,合金不连续动态再结晶最为明显,合金易于失效;同时计算出了平均热变形激活能Q为243.5kJ/mol和应力指数n为4.1972,分析得出变形激活能直接受到温度的影响,间接受到应变速率的影响。     

Mg-11.8Gd-2.8Y-0.44Zr耐热镁合金热压缩变形行为研究

采用Gleeble-1500热/力模拟机,对Mg-11.8Gd-2.8Y-0.44Zr耐热镁合金在温度为573～723 K,应变速率为0.001、0.010、0.100 s-1,应变量为60%的塑性变形行为以及热压缩后镁合金组织的变化进行了研究.分析了流变应力与应变速率和温度的关系.结果表明,合金的稳态流变应力随应变速率的增大而增大,在恒应变速率条件下,合金的真应力水平随温度的升高而降低,根据试验分析,合金的热加工宜在623 K时进行.     

AZ70镁合金热压缩变形特性

在温度为300℃～420℃、应变速率为0.001s-1～1s-1的变形条件下,采用Gleeble-1500热模拟机对AZ70镁合金热压缩变形特性进行了研究。结果表明,合金的流变应力随应变速率的增大而增大,随温度的升高而降低;在给定的变形条件下,计算出合金的变形激活能为132kJ/mol,应力指数为6.2;建立了合金高温变形的本构方程;降低变形温度和提高应变速率可使再结晶晶粒平均尺寸减小。根据实验分析得出,材料的最佳热加工工艺条件为变形温度340℃～400℃,应变速率0.001s-1～0.1s-1,并提出以低速为宜。     

铸态Mg-7Gd-5Y-1．2Nd—Zr镁合金热变形行为研究

针对Mg-7Gd-5Y-1.2Nd-Zr镁合金,研究了其铸态显微组织以及在Gleeble-1500D热模拟机上单向压缩的力学行为,其应变速率为2×10-3～1 s-1,变形温度为573～723 K,压下量为60%.铸态Mg-7Gd-5Y-1.2Nd-Zr合金组织由α-Mg基体和网状的共晶构成;变形温度和应变速率对合金的峰值应力有明显的影响,在相同变形温度条件下,峰值应力随应变速率的增加而升高;在相同的应变速率条件下,峰值应力随变形温度的升高而降低;高温条件下的共晶组织的软化也是合金变形抗力下降的重要原因;应变速率为10-1 s-1 时,合金不连续动态再结晶最为明显,合金易于失效;同时计算出了平均热变形激活能Q为243.5 kJ/mol和应力指数n为4.197 2,分析得出变形激活能直接受到变形温度的影响,间接受到应变速率的影响.     

快速凝固/粉末冶金镁合金的压缩变形行为

采用雾化-双辊急冷法和热挤压工艺,成功地制备了快速凝固/粉末冶金(RS/PM)Mg-6wt%Zn、Mg-6wt%Zn-5wt%Ce和Mg-6wt%Zn-5wt%Ce-1.5wt%Ca合金,并对合金的压缩变形行为进行了研究,其中测试温度为25～300℃,初始应变速率为5×10<'-4>/s.结果表明,合金的变形行为强烈依赖于变形温度.合金中细小、弥散的析出相为主要的非位错型障碍物,可能是造成合金硬化的主要原因;而随着温度的升高,软化机制的激活会引起合金变形行为的不同.其中,位错的交滑移、攀移以及晶界滑动可能是软化的主要原因.     

AZ91镁合金高温变形本构关系

采用Gleeble-1500热模拟机对AZ91镁合金进行了高温压缩变形实验,分析了该合金在变形温度为250-400℃,应变速率为0.001-1 s-1条件下流变应力的变化规律.结果表明,变形温度和应变速率均对流变应力有显著的影响,流变应力随变形温度的升高和应变速率的降低而降低,当变形温度≥400℃、应变速率≤0.001 s-1时,流变应力随变形量的增加达峰值后呈稳态流变特征.并采用双曲正弦模型确定了该合金的变形激活能Q和应力指数n随应变量的变化规律,建立了相应的热变形本构关系.经实验验证,所建立的本构关系能较好地反映AZ91镁合金实际热变形行为特征.     

Fracture behavior of high strength Mg-Gd-Y-Zr magnesium alloy

The fracture behavior of a permanent mould casting Mg-8.57Gd-3.72Y-0.54Zr(mass fraction,%)(GW94) alloy was investigated under different thermal conditions,including as-cast,solution-treated,peak-aged,and over-aged states.Scanning electron microscopy(SEM) and optical microscopy(OM) were employed to examine the crack nucleation and fracture model.The results indicate that the GW94 alloy shows different behaviors of crack initiation and fracture under different thermal conditions. During tensile test at room temperature,the fracture model of the as-cast GW94 alloy is quasi-cleavage,while that of the solution-treated alloy is transgranular cleavage.It is a mixed pattern of transgranular and intergranular fracture for both the aged conditions.Large cavities formed at grain boundaries are observed in the peak-aged sample tested at 300℃,corresponding to the intergranular fracture.Localized plastic deformation at grain boundaries is also observed and corresponds to the high elongation at 300℃.     

Hot deformation behavior of Mg-7.22Gd-4.84Y-1.26Nd-0.58Zr magnesium alloy

The behavior evolvement of Mg-7.22Gd-4.84Y-1.26Nd-0.58Zr(GWN751K) magnesium alloy during the hot deformation process was discussed.The flow stress behavior of the magnesium alloy over the strain rate range of 0.002 to 2.000 s-1 and in the temperature range of 623 to 773 K was studied on a Gleeble-1500D hot simulator under the maximum deformation degree of 60%.The experimental results showed that the relationship between stress and strain was obviously affected by strain rate and deformation temperature.The flow stress of GWN751K magnesium alloy during high temperature deformation could be represented by the Zener-Hollomon parameter in the hyperbolic Arrhenius-type equation.The stress exponent n and deformation activation energy Q were evaluated by linear regression analysis.The stress exponent n was fitted to be 3.16.The hot deformation activation energy of the alloy during hot deformation was 230.03 kJ/mol.The microstructures of hot deformation were also influenced by strain rate and compression temperature strongly.It was found that the alloy could be extruded at 723 K with the mechanical properties of σ0.2 = 260 MPa,σb = 320 MPa,and δ = 18%.     

耐热镁合金的开发与研究现状

分析了镁合金的高温蠕变机制及耐热镁合金的设计思路,综述了通过添加稀土元素(RE)、碱土元素(Ca、Sr)及其他元素(Si、Bi、Sn)开发耐热镁合金的现状,指出研究与开发价格低廉、工艺性能良好、综合力学性能良好的耐热镁合金是今后耐热镁合金的发展方向.     

GWN751K镁合金均匀化热处理

通过OM、SEM及布氏硬度分析,研究GWN751K镁合金在不同状态下的显微组织与性能,确定该合金的双级均匀化工艺参数。结果表明:合金经过440℃、6h初级均匀化后,共晶组织开始发生分解,晶粒开始长大;经过535℃、16h热处理后,合金晶粒明显长大,但元素分布较为均匀,晶界处仅明显残留含Y化合物;均匀化处理使合金的力学性能得到改善,合金断裂强度为245MPa,屈服强度为192MPa,伸长率为12%,较铸态合金的力学性能均有所提高;合金变形抗力较铸态合金的有所增加,这种特性在450℃仍保留下来,但差别减小。     

Hot compression deformation behavior of the Mg-Al-Y-Zn magnesium alloy

The hot deformation behavior of a Mg-Al-Y-Zn magnesium alloy was investigated by hot compressive testing on a Gleeble-1500 thermal simulator at the temperanging from 523 to 673 K with the swain rate varying from 0.001 to 1s-1.The relationships among flow stress,swain rate,and deformation temperature were analyzed,and the deformation activation energy and stress exponent were calculated.Microstructure evolution of the alloy under different conditions was examined.The results indicated that the maximum value of the flow stress increased with the decrease of deformation temperature or the increase of swain rate.Under the present deformation conditions,dynamic recrystallization (DRX) oeettrred in the alloy,which was the main softening mechanism during deformation at elevated temperature.The deformation temperature and strain had significant effects on the microstructure of the alloy.     

Hot compression deformation behavior of the Mg-AI-Y-Zn magnesium alloy

The hot deformation behavior of a Mg-Al-Y-Zn magnesium alloy was investigated by hot compressive testing on a Gleeble-1500 thermal simulator at the temperanging from 523 to 673 K with the swain rate varying from 0.001 to 1s-1.The relationships among flow stress,swain rate,and deformation temperature were analyzed,and the deformation activation energy and stress exponent were calculated.Microstructure evolution of the alloy under different conditions was examined.The results indicated that the maximum value of the flow stress increased with the decrease of deformation temperature or the increase of swain rate.Under the present deformation conditions,dynamic recrystallization (DRX) oeettrred in the alloy,which was the main softening mechanism during deformation at elevated temperature.The deformation temperature and strain had significant effects on the microstructure of the alloy.