The U–Pb age and Lu–Hf isotope composition of detrital zircon from metasedimentary rocks of the Onot greenstone belt (Sharyzhalgay uplift,southern Siberian craton)

We present data on the composition of metasedimentary rocks from the greenstone belt of the Onot terrane (Sharyzhalgay uplift) and results of U–Pb dating (SHRIMP II) and Lu–Hf isotope study of detrital zircon from garnet–staurolite schists. The metasedimentary rocks of the Onot greenstone belt are dominated by garnet- and staurolite-bearing schists alternating with amphibolites (metabasalts) in the upper part of the section. Compositionally the protoliths of garnet–staurolite schists correspond to sedimentary rocks, ranging from siltstone to pelitic mudstone. The trace-element characteristics of the garnet–staurolite schists indicate that the terrigenous material was derived from three different rock types, such as tonalite–trondhjemite plagiogneisses (elevated Gd/Yb ratios), mafic rocks (elevated Cr/Th ratios and reduced Th/Sc ratios), and felsic igneous rocks formed by crustal melting (the presence of a Eu minimum), which agrees with the set of potential source rocks from the Onot terrane. The age of predominant detrital zircon reflects the erosion of mainly Neoarchean igneous rocks; this fact, combined with the poor rounding of zircon and tectonically active sedimentation conditions accompanied by mafic volcanism, suggests that the probably depositional age is ca. 2.7 Ga. Older source rocks (2.80–3.35 Ga) contributed to the sediment deposition along with the Neoarchean ones. According to the Hf isotope composition of detrital zircon from the garnet–staurolite schists, the source provenances had different crustal prehistories. The source provenances include Paleoarchean and juvenile Neoarchean crust and rocks formed by the mixing of melts from ancient and juvenile crustal sources.     

Geochemistry of metabasites of the Kolpakov Group of the Sredinny crystalline Massif in Kamchatka

Metabasites (amphibolites, garnet amphibolites, and basic crystalline schists) compose numerous sheeted bodies (often highly boudined) from a few to 100 meters thick in the plagiogneisses and migmatites of the Kolpakov Group. Chemically, they are reconstructed as basalts and picrites that were metamorphosed, as host terrigenous rocks, under the kyanite-sillimanite subfacies of the amphibolite facies (t = 620–650°C, P _s = 5.9–6.9 kbar). Metabasites are dominated by amphibolites and basic crystalline schists distributed throughout the entire section of the Kolpakov Group, whereas garnet amphibolites are more typical of the upper parts of the group, where they are intercalated with amphibolites, basic crystalline schists, plagiogneisses, and quartzites. Metaultrabasites (plagioclase-free amphibolites) occur much more rarely as small boudins up to few meters in size. According to U-Pb SHRIMP zircon dating, the plagiogneiss protolith age corresponds to the end of the Early-Late Cretaceous (90–100 Ma), which is similar in age to the weakly metamorphosed terrigenous deposits of the Kikhchik Group of the Sredinny Range. This allows us to consider the terrigenous rocks of these groups as isofacial sedimentary rocks. The same age (Early-Late Cretaceous boundary) was taken for protoliths of metabasites forming interbeds among metaterrigenous deposits of the Kolpakov Group. The interval of 100?90 Ma coincides with the beginning of the formation of the Okhotsk-Chukotka volcanogenic marginal-continental belt in East Asia. It is shown that the Kolpakov Group possesses the geochemical features of tholeiitic basalts of different geodynamic settings and comprises both typically island arc (low-Ti) and oceanic (moderate to high-Ti) tholeiites associated with ultrabasic volcanic rocks—picrites. Such a chemical peculiarity of basic rocks is typical of the marginal-continental extension zones (pull-apart basin) that were initiated on the sialic crust. It is obvious that similar geodynamic setting of the basite magmatism existed for the Sredinny Range of Kamchatka. The ascent of the mantle matter beneath the extension zone of the continental crust of the sedimentary basin and its intersection by faults that formed simultaneously with the Okhotsk-Chukotka volcanogenic belt served as the beginning of the basite volcanism in the sedimentary basin. They provided an intense fluid effect and a temperature increase in the crust with subsequent granitization and metamorphism of volcanogenic-terrigenous deposits and, finally, the development of the modern structure of the Sredinny Kamchatka Massif. The intense Late Cretaceous basite volcanism and associated granitoid magmatism in Kamchatka were presumably caused by the ascent of mantle plumes bearing hydrogen fluids.     

The isotope composition of Hf in zircon from Paleoarchean plagiogneisses and plagiogranitoids of the Sharyzhalgai uplift (southern Siberian craton): Implications for the continental-crust growth

This paper presents results of U–Pb dating (SHRIMP-II) and Lu–Hf (LA–ICP MS) isotope study of zircon from Paleoarchean plagiogneisses and plagiogranitoids of the Onot and Bulun blocks of the Sharyzhalgai uplift. Magmatic zircons from the Onot plagiogneiss and Bulun gneissic trondhjemite are dated at 3388±11 and 3311±16 Ma, respectively. Magmatic zircons from plagiogneisses and plagiogranitoids of the studied tonalite–trondhjemite–granodiorite (TTG) complexes are characterized mainly by positive values of εHf indicating that felsic melts were generated mainly from juvenile (mafic) sources, which are derived from a depleted mantle reservoir. The variable Hf isotope composition in magmatic zircons and the lower average εHf values in comparison with the depleted mantle values suggest the contributions of both mafic and more ancient crustal sources to magma formation. Metamorphic zircons from the gneissic plagiogranite and migmatized plagiogneiss either inherited the Hf isotope composition from magmatic zircon or are enriched in radiogenic Hf. The more radiogenic Hf isotope composition of metamorphic zircons from the migmatized plagiogneisses is due to their interaction with melt during partial melting. Variations in the Lu–Hf isotope composition of zircon from the Bulun rocks in the period 3.33–3.20 Ga are due to the successive melting of mafic crust or the growing contribution of crustal material to their genesis. Correlation between the Lu–Hf isotope characteristics of zircon and the Sm–Nd parameters of the Onot plagiogneisses points to the contribution of ancient crustal material to their formation. The bimodal distribution of the model Hf ages of zircons reflects two stages of crustal growth in the Paleoarchean: 3.45–3.60 and ~ 3.35 Ga. The isotope characteristics of zircon and rocks of the TTG complexes, pointing to recycling of crustal material, argue for the formation of plagiogneisses and plagiogranitoids as a result of melting of heterogeneous (mafic and more ancient crustal) sources in the thickened crust.     

Gold-bearing rocks of Mangalur greenstone belt,Gulbarga District,Karnataka

The Mangalur greenstone belt of Dharwar Craton, South India, is an Archaean schist belt dominated by metavolcanic rocks. The gold mineralization occurs within the metavolcanics and the fabric, mineralogy and geochemistry of these host rocks indicate that they were tholeiitic basalts regionally metamorphosed under medium to low-grade greenschist facies. The basic metavolcanic rocks occur as tholeiitic metabasalts and amphibolites. The rocks have undergone some fractionation and appear to be derived from melts generated by 10 to 25% melting of the mantle at depths 30 to 35 km around temperature 1200°C and pressure 12 kb. The source of gold is mainly in the basalts and not in the surrounding granites.     

Possibility of identification of back-arc paleobasins from high-grade orthometamorphite rocks: Evidence from basic crystalline schists of the Slyudyanka crystalline complex,South Baikal region

The Slyudyanka crystalline complex is located within the composite Khamar-Daban metamorphic terrane, the part of the Central Asian fold belt. Geochemical composition of the basic crystalline schists of the Slyudyanka Group (subterrane) metamorphosed under the high-temperature subfacies of the granulite facies suggests that their protoliths were tholeiitic basalts. Their geochemical signatures are intermediate between mid-ocean ridges and island arc basalts, best approximating back-arc basin basalts. The types of the metamorphic rocks of the Slyudyanka Group and their combination in sequences also most correspond to accumulation in back-arc basins. It was concluded that the high-grade metavolcanic rocks retain main geochemical signatures of protoliths, which allows the reconstruction of their paleogeodynamic settings, including back-arc basins.     

Provenance of the Sumian basal schists and age of the Lopian metavolcanic rocks at the Archean-Proterozoic boundary in the Kukasozero structure,North-Karelian zone of the Karelides,Baltic Shield

This paper presents the results of a study of the Paleoproterozoic basal garnet-kyanite-staurolite-two-mica paraschists from the Kukasozero structure of the Karelides of Northern Karelia, Baltic Shield, underlying Neoarchean acid metavolcanic rocks, and schists with quartz, phengite, kyanite, staurolite, garnet, and tschermakite located in the Paleoproterozoic rocks and considered to be metasomatic in origin. It was established that the sedimentary protolith of the Paleoproterozoic paraschists contains detritus of Neoarchean igneous rocks as follows from detrital 2737 ± 11 Ma zircons with oscillatory magmatic zoning. Metavolcanic 2757 ± 13 Ma rocks, close in age and composition, are known directly in the framework of the Kukasozero structure and are considered to be the most likely source of the sedimentary schist protolith. The coincidence of the Nd-model ages of paraschists (t _DM is 2.73–2.76 Ga) with the age of detrital zircons indicates no contribution of older rocks to the protolith composition. The age of magmatic crystallization of metavolcanic rocks directly underlying the Paleoproterozoic paraschists is 2681 ± 18 Ma and coincides with the age of porphyry granites in the western framework of the structure (2680.3 ± 3.6 Ma). No detrital zircons of similar age were found in basal paraschists, but the restricted amount of dated zircons does not allow us to draw a final conclusion about the absence of detritus of the underlying metavolcanic rocks in the paraschist protolith. It was confirmed that phengite-bearing schists are the products of acid metasomatism of the Paleoproterozoic amphibolites and amphibole schists (metavolcanic rocks). The metasomatic features were revealed in garnet-kyanite-staurolite-two-mica paraschists, so the strict identification of their sedimentary protolith is impossible. The paraschists do not represent metamorphosed weathering crust, because acid metasomatism gives a false impression of the greater maturity of the primary sedimentary rocks.     

Pan-African magmatism in the Menderes Massif: geochronological data from leucocratic tourmaline orthogneisses in western Turkey

The Menderes Massif, exposed in western Anatolia, is a metamorphic complex cropping out in the Alpine orogenic belt. The metamorphic rock succession of the Massif is made up of a Precambrian basement and overlying Paleozoic-early Tertiary cover series. The Pan-African basement is composed of late Proterozoic metasedimentary rocks consisting of partially migmatized paragneisses and conformably overlying medium- to high-grade mica schists, intruded by orthogneisses and metagabbros. Along the southern flank of the southern submassif, we recognized well-preserved primary contact relationship between biotite and leucocratic tourmaline orthogneisses and country rocks as the orthogneisses represent numerous large plutons, stocks and vein rocks intruded into a basement of garnet mica schists. Based on the radiometric data, the primary deposition age of the precursors of the country rocks, garnet mica schist, can be constrained between 600 and 550?Ma (latest Neoproterozoic). The North Africa–Arabian-Nubian Shield in the Mozambique Belt can be suggested as the possible provenance of these metaclastics. The intrusion ages of the leucocratic tourmaline orthogneisses and biotite orthogneisses were dated at 550–540?Ma (latest Neoproterozoic–earliest Cambrian) by zircon U/Pb and Pb/Pb geochronology. These granitoids represent the products of the widespread Pan-African acidic magmatic activity, which can be attributed to the closure of the Mozambique Ocean during the final collision of East and West Gondwana. Detrital zircon ages at about 550?Ma in the Paleozoic muscovite-quartz schists show that these Pan-African granitoids in the basement form the source rocks of the cover series of the Menderes Massif.     

Archaean greenstone belt from the Central African Republic (Equatorial Africa)

The Bandas belt, one of two prominent Archaean greenstone belts in the Central African Republic (Equatorial Africa), is ca. 250 km long. At the southernmost part of the belt, a metasedimentary—metavolcanic rock suite is preserved only in brachysynclines. The suite can be divided into two lithostratigraphic units. The lower unit is composed predominantly of volcanic rocks, while the upper one contains mainly metasedimentary rocks. The volcanic rocks, which are part of a sequence ca. 3600 m thick, can be sub-divided according to stratigraphic position, lithology and geochemistry into three groups. The lowermost group includes low-K tholeiitic basalts depleted in light REE. The second group consists of tholeiitic basalts with light REE-enriched patterns and the third, uppermost, group includes andesites, which are similar in several respects to Recent calc-alkaline andesites.The tholeiitic basalts of the first two groups are probably related to different upper mantle sources. The andesites of the third group were produced either by fractional crystallization from a basaltic magma enriched in light REE or equilibrium melting of eclogite or garnet amphibolite.     

Geochemistry and Petrogenesis of Amphibolites, Kolar Schist Belt, South India: Evidence for Komatiitic Magma Derived by Low Percentages of Melting of the Mantle

The Kolar Schist Belt of the Dharwar Craton of South India isan Archean greenstone belt dominated by metavolcanic rocks.The mafic metavolcanic rocks occur as komatiitic and tholeiiticamphibolites. The komatiitic amphibolites occur along the marginsof the N–S trending, synformal belt. They are much lessabundant than the tholeiitic amphibolites and have 14 to 21–3wt. per cent MgO. The komatiitic amphibolites from the west/centralpart of the belt have two distinctive REE patterns: (1) thoseenriched in the middle to light REE but depleted in Ce relativeto Nd; and (2) those with patterns that are convex up, i.e.depleted in both light and heavy REE, although more depletedin the light REE. Associated tholeiites have light REE depletedto flat REE patterns. Komatiitic and tholeiitic amphibolitesfrom the eastern part of the belt have enriched light REE patterns. The tholeiitic amphibolites from the Kolar Schist Belt are similarto the TH I and TH II types of Archean tholeiites of Condie(1981). The komatiitic amphibolites are similar to komatiitesand komatiitic basalts of Barberton Mountainland, but have higherFeO and TiO2 abundances and lower Yb/Gd ratios. The petrogenetic interpretations for these rocks are based primarilyon a modification of the MgO-FeO diagram of Hanson & Langmuir(1978), and modelling of Zr, Ni and REE. All of the rocks haveundergone some fractionation. While the modelling does not giveaccurate temperatures, pressures, compositions and extents ofmelting of the mantle sources for the various amphibolites,it does present an approach which can be used for estimatingthese parameters. For example, the komatiitic amphibolites appearto be derived from melts generated by 10 to 25 per cent meltingof the mantle over a range of depths and temperatures greaterthan 80 km and 1575?C. The variation in the P-T conditions ofmagma generation is possibly due to adiabatic melting in mantlediapirs with a range of FeO/MgO ratios. If the tholeiitic amphibolitesare derived from similar mantle sources (it is not clear thatthey are), their parent melts may have been generated by similarextents of melting, but at depths of less than 80 km. The komatiiticamphibolites from the west central part of the belt were generatedfrom light REE depleted mantle, whereas those from the easternpart of the belt appear to have been generated from light REEenriched mantle. The sources for the komatiitic amphibolitesin both areas were significantly enriched in FeO relative topyrolite. Thus, a light REE depleted and a light REE enrichedsource appear to have provided mafic volcanics with similarmajor element chemistry to this belt during its evolution.     

Neoproterozoic nascent island arc volcanism from the Nubian Shield of Egypt: Magma genesis and generation of continental crust in intra-oceanic arcs

The Neoproterozoic Wadi Ranga metavolcanic rocks, South Eastern Desert of Egypt, constitute a slightly metamorphosed bimodal sequence of low-K submarine tholeiitic mafic and felsic volcanic rocks. The mafic volcanic rocks are represented by massive and pillow flows and agglomerates, composed of porphyritic and aphyric basalts and basaltic andesites that are mostly amygdaloidal. The felsic volcanic rocks embrace porphyritic dacites and rhyolites and tuffs, which overlie the mafic volcanic rocks. The geochemical characteristics of Wadi Ranga volcanic rocks, especially a strong Nb depletion, indicate that they were formed from subduction-related melts. The clinopyroxene phenocrysts of basalts are more akin to those crystallizing from island-arc tholeiitic magmas. The tholeiitic nature of the Wadi Ranga volcanics as well as their LREE-depleted or nearly flat REE patterns and their low K₂O contents suggest that they were developed in an immature island arc setting. The subchondritic Nb/Ta ratios (with the lowest ratio reported for any arc rocks) and low Nb/Yb ratios indicate that the mantle source of the Wadi Ranga mafic volcanic rocks was more depleted than N-MORB-source mantle. Subduction signature was dominated by aqueous fluids derived from slab dehydration, whereas the role of subducted sediments in mantle-wedge metasomatization was subordinate, implying that the subduction system was sediment-starved and far from continental clastic input. The amount of slab-derived fluids was enough to produce hydrous magmas that follow the tholeiitic but not the calc-alkaline differentiation trend. With Mg# > 64, few samples of Wadi Ranga mafic volcanic rocks are similar to primitive arc magmas, whereas the other samples have clearly experienced considerable fractional crystallization.The low abundances of trace elements, together with low K₂O contents of the felsic metavolcanic rocks indicate that they were erupted in a primitive island arc setting. The felsic volcanic rocks are characterized by lower K/Rb ratios compared to the mafic volcanic rocks, higher trace element abundances (~ 2 to ~ 9 times basalt) on primitive arc basalt-normalized pattern and nearly flat chondrite-normalized REE patterns, which display a negative Eu anomaly. These features are largely consistent with fractional crystallization model for the origin of the felsic volcanic rocks. Moreover, SiO₂-REE variations for the Wadi Ranga volcanic rocks display steadily increasing LREE over the entire mafic to felsic range and enriched La abundances in the felsic lavas relative to the most mafic lavas, features which are consistent with production of the felsic volcanic rocks through fractional crystallization of basaltic melts. The relatively large volume of Wadi Ranga silicic volcanic rocks implies that significant volume of silicic magmas can be generated in immature island arcs by fractional crystallization and indicates the significant role of intra-oceanic arcs in the production of Neoproterozoic continental crust. We emphasize that the geochemical characteristics of these rocks such as their low LILE and nearly flat REE patterns can successfully discriminate them from other Egyptian Neoproterozoic felsic volcanic rocks, which have higher LILE, Zr and Nb and fractionated REE patterns.     

抚顺—清原地区鞍山群块状硫化物矿床的区域地质特征

抚顺-清原地区位于辽宁省东北部,面积约2500Km~2.区内太古代变质岩系广泛发育,其下部为深变质的麻粒岩相地层,上部为中深变质的角闪岩相地层,后者产出红透山式铜锌矿床多处(属红透山地区),以及张胡子沟铜矿床和大荒沟硫铁矿床(属清原北部地区)等一系列块状硫化物矿床(图1).矿石中铅同位素年令为25～26亿年,在形成时代上可以和鞍本地区鞍山群对比.     

Geochemistry and Crustal Evolution of Volcano-sedimentary Successions and Orthogneisses in the São Gabriel Block, Southernmost Brazil — Relics of Neoproterozoic Magmatic Arcs

Precambrian metaplutonic rocks of the São Gabriel block in southernmost Brazil comprise juvenile Neoproterozoic calc-alkaline gneisses (Cambaí Complex). The connection with associated (ultra-)mafic metavolcanic and metasedimentary rocks (Palma Group) is not well established. The whole complex was deformed during the Brasiliano orogenic cycle. Both metasedimentary and metavolcanic rocks as well as metaplutonic rocks of the Cambaí Complex have been sampled for geochemical analyses in order to get constraints on the tectonic setting of these rocks and to establish a tectonic model for the São Gabriel block and its role during the assembly of West-Gondwana. The major element compositions of the igneous rocks (Palma Group and Cambaí Complex) indicate a subalkaline character; most orthogneisses have a calc-alkaline chemistry; many metavolcanic rocks of the Palma Group show signatures of low-K tholeiitic volcanic arc basalts. Trace element data, especially Ti, Zr, Y, Nb, of most igneous samples from both the lower Palma Group and the Cambaí Complex indicate origin at plate margins, i.e., in a subduction zone environment. This is corroborated by relative enrichment in LREE, low contents of Nb and other high field strength elements and enrichment in LILE like Rb, Ba, and Th. The data indicate the possible existence of two suites, an oceanic island arc and a continental arc or active continental margin. However, some ultramafic samples of the lower Palma Group in the western São Gabriel block indicate the existence of another volcanic suite with intra-plate character which possibly represents relics of oceanic island basalts (OIB). Trace element data indicate contributions from andesitic to mixed felsic and basic arc sources for the metasedimentary rocks. The patterns of chondrite- and N-MORB-normalized spider diagrams resemble the patterns of the igneous rocks, i.e., LILE and LREE enrichment and HFS depletion. The geochemical signatures of most igneous and metasedimentary samples and their low (⁸⁷Sr/⁸⁶Sr)_t ratios suggest only minor contribution of old continental crust.A geotectonic model for the São Gabriel block comprises east-ward subduction and following accretion of an intra-oceanic island arc to the eastern border of the Rio de la Plata Craton at ca. 880 Ma, and westward subduction beneath the newly formed active continental margin between ca. 750 and 700 Ma. The São Gabriel block represents relics of an early Brasiliano oceanic basin between the Rio de la Plata and Kalahari Cratons. This ocean to the east of the Rio de la Plata Craton might be traced to the north and could possibly be linked with Neoproterozoic juvenile oceanic crust in the western Brasília belt (Goiás magmatic arc).     

Geothermobarometry in albite-garnet orthogneisses: A case study from the Gran Paradiso nappe (Western Alps)

The aim of this paper is to estimate syntectonic P-T conditions within albite- and garnet-bearing orthogneisses. These rocks are generally characterized by the assemblage quartz + albite + biotite + phengite + CaFe-garnet + epidote + titanite. Garnet contains up to 55 mole per cent of grossular. K-feldspar is a relict magmatic phase.

P-T conditions are estimated using several independent methods. First, it is shown that exchange reactions based on the Fe---Mg partitioning between garnet and biotite or garnet and phengite cannot be used to estimate temperatures in these rocks, due to the high grossular content of garnet. Second, maximum and minimum pressures are constrained, respectively, by the occurrence of albite instead of jadeite + quartz and by the assemblage phengite + biotite + quartz. Third, phase equilibria in albite- and garnet-bearing metagranites are modelled in the system K₂O---CaO---FeO---Al₂O₃---SiO₂---H₂O. Equilibrium curves are calculated for the observed phase compositions. Uncertainties in P-T estimates mainly result from the choice of appropriate non-ideal solution models for the garnet.

An application is developed for granites from the Gran Paradiso nappe (Western Alps). These granites show an heterogeneous deformation of Alpine age expressed by mylonitic shear zones cutting across weakly deformed domains. Estimated P-T conditions for the synkinematic assemblages are 10–16 kbar at 550±50°C.     

Major,trace and platinum group element (PGE) geochemistry of Archean Iron Ore Group and Proterozoic Malangtoli metavolcanic rocks of Singhbhum Craton,Eastern India: Inferences on mantle melting and sulphur saturation history

The geological and metallogenic history of the Singhbhum Craton of eastern India is marked by several episodes of volcanism, plutonism, sedimentation and mineralization spanning from Paleoarchean to Mesoproterozoic in a dynamic tectonic milieu. Distinct signatures of this Archean-Proterozoic geodynamic process are preserved in discrete crustal provinces that constitute the Singhbhum Craton. Here we report new major, trace and PGE geochemical data from the ~ 3.4 Ga Iron Ore Group (IOG) volcanic rocks of the Jamda-Koira basin, a part of the BIF-bearing volcano-sedimentary sequences of the Noamundi-Jamda-Koira iron ore basin in the western part of Singhbhum Granite (SBG), and ~ 2.25 Ga metavolcanic rocks of Malangtoli. The IOG and Malangtoli volcanic rocks are porphyritic basalts and despite belonging to different ages, they exhibit similar mineralogical composition marked by clinopyroxene, plagioclase (present as both phenocryst and groundmass), opaques and volcanic glass (restricted to groundmass). The igneous mineralogy of these rocks has been overprinted by greenschist to lower amphibolite grade of metamorphism. The Malangtoli samples show low and high MgO compositional varieties. Immobile trace element compositions classify the IOG samples as andesite having a calc-alkaline composition, whereas the Malangtoli rocks correspond to basalt and andesite displaying a tholeiitic to calc-alkaline trend. The IOG basalts show low to moderate PGE contents marked by 26.23–68.35 ppb of ΣPGE, whereas the Malangtoli basalts display a moderate to high concentration of PGE (ΣPGE = 43.01–190.43 ppb). The studied samples have relatively enriched ΣPPGE ranging from 24.1–63.3 ppb (IOG) and 34–227.3 ppb (Malangtoli) against 2.2–4.1 ppb and 1.9–8.9 ppb ΣIPGE contents respectively. PPGE/IPGE ratios for IOG and Malangtoli samples range from 7.7–17.6 and 4.8–59.9. HFSE, REE and PGE compositions suggest a low degree (< 1 to 1%) of partial melting in the garnet lherzolite domain for the generation of IOG volcanic rocks. The parental magma of the Malangtoli basalts were generated by lower to higher degrees (3–< 10%) of mantle melting at depths corresponding to spinel to garnet lherzolite regime. Trace element (Zr/Nb, Th/Ta, Th/Nb, Ni/Cu) and PGE (Pd/Ir, Pd/Pt, Cu/Pd, Ni/Pd, Cu/Ir) ratios corroborate a sulphide saturated and PGE depleted character of IOG volcanic rocks that underwent crustal assimilation. In contrast, the high MgO Malangtoli basalts exhibit sulphide undersaturated, PGE undepleted nature devoid of crustal contamination whereas the low MgO Malangtoli basalts are sulphide saturated, PGE depleted and crustally contaminated. The IOG volcanic rocks correspond to intraoceanic arc with polygenetic crustal signatures, and show affinity towards arc-generated calc-alkaline basalts. The low- and high MgO basalts of Malangtoli are affiliated to transitional arc to rift-controlled back arc tectonic setting in a basinal environment that developed proximal to an active convergent margin.     

Geochronology and geochemistry of the Yilan greenschists and amphibolites in the Heilongjiang complex,northeastern China and tectonic implications

The Heilongjiang complex, extending along a suture zone between the Jiamusi and Songliao blocks in Northeast China, is composed mainly of blueschists, greenschists, meta-ultramafic rocks, quartzites, muscovite–albite schists and two-mica schists. Controversy has long surrounded the ages and tectonic settings of mafic rocks from the complex, which are crucial part of the complex. The lithological associations and their major and trace element compositions indicate that the mafic protoliths of the Yilan greenschists can be subdivided into alkali and tholeiitic basalts, which were derived from partial melting of a garnet-bearing and spinel-bearing mixed source, whereas the protoliths of the amphibolites are tholeiitic and were generated from the partial melting of spinel peridotite. Magmatic zircons from a tholeiitic amphibolite sample yielded a 206Pb/238U age of 256 ± 2 Ma, interpreted as its protolithic age. The sample also contains small amounts of older inherited zircons up to 344 Ma, which, together with its origin from shallow lithospheric mantle, indicate that the tholeiitic rocks were generated in a continental rift. The geochemical data suggest that further rifting led to the formation of an ocean between the Jiamusi and Songliao blocks, in which some oceanic islands developed, represented by the alkali basaltic protoliths of the Yilan greenschists. Magmatic zircons from an alkaline greenschist sample yielded a 206Pb/238U age of 162 ± 3.9 Ma, which, together with protolithic age of 141.8 ± 1 Ma previously obtained for the Yilian blueschist, support the model that the ocean between the Jiamusi and Songliao blocks closed at some time after ~ 141 Ma, not earlier at 210–180 Ma as previously considered.     

Geology and geochemistry of metabasalts of Shimoga schist belt,Dharwar Craton: implications for the late Archean basin development

The late Archaean Shimoga schist belt in the Western Dharwar Craton, with its huge dimensions and varied lithological associations of different age groups, is an ideal terrane to study Archean crustal evolution. The rock types in this belt are divided into Bababudhan Group and Chitradurga Group. The Bababudhan Group is dominated by mafic volcanic rocks followed by shallow marine sedimentary rocks while the Chitradurga Group is dominated by greywackes, pillowed basalts, and deep marine sedimentary rocks with occasional felsic volcanics. The Nb/Th and Nb/La ratios of the studied metabasalts of the Bababudhan Group indicate crustal contamination. They were extruded onto the vast Peninsular Gneisses through the rifting of the basement gneiss. The Nb/Yb ratios of high-magnesium basalts and tholeiitic basalts of Chitradurga Group suggest the enrichment of their source magma. Based on the flat primitive mantle-normalized multi-element plot with negative Nb anomalies and Th/Ta-La/Yb ratios, the high-magnesium basalts and tholeiitic basalts are considered to have erupted in an oceanic plateau setting with minor crustal contamination. The high-magnesium basalts and tholeiitic basalts formed two different pulses of same magma type, in which the first pulse of magma gave rise to high-magnesium basalts which were derived from deep mantle sources and underwent minor crustal contamination en route to the surface, while the second pulse of magma gave rise to tholeiitic basalts formed at similar depths to that of high-magnesium basalts and escaped crustal contamination. The associated lithological units found with the studied metavolcanic rock types of Bababudan and Chitradurga Groups of Dharwar Supergroup of rocks in Shimoga schist belt of Western Dharwar Craton confirm the mixed-mode basin development with a transition from shallow marine to deep marine settings.     

滇东南建水地区高镁火山岩包体的成因和构造背景

在滇东南建水地区发现产于峨眉山玄武岩中的高镁火山岩包体,这对于地幔柱的形成演化具有重要研究意义.对这些包体进行了锆石U-Pb年代学、地球化学和岩矿分析.高镁火山岩包体具斑状结构,致密块状构造,斑晶主要为贵橄榄石和透辉石.13颗锆石U-Pb LA-ICP-MS加权平均年龄为259±2Ma(MSWD=1.9),显示与寄主岩石同期形成.包体岩石具有高镁(Mg~#=68～75)、低硅(SiO_2=45.11%～45.93%)特征,轻稀土元素(LREE)、高场强元素(HFSE)富集而重稀土元素(HREE)亏损,属于亚碱性、拉斑玄武岩系列,具有板内玄武岩(IPB)特征.火山岩包体的原始岩浆起源于石榴子石二辉橄榄岩低程度部分熔融的产物,岩浆演化过程中发生了橄榄石和单斜辉石的分离结晶作用,在侵位上升过程中未受明显的地壳混染作用.该高镁火山岩的存在,显示地幔柱除了垂直上升运动外,在地球深部不同的边界还有多次侧向扩展移动,表明滇东南晚二叠世存在峨眉山地幔柱的一个分支-地幔枝活动.     

东南亚新生代两类埃达克岩的分布、成因和含矿性

东南亚的巽他群岛-巴布亚新几内亚是新生代埃达克岩和类埃达克岩发育的地区。这些中酸性岩浆岩广泛见于印度尼西亚几内亚岛、苏拉威西和巴布亚新几内亚, 零星见于苏门答腊、班达岛弧、西爪哇和中加里曼丹等地。本区埃达克岩和类埃达克岩岩石类型分别属于岛弧拉斑钙碱性系列和高钾钙碱性系列, 以重稀土元素Y, Yb含量低(分别为Y ≤19 ×10-6和Yb ≤1.8 ×10-6)和高Sr值(＞355 × 10-6)为特征。微量元素蛛网图上有明显的Ba、K、Sr正异常峰和负的Th、Nb (Ta)异常谷。大离子亲石元素(LILE)和高场强元素(HFSE)相对富集。本区埃达克岩和类埃达克岩的构造位置为新生代缝合线附近的大洋岛弧和陆缘造山带, 可划分为两种成因类型:第一种为岛弧拉斑/钙碱性系列, 其REE配分模式属于大洋岛弧型, 见于现代大洋岛弧, 称为岛弧型(O-型)埃达克岩; 另一种为高钾钙碱性系列, 其REE配分模式属于大陆型, 产于大陆板块边缘造山带, 与弧-陆碰撞和后碰撞构造环境有成因联系, 见于大陆边缘, 称为大陆型(C-型)埃达克岩。 研究结果表明:大陆型(C-型)埃达克岩和类埃达克岩分布区域与世界级斑岩铜-金矿分布相一致, 而大洋岛弧型(O-型)主要与浅成热泉金矿和喷气型有成因联系。      

Geochemistry and tectonic significance of metamorphic sole rocks beneath the Beyşehir–Hoyran ophiolite (SW-Turkey)

The Beyşehir–Hoyran ophiolite is situated in the western part of the Tauride belt (SW Turkey) and crops out at two localities north of the lake Beyşehir. It mainly comprises harzburgitic peridotites that were tectonically emplaced to their present position during the Late Eocene. The ophiolites themselves are tectonically overlain by either slope basin deposits with lava blocks (Eğirler formation) or massive Triassic limestone blocks (Deliktaş formation). High-grade sub-ophiolitic metamorphic rocks, i.e. epidote amphibolite, amphibolite, and pyroxene amphibolite, together with minor quartzite and calcschist, are observed at the base of the ophiolite sequence, where they occur as thin tectonic slices with an inverted metamorphic gradient. Average P–T conditions of 630–770 °C and c. 6 ± 1.5 kbar are calculated for the metamorphism of the amphibolites by conventional geothermobarometry, corresponding to a burial depth of 18–20 km. Both the sub-ophiolitic metamorphic rocks and the overlying mantle tectonites were intruded by isolated tholeiitic (Nb/Y = 0.041–0.108) diabase dikes, which do not transect the tectonic contact between the two units. Geochemical investigations of the amphibolites of the sub-ophiolitic rock suite show two different geochemical affinities, with the first group being alkaline in character (Nb/Y = 1–3.86) and the second one being tholeiitic (Nb/Y = 0.064–0.13). REE patterns, trace element plots and tectonomagmatic discrimination diagrams indicate that the most probable protoliths for alkaline amphibolites are within-plate type alkali basalts, whereas those of the tholeiitic group resemble tholeiitic island arc basalts. Similarities between the geochemical characteristics of the amphibolites and those of the volcanic rocks of the Eğirler formation strongly suggest that the latter are the protoliths of the amphibolites.     

Spinel-anthophyllite rocks of the Kokchetav massif (northern Kazakhstan)

Spinel-anthophyllite rocks that may be classified as ultrabasic low-Ca spinel amphibolites have been first discovered in the Kokchetav collision zone (northern Kazakhstan). They outcrop 2 km west of Enbek-Berlyk Village among schists and quartzites and are closely associated with spinel harzburgites and garnet pyroxenites. The main hosted minerals are spinel (hercynite) and anthophyllite. The rocks bear magnetite-hornblende-spinel-anthophyllite pseudomorphs with rounded and polygonal sections, which might have been resulted from the replacement of garnet grains. The prismatic anthophyllite crystals and scarce olivine relics contain elongate parallel spinel inclusions resembling spinel-olivine syntactic intergrowths in the Enbek-Berlyk spinel harzburgites. The spinel-anthophyllite rocks are similar to the associated spinel harzburgites in CaO, MnO, SiO₂, and Al₂O₃ contents but are richer in FeO and poorer in MgO (F = FeO/(FeO + MgO) = 57% against 35% in the harzburgites). Geological, mineralogical, and geochemical data suggest that the spinel-anthophyllite rocks formed during the isochemical contact metamorphism of garnet-bearing spinel harzburgites, which contained more FeO and less MgO than garnet-free harzburgites of the same area. Variations in FeO and MgO contents in both types of harzburgites seem to be due to different chemical compositions of the chlorite protoliths of these rocks.