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1.
Scientific debates on environmental impacts in cost-benefit analysis (CBA) focus on methodological questions. The literature, however, contains very little information on the influence of these debates on CBAs made in spatial planning practice. In this paper, this gap is filled by a qualitative analysis of 67 CBAs made in the Netherlands between 2000 and 2011. From the literature on environmental valuation, we derive criteria to evaluate the quality of CBA practice, such as completeness and the inclusion of uncertainties. The analysis shows that in many cases relevant environmental effects are omitted or not monetised. Moreover, non-monetised effects are often not included in CBA conclusions. If impacts are monetised, the methods used are frequently not very sophisticated. The consequences of assumptions are often not communicated, for example, where high discount rates make long-term effects seem unimportant. In this research we identify four main points for good practice.  相似文献   

2.
A promising alternative to conventional single phase processing, the use of sequential anaerobic-aerobic digestion, was extensively investigated on municipal sewage sludge from a full scale wastewater treatment plant. The objective of the work was to evaluate sequential digestion performance by testing the characteristics of the digested sludge in terms of volatile solids (VS), Chemical Oxygen Demand (COD) and nitrogen reduction, biogas production, dewaterability and the content of proteins and polysaccharides. VS removal efficiencies of 32% in the anaerobic phase and 17% in the aerobic one were obtained, and similar COD removal efficiencies (29% anaerobic and 21% aerobic) were also observed. The aerobic stage was also efficient in nitrogen removal providing a decrease of the nitrogen content in the supernatant attributable to nitrification and simultaneous denitrification. Moreover, in the aerobic phase an additional marked removal of proteins and polysaccharides produced in the anaerobic phase was achieved. The sludge dewaterability was evaluated by determining the Optimal Polymer Dose (OPD) and the Capillary Suction Time (CST) and a significant positive effect due to the aerobic stage was observed. Biogas production was close to the upper limit of the range of values reported in the literature in spite of the low anaerobic sludge retention time of 15 days. From a preliminary analysis it was found that the energy demand of the aerobic phase was significantly lower than the recovered energy in the anaerobic phase and the associated additional cost was negligible in comparison to the saving derived from the reduced amount of sludge to be disposed.  相似文献   

3.
Knowledge of phosphorus (P) fractions in dung of animals (dairy cattle, deer, sheep) grazing pasture is important for soil fertility and the potential for P transport in runoff and subsequent surface water quality deterioration. We used sequential fractionation and 31P nuclear magnetic resonance (NMR) spectroscopy to determine P forms in fresh and air-dried (to simulate field conditions during grazing) dung. Sheep dung was richest in P (8 g kg(-1)), and cattle dung poorest (5.5 g kg(-1)). Data for sequential fractionation indicated that most P was extractable by water (15-36%) and bicarbonate (36-45%) in fresh dung, and shifted toward recalcitrant, HCl (12-28%), and residual P forms (15-31%) with drying. Organic P concentration in dung was poor (maximum of 15% of total P), probably due to the poor concentration of phytate in pasture. The 31P NMR spectra of NaOH-EDTA extracts supported this by detecting a low concentration of monoesters (9-19% of total P in extracts), of which phytate is a major component. The 31P NMR data also showed that changes in organic P concentration with drying could be due to the degradation of diesters. Data indicate the decreasing bioavailability of dairy cattle, deer, and sheep dung with drying and the need to consider this effect with respect to P returns for soil fertility and the potential for runoff.  相似文献   

4.
A field lysimeter study with bare ground and five different ground covers was established to evaluate the effect of forage grasses on the fate and transport of two herbicides in leachate. The herbicides were atrazine (ATR; 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) and isoxaflutole [IXF; 5-cyclopropyl-4-(2-methylsulfonyl-4-trifluormethyl-benzoyl)isoxazole], which has the commercial name Balance (Aventis Crop Science, Strasbourg, France). The ground covers included orchardgrass (Dactylis glomerata L.), smooth bromegrass (Bromus inermis Leyss.), tall fescue (Festuca arundinacea Schreb.), timothy (Phleum pratense L.), and switchgrass (Panicum virgatum L.). The results suggested that the total IXF (parent + metabolites) showed higher mobility than ATR and its metabolites. Differences in the timing of transport reflected the rapid degradation of IXF to the more soluble, stable, and biologically active diketonitrile (DKN) metabolite in the system. Although grass treatments did not promote the hydrolysis of DKN, they significantly reduced its transport in the leachate through enhanced evapotranspiration. Grass treatments significantly enhanced ATR degradation in the leachates and soils, especially through N dealkylation, but they did not reduce total ATR transported in the leachate. Leachate from the orchardgrass lysimeters contained the highest proportion of ATR metabolites (64.2%). Timothy and smooth bromegrass treatments also displayed a significant increase in ATR metabolites in leachate. Grass-treated lysimeters showed higher microbial biomass carbon than bare ground. For ATR treatments, the proportion of metabolites in the leachate strongly correlated with the elevated soil microbial biomass carbon in forage treatments. In contrast, DKN degradation was poorly correlated with soil microbial biomass carbon, suggesting that DKN degradation is an abiotic process.  相似文献   

5.
A sequential sampling program using previously published zoobenthos data is described for ubiquitous, cost-effective biomonitoring of the effects of lake acidification. Spring densities of the littoral amphipodHyalella azteca are quantitatively sorted into five abundance catagories. An essential step in the a priori definition of decision criteria is the stratification of proportional densities per unit macrophyte biomass in relation to aqueous total phosphorus concentrations. Density rankings were related to lake acidity and to detailed lake-specific information on patterns ofHyalella life history and acid tolerance. Incorporation ofHyalella abundance as a potential metric for the assessment of the biological integrity of acid-sensitive waters is recommended. The temporal integration of transient changes in spring meltwater chemistry is an important rationale for the development of such biomonitoring procedures.  相似文献   

6.
Federal and many state agencies are required to perform environmental justice analyses of their policies prior to implementing them to prevent undue impacts on low income and minority populations. However, little academic attention has been paid to the quality of these ex-ante environmental justice analyses. This investigation evaluates the methods used to perform environmental justice analyses during siting and permitting processes. The study uses both the California Energy Commission guidelines for environmental justice analyses and a method that geographically maps air pollution to perform ex-ante environmental justice analyses of three power plants. The objective is to see if results from using these two analysis methods differ substantially. Findings indicate that the mapping technique employed represents a substantial improvement over defining the impacted population using proximity methods because it accounts for the geographical distribution of the hazard. Furthermore, using multiple comparison benchmarks to determine whether the impacted population constitutes an environmental justice population improves upon existing methods by accounting for the spatial distribution of minority and low income populations and for the possibility that there is a relatively high or relatively low percentage of low income and minority persons in both the impacted and comparison regions.  相似文献   

7.
Recent molecular modeling and spectroscopic studies have suggested that relatively strong interactions can occur between aromatic pi donors and metal cations in aqueous solutions. The objective of this study was to characterize potential cation-pi interactions between pi donors and exchangeable cations accumulated at mineral surfaces via both spectroscopic and batch sorption methods. Quadrupolar splitting in deuterium nuclear magnetic resonance ((2)H NMR) spectroscopy for d(2)-dichloromethane, d(6)-benzene, and d(8)-toluene (C(6)D(5)- moiety) in aqueous suspensions of a Na-saturated reference montmorillonite unambiguously indicated the ordering of solute molecules with respect to the clay surface. The half line broadening (Delta nu(1/2)) of (2)H NMR of d(6)-benzene in montmorillonite suspensions showed that soft exchangeable cations generally resulted in more benzene sorption compared with harder cations (e.g., Ag(+) > Cs(+) > Na(+) > Mg(2+), Ba(2+)). In batch sorption experiments, saturating minerals (e.g., porous silica gels, kaolinite, vermiculite, montmorillonite) with a soft transition metal or softer base cations generally increased the polycyclic aromatic hydrocarbon (PAH) sorption relative to harder cations (e.g., Ag(+) > Cs(+) > K(+) > Na(+); Ba(2+) > Mg(2+)). Sorption of phenanthrene to Ag(+)-saturated montmorillonite was much stronger compared with 1,2,4,5-tetrachlorobenzene, a coplanar non-pi donor having slightly higher hydrophobicity. In addition, a strong positive correlation was found between the cation-dependent sorption and surface charge density of the minerals (e.g., vermiculite, montmorillonite > silica gels, kaolinite). These results, coupled with the observations in (2)H NMR experiments with montmorillonite, strongly suggest that cation-pi bonding forms between PAHs and exchangeable cations at mineral surfaces and affects PAH sorption to hydrated mineral surfaces.  相似文献   

8.
In this paper we look behind the notion of sustainable transport and highlight the tensions and contradictions between the different ways of achieving this. The paper examines transportation plans for a major UK city and describes how these develop the idea and practice of sustainable transport and demand management along three quite distinct trajectories. By focusing on both the technological and the institutional dimensions of three different routes to sustainable transport, the analysis explicates the different ways in which the urban transport problem is framed, the different socio-technical logics of demand management embodied in the plans and the differing ways in which institutional relationships are (re)constituted. A key finding is that technological and institutional innovations are inversely related so that radical technological innovation often serves to reinforce existing social relations of power and exclusion. The conclusion drawn is that the choice is not just between a sustainable and an unsustainable transport future, but also between different forms of sustainability.  相似文献   

9.

In this paper we look behind the notion of sustainable transport and highlight the tensions and contradictions between the different ways of achieving this. The paper examines transportation plans for a major UK city and describes how these develop the idea and practice of sustainable transport and demand management along three quite distinct trajectories. By focusing on both the technological and the institutional dimensions of three different routes to sustainable transport, the analysis explicates the different ways in which the urban transport problem is framed, the different socio-technical logics of demand management embodied in the plans and the differing ways in which institutional relationships are (re)constituted. A key finding is that technological and institutional innovations are inversely related so that radical technological innovation often serves to reinforce existing social relations of power and exclusion. The conclusion drawn is that the choice is not just between a sustainable and an unsustainable transport future, but also between different forms of sustainability.  相似文献   

10.
11.
A solid-phase microbiological assay was used to determine the changes in genotoxicity associated with sequestration or biodegradation of carcinogenic compounds in contaminated soils. The concentration of six carcinogenic polycyclic aromatic hydrocarbons (PAHs) did not change in 59 d in sterile soil, but the genotoxicity declined markedly. In a soil undergoing bioremediation in the field for 147 d or biodegradation in the laboratory for 180 d, the concentrations either changed little or declined at different rates, but the genotoxicity increased followed by a decline. The genotoxicity of a second soil declined as a result of biological treatment. The data show that genotoxicity of contaminated soils may be unrelated to the concentration of carcinogenic PAHs because of aging or new mutagens formed during biological treatment.  相似文献   

12.
Phosphorus (P) loss in overland flow varies with spatial distribution of soil P, management, and hydrological pathways. The effect of flow time, flowpath length, and manure position on P loss in overland flow from two central Pennsylvania soils packed in boxes of varying length (0.5, 1.0, 1.5, 2.75, and 4.0 m long x 15 cm wide x 5 cm deep) were examined by collecting flow samples at 5-min intervals for 30 min (50 mm h(-1) rainfall) without and with 75 kg P ha(-1) applied as swine (Sus scrofa) manure over 0.5 m of the box slope length at distances of 0 to 3.5 m from the downslope collection point. Dissolved reactive P concentration was more closely related to the proportion of clay in sediment of overland flow before (r = 0.98) than after (r = 0.56) manure application. This was attributed to the transport of larger, low-density particles after applying manure. The concentration of dissolved and particulate P fractions decreased with increasing flowpath length, due to dilution rather than sorption of P by surface soil during overland flow. Total P loss (mainly as particulate P) from the Watson channery silt loam (fine-loamy, mixed, active, mesic Typic Fragiudult) was more than from Berks channery silt loam (loamy-skeletal, mixed, active, mesic Typic Dystrudept), even with manure applied. Thus, while P loss in overland flow is affected by where manure is applied relative to flowpath length, initial soil P concentration should not be discounted when looking at areas of potential P loss within a watershed.  相似文献   

13.
The type of contract model may have a significant influence on achieving project objectives, including environmental and climate change goals. This research investigates non-standard contract models impacting greenhouse gas emissions (GHG) in transport infrastructure construction in Australia. The research is based on the analysis of two case studies: an Early Contractor Involvement (ECI) contract and a Design and Construct (D&C) contract with GHG reduction requirements embedded in the contractor selection. Main findings support the use of ECIs for better integrating decisions made during the planning phase with the construction activities, and improve environmental outcomes while achieving financial and time savings.  相似文献   

14.
The dwindling global reserves of extractable phosphorus (P) and its growing demand to produce the required food for a burgeoning global population (the global P crisis) necessitate the sustainable use of this crucial resource. To advert the crisis requires informed policy decisions which can only be obtained by a better understanding of the nature and magnitude of P flow through different systems at different geographical scales. Through a systematic and in-depth review of twenty one recent substance flow analyses of P, we have assessed the key P inflows, outflows, stocks, internal flows, and recycling flows at the city, regional, and country scales. The assessment has revealed, the main inflow and outflow of P at the city scale occurs through food and wastewater respectively, while the main stock of P occurs in landfill. At the regional scale, mineral ore is the main P inflow and chemical P fertilizer is the main outflow particularly in the regions that have P fertilizer production sector. In contrast, either chemical P fertilizer or animal feed is the key inflow and either food and agricultural products or soil losses (erosion, runoff, and/or leaching) is the major outflow especially in the regions without P fertilizer production sector. At the country scale, the key P inflow occurs either through mineral ore or chemical P fertilizer and the key outflow takes place either as food and agricultural products, waste (both solid and liquid), or soil losses (erosion, runoff, and/or leaching). The main stock of P both at the regional and country scales occurs in the soil of the agricultural production sector. As identified in this assessment, the key unproductive outflows and stocks at different geographical scales indicate that there is a potential scope to improve P management through the increased P recovery and recycling, and by the utilization of available soil P stocks. In many of the studies at all the geographical scales, P recycling flow has been found to be less than 20% of the total inflow, and even in some studies at the country scale, P recycling has been found to be entirely absent, which is a clear indication of poor P management. This study has also identified, there is a clear knowledge gap in relation to understanding the P flow over multiple years at the regional scale. The information about the key flows and stocks at different geographical scales as we identified can be utilized to make better P policy and management decisions for a city, region, or country. The information can also be used to guide future research that aims to analyze P flow at the city, regional, and country scales.  相似文献   

15.
Phosphate treatments can reduce metal dissolution and transport from contaminated soils. However, diammonium phosphate (DAP) has not been extensively tested as a chemical immobilization treatment. This study was conducted to evaluate DAP as a chemical immobilization treatment and to investigate potential solids controlling metal solubility in DAP-amended soils. Soil contaminated with Cd, Pb, Zn, and As was collected from a former smelter site. The DAP treatments of 460, 920, and 2300 mg P kg-1 and an untreated check were evaluated using solute transport experiments. Increasing DAP decreased total metal transported. Application of 2300 mg P kg-1 was the most effective for immobilizing Cd, Pb, and Zn eluted from the contaminated soil. Metal elution curves fitted with a transport model showed that DAP treatment increased retardation (R) 2-fold for Cd, 6-fold for Zn, and 3.5-fold for Pb. Distribution coefficients (Kd) increased with P application from 4.0 to 9.0 L kg-1 for Cd, from 2.9 to 10.8 L kg-1 for Pb, and from 2.5 to 17.1 L kg-1 for Zn. Increased Kd values with additional DAP treatment indicated reduced partitioning of sorbed and/or precipitated metal released to mobile metal phases and a concomitant decrease in the concentration of mobile heavy metal species. Activity-ratio diagrams indicated that DAP decreased solution Cd, Pb, and Zn by forming metal-phosphate precipitates with low solubility products. These results suggest that DAP may have potential for protecting water resources from heavy metal contamination near smelting and mining sites.  相似文献   

16.
An issue in evaluating the success of agricultural management practices is the speed that eroded particles make their way through the downstream waters. In this study at Old Woman Creek (OWC) and Rock Creek (RC), two largely agricultural watersheds in Ohio, the flux of sediment and radionuclides (7Be, 210Pb, and 137Cs) in thunderstorm runoff was examined to better understand transport of eroded agricultural soils. The hydrograph in an agricultural area under no-till was similar in timing, but of lesser magnitude, than the hydrograph from a similar-sized area under conventional tillage. The activities of 210Pb and 7Be are linearly correlated and are higher in suspended sediments derived from no-till subbasins than those derived from conventionally tilled subbasins. A suspended sediment plume, identified by its unique radionuclide signature, was traced through 17 km of OWC stream channel in approximately 13.4 h (0.35 m/s). The downstream exponential decrease of 7Be activities in suspended sediments 3 to 12 h after passage of the sediment plume was used to estimate transport distances of suspended sediment from 2 to 17 km, respectively. Transport distances of suspended sediments were also calculated from wave kinematics and indicate that at OWC suspended sediment transport distances were longer in streams draining areas of no-till (19-26 km) than in the streams draining areas of conventional tillage (6-15 km). Suspended sediments travel 7 to 22 km at RC. The transport distances are long relative to the lengths of the stream channel and indicate that erosion control methods implemented in the watershed should be reflected quickly in downstream waters.  相似文献   

17.
Soybean production and its supply chain are highly dependent on inputs such as land, fertilizer, fuel, machines, pesticides and electricity. The expansion of this crop in Brazil in recent decades has generated concerns about its environmental impacts. To assess these impacts, two representative chains supplying soybeans to Europe were identified: Center West (CW) and Southern (SO) Brazil. Each supply chain was analyzed using Life Cycle Assessment methodology. We considered different levels of use of chemical and organic fertilizers, pesticides and machinery, different distances for transportation of inputs and different yield levels. Because transportation contributed strongly to environmental impacts, a detailed study was performed to identify the routes used to transport soybeans to seaports. Additionally, we considered different levels of land occupation and land transformation to represent the impact of deforestation in the CW region. Environmental impacts were calculated for 1000 kg of soybean up to and including the delivery to Europe at the seaport in Rotterdam, at 13% humidity. Overall results showed that the impacts are greater for CW than for SO for all impact categories studied, including acidification (7.7 and 5.3 kg SO2 eq., respectively), climate change (959 and 510 kg CO2 eq.), cumulative energy demand (12,634 and 6,999 MJ) and terrestrial ecotoxicity (4.9 and 3.1 kg 1,4-DCB eq.), except eutrophication and land occupation. The same trend was observed for the crop-production stage. Efforts to reduce chemical fertilizers and diesel consumption can reduce CO2 emissions. Although deforestation for crop production has decreased in recent years, the contribution of deforestation to climate change and cumulative energy demand remains significant. In the CW scenario deforestation contributed 29% to climate change and 20% to cumulative energy demand. Results also showed that although there are different transportation options in Brazil, the current predominance of road transport causes severe environmental impacts. In CW, road transport contributed 19% to climate change and 24% to cumulative energy demand, while in SO it contributed 12% and 15% to these impacts, respectively. Improvements in the logistics of transportation, giving priority to rail and river transports over road transport, can contribute significantly to reducing greenhouse gas emissions and decreasing energy use. Future studies involving Brazilian soybeans should take into account the region of origin as different levels of environmental impact are predicted.  相似文献   

18.
Organic pollutants are degraded in soil and simultaneously nonextractable residues are formed. However, proof is lacking that this fixation has a detoxifying effect. We investigated the transformation and binding of 2,4,6-trinitrotoluene (TNT) with catechol or soil humic acid as cosubstrates. Carbon-14-labeled TNT and its reaction products were quantified by radiocounting; extractable compounds were identified by high performance liquid chromatography (HPLC). Bound and extractable residues of 15N-labeled TNT and metabolites were studied by 15N nuclear magnetic resonance spectroscopy (15N NMR). Since TNT is not easily transformed under oxidizing conditions an anaerobic/aerobic treatment was used. Anaerobic microorganisms from cow manure were used to reduce TNT during the anaerobic phase and subsequently, a laccase from Trametes villosa was used in the aerobic phase to oxidatively couple the metabolites to humic matter. Seventy-four percent of TNT was immobilized with catechol as cosubstrate, but only 25% with humic acid. With catechol the main extractable component was TNT, while with humic acid it was mostly the metabolite 4-aminodinitrotoluene. For both co-substrates, the spectra of immobilized metabolites obtained by solid-state 15N-cross polarization magic angle spinning (CPMAS) NMR spectroscopy showed signals in the chemical shift region for protonated aromatic amino compounds. However, in the presence of catechol, an additional signal from nonextractable nitro groups was found, which could represent sequestered TNT. The partially reduced metabolites of TNT that formed nonextractable residues in humic acid are not likely to be remobilized easily and are thus regarded as detoxified.  相似文献   

19.
The diffusion of renewable energy – particularly in transport – in cities may facilitate the transition away from fossil fuels, improve air quality and reduce greenhouse gas emissions. Past studies on this topic have focused on system modelling of diffusion pathways, technology characteristics and also estimations of future availability of renewable energy, whilst neglecting the agency of producers and users. This article assesses barriers to the diffusion of biogas for transportation in cities from a system and actor perspective. Using document studies and interviews in the cities of Basel, Switzerland, and Odense, Denmark, we identify the presence of conflicting political priorities and shifting strategic objectives, resulting in mixed signals concerning the role and viability of biogas for transportation. This underlines the importance of public sector support and coherent design and implementation of strategy and policy enabling the diffusion of renewable energy.  相似文献   

20.
Continued public support for U.S. taxpayer funded programs aimed at reducing agricultural pollutants depends on clear demonstrations of water quality improvements. The objective of this research was to determine if implementation of agricultural best management practices (BMPs) in the Goodwater Creek Experimental Watershed (GCEW) resulted in changes to atrazine and nitrate (NO3–N) loads during storm events. An additional objective was to estimate future monitoring periods necessary to detect a 5, 10, 20, and 25% reduction in atrazine and NO3–N event load. The GCEW is a 73 km2 watershed located in northcentral Missouri, USA. Linear regressions and Akaike Information Criteria were used to determine if reductions in atrazine and NO3–N event loads occurred as BMPs were implemented. No effects due to any BMP type were indicated for the period of record. Further investigation of event sampling from the long-term GCEW monitoring program indicated errors in atrazine load calculations may be possible due to pre-existing minimum threshold levels used to trigger autosampling and sample compositing. Variation of event loads was better explained by linear regressions for NO3–N than for atrazine. Decommissioning of upstream monitoring stations during the study period represented a missed opportunity to further explain variation of event loads at the watershed outlet. Atrazine requires approximately twice the monitoring period relative to NO3–N to detect future reductions in event load. Appropriate matching of pollutant transport mechanisms with autosampling protocols remains a critical information need when setting up or adapting watershed monitoring networks aimed at detecting watershed-scale BMP effects.  相似文献   

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