Das integrale Reflexionsvermögen von gebogenen Quarzkristallen für Röntgenstrahlen im Transmissionsfall

A calculation procedure is described which permits evaluation of the material functions (electrical conductivityσ and radiation densityu as a function of the heat flux potentialS)from the measured arc characteristicsE(I) andU(I) (field strength and radiated power per unit arc length as a function of current strength). Hereto must be employed the additional relationship of energy balance and the current transport equation. The procedure is applied to N₂ and Ar. If furthermore the radial temperature distribution is known the temperature dependence ofσ, u.S andκ (thermal conductivity) may also be determined. In this way the material functions of the N₂-plasma are evaluated from available measurements.     

Model basis states for photons and "empty waves"

From the perspective of physical realism (PR), a photon is a localized entity that carries energy and momentum, and which is surrounded by a wave packet (anempty wave) that is devoid of observable energy or momentum. In creating quantized PR basis states for a photon wave packet, three requirements must be met:(1) The basis states must each carry the frequency of the wave;(2) They must closely resemble the photon, so that e.g. they scatter in the same manner from an optical mirror;(3) They must have infinitesimal energy, linear momentum, and angular momentum. An essentially zero-energy "empty wave" quantum-a "zeron"-is defined which meets these requirements. It is created as an asymmetric single-particle (or single-antiparticle) excitation of the vacuum state, with the "particle" (or "antiparticle") and its associated "hole" (or "antihole") forming a rotational bound state. The photon is reproduced as a symmetric particle-antiparticle excitation of the vacuum state, with the "particle" and "antiparticle" also forming a rotational bound state. The relativistic transformation problem is discussed. A key point in this development is the deduction of the correct equation of motion for a "hole" state in an external electrostatic field.     

State equation of condensed matter at high pressure: <Emphasis Type="Italic">D-U</Emphasis> diagram approach

For solids and liquids, an equation of state is suggested at high pressures up to a few megabars, for densities greater than that at normal conditions and for temperatures up to the melting point. Shock wave loading test data are analyzed for 40 basic chemical elements, and they prove the state equation suggested, within the limits of test error. The method is based on the analysis of D-U diagrams where D is the shock wave velocity and U is the material velocity behind the shock wave (both with respect to the material in front of the shock wave). Based on the state equation suggested the velocity of shock wave is shown to be a linear function of the material velocity behind the shock wave, the function being a specific characteristic of the material and its structure. Most significant anomaly belonging to carbon, iron, ice, and water is explained by the formation of new phases at high pressure, with two new phases of iron, and one phase in the case of water. For water, a simple nearly exact equation of state is suggested for pressures from 0.1 MPa to 150 GPa. For pressures from 0.1 to 300 MPa, it fits very well the extremely complicated state equation of the American standard obtained by static tests, and for pressures from 2 to 50 GPa it fits well the data of shock wave tests. In the pressure range from 45 to 1500 GPa liquid water becomes solid, which equation of state coincides with that of alkaline metal sodium. The model of ideal solid as contrary to ideal gas is introduced, with internal energy of ideal solid depending only on stresses or strains (and only on pressure or density, at high pressures). The equations of state for iron, diamond, pyrolithic graphite, and for several phases of ice are as well derived based on test data.     

High-current electron gun with a field-emission cathode and diamond grid

Control grids used in high-current devices with field emission cathodes should be made of an appropriate, “grid-grade” material. Such a material must offer a high mechanical strength, thermal conductivity, and electric conductivity. In addition, grids as thin as several microns must be available. As a grid material, boron-doped diamond is tested.     

"Snowflake" H mode in a tokamak plasma

An edge-localized mode (ELM) H-mode regime, supported by electron cyclotron heating, has been successfully established in a "snowflake" (second-order null) divertor configuration for the first time in the TCV tokamak. This regime exhibits 2 to 3 times lower ELM frequency and 20%-30% increased normalized ELM energy (ΔWELM/Wp) compared to an identically shaped, conventional single-null diverted H mode. Enhanced stability of mid- to high-toroidal-mode-number ideal modes is consistent with the different snowflake ELM phenomenology. The capability of the snowflake to redistribute the edge power on the additional strike points has been confirmed experimentally.     

Exactly solvable toy model that mimics the mode coupling theory of supercooled liquid and glass transition

A toy model is proposed which incorporates the reversible mode coupling mechanism responsible for ergodic-nonergodic transition of the mode coupling theory (MCT) of structural glass transition with trivial Hamiltonian. The model can be analyzed without relying on uncontrolled approximations inevitable in the current MCT. The strength of hopping processes can be easily tuned and the ideal glass transition is reproduced only in a certain range of the strength. On the basis of the analyses of our model, we discuss about a sharp ergodic-nonergodic transition and its smearing out by "hopping."     

Resonant "forbidden" reflections in magnetite

Resonant x-ray scattering was used to investigate electronic fluctuations of the octahedral iron atoms in magnetite. We measured the (002) and (006) "forbidden" x-ray diffraction reflections permitted by the anisotropy of the iron anomalous scattering factor. The energy and azimuthal angle dependencies of these reflections, and the polarization analysis, are shown and discussed. The results clearly show p and d iron empty states ordering in magnetite at room temperature. Moreover, the octahedral iron atoms are electronically equivalent in a time scale lower than 10(-16) sec. Therefore, magnetite should be considered as an itinerant magnet and not as a fluctuating mixed valence material.     

Thermal and electrical conductivity of poly(l-lactide)/multiwalled carbon nanotube nanocomposites

Multiwalled carbon nanotubes (MWCNTs) are considered to be the ideal reinforcing agent for high-strength polymer composites, because of their fantastic mechanical strength, high electrical and thermal conductivity and high aspect ratio. Polymer/MWCNTs composites are easily molded, and the resulting shaped plastic articles have a perfect surface appearance compared with polymer composites made using usual carbon or glass fibers. Good interfacial adhesion between the MWCNTs and the polymer matrix is essential for efficient load transfer in the composite. The ultrahigh strength polymer composites demand the uniform dispersion of the MWCNTs in the polymer matrix without their aggregation and the good miscibility between MWCNT and polymer matrix. This approach can also be applied to biodegradable synthetic aliphatic polyesters such as poly(l-lactide) (PLLA), which has received a great deal of attention due to environmental concerns. In this study, PLLA was melt-compounded with MWCNTs. A high degree of dispersion of the MWCNTs in the composites was obtained by grafting PLLA onto the MWCNTs (PLLA-g-MWCNTs). After oxidizing the MWCNTs by treating them with strong acids, they were reacted with l-lactide to produce the PLLA-g-MWCNTs. The mechanical properties of the PLLA/PLLA-g-MWCNT composite were higher than those of the PLLA/MWCNT composite. The electrical conductivity of the composites was determined by measuring the volume resistivity, which is a value of the resistance expressed in a unit volume by two-probe method. The thermal diffusivity and heat capacity of composites was measured by laser flash method, and the effects of modification of the MWCNT in PLLA matrix are discussed.     

Accessing the optical nonlinearity of metals with metal- dielectric photonic bandgap structures

Metals typically have very large nonlinear susceptibilities (~10(6) times larger than those of typical dielectrics), but because they are nearly opaque their nonlinear properties are effectively inaccessible. We demonstrate numerically that a multilayer metal-dielectric structure in which the metal is the dominant nonlinear [chi((3))] material can have much larger intensity-dependent changes in the complex amplitude of the transmitted beam than a bulk sample containing the same thickness of metal. For 80 nm of copper the magnitude of the nonlinear phase shift is predicted to be as much as 40 times larger for the layered copper-silica sample, and the transmission is also greatly increased. The effective nonlinear refractive-index coefficient n(2) of this composite material can be as large as (3+6iota)x10(-9) cm (2)/W , which is among the largest values for known, reasonably transmissive materials.     

"Work-Hardenable" ductile bulk metallic glass

Usually, monolithic bulk metallic glasses undergo inhomogeneous plastic deformation and exhibit poor ductility (< 1%) at room temperature. We present a new class of bulk metallic glass, which exhibits high strength of up to 2265 MPa together with extensive "work hardening" and large ductility of 18%. Significant increase in the flow stress was observed during deformation. The "work-hardening" capability and ductility of this class of metallic glass is attributed to a unique structure correlated with atomic-scale inhomogeneity, leading to an inherent capability of extensive shear band formation, interactions, and multiplication of shear bands.     

“Hopf/homoclinic”簇放电和“SubHopf/homoclinic"簇放电之间的同步

以修正过的Morris-Lecar神经元模型为例,讨论了“Hopf/homoclinic”簇放电和“SubHopf/homoclinic"簇放电之间的同步行为.首先,分别考察了同一拓扑类型的两个耦合簇放电神经元的同步行为,发现“Hopf/homoclinic”簇放电比“SubHopf/homoclinic”簇放电达到膜电位完全同步所需要的耦合强度小,即前者比后者更容易达到膜电位完全同步.其次,对这两个不同拓扑类型的簇放电神经元的耦合同步行为进行了讨论.通过数值分析发现随着耦合强度的增加,两种不同类型的簇放电首先达到簇放电同步,然后当耦合强度足够大时甚至可以达到膜电位完全同步,并且同步后的放电类型更接近容易同步的簇放电类型,即“Hopf/homoclinic”簇放电.然而令人奇怪的是此时慢变量并没有达到完全同步,而是相位同步;慢变量之间呈现为一种线性关系.这一点和现有文献的结果截然不同.     

Influence of microporosity on the strength properties of SiC ceramic materials

A series of silicon carbide ceramic samples with variable characteristics of the microporosity and strength, such as the ballistic strength σ _B and the static strength σ _S , are investigated. The dependences of the strength on the integral porosity for ceramic materials are determined. It is established that the strength (both σ _B and σ _S ) is directly proportional to the average length of the bridges between micropores. The mechanism of the influence of microporosity on the strength of the ceramic materials is elucidated. According to this mechanism, interpore bridges are concentrators of stresses and, hence, are broken when a load is applied to the ceramic material. Numerous breakings of bridges bring about the failure of the ceramic body. The average stress concentration coefficient is estimated as a function of the integral porosity of the ceramic material. It is demonstrated that the static strength of the ceramic material is determined by the presence of large micropores (50–100 μm).     

Fast chain contraction during protein folding: "foldability" and collapse dynamics

Theory indicates that at least some proteins will undergo a rapid and unimpeded collapse, like a disorganized hydrophobic chain, prior to folding. Yet experiments continue to find signs of an organized, or barrier-limited, collapse in even the fastest (approximately mus) folding proteins. Does the kinetic barrier represent a signature of the equilibrium "foldability" of these molecules? We have measured the rate of chain contraction in two nonfolding analogs of a very fast-collapsing protein. We find that these chains contract on the same time scale (approximately 10(-5)s) as the natural protein, and both pass over an energetic barrier at least as large as that encountered by the protein. The equilibrium foldability of the native structure therefore does not alone determine the dynamics of collapse; even the disordered chains contract approximately 1000x slower than expected for an ideal chain.     

Mechanisms of visible electroluminescence in diode structures on the basis of porous silicon: A review

The main mechanisms of the visible electroluminescence (EL) of porous silicon are reviewed. Characteristics of photoluminescence and EL of diode structures based on porous silicon are compared. Metals having a smaller value of the electron work function (3.6 eV, Mg) than do Al and Au are proposed as the material for making contacts in such diode structures to increase the efficiency of their EL in the visible region of the spectrum. The main problems and prospects of light-emitting devices based on porous silicon are formulated.     

Enhanced suppression of residual water in a "270" WET sequence

In certain water suppression experiments, the residual water, which comes from a region away from the center of the RF coil and experiences a much smaller flip angle than the designed one, may appear. The residual water in the WET sequence can be reduced significantly by using a composite 90(x)( degrees )90(y)( degrees )90(-x)( degrees )90(-y)( degrees ) pulse, which de-excites molecules experiencing a small flip angle. The composite pulse, however, has two null excitation points near on resonance, causing a severe loss of spectrum intensity and baseline distortion toward the null points. Since the residual water experiences a very small flip angle, it can be treated as a linear spin system; i.e., the intensity of the residual water is proportional to the pulse strength and width. Based on this principle, the residual water can be reduced dramatically by replacing the 90 degrees pulse in the "270" WET sequence with a 270 degrees pulse for one out of every four scans, without noticeable loss of intensity and baseline distortion.     

Validity diagrams of statistical energy analysis

This paper is concerned with the validity domain of statistical energy analysis (SEA) which is defined in terms of four criteria. The mode count N and the modal overlap M must be high, the normalized attenuation factor and the coupling strength γ must be small. The application of dimensional analysis on the governing equations of plates gives the space of dimensionless parameters in which the validity domain of SEA must be delimited. This domain is discussed on the basis of geometry of the surfaces delimiting it. The diagrams of validity of SEA are introduced and discussed. A numerical simulation on a couple of rectangular plates coupled along one edge illustrates the theoretical approach.     

Process optimization of ultrasound-assisted curcumin nanoemulsions stabilized by OSA-modified starch

This study reports on the process optimization of ultrasound-assisted, food-grade oil–water nanoemulsions stabilized by modified starches. In this work, effects of major emulsification process variables including applied power in terms of power density and sonication time, and formulation parameters, that is, surfactant type and concentration, bioactive concentration and dispersed-phase volume fraction were investigated on the mean droplet diameter, polydispersity index and charge on the emulsion droplets. Emulsifying properties of octenyl succinic anhydride modified starches, that is, Purity Gum 2000, Hi-Cap 100 and Purity Gum Ultra, and the size stability of corresponding emulsion droplets during the 1 month storage period were also investigated. Results revealed that the smallest and more stable nanoemulsion droplets were obtained when coarse emulsions treated at 40% of applied power (power density: 1.36 W/mL) for 7 min, stabilized by 1.5% (w/v) Purity Gum Ultra. Optimum volume fraction of oil (medium chain triglycerides) and the concentration of bioactive compound (curcumin) dispersed were 0.05 and 6 mg/mL oil, respectively. These results indicated that the ultrasound-assisted emulsification could be successfully used for the preparation of starch-stabilized nanoemulsions at lower temperatures (40–45 °C) and reduced energy consumption.     

Novel methods for characterizing a decoupler channel using "undetectable" quantum coherences.

Exact solutions for the effect of time-independent RF pulses on any initial configuration of an IS J-coupled system demonstrate that on-resonance CW decoupling yields signals whose frequency depends on RF field strength and homogeneity. These signals are enhanced starting with "undetectable" antiphase and multiple quantum coherences, which can also produce centerband intensity to mimic the signal from decoupled Sx. Conversely, these coherences can be generated from Sx using a low-power pulse, B1 = J/2, of length (2J)-1, dubbed a "90J pulse" since it is the selective equivalent of {(2J)-1-90[I]}. Utilizing 90J pulses, new characterization-of-decoupler (COD) pulse sequences can determine the performance of an insensitive I-spin channel by observing large signals from either antiphase or multiple quantum coherences with the S-spin channel, allowing, in minutes rather than hours: (i) frequency calibration to an accuracy of 0.1 Hz; (ii) measurement of RF amplitudes over a 500-fold variation; and (iii) mapping of RF homogeneity along the sample axis with a single 1D B1 spectrum. These 90J coherence transfer pulses are of potential general use for selective spectroscopy.     

外表面应力自由的充液有限壁厚井孔中的声场及其频散曲线的“平台”特征

为了开发一种新型标准刻度井,对外表面应力自由的充液有限壁厚井孔中的声场进行了更加深入的研究,计算分析了这种圆柱形封闭声波导结构中的声场和多阶对称模式波的频散特性。结果表明:充液有限壁厚井孔中高阶对称模式波的相速度频散曲线在一定频率范围内出现“平台”现象;当声源激发主频大于5 kHz且慢度时间相关法(STC)的窗长取4到5个周期时,得到全波波形中的“首波”速度与高阶模式波相速度频散曲线上的“平台”区域速度接近,该“平台”区域的速度与有限壁厚管材的纵波速度相差百分比随管材泊松比增加呈指数型上升;通过选择合适的管材材料以及改变其几何尺寸,可在一定频率范围内控制对称模式波相速度频散曲线的“平台”宽度、位置及平稳度。这一研究可为建立行业标准的声速刻度井提供新思路。      

Influence of indenter tip geometry on elastic deformation during nanoindentation

Nanoindentation with a Berkovich indenter is commonly used to investigate the mechanical behavior of small volumes of materials. To date, most investigators have made the simplifying assumption that the tip is spherical. In reality, indenter tips are much more complex. Here, we develop a new method to describe the tip shape using the experimentally determined area function of the indenter at small depths (0-100 nm). Our analysis accurately predicts the elastic load-displacement curve and allows the theoretical strength of a material to be determined from pop-in data. Application of our new method to single crystal Cr3Si shows that the predicted theoretical strengths are within 12% of the ideal strength G/2pi, where G is the shear modulus.