The contaminant removal efficiency of an air cleaner using the adsorption/desorption effect

The adsorption and desorption of volatile organic compounds (VOCs) in relation to material surfaces were conducted to control indoor air quality. The VOC removal performance of building materials using sorption effects was validated in cases related to poor indoor air quality that occurred during non-ventilation periods during intermittent-ventilation situations. The objective of this investigation is to present the contaminant removal efficiency and practicality of a prototype air cleaner which uses sorption effects. Toluene and formaldehyde were used as pollutant sources and were continuously emitted into the test chamber. Effects due to the number of sorption units, operation time and mode of contaminant removal performance were examined. The sorption materials evaluated in this investigation were a porous material, zeolite, pumice stone and hydro-corn. As a result of the experiments, zeolite exhibited relatively high contaminant removal efficiency with toluene, and zeolite and the porous material exhibited high removal efficiency with formaldehyde for both one-cycle and two-cycle sorption modes. Moreover, significant removal performances were observed in the numerical analysis of the continuous-operation mode.     

Influence of the redox condition dynamics on the removal efficiency of a laboratory-scale constructed wetland

A laboratory reactor planted with Juncus effusus treating an artificial wastewater was used to investigate the short-term and long-term variations and interactions in the redox conditions as well as the removal efficiency of C and the N turnover. The permanent circulation of the process water enabled the micro-gradient processes to be evaluated for an operating period of 20 months. Steady-state conditions were achieved throughout the operating period with high mean removal efficiencies of 92.7% total organic carbon, 82.0% ammonia and 97.6% nitrate. Daily variations in the redox state of the rhizosphere of a few hundred mV were observed, ranging from about -200 to oxidized conditions of about +200 mV and driven by daylight. Variations in pH associated with changes in light and redox were linked to the dynamics of the fates of organic and inorganic carbon species. The ammonia removal processes were found to be firmly established, including for moderately reduced redox conditions with high efficiencies for E(h)>-50 mV. The enrichment of ammonia (up to 13 mg l(-1)) closely linked to the light, particularly during summertime, indicates the existence of hitherto unconsidered additional N turnover pathways in the rhizoplane involving N(2) produced by microbes or released by plants. C turnover was strongly related to the seasonal variation in illumination with minimum efficiencies during the dark season. In addition, it was characterized by oscillation with periods of approximately 1 month. The relationships found are dominant for biofilms on the rhizoplane and decisive for the removal efficiency of especially simple constructed and natural wetlands. The results highlight the importance of helophytes and their physiological specifics for removal processes.     

铁砷复合污染下铁砷比对除砷效果的影响研究

针对铁砷复合污染型地下水,以原水铁砷比作为控制参数,通过烧杯试验研究了曝气接触氧化除铁工艺的除砷效果。结果表明,当初始砷含量分别为100,200,300和400μg/L时,原水铁砷比分别为35∶1,50∶1,52∶1和55∶1,能达到除铁效果且同时满足出水砷含量小于10μg/L的限值要求;根据氢氧化铁对砷的吸附机理,利用Freundlich吸附等温式建立了铁砷比与残余砷含量的数学模型,试验数据拟合结果与模型相吻合。此外,采用曝气氧化工艺处理铁砷复合污染地下水时,可以通过投加二价铁盐控制原水铁砷比,以实现同时去除铁砷的目的。     

Influence of operational parameters on nitrogen removal efficiency and microbial communities in a full-scale activated sludge process

To improve the efficiency of total nitrogen (TN) removal, solid retention time (SRT) and internal recycling ratio controls were selected as operating parameters in a full-scale activated sludge process treating high strength industrial wastewater. Increased biomass concentration via SRT control enhanced TN removal. Also, decreasing the internal recycling ratio restored the nitrification process, which had been inhibited by phenol shock loading. Therefore, physiological alteration of the bacterial populations by application of specific operational strategies may stabilize the activated sludge process. Additionally, two dominant ammonia oxidizing bacteria (AOB) populations, Nitrosomonas europaea and Nitrosomonas nitrosa, were observed in all samples with no change in the community composition of AOB. In a nitrification tank, it was observed that the Nitrobacter populations consistently exceeded those of the Nitrospira within the nitrite oxidizing bacteria (NOB) community. Through using quantitative real-time PCR (qPCR), nirS, the nitrite reducing functional gene, was observed to predominate in the activated sludge of an anoxic tank, whereas there was the least amount of the narG gene, the nitrate reducing functional gene.     

Influence of movements on contaminant transport in an operating room

The influence of persons' movements on contaminant transport during an orthopedic surgical operation is examined. Orthopedic surgical operations require an ultra clean environment usually provided by a LAF device (laminar airflow). During hip replacements bone cement is sometimes applied. Due to practical reasons cement mixing is performed outside the LAF area. During the cement transport from the mixing location to the surgeon there is a potential risk of bacterial transport to the clean zone. This phenomenon is examined by smoke visualization and computational fluid dynamics (CFD). The movements are modeled by CFD using distributed momentum sources as well as a turbulent kinetic energy source. A significant risk of contaminant transport from the less clean zone to the ultra clean zone is found. The results indicate that it is possible to simulate the influence of movements using a relatively simple CFD model that considers the significant influence of a transient phenomenon in an approximate way. PRACTICAL IMPLICATIONS: In real-life ventilated enclosures like operating rooms movements take place. Persons' movements may influence the local flow field as well as the contaminant field substantially. Most often movements are ignored in simulations due to the complexity of the phenomenon. This paper presents an indirect and simple method to consider the influence of movements that may enable modelers to include this important phenomenon in the engineering application of CFD. This may improve practical risk assessment--for instance risk assessment of unintended transport of bacteria during orthopedic surgical operations that may jeopardize the hygiene.     

Pollution removal effectiveness of the pedestrian ventilation system

Dispersion of vehicular pollution through street canyons has been widely studied in order to find strategies for reducing concentration level. Recently, a pedestrian ventilation system (PVS), an active mitigation strategy, has been proposed to enhance pedestrian comfort indices and to induce appropriate air movement. This paper investigates the performance of PVS to control pollution dispersion within street canyons. Pollution control is achieved by exhausting/supplying air from/to the street canyon through the PVS. In the present paper, the effectiveness of these strategies was studied by varying the parameters that affect dispersion, such as aspect ratios (AR) and thermal stratifications.Computational Fluid Dynamics (CFD) has been selected as the investigation tool. Prior to simulations, the proposed model was successfully validated using two sets of experimental data. Four case-studies were also used to investigate the aspect ratio and the stratification effect. These test cases were developed based on small scale studies in a wind tunnel. Results show the ability of the PVS to change the airflow pattern through the street canyon, resulting in significant pollution removal, especially from the pedestrian level. Moreover, the air and pollution exchange rate concepts have been used for better evaluation of the PVS performance. Furthermore, a breakthrough index was proposed to evaluate the effect of the PVS airflow rate.     

Evaluating emergency ventilation strategies under different contaminant source locations and evacuation modes by efficiency factor of contaminant source (EFCS)

Emergency ventilation plays an important role in protecting occupants when a hazardous contaminant is released indoors. A number of studies have been conducted to better understand how to protect indoor occupants with effective ventilation strategies. However, little attention has been paid to the impact of the non-uniform and time-dependent distribution of occupants during evacuation. A new concept, Efficiency Factor of Contaminant Source (EFCS), has recently been proposed to evaluate the performance of emergency ventilation by comprehensively considering the spatial and temporal distributions of both the contaminant and occupants. This paper aims to: (1) propose and demonstrate a procedure for determining an optimal ventilation strategy by using EFCS; (2) examine the effects of source locations, ventilation modes, and evacuation modes on the performance of emergency ventilation. One hundred cases with ten ventilation modes, two evacuation modes, and five source locations were investigated numerically. The results show that the EFCS concept can provide a reasonable way to evaluate the performance of emergency ventilation. The threats of different source locations may vary over a large range, and certain measures should be taken to monitor and prevent the releases at high threat locations. A system equipped with multiple ventilation modes is necessary since no universal ventilation mode can successfully mitigate all hazardous situations. The effects of an evacuation mode may be more significant than that of a ventilation mode under certain situations.     

奥贝尔氧化沟总磷去除效果浅析

以某污水处理厂的污水处理为例,研究了生物除磷原理,针对该污水处理厂出水总磷去除率较差的现象,对流程各阶段溶氧数值进行了相应的实验分析,从而探索提高奥贝尔氧化沟处理工艺除磷效率的途径。     

Influence of operating parameters on the arsenic removal by nanofiltration

Arsenic contamination of surface and groundwater is a worldwide problem in a large number of Countries (Bangladesh, Argentina, Italy, USA, New Zealand, etc.). In many contaminated areas a continuous investigation of the available arsenic removal technologies is essential to develop economical and effective methods for removing arsenic in order to meet the new Maximum Contaminant Level (MCL) standard (10 μg/l) recommended by the World Health Organization (WHO).In this work the removal of pentavalent arsenic from synthetic water was studied on laboratory scale by using two commercial nanofiltration (NF) spiral-wound membrane modules (N30F by Microdyn-Nadir and NF90 by Dow Chemical). The influence of main operating parameters such as feed concentration, pH, pressure and temperature on the As rejection and permeate flux of both membranes, was investigated. An increase of pH and a decrease of operating temperature and As feed concentration led to higher As removal for both membranes, whereas higher transmembrane pressure (TMP) values slightly reduced the removal achievable with the N30F membrane. In both cases, the permeate flux increased with temperature and pressure and reached its maximum value at a pH of around 8.Among the parameters affecting the As rejection, feed concentration plays a key role for the production of a permeate stream respecting the limits imposed by WHO.     

Influence of river discharge patterns on the hydrodynamics and potential contaminant dispersion in the Douro estuary (Portugal)

Freshwater input to estuaries is a fundamental feature of these ecosystems, which may be profoundly altered by river damming as human needs for water consumption, irrigation or energy production increase. The Douro estuary is limited upstream by a dam since 1985, which reduced its length by ca. 60%. Freshwater inputs to the estuary are now irregular and greatly dependent on hydroelectric power demand; values ranging from zero to over 1000 m³ s⁻¹, in a matter of hours, especially in summer are common. In the present study, a three-dimensional hydrodynamic model was applied to the Douro estuary. The model was calibrated and validated against water elevation, current velocity, salinity and temperature data. Thereafter, it was used to analyse the effects of different flow regimes and magnitudes on estuarine hydrodynamics and contaminant dispersion. Results obtained suggest that the highly variable flow regimes, currently observed in the Douro, tend to reduce water column stratification and to enhance seawater intrusion, when compared with flow discharges of similar average magnitude, but lower variability. Stable flows seem to be the most effective in dispersing contaminants eventually introduced into the estuary through its small river tributaries. Overall results suggest that flow management may have important effects on estuarine hydrodynamics through non-linear interactions between flow magnitude and variability.     

强化污水除磷效果的措施探讨

结合某城镇污水处理厂的工程概况,介绍了其污水处理工艺流程,并提出了改善氧化沟内溶解氧浓度、科学选配除磷剂、提高药剂混合强度等除磷措施,既达到了污水处理标准,又降低了药剂费用。     

初雨处理站对污染物的去除效率研究

介绍了高效沉淀池+深层床纤维束滤池结合的初期雨水处理工艺,并通过实验,分析了初雨处理站对主要污染物COD_(Cr),BOD_5,TP,NH_3-N的去除效果,结果表明,其处理效能稳定,出水水质能够达到GB 18918—2002城镇污水处理厂污染物排放标准的一级B排放标准。     

Social housing management: Concerns about effectiveness and efficiency in the Netherlands

Recently a discussion flared up in the Netherlands on the effectivenessand efficiency of providers of social housing. Though most people feel that Dutch housing associations are run effectively, there are no data to underpin this conclusion. The government is not clear about the criteria for each housing association: most of the criteria are unquantified and, to some extent, contradictory. Nor is it clear whether every individual housing association has to meet these criteriato the same extent. Many more doubts have been raised about the efficiencyof social housing providers, as housing associations do not act as if theywant to maximize profits.Several suggestions have been put forward to improve efficiency: periodicalexternal visitations, benchmarking, the introduction of a Real Estate Index,and outsourcing a substantial part of the management and development activities. The main conclusion so far is that we are under-informed aboutthe efficiency of housing associations. Some advisory bodies argue that theoverall efficiency of housing associations would improve if they were transferred from the semi-public to the private sector. They claim that thedemand side of the housing market could be strengthened by the introductionof housing vouchers and suggest that housing associations opt out of the public sector.These options fail to take account of the fact that we are insufficiently informed about the efficiency of commercial players on the housing market and the inherent shortcomings of free housing markets when it comes to accessibility, affordability and quality for low-income households, externaleffects and the cherry-picking of tenants by commercial landlords. Hence, weconclude that until more information is available on the true effectivenessand efficiency of housing associations, there are good reasons to continue their current hybrid status, which combines public tasks and market activities.     

Influence of electrostatic interactions on the rejection with NF and assessment of the removal efficiency during NF/GAC treatment of pharmaceutically active compounds in surface water

The removal efficiency of several pharmaceutically active compounds from two different surface water types was investigated. Two different nanofiltration (NF) membranes (Trisep TS-80 and Desal HL) were first studied at low feed water recoveries (10%). In a second phase, the combination of an NF unit at higher feed water recovery (80%) with subsequent granular activated carbon (GAC) filtration of the permeate was investigated. Results indicate that removal of the selected pharmaceuticals with NF is mainly influenced by charge effects: negatively charged solutes are better removed, compared with uncharged solutes, which are, in turn, better removed compared with positively charged solutes. This latter trend is mainly due to charge attractions between the negatively charged membrane surface and positively charged solutes. Increasing feed concentrations of positively charged pharmaceuticals lead to increasing rejection values, due to membrane charge-shielding effects. The removal efficiency of pharmaceuticals with the combination NF/GAC is extremely high. This is mainly due to an increased adsorption capacity of the activated carbon since the largest part of the natural organic matter (NOM) is removed in the NF step. This NOM normally competes with pharmaceuticals for adsorption sites on the carbon.     

雾状水滴喷射位置对灭火效能的影响分析

针对消防灭火过程中雾状水滴喷射位置对灭火效率的影响问题,基于火灾动力学理论,分析灭火过程中的传热传质过程,构建了消防人员灭火过程的模拟环境和仿真模型,根据人员灭火过程中可能采取的灭火动作,运用火灾动力学软件对15种典型行为状态下灭火过程进行数值仿真,绘制针对具体火源的灭火动作与灭火效率关系图谱,并结合消防人员实际灭火训练数据分析水枪位置、入射角度、入射高度以及火源位置等因素耦合作用对灭火效率的影响,给出验证消防人员灭火行为和灭火战术有效性的仿真计算方法.     

Ventilation effectiveness measures based on heat removal: Part 1. Definitions

The effectiveness of ventilation flows is considered from the perspective of buoyancy (or heat) removal from a space. This perspective is distinct from the standard in which the effectiveness is based on the concentrations of a neutrally buoyant contaminant/passive tracer. Three new measures of effectiveness are proposed based on the ability of a flow to flush buoyancy from a ventilated space. These measures provide estimates of instantaneous and time-averaged effectiveness for the entire space, and local effectiveness at any height of interest. From a generalisation of the latter, a vertical profile of effectiveness is defined. These measures enable quantitative comparisons to be made between different flows and they are applicable when there is a difference in density (as is typical due to temperature differences) between the interior environment and the replacement air. Applications, therefore, include natural ventilation, hybrid ventilation and a range of forced ventilation flows. Finally, we demonstrate how the ventilation effectiveness of a room may be assessed from simple traces of temperature versus time.     

Fine and ultrafine particle removal efficiency of new residential HVAC filters

Particle air filters used in central residential forced‐air systems are most commonly evaluated for their size‐resolved removal efficiency for particles 0.3‐10 µm using laboratory tests. Little information exists on the removal efficiency of commercially available residential filters for particles smaller than 0.3 µm or for integral measures of mass‐based aerosol concentrations (eg, PM_2.5) or total number concentrations (eg, ultrafine particles, or UFPs) that are commonly used in regulatory monitoring and building measurements. Here, we measure the size‐resolved removal efficiency of 50 new commercially available residential HVAC filters installed in a recirculating central air‐handling unit in an unoccupied apartment unit using alternating upstream/downstream measurements with incense and NaCl as particle sources. Size‐resolved removal efficiencies are then used to estimate integral measures of PM_2.5 and total UFP removal efficiency for the filters assuming they are challenged by 201 residential indoor particle size distributions (PSDs) gathered from the literature. Total UFP and PM_2.5 removal efficiencies generally increased with manufacturer‐reported filter ratings and with filter thickness, albeit with numerous exceptions. PM_2.5 removal efficiencies were more influenced by the assumption for indoor PSD than total UFP removal efficiencies. Filters with the same ratings but from different manufacturers often had different removal efficiencies for PM_2.5 and total UFPs.     

电解质溶液对电化学除氯效果的影响

电解质溶液是电化学除盐过程中必备的物质条件之一,着重研究不同电解质对电化学除盐效果的影响。试验结果表明:在0.1mol/LNa3BO3溶液中和饱和Ca(OH)2溶液的除盐效果相差不大,且除盐效率比较好;无论在哪种电解质中进行电化学除盐,混凝土中的Cl-含量以钢筋为中心由内及外呈梯度递增分布;而K+、Na+等阳离子含量则是由内及外呈梯度递减的规律,且内层含量远远高于外层含量。     

Influence of the boundary thermal conditions on the air change efficiency indexes

The influence of a thermal heterogeneity boundary conditions on the air change efficiency (ACE) of a mechanical ventilation system in a test room was experimentally evaluated by means of the "step-down" tracer gas technique in 24 different experimental conditions. The experiments were performed under isothermal condition, varying the air supply temperature with respect to the walls and varying the surface temperature of a wall with respect to the other walls and the supply air, simulating both heating and cooling situations. Changing the position of the outlet grid two different configurations of the ventilation system were tested. The nominal supply air velocity varied between 0.04 and 0.11 m/s, corresponding to a range from 1 to 3 ach, and the temperature differences varied from 0 to 5 degrees C. Results are reported in terms of air change efficiency indexes, both local and global. The global air change efficiency (ACE), values are presented as a function of the Archimedes number (Ar), whose values were in the range 0 to 181. The reported results suggest that the Ar number may be used to organize the ACE values when in the presence of thermal heterogeneity, both in the external envelope and in the supplied air. The obtained results show that there is a logarithmic relation between Ar and ACE. In particular, for both ventilation strategies tested, the increase of the absolute value of Ar leads to an increase of ACE when the supply air is warmer than the walls, and to a decrease of ACE when the supply air is colder than the walls. Under isothermal conditions the Reynolds number (Re) fairly correlates the experimental results.