Degradation study of a reversible solid oxide cell (rSOC) short stack using distribution of relaxation times (DRT) analysis

Reversible solid oxide cells (rSOC) can convert excess electricity to valuable fuels in electrolysis cell mode (SOEC) and reverse the reaction in fuel cell mode (SOFC). In this work, a five – cell rSOC short stack, integrating fuel electrode (Ni-YSZ) supported solid oxide cells (Ni-YSZ || YSZ | CGO || LSC-CGO) with an active area of 100 cm², is tested for cyclic durability. The fuel electrode gases of H₂/N₂:50/50 and H₂/H₂O:20/80 in SOFC and SOEC mode, respectively, are used during the 35 reversible operations. The voltage degradation of the rSOC is 1.64% kh^?1 and 0.65% kh^?1 in SOFC and SOEC mode, respectively, with fuel and steam utilisation of 52%. The post-cycle steady-state SOEC degradation of 0.74% kh^?1 suggests improved lifetime during rSOC conditions. The distribution of relaxation times (DRT) analysis suggests charge transfer through the fuel electrode is responsible for the observed degradation.     

Hybrid Hydrogen Home Storage for Decentralized Energy Autonomy

As the share of distributed renewable power generation increases, high electricity prices and low feed-in tariff rates encourage the generation of electricity for personal use. In the building sector, this has led to growing interest in energy self-sufficient buildings that feature battery and hydrogen storage capacities. In this study, we compare potential technology pathways for residential energy storage in terms of their economic performance by means of a temporal optimization model of the fully self-sufficient energy system of a single-family building, taking into account its residential occupancy patterns and thermal equipment. We show for the first time how heat integration with reversible solid oxide cells (rSOCs) and liquid organic hydrogen carriers (LOHCs) in high-efficiency, single-family buildings could, by 2030, enable the self-sufficient supply of electricity and heat at a yearly premium of 52% against electricity supplied by the grid. Compared to lithium-ion battery systems, the total annualized cost of a self-sufficient energy supply can be reduced by 80% through the thermal integration of LOHC reactors and rSOC systems.     

Model validation and performance analysis of regenerative solid oxide cells for energy storage applications: Reversible operation

The need for electrical energy storage (EES) is being driven by the deployment of increasing amounts of intermittent renewable energy resources. In addition to their fuel flexibility, high efficiency, scalability, and long-term cost outlook, reversible (regenerative) solid oxide cell (rSOC) systems have the potential for round-trip efficiencies competitive with the other available energy storage technologies. Accordingly, the focus of the current study is to investigate modeling methods for high temperature rSOCs in order to facilitate future endeavors related to establishing optimal operating conditions and system designs. Previously developed solid oxide fuel cell (SOFC) and solid-oxide electrolytic cell (SOEC) models are integrated to form a general rSOC model. The model is first calibrated and validated based on the available experimental data in the extant literature. The validation results show that the fitting parameters extracted from the calibration study can precisely simulate the cell behavior under various operating conditions. The effects of key operating parameters, such as temperature, gas composition and fuel utilization, on the voltage–current density performance characteristic and thermoneutral voltage are then investigated. It is also observed that the total electrochemical losses of the cell can be significantly different in each operating mode (fuel cell and electrolyzing) under certain operating conditions. Advantages of pressurized operation on thermal management are also discussed.     

Optimal dispatch for reversible solid oxide cell-based hydrogen/electric vehicle aggregator via stimuli-responsive charging decision estimation

The ongoing growth of green vehicles had led to an increase in demand of cost-effective and driver-satisfactory hydrogen/electric vehicle aggregators (HEVAs). However, existing approaches for cost minimization of HEVA can lead to poor performance due to the inaccurate modelling of power–gas exchange system and neglection of schedulable characteristics of loads. Furthermore, the behaviour of drivers was rarely considered from a psychological perspective. To resolve these limitations, the optimal dispatch scheme of HEVA, equipped with reversible solid oxide cell (rSOC), is investigated by quantifying drivers’ charging decision response toward pricing stimuli. As the core of the bi-directional energy conversion, rSOC is modelled by considering the climbing power constraints and time-dependent restart-up cost. At the driver side, EVs are aggregated as clusters for efficient computation. Two charging modes are designed for drivers with incentive discounts. To measure the relationship between external factors and charging decision response, the stimuli-responsive charging decision estimation is proposed by introducing Weber–Fechner law (W–F Law). To minimum operation cost, a mixed integer nonlinear programming (MINP) method is presented. The results validate that the operation cost of HEVA can be decreased by 19.37%, and the maximum utilization of energy is realised in the proposed scheme. Additionally, the impacts of sizes of power–gas exchange devices are investigated for practical reference. Under a given charging demand, the proposed dispatch scheme can realise installation of smaller devices, and thereby, resulting in lower construction cost.     

Fabrication of hydrogen electrode supported cell for utilized regenerative solid oxide fuel cell application

A utilized regenerative solid oxide fuel cell (URSOFC) provides the dual function of performing energy storage and power generation, all in one unit. When functioning as an energy storage device, the URSOFC acts like a solid oxide electrolyzer cell (SOEC) in water electrolysis mode; whereby the electric energy is stored as (electrolyzied) hydrogen and oxygen gases. While hydrogen is useful as a transportation fuel and in other industrial applications, the URSOFC also acts as a solid oxide fuel cell (SOFC) in power generation mode to produce electricity when needed. The URSOFC would be a competitive technology in the upcoming hydrogen economy on the basis of its low cost, simple structure, and high efficiency. This paper reports on the design and manufacturing of its anode support cell using commercially available materials. Also reported are the resulting performance, both in electrolysis and fuel cell modes, as a function of its operating parameters such as temperature and current density. We found that the URSOFC performance improved with increasing temperature and its fuel cell mode had a better performance than its electrolysis mode due to a limited humidity inlet causing concentration polarization. In addition, there were great improvements in performance for both the SOFC and SOEC modes after the first test and could be attributed to an increase in porosity within the oxygen electrode, which was beneficial for the oxygen reaction.     

Analysis of a polygeneration plant based on solar energy,dual mode solid oxide cells and desalination

Fossil fuels are stored energy during millions of years and we are using it in a rate that new fuels cannot be formed. Renewable energies are not available all the time and there is a need to find ways to store them. One way of storing renewable energies is in fuel form, similar to the fossil fuels and then use this stored fuel whenever needed. The plant design proposed in this paper consists of Dish-Stirling collectors supported by a reversible solid oxide cell acting as a power generator and storage unit, and therefore offering dispatchable power on demand. Further, the system reuses the waste heat for seawater desalination. The present work is an analytical study in which the performance evaluation of a self-sustainable polygeneration system with integrated hydrogen production, power generation, and freshwater production is conducted. An evaluation for selected days, representative for summer, fall, winter and spring in an area with low solar irradiation is studies to investigate the potential of this system to supply 500 kW continuously and simultaneously producing a considerable amount of freshwater. The study shows that the plant can produced hydrogen even in low irradiation winter days together with at least 6500 L of freshwater daily.     

Performance evaluation of a 4-stack solid oxide module in electrolysis mode

To support the current trend of testing bigger reversible Solid Oxide Cell (rSOC) modules, CEA has built the 120 kW_DC Multistack platform. It was used to test SOLIDpower recently developed-Large Stack Module (LSM) in electrolysis mode.Results show high thermal performance of the LSM, with homogeneous temperature distribution and losses in the kilowatt range above 700 °C. A performance map was recorded between 712 and 744 °C over 22.4-to-29.6 kg h^?1 steam flowrates using a fast control strategy to avoid endothermic operation. A peak power of 74 kW_DC was converted into more than 50 kg day^?1 of H₂ (35.5 kWh_DC kgH₂^?1). In addition, fuel utilization of more than 90% and steam conversion above 80% were demonstrated at the module level. In the end, the modular design of the LSM seems well suited for system scale up, paving the way for mutualization of auxiliaries and CAPEX reduction.     

Efficient hydrogen production for industry and electricity storage via high-temperature electrolysis

The paper describes the development status of Sunfire's reversible solid oxide cell (RSOC) technology. Here, Sunfire is a pioneer in the field of high-temperature electrolysers (HTE) for renewable hydrogen production which can be operated as a fuel cell for power generation in a reverse mode. The maturity of the technology is improved stepwise so that first applications in the field of hydrogen production for industry and electricity storage can be tackled. Three application examples where larger scale prototype has been installed will be discussed: 1) A power-to-power electricity storage based on hydrogen, 2) a RSOC unit that is installed in an iron and steel works, and 3) a pressurized SOEC prototype which will be integrated with a methanation unit. Results show the potentials of the technology in connection with fluctuating renewable energy sources.     

Review: Enhancement of composite anode materials for low-temperature solid oxide fuels

Solid oxide fuel cell (SOFC) technology is attractive for its high-energy efficiency and expanded fuel flexibility. It is also more environmentally benign than conventional power generation systems. Recently, increasing attention has been paid to intermediate-to-low-temperature solid oxide fuel cells, which operating at 400–800 °C. Reducing its operating temperature can render SOFC more competitive with other types of fuel cells and portable energy storage system (EES) over a range of applications (eg: transportation, portable, stationary) and more conducive for commercialization. The high-performance composite anode requirements for low operating temperature (400–600 °C) demand microstructural and chemical stability, high electronic conductivity, and good electrochemical performance. The current high-temperature anode, Ni-YSZ (nickel-yttria stabilized zirconia) is generally reported with high interfacial resistance at reduced temperatures. This review highlights several potential composite anode materials (Ni-based and Ni-free) that have been developed for low-temperature SOFCs within the past 10 years. This literature survey shows that most of these anodes still exhibit relatively high polarization resistance. Focus is also given on reducing polarization resistance to maintain the cell power density. In literature, common approaches that have been adopted to enhance the performance of anodes are (i) selecting high-performance electrolyte, (ii) exploiting nanopowder properties, and (iii) adding noble metals as electrocatalysts.     

Numerical modeling of an automotive derivative polymer electrolyte membrane fuel cell cogeneration system with selective membranes

Cogeneration power plants based on fuel cells are a promising technology to produce electric and thermal energy with reduced costs and environmental impact. The most mature fuel cell technology for this kind of applications are polymer electrolyte membrane fuel cells, which require high-purity hydrogen.The most common and least expensive way to produce hydrogen within today's energy infrastructure is steam reforming of natural gas. Such a process produces a syngas rich in hydrogen that has to be purified to be properly used in low temperature fuel cells. However, the hydrogen production and purification processes strongly affect the performance, the cost, and the complexity of the energy system.Purification is usually performed through pressure swing adsorption, which is a semi-batch process that increases the plant complexity and incorporates a substantial efficiency penalty. A promising alternative option for hydrogen purification is the use of selective metal membranes that can be integrated in the reactors of the fuel processing plant. Such a membrane separation may improve the thermo-chemical performance of the energy system, while reducing the power plant complexity, and potentially its cost. Herein, we perform a technical analysis, through thermo-chemical models, to evaluate the integration of Pd-based H₂-selective membranes in different sections of the fuel processing plant: (i) steam reforming reactor, (ii) water gas shift reactor, (iii) at the outlet of the fuel processor as a separator device. The results show that a drastic fuel processing plant simplification is achievable by integrating the Pd-membranes in the water gas shift and reforming reactors. Moreover, the natural gas reforming membrane reactor yields significant efficiency improvements.     

Decarbonising road transport with hydrogen and electricity: Long term global technology learning scenarios

Both fuel cell and electric vehicles have the potential to play a major role in a transformation towards a low carbon transport system that meets travel demands in a cleaner and more efficient way if hydrogen and electricity was produced in a sustainable manner. Cost reductions are central to this challenge, since these technologies are currently too expensive to compete with conventional vehicles based on fossil fuels. One important mechanism through which technology costs fall is learning-by-doing, the process by which cumulative global deployment leads to cost reduction. This paper develops long-term scenarios by implementing global technology learning endogenously in the TIAM-UCL global energy system model to analyse the role of hydrogen and electricity to decarbonise the transport sector. The analysis uses a multi-cluster global technology learning approach where key components (fuel cell, electric battery and electric drive train), to which learning is applied, are shared across different vehicle technologies such as hybrid, plug-in hybrid, fuel cell and battery operated vehicles in cars, light goods vehicles and buses. The analysis shows that hydrogen and electricity can play a critical role to decarbonise the transport sector. They emerge as complementary transport fuels, rather than as strict competitors, in the short and medium term, with both deployed as fuels in all scenarios. However, in the very long-term when the transport sector has been almost completely decarbonised, technology competition between hydrogen and electricity does arise, in the sense that scenarios using more hydrogen in the transport sector use less electricity and vice versa.     

A concept of combined cooling,heating and power system utilising solar power and based on reversible solid oxide fuel cell and metal hydrides

In energy systems, multi-generation including co-generation and tri-generation has gained tremendous interest in the recent years as an effective way of waste heat recovery. Solid oxide fuel cells are efficient power plants that not only generate electricity with high energy efficiency but also produce high quality waste heat that can be further used for hot and chilled water production. In this work, we present a concept of combined cooling, heating and power (CCHP) energy system which uses solar power as a primary energy source and utilizes a reversible solid oxide fuel cell (R-SOFC) for producing hydrogen and generating electricity in the electrolyser (SOEC) and fuel cell (SOFC) modes, respectively. The system uses “high temperature” metal hydride (MH) for storage of both hydrogen and heat, as well as “low temperature” MH's for the additional heat management, including hot water supply, residential heating during winter time, or cooling/air conditioning during summer time.The work presents evaluation of energy balances of the system components, as well as heat-and-mass transfer modelling of MH beds in metal hydride hydrogen and heat storage system (MHHS; MgH₂), MH hydrogen compressor (MHHC; AB₅; A = La + Mm, BNi + Co + Al + Mn) and MH heat pump (MHHP; AB₂; A = Ti + Zr, BMn + Cr + Ni + Fe). A case study of a 3 kWe R-SOFC is analysed and discussed. The results showed that the energy efficiencies are 69.4 and 72.4% in electrolyser and fuel cell modes, respectively. The round-trip COP's of metal hydride heat management system (MHHC + MHHP) are close to 40% for both heating and cooling outputs. Moreover, the tri-generation leads to an improvement of 36% in round-trip energy efficiency as compared to that of a stand-alone R-SOFC.     

The fuel cell electric vehicles: The highlight review

Transportation sector is the important sector and consumed the most fossil fuel in the world. Since COVID-19 started in 2019, this sector had become the world connector because every country relies on logistics. The transportation sector does not only deal with the human transportation but also relates to logistics. Research in every country has searched for alternative transportation to replace internal combustion engines using fossil fuel, one of the most prominent choices is fuel cells. Fuel cells can use hydrogen as fuel. Hydrogen can be fed to the fuel cells to provide electric power to drive vehicles, no greenhouse gas emission and no direct combustion required. The fuel cells have been developed widely as the 21st century energy-conservation devices for mobile, stationary, and especially vehicles. The fuel cell electric vehicles using hydrogen as fuel were also called hydrogen fuel cell vehicles or hydrogen electric vehicles. The fuel cells were misconceived by several people that they were batteries, but the fuel cells could provide electric power continuously if their fuel was provided continuously. The batteries could provide electric power as their only capacities, when all ions are released, no power could be provided. Because the fuel cell vehicles play important roles for our future transportation, the overall review for these vehicles is significantly interesting. This overall review can provide general and technical information, variety of readers; vehicle users, manufacturers, and scientists, can perceive and understand the fuel cell vehicles within this review. The readers can realize how important the fuel cell technologies are and support research around the world to drive the fuel cell vehicles to be the leading vehicles in our sustainable developing world.     

Fuel cell vehicles: State of the art with economic and environmental concerns

Hydrogen fueled fuel cell vehicles (FCVs) will play a major role as a part of the change toward the hydrogen based energy system. When combined with the right source of energy, fuel cells have the highest potential efficiencies and lowest potential emissions of any vehicular power source. As a result, extensive work into the development of hydrogen fueled FCVs is taking place. The aim of this paper is to highlight some of the research and development work which has occurred in the past five years on fuel cell vehicle technology, with a focus on economic and environmental concerns. It is observed that the current efforts are divided up into several parts. The performance, durability, and cost of fuel cell technology continue to be improved, and some fuel cells are currently ready to be mounted on vehicles and tested. Environmental and economic assessments of the entire hydrogen supply chain, including fuel cell end-use, are being carried out by groups of researchers around the world. It is currently believed that fuel cells need at least five more years of testing and improvement before large scale commercialization can begin. Economic and environmental analyses show that FCVs will likely be both economically competitive and environmentally benign. Indeed, the transition of the transportation sector to the use of hydrogen FCVs will represent one of the biggest steps toward the hydrogen economy.     

Performance assessment of industrial-sized solid oxide cells operated in a reversible mode: Detailed numerical and experimental study

Reversible solid oxide cells (rSOCs) present a unique possibility in comparison to other available technologies to generate electricity, heat and valuable fuels in one system, in a highly-efficient manner. The major issue hindering their commercialization are system reliability and durability. A detailed understanding of the processes and mechanisms that occur within rSOCs of industrial-size, is of critical importance for addressing this challenge. This study provides in-depth insight into behavior of large planar rSOCs based on a comprehensive experimental and numerical study. All the numerical data obtained are validated with the in-house made cells and experiments. The sensitivity analysis, which covers a wide range of operating conditions relevant for industrial-sized systems, such as varying operating temperature, H₂/H₂O-ratio, operating current etc., provides very good accordance of the cell performance measured and simulated. It reveals that lowering fuel volume and thus causing fuel starvation has more pronounced effect in an electrolysis mode, which is visible in both the low-frequency and the middle-frequency range. Moreover, both co- and counter-flow are appropriate for the reversible operation. However, more uniform current density distribution is achievable for the counter-flow, which is of crucial importance for the real system design. The most accurate performance prediction can be achieved when dividing the cell into 15 segments. Slightly lower accuracy is reached by logarithmic averaging the fuel compositions, thus reducing the calculation time required. A computationally- and time-efficient model with very precise performance prediction for industrial-sized cells is thus developed and validated.     

Effect of orthohydrogen–parahydrogen composition on performance of a proton exchange membrane fuel cell

The effect of orthohydrogen–parahydrogen concentration on the performance of a proton exchange membrane fuel cell is calculated and experimentally investigated. Gibbs free energy and reversible cell potential calculations predict that parahydrogen at room temperature produces a voltage 20 mV/cell higher than normal hydrogen and a 1.6% increase in efficiency over normal hydrogen. Experimental data based on a 1 kW proton exchange membrane fuel cell rapidly switched between normal and parahydrogen did not show a statistically significant difference in performance. Variations due to stack humidity and anode purging are found to dominate fuel cell output. The experimental results confirm that, as anticipated, parahydrogen concentration has a negligible impact on fuel cell performance for the majority of practical applications.     

Y type zeolites/PI membranes for sulfur-free hydrogen source and for fuel cell applications

Sulfur removal is significant for fuels used as hydrogen source for modern fuel cell applications and to avoid sulfur poisoning of therein used catalysts. Novel membranes for the polymer–zeolite system with well-defined transport channels are proposed for the sulfur removal. Membranes are fabricated using polyimide (PI) as matrix material and Y zeolites as adsorptive functional materials. By detailed analysis of FT-IR, morphology and adsorption performance of membranes, the process-structure-function relationship is obtained. The results show that the functional zeolites particles are incorporated into three-dimensional channels. For all cases, the inlet fuel can be desulfurized to below 0.1 mg L⁻¹, which means that the outlet fuel can be used as sulfur-free hydrogen source for fuel cell applications. The proposed membranes adsorber may be applied as sulfur trap before the reformer for fuel cells on-board or on-site, and it may be applied in a periodically replaceable form. The desulfurization efforts by membrane are likely to play an influential role for the development of sulfur-free hydrogen source and fuel cell area.     

Evaluating the perspectives for hydrogen energy uptake in communities: Success criteria and their application

In recent years, a number of initiatives have been supported in Europe in the hydrogen energy sector. Communities can play an important role in the adoption process of these emerging technologies: supporting pre-commercial deployment, building public acceptance, and promoting innovation clusters, all of which lay the foundations for more widespread and sustained technology deployment. Participation by communities is hinged on the perceived contribution of technology adoption to community socio-economic and energy related goals, such as, climate change mitigation, air quality improvement, creation of new industries and businesses, exploitation of abundant renewable resources, and meeting growing energy needs. Hydrogen uptake in communities therefore stands to benefit development of the hydrogen energy sector and the communities themselves. This paper presents a methodology for evaluating the potential for successful large-scale hydrogen and fuel cell technology adoption—beyond demonstration projects—within defined community frameworks. This methodology can be a valuable tool, for community decision-makers and industry stakeholders alike, to evaluate and identify opportunities for large-scale hydrogen technology adoption. Results of applying the methodology are presented for three community types: islands, cities and regions. The work in this paper reflects work done within the frame of the European Commission-funded ‘Roads2HyCom’ project, Work Package 3.¹     

SOFC-APU systems for aircraft: A review

This review brings together publications in the form of articles, reports, theses and patents related to the use of solid oxide fuel cells in aircraft with a focus on replacing the current auxiliary units with a hybrid system. The potential advantages and main challenges of the new technology are reported, indicating some possible trends in this technology. However, even after many studies, some initial challenges remain. For example, the hybrid system did not achieve the necessary weight-efficiency-ratio, and there seems to be no consensus on the choice of the best fuel. We conclude that the most viable short-term applications appear to be unmanned units, particularly because of security issues and low technology maturity. Smaller power applications, in which the new system is responsible for peripheral services such as a power supply for air conditioning, toilets, and heating up food, are candidates to enter the market in the short or medium term. In the long term, applications for fully electric aircraft and clean fuels will certainly be the focus of larger aircraft manufacturers.     

Overview of the next quarter century vision of hydrogen fuel cell electric vehicles

Last three decades, costumers and manufacturers of automotive sector have been influenced positively by Hydrogen and fuel cells (FCs). The main goal of automakers can be pointed as minimizing the fuel consumption and exhaust emissions while improving the range limits, energy efficiency and latest technology adaptation. Therewithal, electric assisted propulsion systems added to vehicles and are called as electric vehicles (EVs). For that matter, Battery Electric Vehicles (BEVs) and hydrogen Fuel Cell Electric Vehicles (FCEVs) have become the focus of researchers and producers. In this mini foreseen review, overview of the next quarter century vision of FCEVs are expressed and discussed by the helped of previous researches and with future forecast reports. The introduction part is summarized the general approach and future expectations of FCs in detailed. Technical overview is represented for FCs and FCEVs in terms of current state of technology to foreseen expectancy. Infrastructure analysis and future aspects overview part is also discussed for sector's perspective on FCEVs. The near future perspective of the FCEVs, which is seen as the next step in EVs, is discussed in detail in the next quarter century vision. Authors concluded that, between the 2030s-2050s, hydrogen FCEVs will continue their rising demand scale under the circumstances of decreasing expensive technology; enhanced energy optimization; extended range limits and increasing hydrogen refueling stations.