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深紫外相干光源对于光刻技术、光电子能谱仪、激光精密机械加工等均具有十分重要的意义.本文将系统地阐述可产生深紫外谐波光输出的非线性光学晶体是如何被发现的,这些晶体的基本线性、非线性光学性质和使用它们产生深紫外谐波光的方法.最后还简单介绍深紫外谐波光的几个典型例子. 相似文献
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深紫外相干光源对于光刻技术、光电子能谱仪、激光精密机械加工等均具有十分重要的意义。本文系统地阐述了可产生深紫外谐波光输出的非线性光学晶体的发现、基本线性、非线性光学性质,以及用它产生深紫外谐波光的方法。最后简介了深紫外谐波光的几个实例。 相似文献
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深紫外非线性光学晶体KBe2BO3F2(KBBF)发展至今,已有将近20年的历史。首先简单回顾了KBBF化合物的发现、晶体生长以及基本光学性质,同时对KBBF族(MBe2BO3F2,M=K,Rb,Cs)的其它化合物如:RbBe2BO3F2和CsBe2BO3F2的晶体生长和其基本光学性质进行了报道,然后对这些新晶体产生深紫外谐波光输出的能力做了评估,最后介绍了利用KBBF晶体器件产生的深紫外相干光源在先进仪器等方面的应用。 相似文献
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采用水热法合成出一种新型碳酸盐非线性光学晶体材料KNa5Ca5(CO3)8, 该晶体属于六方晶系, 空间群为P63mc, 晶胞参数为a=b=1.00786(4) nm, c=1.26256(8) nm, Z=2。其晶体结构可以看作是由站立的[CO3]基团连接相邻的两个[CaCO3]∞层, 从而沿[010]方向形成了四种不同类型的孔洞, 在这些孔洞中填充着K、Na 和[Na0.67Ca0.33]原子。KNa5Ca5(CO3)8晶体的粉末倍频效应为KDP的1.2倍, 且能够在可见光区实现相位匹配。紫外-可见-近红外漫反射光谱测试结果表明其晶体具有较大的光学带隙, 大概为5.95 eV, 是具有潜在应用前景的紫外非线性光学晶体材料。此外, 第一性原理的计算结果表明, 晶体的非线性系数主要来源于CO3基团。 相似文献
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非线性光学活性分子的EFISH研究 总被引:4,自引:1,他引:3
非线性极化率是衡量非线性光学材料品质的主要指标之一,本文用电场诱导二次谐波方法测定了一种新型金属有机分子碘化(反式)-[1-二茂铁基-2-(N-十八烷基-4-吡啶基)乙烯]的二阶非线性极化率,研究表明该分子具有较强的非线性光学活性。 相似文献
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Benzothiazolium Single Crystals: A New Class of Nonlinear Optical Crystals with Efficient THz Wave Generation 下载免费PDF全文
Seung‐Heon Lee Jian Lu Seung‐Jun Lee Jae‐Hyun Han Chan‐Uk Jeong Seung‐Chul Lee Xian Li Mojca Jazbinšek Woojin Yoon Hoseop Yun Bong Joo Kang Fabian Rotermund Keith A. Nelson O‐Pil Kwon 《Advanced materials (Deerfield Beach, Fla.)》2017,29(30)
Highly efficient nonlinear optical organic crystals are very attractive for various photonic applications including terahertz (THz) wave generation. Up to now, only two classes of ionic crystals based on either pyridinium or quinolinium with extremely large macroscopic optical nonlinearity have been developed. This study reports on a new class of organic nonlinear optical crystals introducing electron‐accepting benzothiazolium, which exhibit higher electron‐withdrawing strength than pyridinium and quinolinium in benchmark crystals. The benzothiazolium crystals consisting of new acentric core HMB (2‐(4‐hydroxy‐3‐methoxystyryl)‐3‐methylbenzo[d]thiazol‐3‐ium) exhibit extremely large macroscopic optical nonlinearity with optimal molecular ordering for maximizing the diagonal second‐order nonlinearity. HMB‐based single crystals prepared by simple cleaving method satisfy all required crystal characteristics for intense THz wave generation such as large crystal size with parallel surfaces, moderate thickness and high optical quality with large optical transparency range (580–1620 nm). Optical rectification of 35 fs pulses at the technologically very important wavelength of 800 nm in 0.26 mm thick HMB crystal leads to one order of magnitude higher THz wave generation efficiency with remarkably broader bandwidth compared to standard inorganic 0.5 mm thick ZnTe crystal. Therefore, newly developed HMB crystals introducing benzothiazolium with extremely large macroscopic optical nonlinearity are very promising materials for intense broadband THz wave generation and other nonlinear optical applications. 相似文献
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Optical Crystals: Benzothiazolium Single Crystals: A New Class of Nonlinear Optical Crystals with Efficient THz Wave Generation (Adv. Mater. 30/2017) 下载免费PDF全文
Seung‐Heon Lee Jian Lu Seung‐Jun Lee Jae‐Hyun Han Chan‐Uk Jeong Seung‐Chul Lee Xian Li Mojca Jazbinšek Woojin Yoon Hoseop Yun Bong Joo Kang Fabian Rotermund Keith A. Nelson O‐Pil Kwon 《Advanced materials (Deerfield Beach, Fla.)》2017,29(30)
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Zhiyong Bai Jihyun Lee Heewon Kim Yunseung Kuk Myung-Ho Choi Chun-Li Hu Kang Min Ok 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(19):2207709
Establishing high performance ultraviolet (UV) nonlinear optical (NLO) selenite crystals with well-balanced properties is very challenging attributable to their strong absorption for UV light. Here a rare-earth selenite, Sc(HSeO3)3, with excellent UV NLO properties is introduced. Sc(HSeO3)3 crystallizing in the polar NCS space group, Cc, features a 3D archetiture built up by interconnected ScO6 octahedra and HSeO3 groups. The crystal exhibits remarkably well-balanced UV-NLO functionality, namely, the shortest absorption edge (214 nm) among NLO-active selenites, wide bandgap (5.28 eV), large phase-matchable SHG response (5 × KDP), and sufficiently large birefringence (cal. 0.105 @1064 nm). Detailed DFT calculations have been performed to elucidate the structure–property relationships. This work provides a new example of discovering novel UV NLO selenite materials. 相似文献
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有机低分子三阶非线性光学材料 总被引:4,自引:0,他引:4
根据分子结构特征对各类有机低分子三阶非线性光学材料结构与性能的关系作了评述。根据三阶非线性光学基本原理对有机材料三阶非线性光学效应的机理和材料的分子设计作了分析。 相似文献
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Molecular Dynamics of Flexible Polar Cations in a Variable Confined Space: Toward Exceptional Two‐Step Nonlinear Optical Switches 下载免费PDF全文
Wei‐Jian Xu Chun‐Ting He Cheng‐Min Ji Shao‐Li Chen Rui‐Kang Huang Rui‐Biao Lin Wei Xue Jun‐Hua Luo Wei‐Xiong Zhang Xiao‐Ming Chen 《Advanced materials (Deerfield Beach, Fla.)》2016,28(28):5886-5890
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Beibei Fu Cong Wang Yantao Sun Jiarong Yao Yu Wang Fayuan Ge Fangxu Yang Zheyuan Liu Yanfeng Dang Xiaotao Zhang Xiangfeng Shao Rongjin Li Wenping Hu 《Advanced materials (Deerfield Beach, Fla.)》2019,31(35)
2D molecular crystals (2DMCs) have attracted considerable attention because of their unique optoelectronic properties and potential applications. Taking advantage of the solution processability of organic semiconductors, solution self‐assembly is considered an effective way to grow large‐area 2DMCs. However, this route is largely blocked because a precise molecular design towards 2DMCs is missing and little is known about the relationship between 2D solution self‐assembly and molecular structure. A “phase separation” molecular design strategy towards 2DMCs is proposed and layer‐by‐layer growth of millimeter‐sized monolayer or few‐layer 2DMCs is realized. High‐performance organic phototransistors are constructed based on the 2DMCs with unprecedented photosensitivity (2.58 × 107), high responsivity (1.91 × 104 A W?1), and high detectivity (4.93 × 1015 Jones). This “phase separation” molecular design strategy provides a guide for the design and synthesis of novel organic semiconductors that self‐assemble into large‐area 2DMCs for advanced organic (opto)electronics. 相似文献