共查询到18条相似文献,搜索用时 69 毫秒
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高功率高透波材料的研究 总被引:9,自引:1,他引:9
本文叙述了以 TRR 树脂为基体,分别用 B 型石英玻璃纤维和 UHMWPE 纤维为增强材料,与 T 蜂窝复合制得高功率高透波材料的研究情况,两种蒙皮和 T 蜂窝在 9.375GHz 下的?和 ?分别为 2.79、3×10-4;2.13、4×10-4 和 1.14、9.43×10-4;夹层结构的插入损耗分别为 0.019-0.02dB 和 0.030-0.041dB。 相似文献
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多孔氮化硅(Si_3N_4)陶瓷由于具有优异的力学性能、良好的抗热震和低介电常数等特点,在极端力/热环境下具有很大的应用潜力。研究表明:不同的制备工艺对多孔氮化硅陶瓷晶粒尺寸、微结构有很大影响,从而影响材料的力学性能;介电性能受气孔率、相组成影响;渗透率受气孔率、气孔尺寸、弯曲度的影响。综述了多孔Si_3N_4陶瓷的烧结工艺、成型工艺及其相关性能研究,并结合目前的研究热点,指出了未来多孔氮化硅陶瓷研究的发展方向。 相似文献
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氮化硅陶瓷不仅具有较高的力学性能还具有良好的透波性能、导热性能以及生物相容性能,是公认的综合性能最优的陶瓷材料。作为轴承球的致密氮化硅陶瓷广泛应用在机械领域;作为透波材料的多孔氮化硅陶瓷广泛应用在航空航天领域;随着对氮化硅陶瓷材料的深入研究,其在导热性和生物相容性方面的优异特性逐渐被科研工作者认识并得到开发和应用。本文详细阐述了氮化硅粉体的制备方法,并综述了氮化硅陶瓷作为结构陶瓷在机械领域和航空航天领域的研究进展,此外还介绍了其作为功能陶瓷在半导体领域、生物制药领域的研究和应用现状,最后对其未来发展进行了展望。 相似文献
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Synthesis of Porous Silicon Nitride with Unidirectionally Aligned Channels Using Freeze-Drying Process 总被引:4,自引:0,他引:4
Takayuki Fukasawa Zhen-Yan Deng Motohide Ando Tatsuki Ohji Shuzo Kanzaki 《Journal of the American Ceramic Society》2002,85(9):2151-2155
Porous silicon nitride with macroscopically aligned channels was synthesized using a freeze-drying process. Freezing of a water-based slurry of silicon nitride was done while unidirectionally controlling the growth direction of the ice. Pores were generated subsequently by sublimation of the columnar ice during freeze-drying. By sintering this green body, a porous silicon nitride with high porosity (over 50%) was obtained and its porosity was controllable by the slurry concentration. The porous Si3 N4 had a unique microstructure, where macroscopically aligned open pores contained fibrous grains protruding from the internal walls of the Si3 N4 matrix. It is hypothesized that vapor/solid phase reactions were important to the formation mechanism of the fibrous grains. 相似文献
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运用热力学方法分析了氮化硅陶瓷在制备和使用过程中涉及的物理化学过程,包括Si3N4烧结、Si3N4在真空中的挥发、Si3N4的稳定性、Si3N4与金属固体的作用4个方面,结合实际论述了反应发生、发展的条件、反应的优先性、生成化合物的稳定性及热力学方法的适用性. 相似文献
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Fabrication of Low-Shrinkage, Porous Silicon Nitride Ceramics by Addition of a Small Amount of Carbon 总被引:4,自引:0,他引:4
Jian-Feng Yang Guo-Jun Zhang Tatsuki Ohji 《Journal of the American Ceramic Society》2001,84(7):1639-1641
Successful net-shape sintering offers a significant advantage for producing large or complicated products. Porous Si3 N4 ceramics with very low shrinkage were developed, in the present investigation, by the addition of a small amount of carbon. Carbon powders (1–5 vol%) of two types, with different mean particle sizes (13 nm and 5 μm), were added to α-Si3 N4 −5 wt% Y2 O3 powders. SiC nanoparticles formed through reaction of the added carbon with SiO2 on the Si3 N4 surface or with the Si3 N4 particles themselves. Such reaction-formed SiC nanoparticles apparently had an effective reinforcing effect, as in nanocomposites. Sintered Si3 N4 porous ceramics with a high porosity of 50%–60%, a very small linear shrinkage of ∼2%–3%, and a strength of ∼100 MPa were obtained. 相似文献
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Jihong She Jian-Feng Yang Daniel Doni Jayaseelan Naoki Kondo Tatsuki Ohji Shuzo Kanzaki Yoshiaki Inagaki 《Journal of the American Ceramic Society》2003,86(4):738-40
The thermal shock behavior of isotropic and anisotropic porous Si3 N4 was evaluated using the water-quenching technique. The critical temperature difference for crack initiation was found to be strongly dependent on the ratio of fracture strength to elastic modulus. Because of a very high strain-to-failure, anisotropic porous Si3 N4 showed no macroscopic cracks and was able to retain its strength even at a quenching-temperature difference of ∼1400°C. 相似文献
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Ultralight Silicon Nitride Ceramic Foams from Foams Stabilized by Partially Hydrophobic Particles 下载免费PDF全文
Xiao‐Yan Zhang Wen‐Long Huo Fei Qi Ya‐Nan Qu Jie Xu Ke Gan Ning Ma Jin‐Long Yang 《Journal of the American Ceramic Society》2016,99(9):2920-2926
Ultralight Si3N4 ceramic foams have been successfully prepared through particle‐stabilized foams method, which is based on the adsorption of in situ hydrophobized Si3N4 particles to the liquid/air interface of the foams. Here, we firstly used a long‐chain surfactant cetyltrimethylammonium chloride to render the Si3N4 particles partially hydrophobic. By tailoring the surfactant concentration and pH values of the suspensions, the wet foams were stabilized to avoid coarsening and coalescence. SEM results show that the Si3N4 ceramic foams possess single strut walls with elongated β‐Si3N4 grains interlocking with each other, and their pores are uniform with an average pore size of 95 μm. The obtained ceramic foams maintain compressive strength of 1.34 ± 0.13 MPa with porosity of 92.0%, when the suspension contains 3 mmol/L surfactant at the pH of 11.0. 相似文献
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采用有机泡沫前躯体浸渍工艺制备了低介电、低密度的氮化硅陶瓷。以氮化硅粉体为主要原料,制备粘度和流动性合适的水基料浆,并以软质聚氨酯泡沫塑料为载体,在真空状态下浸渍,然后在氧化气氛下排塑,在氮气气氛下烧结,得到了低介电常数的多孔氮化硅陶瓷材料。所制备的材料性能可达到:容积密度为0.12g/cm3、介电常数为1.15、介电... 相似文献