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电子束蒸发沉积Al-Cr合金涂层研究 总被引:5,自引:0,他引:5
研究了电子束蒸发镀沉积Al-Cr合金涂层的工艺,探讨了铬含量对涂层耐蚀性的影响。对涂层的物相、形貌以及热处理对涂层和基体之间热扩散的影响进行了分析.结果表明:涂层中铬含量与膜料中铬含量有较大差异;在温度为283K,30g/L NaCl溶液中含1.5%Cr、2.5%Cr、5%Cr的Al-Cr合金涂层的自腐蚀电位均比普通钢基材的电位负,因此它们作为阳极性涂层对普通钢基材能起到较好的电化学保护;涂层为晶态组织,其物相为Al和少量的Cr9Al17。随膜料中Cr含量的增加,其生成的Cr9Al17的量也随之增多;在真空蒸镀时涂层沉积有方向性;对涂层进行600℃,lh热处理后,涂层与基体间元素产生了互扩散. 相似文献
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弧离子镀TiAlN涂层与模具钢基材的结合力的优化 总被引:1,自引:0,他引:1
采用弧离子镀方法在SKD61模具钢基体上制备TiAIN薄膜,分析了工艺参数对膜层与模具钢基体结合力的影响.应用正交法.依据涂层与基体的临界载荷越大结合力越好的原则,得出了最优涂层的工艺参数:基体温度220℃、弧流60A、沉积基体偏压-800V、气体压强1.3 Pa、预处理基体偏压-450V和预处理时间15min.优化后的涂层与基体的临界载荷达到56 N,比优化前最大临界载荷增加43%.TiAIN薄膜与模具钢基体结合力的改进主要归功于涂层的高硬度和TiAIN相(111)、(200)和(220)取向的竞争生长. 相似文献
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Al箔溅射沉积Cu膜的工艺研究 总被引:2,自引:2,他引:0
为了研究溅射工艺对膜-基间结合力的影响,获得成本较低、膜-基间结合较好的表层导电薄膜电磁屏蔽材料,利用磁控溅射镀膜方法在Al箔基体上溅射沉积Cu膜,采用胶粘带拉剥法测试了膜-基间的结合力,使用扫描电子显微镜观察了Cu膜的组织和Al/Cu的界面形貌.结果表明:溅射工艺对膜-基间的结合力有着明显的影响,镀Cu前对Al箔进行反溅射和在溅射沉积过程中对工件施加负偏压都可有效地提高膜-基间的结合力.分析认为:镀Cu前反溅射可有效地去除Al箔表面的氧化膜,使Al箔表面得到净化;在磁控溅射沉积过程中对工件施加较高负偏压将产生辉光放电,使工艺转化成溅射离子镀,从而获得与基体结合良好、晶粒细小、致密的镀层. 相似文献
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化学复合镀镍-磷-金刚石镀层性能的研究 总被引:3,自引:1,他引:3
研究了化学复合镀Ni—P-金刚石镀层的金相组织、显微硬度、结合力及耐磨性能。结果表明:采用合适的工艺条件,可获得金刚石微粒含量较高、微粒分布均匀的镀层,镀层硬度可达1850HV左右,且镀层与基体结合力良好、耐磨性比化学镀Ni—P镀层大大提高。 相似文献
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为实现对玻璃表面的金属化改性,试验研究了高硼硅玻璃表面化学镀镍工艺。在前处理阶段采用喷砂和酸蚀结合的方法对玻璃基体表面进行粗化,使用PdCl2对玻璃基体表面进行活化。采用划线、划格试验法对镀层与基体的结合力进行了测试,并利用扫描电镜(SEM)、能谱成分分析(EDS)和X射线衍射(XRD)等方法对镀镍层的表面形貌、镀层成分及物相结构进行了分析表征。结果表明,施镀速度约为20μm/h,当施镀时间达到1h,所得镀层致密且厚度均匀,得到的非晶态镀层与玻璃基体之间的结合力良好。 相似文献
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金属刷镀是快速局部电镀新技术,其工艺名称目前提法不一,美国称之为选择性电镀(Selective plating)或刷镀(Brush plating),英国和法国称之为达力克工艺(Dalic process),我国国家标准则正式命名为刷镀.从原理上讲,刷镀与普通槽镀无异,同属于电化学沉积技术.但刷镀阳极、刷镀液及工艺形式与普通槽镀迥然不同.因而在阴极极化、镀层结构、镀层与基体的结合型式、镀层的机械性能等与槽镀有明显区别,而发 相似文献
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采用电子束物理气相沉积技术(Electron Beam Physical Vapor Disposition, EB-PVD)通过连续蒸镀成功制备陶瓷ZrO_2涂层和以镍基合金为基体的一体化薄板材料.结果表明,ZrO_2涂层致密,具有柱状晶组织,无明显的织构存在.涂层与基体材料间有明显的成分连续梯度变化区域.抗热震性能测试结果显示,一体化材料的ZrO_2梯度涂层能明显延缓热震裂纹的形成和扩展,具有良好的抗热震性能. 相似文献
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不同工艺制备的铁电薄膜底电极Pt/Ti 总被引:4,自引:0,他引:4
采用高真空电子束蒸与直流溅射在SiO2/Si基底上制备Pt/Ti底电极,对Pt/Ti在不同热处理温度下的结构与形貌进行对比研究。结果表明;由于采用不同的制备工艺,Pt晶粒在成核与生长方式上有所不同,导致了Pt薄膜在结构与形貌的差异。 相似文献
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Thin film of Ti-Ni alloy has a potential to perform the microactuation functions required in the microelectromechanical system (MEMS).It is essential, however, to have good uniformity in both chemical composition and thickness to realize its full potential as an active component of MEMS devices.Electron beam evaporation technique was employed in this study to fabricate the thin films of Ti-Ni alloy on different substrates.The targets used for the evaporation were first prepared by electron beam melting.The uniformity of composition and microstructure of the thin films were characterized by electron probe microanalysis (EPMA), Auger electron spectroscopy (AES), X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and transmission electron microscopy (TEM).The mechanical property of the thin films was evaluated by the nano-indentation test.The martensitic transformation temperature was measured by differential scanning calorimetry (DSC).It is confirmed that the chemical composition of deposited thin films is identical to that of the target materials.Furthermore, results from depth profiling of the chemical composition variation reveal that the electron beam evaporation process yields better compositional homogeneity than other conventional methods such as sputtering and thermal evaporation.Microstructural observation by TEM shows that nanometer size precipitates are preferentially distributed along the grain boundaries of a few micron size grains.The hardness and elastic modulus of thin films decreases with an increase in Ti contents. 相似文献
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用电子束蒸发的方法在单晶硅(100)基片上制备了硼碳氮薄膜,通过椭圆偏振仪、X射线衍射仪(XRD)、X光电子能谱仪(XPS)、傅立叶红外光谱仪(FTIR),测试分析了薄膜厚度均匀性、成分与结构.结果表明,薄膜均匀性较好,薄膜的沉积速率非常慢;薄膜在衬底温度为常温下沉积已是晶态的,随着衬底温度升高到450 ℃,其结晶性逐渐增强;薄膜不是石墨与BN的混和膜而是C、B、N相互结合成键. 相似文献
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WANG Xi YANG Genqing LIU Xianghuai ZHENG Zhihong HUANG Wei ZHOU Zuyao ZOU Shichang Ion Beam Laboratory Shanghai Institute of Metallurgy Academia Sinica shanghai China 《金属学报(英文版)》1992,5(11):370-374
A new method for preparation of hard TiN films has been developed by using electronbeam evaporation-deposition of Ti and bombardment with 40 keV Xe~+ ion beam ina N_2 gas environment.The synthesized TiN films were superior to PVD and CVDones in respects of improved adhesion to substrate and low preparing temperature.Theyexhibited good wear resistance and high hardness up to 2200 kg/mm~2.Some industrialapplications have been reported. 相似文献
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Thin film hard coatings on rolling element surfaces can enhance the overall wear resistance of rolling element bearings, as demonstrated previously for coated tapered, cylindrical, and spherical roller bearings. Hard coatings in ball bearings are less common because of the difficulty in achieving uniform film thickness on a ball surface. This limitation is overcome by a new process for depositing chromium nitride coatings with uniform thickness on precision balls using ion beam assisted deposition (IBAD) e-beam evaporation. Scanning electron microscopy indicated that the deposited films were smooth and conformal on the ball surfaces with no areas of localized delamination. Auger electron spectroscopy confirmed that Cr2N and CrN bulk film stoichiometry was achievable by modulating the argon to nitrogen process gas ratio during deposition. Transmission electron microscopy revealed dense, polycrystalline film structure. Film hardness and elastic modulus as measured using nanoindentation on the coated balls met expectations for chromium nitride, and tribological testing of the coated balls in angular contact ball bearings under moderate contact stress levels demonstrated adequate film adhesion for practical use of these coatings in bearing applications. 相似文献
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The Fe/Mo multilayers were prepared by electron beam evaporation, the micro structure and magnetic properties of the multilayers were studied by X-ray diffraction, vibrating-sample magnetometer (VSM) et al. The experimental results revealed that the Fe/Mo multilayers in our experimental conditions behaved magnetoresistance effect with a sharp peak on magnetoresistance (MR) ratio curve, and magnetoresistance is easily saturated at low applied magnetic fields. For [Fe(1.5nm)/Mo(1.0nm)]4,2 multilayers, MR ratio could arrive to 0.1%. The antiferromagnetic interlayer coupling could be observed in some films at room temperature. The strength of the antiferromagnetic interlayer coupling J in the films is low because of the low saturation field Hs. The relationship between magnetic properties and micro structure was also discussed in this paper. 相似文献
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The SrS:HoF3 Electroluminescent (EL) thin films are prepared at the different substrate temperature by electron beam evaporation. The crystallinity and EL characteristics of the samples are analyzed. It is found that the main diffraction peak is (200) at the higher substrate temperature and the main diffraction peak is (111) at the lower substrate temperature. The blue emission intensity and EL brightness of the SrS∶HoF3 thin films increase with the increase of the substrate temperature. Annealing the samples can change the cyrstal phase and strengthen the blue emission of EL thin film. 相似文献
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《Acta Materialia》2003,51(7):2079-2087
The room temperature mechanical behavior of thin gold films (0.2–2.0 μm thickness) was investigated through uniaxial tensile testing. Films were deposited by electron beam and thermal evaporation, under varying conditions, in order to produce films with different microstructures. This particular study concentrated on the behavior of the films with grain sizes of less than about 0.5 μm. The testing showed that these fine-grained films exhibited significant strain rate dependence, in contrast with a previous study of gold films with more coarse grain sizes [1]. The results are discussed in terms of existing theories for rate-dependent metals. 相似文献