共查询到19条相似文献,搜索用时 140 毫秒
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利用一种改进后的U型管圆锥泡声致发光装置,研究了乙二醇溶液中圆锥泡声致发光的发光光谱.实验结果表明,光谱为从紫外到可见光波长范围的连续谱,在589 nm附近叠加有钠的3p-3s原子发射谱线.在钠的原子发射谱线左侧测量得到了Na-Ar分子激发态跃迁形成的蓝卫星带,并首次在声致发光实验中测得了Na-Ar的红卫星带以及钠的3d-3p原子发射谱线.最后,讨论了钠的原子发射谱线以及卫星带的形成机理. 相似文献
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在某些混合染料体系中,能量转移已成为扩展激光波长范围的一种有效方法,当施主吸收光谱与受主荧光光谱部分重叠时,有可能出现能量转移过程.同时,进一步研究能量转移过程,可对生物分子中分子间能量转移进行分析.本文研究若丹明 B 通过若丹明6G 转移能量 相似文献
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为了提高染料激光器激光介质的波长范围和发光稳定性,在SiO2凝胶基质中掺杂混合染料:香豆素102和若丹明6G掺杂后的荧光光谱可调谐波长展宽.而且两种染料之间能量传递效率提高. 相似文献
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利用单泡声致发光光脉冲间期短以及与声场精确同步的特点,首次把高时辨的光子计数器用于单泡声致发光光谱的测量,极大程度地提高了信噪比,在较高的灵敏度下亦可达到较高的分辨率.利用该方法得到了稳态单泡声致发光的光谱曲线,并且对原始光谱曲线进行了校准. 相似文献
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《内蒙古师范大学学报(自然科学版)》2014,(1)
以磷酸和丙二醇两种黏滞系数不同的液体为实验对象,利用磁力加热搅拌器,观测到比较集中和稳定的多泡声致发光现象.通过测量三维和二维结构谐振腔中磷酸和丙二醇液体的声致发光强度,验证了多泡声致发光的周期性.实验结果表明,液体的声致发光强度对谐振腔电压、驱动信号频率、电感等可控参数非常敏感,并且与液体黏滞性和谐振腔结构有关.黏滞性大的液体不利于气泡脉动,发光强度较弱;三维结构的谐振腔比二维结构更容易实现声致发光,并且发光强度较强;在二维结构谐振腔中,磷酸的发光强度与液体厚度有关,而丙二醇的声致发光现象不容易观测到. 相似文献
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在硫酸溶液中实现了稳定悬浮的单泡声致发光,分别用锁相积分频闪拍摄方法和光谱仪对不同浓度硫酸溶液中的声致发光气泡进行了气泡动力学和光谱学方面的研究,并且与水中的单泡声致发光气泡相比较,发现了一系列有价值的结果.硫酸中声致发光比水中的明亮,这其中很重要的一个原因是由于硫酸的黏度高,导致气泡的平衡半径较大,气泡内容纳的用来发光的工作物质较多.但是硫酸中声致发光气泡的膨胀塌缩程度并没有水中的剧烈,反映在光谱学测量方面就是其黑体辐射拟合温度较水中的低. 相似文献
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采用选择激发的实验手段,在混晶GaAs1-xPx∶N(x=0.88)的光致发光谱中观察到NN1对束缚激子发光的声子伴线.通过荧光谱线窄化效应,在发光谱中得到与GaP∶N低温光致发光谱中A线相似的NN1线的声子伴线精细结构,其中包括TA,LA,LO等声子伴线.这个结果在实验上有力地证实了在混晶GaAs1-xPx∶N中的确存在着NN1发光中心. 相似文献
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采用选择激发的实验手段,在混晶GaAs1-xPx;N的光致发光谱中观察2到NN1对束缚激子发光的声子伴线。通过荧光谱线窄化效应,在发光谱中得到了GaP:N低温光致发光谱中A线相似的NN1线的声子伴线精细结构,其中包括TA,LA,LO等声子伴线。 相似文献
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Molecular emission from single-bubble sonoluminescence 总被引:5,自引:0,他引:5
Ultrasound can drive a single gas bubble in water into violent oscillation; as the bubble is compressed periodically, extremely short flashes of light (about 100 ps) are generated with clock-like regularity. This process, known as single-bubble sonoluminescence, gives rise to featureless continuum emission in water (from 200 to 800 nm, with increasing intensity into the ultraviolet). In contrast, the emission of light from clouds of cavitating bubbles at higher acoustic pressures (multi-bubble sonoluminescence) is dominated by atomic and molecular excited-state emission at much lower temperatures. These observations have spurred intense effort to uncover the origin of sonoluminescence and to generalize the conditions necessary for its creation. Here we report a series of polar aprotic liquids that generate very strong single-bubble sonoluminescence, during which emission from molecular excited states is observed. Previously, single-bubble sonoluminescence from liquids other than water has proved extremely elusive. Our results give direct proof of the existence of chemical reactions and the formation of molecular excited states during single-bubble cavitation, and provide a spectroscopic link between single- and multi-bubble sonoluminescence. 相似文献
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从Keller-Miksis方程出发,推导出声致发光气泡半径微分方程,通过数值计算,计算出不同驱动声压,不同驱动声压频率下的气泡半径,讨论了驱动声压,驱动声压频率与声致发光气泡半径的关系,得到理论计算结果与实验数据很好的吻合. 相似文献
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新型双发色团固体激光染料的荧光性能 总被引:1,自引:0,他引:1
合成了带可聚合双键的若丹明,1,8-萘酰亚胺衍牲单体,并将它们与甲基丙烯酸甲酯共获得一系列双发色团共聚物。测定了其中各个单体的含量以及平均分子量。其吸收光谱显示,在基态下共聚物中两个发色团单体之间没有相互作用或作用很小。然而,在荧光光谱中发现某些共的中其N-AE部分荧光部分猝灭,而其R部分荧光增强,说明这些共聚物中存在着有效的分子内单线态-单线态能量传递现象。 相似文献
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合成了Eu(TTA)4Rh6G三元配合物(TTA:2-噻吩甲酰三氟丙酮;Rh6G:Rhodamine6G).对该配合物作了元素分析,DTA-TG分析和电导分析,测定了它的IR和UV吸收光谱,确定其化学组成为Eu:TTA:Rh6G=1:4:1,为离子缔合型.它的不同有机溶剂的溶液,在365nmUV灯照射下均能发出较强的荧光.其甲醇溶液和固态荧光光谱的最大发射峰分别为560.5nm和627.5nm. 相似文献
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气体性质对单泡声致发光平衡参数空间的影响 总被引:2,自引:2,他引:0
构造了一个描述气泡宏观运动的均匀非绝热模型,结合气泡的平衡机制,分析了空气和惰性气体的各种特性对单泡声致发光的平衡参数空间的影响.发现气体性质通过对平衡参数空间的影响对单泡声致发光起着重要作用.其中热传导系数起着主要作用,它的减小将导致气泡的平衡半径与压缩比增大,并导致发光亮度的增强. 相似文献
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LIANG Yue CHEN WeiZhong XU XingHua XU JunFeng 《科学通报(英文版)》2007,52(24):3313-3318
Based on a series of spectral measurements of sonoluminescence, this paper investigates parametric dependence of the line emissions in single bubble sonoluminescence (SBSL) and multi-bubble sonoluminescence (MBSL). The experiments show that the intensities of the OH* radical line, the sodium line and the noble gas lines in SBSL are relevant to the driving pressure of the acoustic field and the concentration of the noble gases dissolved in host liquids. The intensity of line emissions in total spectrum increases with the decreasing driving pressure and the increasing concentration of noble gases. Parametric dependence of line emissions in MBSL consists with that in SBSL. Line emissions in sonoluminescence should correspond to lower temperature inside the bubbles. SBSL and MBSL share the same spectral structure, and the difference between them found by previous experiments should result from the different temperatures inside bubbles. 相似文献
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空化气泡发光机理 总被引:2,自引:0,他引:2
安宇 《中国科学:物理学 力学 天文学》2011,(4):343-349
介绍了单气泡声致发光现象的主要研究进展,总结了理论计算研究结果.通过求解流体力学方程组等比较完全的数值计算,发现空化气泡发光机理就是高温、高压和高密度的气体发光,因气泡达到的温度不同,有时原子或分子线谱贡献占优势,有时连续谱占主导.通过研究单气泡形状不稳定性,发现声压的非球对称微小偏离导致驱动声压上限. 相似文献
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The energy efficiency of formation of photons, radicals and ions during single-bubble cavitation 总被引:6,自引:0,他引:6
It is extremely difficult to perform a quantitative analysis of the chemistry associated with multibubble cavitation: unknown parameters include the number of active bubbles, the acoustic pressure acting on each bubble and the bubble size distribution. Single-bubble sonoluminescence (characterized by the emission of picosecond flashes of light) results from nonlinear pulsations of an isolated vapour-gas bubble in an acoustic field. Although the latter offers a much simpler environment in which to study the chemical activity of cavitation, quantitative measurements have been hindered by the tiny amount of reacting gas within a single bubble (typically <10(-13) mol). Here we demonstrate the existence of chemical reactions within a single cavitating bubble, and quantify the sources of energy dissipation during bubble collapse. We measure the yields of nitrite ions, hydroxyl radicals and photons. The energy efficiency of hydroxyl radical formation is comparable to that in multibubble cavitation, but the energy efficiency of light emission is much higher. The observed rate of nitrite formation is in good agreement with the calculated diffusion rate of nitrogen into the bubble. We note that the temperatures attained in single-bubble cavitation in liquids with significant vapour pressures will be substantially limited by the endothermic chemical reactions of the polyatomic species inside the collapsing bubble. 相似文献