The atmospheric temperatures over Olympus Mons on Mars: An atmospheric hot ring

We study the thermal fields over Olympus Mons separating seasons (northern spring and summer against southern spring and summer) and local time observations (day side versus night side). Temperature vertical profiles retrieved from Planetary Fourier Spectrometer on board Mars Express (PFS-MEX) data have been used. In many orbits (running north to south along a meridian) passing over the top of the volcano there is evidence of a hot air on top of the volcano, of two enhancement of the air temperature both north and south of it and in between a collar of air that is colder than nearby at low altitudes, and warmer than nearby at high altitudes. Mapping together many orbits passing over or near the volcano we find that the hot air has the tendency to form an hot ring around it. This hot structure occurs mostly between LT = 10.00 and 15.00 and during the northern summer. Distance of the hot structure from the top of the volcano is about 600 km (10° of latitude). The hot atmospheric region is 300-420 km (5-7°) wide. Hot ring temperature contrasts of about 40 K occur at 2 km above the surface and decrease to 20 K at 5 km and to 10 K at 10 km. The atmospheric circulation over an area of 40° × 40° (latitudes and longitudes) is affected by the topography and the presence of Olympus Mons (−133°W, 18°N). We discuss also the thermal stability of the atmosphere over the selected area using the potential temperatures. The temperature field over the top of the volcano shows unstable atmosphere within 10 km from the surface. Finally, we interpret the hot temperatures around volcano as an adiabatic compression of down-welling branch coming from over the top of volcano.Different air temperature profiles are observed in the same seasons during the night, or in different seasons. In northern spring-summer during the night the isothermal contours do not show the presence of the volcano until we reach close to the surface very much, where a thermal inversion is observed. The surface temperature shows higher values (by 10 K) in correspondence of the scarp (an abrupt altimetry variation of roughly 5 km) on south (6°N) and north (30°N) sides of volcano. During the southern spring-summer, on the contrary the isothermal curves run parallel to the surface even on top the volcano, just like the GCM have predicted.     

Further observations of regional dust storms and baroclinic eddies in the northern hemisphere of Mars

We have investigated the near-surface meteorology in the northern hemisphere of Mars through detailed analysis of data obtained with Mars Global Surveyor in January-August 2005. The season in the northern hemisphere ranged from midsummer through winter solstice of Mars Year (MY) 27. We examined composite, wide-angle images from the Mars Orbiter Camera and compiled a catalog of the dust storms that occurred in this interval. As in previous martian years, activity in the northern hemisphere was dominated by regional “flushing” dust storms that sweep southward through the major topographic basins, most frequently in Acidalia Planitia. We also used atmospheric profiles retrieved from radio occultation experiments to characterize eddy activity near the surface at high northern latitudes. There are strong correlations between the two sets of observations, which allowed us to identify three factors that influence the timing and location of the regional dust storms: (1) transitions among baroclinic wave modes, which strongly modulate the intensity of meridional winds near the surface, (2) storms zones, which impose strong zonal variations on the amplitude of some baroclinic eddies, and (3) stationary waves, which further modulate the wind field near the surface. The flushing dust storms ceased abruptly in midautumn, possibly in response to source depletion, CO₂ condensation, a shift in the period of the baroclinic eddies, and changes in the tidal wind field near the surface. Our results extend the meteorological record of the northern hemisphere, substantiate the findings of previous investigations, and further illuminate the climatic impact of baroclinic eddies.     

Convective vortices on Mars: a reanalysis of Viking Lander 2 meteorological data, sols 1-60

Dust devil data from Mars is limited by a lack of data relating to diurnal dust devil behaviour. Previous work looking at the Viking Lander meteorological data highlighted seasonal changes in temporal occurrence of dust devils and gave an indication of typical dust devil diameter, size, and internal dynamics. The meteorological data from Viking Lander 2 for sols 1 to 60 have been revisited to provide detailed diurnal dust devil statistics. Results of our analysis show that the Viking Lander 2 experienced a possible 38 convective vortices in the first 60 sols of its mission with a higher occurrence in the morning compared to Earth, possibly as a result of turbulence generated by the Lander body. Dust devil events have been categorised by statistical confidence and intensity. Some initial analysis and discussion of the results is also presented. Assuming a similar dust loading to the vortices seen by Mars Pathfinder, it is estimated that the amount of dust lofted in the locality of the Lander is approximately 800 ± 10 kgsol⁻¹km⁻².     

Estimates of gravity wave drag on Mars: Indication of a possible lower thermospheric wind reversal

Spectral gravity wave parameterization suitable for planetary thermospheres applied to wind and temperature from Mars Climate Database reveals enormously strong drag incompatible with the wind distribution. It points out to a possible wind reversal in the 110-140 km layer similar to the one in the Earth’s lower thermosphere.     

Amazonian northern mid-latitude glaciation on Mars: A proposed climate scenario

Recent geological observations in the northern mid-latitudes of Mars show evidence for past glacial activity during the late Amazonian, similar to the integrated glacial landsystems in the Dry Valleys of Antarctica. The large accumulation of ice (many hundreds of meters) required to create the observed glacial deposits points to significant atmospheric precipitation, snow and ice accumulation, and glacial flow. In order to understand the climate scenario required for these conditions, we used the LMD (Laboratoire de Météorologie Dynamique) Mars GCM (General Circulation Model), which is able to reproduce the present-day water cycle, and to predict past deposition of ice consistent with geological observations in many cases. Prior to this analysis, however, significant mid-latitude glaciation had not been simulated by the model, run under a range of parameters.In this analysis, we studied the response of the GCM to a wider range of orbital configurations and water ice reservoirs, and show that during periods of moderate obliquity (? = 25-35°) and high dust opacity (τ_dust = 1.5-2.5), broad-scale glaciation in the northern mid-latitudes occurs if water ice deposited on the flanks of the Tharsis volcanoes at higher obliquity is available for sublimation. We find that high dust contents of the atmosphere increase its water vapor holding capacity, thereby moving the saturation region to the northern mid-latitudes. Precipitation events are then controlled by topographic forcing of stationary planetary waves and transient weather systems, producing surface ice distribution and amounts that are consistent with the geological record. Ice accumulation rates of ∼10 mm yr⁻¹ lead to the formation of a 500-1000 m thick regional ice sheet that will produce glacial flow patterns consistent with the geological observations.     

Dust devil sediment flux on Earth and Mars: Laboratory simulations

Laboratory simulations using the Arizona State University Vortex Generator (ASUVG) were run to simulate sediment flux in dust devils in terrestrial ambient and Mars-analog conditions. The objective of this study was to measure vortex sediment flux in the laboratory to yield estimations of natural dust devils on Earth and Mars, where all parameters may not be measured. These tests used particles ranging from 2 to 2000 μm in diameter and 1300 to 4800 kg m⁻³ in density, and the results were compared with data from natural dust devils on Earth and Mars. Typically, the cores of dust devils (regardless of planetary environment) have a pressure decrease of ∼0.1-1.5% of ambient atmospheric pressure, which enhances the lifting of particles from the surface. Core pressure decreases in our experiments ranged from ∼0.01% to 5.00% of ambient pressure (10 mbar Mars cases and 1000 mbar for Earth cases) corresponding to a few tenths of a millibar for Mars cases and a few millibars for Earth cases. Sediment flux experiments were run at vortex tangential wind velocities of 1-45 m s⁻¹, which typically correspond to ∼30-70% above vortex threshold values for the test particle sizes and densities. Sediment flux was determined by time-averaged measurements of mass loss for a given vortex size. Sediment fluxes of ∼10⁻⁶-10⁰ kg m⁻² s⁻¹ were obtained, similar to estimates and measurements for fluxes in dust devils on Earth and Mars. Sediment flux is closely related to the vortex intensity, which depends on the strength of the pressure decrease in the core (ΔP). This study found vortex size is less important for lifting materials because many different diameters can have the same ΔP. This finding is critical in scaling the laboratory results to natural dust devils that can be several orders of magnitude larger than the laboratory counterparts.     

Scale-dependent infrared radiative damping rates on Mars and their role in the deposition of gravity-wave momentum flux

Using a Curtis-matrix model of 15 μm CO₂ radiative cooling rates for the martian atmosphere, we have computed vertical scale-dependent IR radiative damping rates from 0 to 200 km altitude over a broad band of vertical wavenumbers ∣m∣ = 2π(1-500 km)⁻¹ for representative meteorological conditions at 40°N and average levels of solar activity and dust loading. In the middle atmosphere, infrared (IR) radiative damping rates increase with decreasing vertical scale and peak in excess of 30 days⁻¹ at ∼50-80 km altitude, before gradually transitioning to scale-independent rates above ∼100 km due to breakdown of local thermodynamic equilibrium. We incorporate these computed IR radiative damping rates into a linear anelastic gravity-wave model to assess the impact of IR radiative damping, relative to wave breaking and molecular viscosity, in the dissipation of gravity-wave momentum flux. The model results indicate that IR radiative damping is the dominant process in dissipating gravity-wave momentum fluxes at ∼0-50 km altitude, and is the dominant process at all altitudes for gravity waves with vertical wavelengths ?10-15 km. Wave breaking becomes dominant at higher altitudes only for “fast” waves of short horizontal and long vertical wavelengths. Molecular viscosity plays a negligible role in overall momentum flux deposition. Our results provide compelling evidence that IR radiative damping is a major, and often dominant physical process controlling the dissipation of gravity-wave momentum fluxes on Mars, and therefore should be incorporated into future parameterizations of gravity-wave drag within Mars GCMs. Lookup tables for doing so, based on the current computations, are provided.     

Extension of atmospheric dust loading to high altitudes during the 2001 Mars dust storm: MGS TES limb observations

Mars Global Surveyor (MGS) visible (solarband bolometer) and thermal infrared (IR) spectral limb observations from the Thermal Emission Spectrometer (TES) support quantitative profile retrievals for dust opacity and particle sizes during the 2001 global dust event on Mars. The current analysis considers the behavior of dust lifted to altitudes above 30 km during the course of this storm; in terms of dust vertical mixing, particle sizes, and global distribution. TES global maps of visible (solarband) limb brightness at 60 km altitude indicate a global-scale, seasonally evolving (over 190-240° solar longitudes, L_S) longitudinal corridor of vertically extended dust loading (which may be associated with a retrograde propagating, wavenumber 1 Rossby wave). Spherical radiative transfer analysis of selected limb profiles for TES visible and thermal IR radiances provide quantitative vertical profiles of dust opacity, indicating regional conditions of altitude-increasing dust mixing ratios. Observed infrared spectral dependences and visible-to-infrared opacity ratios of dust scattering over 30-60 km altitudes indicate particle sizes characteristic of lower altitudes (cross-section weighted effective radius, ), during conditions of significant dust transport to these altitudes. Conditions of reduced dust loading at 30-60 km altitudes present smaller dust particle sizes . These observations suggest rapid meridional transport at 30-80 km altitudes, with substantial longitudinal variation, of dust lifted to these altitudes over southern hemisphere atmospheric regions characterized by extraordinary (m/s) vertical advection velocities. By L_S=230° dust loading above 50 km altitudes decreased markedly at southern latitudes, with a high altitude (60-80 km) haze of fine (likely) water ice particles appearing over 10°S-40°N latitudes.     

Evidence for paleolakes in Erythraea Fossa, Mars: Implications for an ancient hydrological cycle

There is now widespread agreement that the surface of Mars underwent some degree of fluvial modification, but there is not yet full understanding of its surface hydrological cycle and the nature of standing bodies of water, rivers, and precipitation that affected its surface. In this paper we explore Erythraea Fossa (31.5 W, 27.3 S), a graben adjacent to Holden crater, which exhibits strong evidence that it once housed a chain of three lakes, had overland water flow, and was subject to precipitation. The inlet valley, outlet valley, and fan morphologies in the paleolakes are used to qualitatively discern the hydrologic history of the paleolakes; based on topography constraints, the three basins combined once held 56 km³ of water. Depositional features within the basins that change with drainage area and nearby valleys that start near drainage divides indicate that the paleolakes may have been fed by precipitation driven runoff. This suggests the presence of an atmosphere, at least locally, that was capable of supporting a hydrological cycle.     

THEMIS-VIS observations of clouds in the martian mesosphere: Altitudes, wind speeds, and decameter-scale morphology

We present measurements of the altitude and eastward velocity component of mesospheric clouds in 35 imaging sequences acquired by the Mars Odyssey (ODY) spacecraft’s Thermal Emission Imaging System visible imaging subsystem (THEMIS-VIS). We measure altitude by using the parallax drift of high-altitude features, and the velocity by exploiting the time delay in the THEMIS-VIS imaging sequence.We observe two distinct classes of mesospheric clouds: equatorial mesospheric clouds observed between 0° and 180° L_s; and northern mid-latitude clouds observed only in twilight in the 200–300° L_s period. The equatorial mesospheric clouds are quite rare in the THEMIS-VIS data set. We have detected them in only five imaging sequences, out of a total of 2048 multi-band equatorial imaging sequences. All five fall between 20° south and 0° latitude, and between 260° and 295° east longitude. The mid-latitude mesospheric clouds are apparently much more common; for these we find 30 examples out of 210 northern winter mid-latitude twilight imaging sequences. The observed mid-latitude clouds are found, with only one exception, in the Acidalia region, but this is quite likely an artifact of the pattern of THEMIS-VIS image targeting. Comparing our THEMIS-VIS images with daily global maps generated from Mars Orbiter Camera Wide Angle (MOC-WA) images, we find some evidence that some mid-latitude mesospheric cloud features correspond to cloud features commonly observed by MOC-WA. Comparing the velocity of our mesospheric clouds with a GCM, we find good agreement for the northern mid-latitude class, but also find that the GCM fails to match the strong easterly winds measured for the equatorial clouds.Applying a simple radiative transfer model to some of the equatorial mesospheric clouds, we find good model fits in two different imaging sequences. By using the observed radiance contrast between cloud and cloud-free regions at multiple visible-band wavelengths, these fits simultaneously constrain the optical depths and particles sizes of the clouds. The particle sizes are constrained primarily by the relative contrasts at the available wavelengths, and are found to be quite different in the two imaging sequences: r_eff = 0.1 μm and r_eff = 1.5 μm. The optical depths (constrained by the absolute contrasts) are substantial: 0.22 and 0.5, respectively. These optical depths imply a mass density that greatly exceeds the saturated mass density of water vapor at mesospheric temperatures, and so the aerosol particles are probably composed mainly of CO₂ ice. Our simple radiative transfer model is not applicable to twilight, when the mid-latitude mesospheric clouds were observed, and so we leave the properties of these clouds as a question for further work.     

Antarctic dry valleys: Microclimate zonation, variable geomorphic processes, and implications for assessing climate change on Mars

The Antarctic Dry Valleys (ADV) are generally classified as a hyper-arid, cold-polar desert. The region has long been considered an important terrestrial analog for Mars because of its generally cold and dry climate and because it contains a suite of landforms at macro-, meso-, and microscales that closely resemble those occurring on the martian surface. The extreme hyperaridity of both Mars and the ADV has focused attention on the importance of salts and brines on soil development, phase transitions from liquid water to water ice, and ultimately, on process geomorphology and landscape evolution at a range of scales on both planets. The ADV can be subdivided into three microclimate zones: a coastal thaw zone, an inland mixed zone, and a stable upland zone; zones are defined on the basis of summertime measurements of atmospheric temperature, soil moisture, and relative humidity. Subtle variations in these climate parameters result in considerable differences in the distribution and morphology of: (1) macroscale features (e.g., slopes and gullies); (2) mesoscale features (e.g., polygons, including ice-wedge, sand-wedge, and sublimation-type polygons, as well as viscous-flow features, including solifluction lobes, gelifluction lobes, and debris-covered glaciers); and (3) microscale features (e.g., rock-weathering processes/features, including salt weathering, wind erosion, and surface pitting). Equilibrium landforms are those features that formed in balance with environmental conditions within fixed microclimate zones. Some equilibrium landforms, such as sublimation polygons, indicate the presence of extensive near-surface ice; identification of similar landforms on Mars may also provide a basis for detecting the location of shallow ice. Landforms that today appear in disequilibrium with local microclimate conditions in the ADV signify past and/or ongoing shifts in climate zonation; understanding these shifts is assisting in the documentation of the climate record for the ADV. A similar type of landform analysis can be applied to the surface of Mars where analogous microclimates and equilibrium landforms occur (1) in a variety of local environments, (2) in different latitudinal bands, and (3) in units of different ages. Documenting the nature and evolution of the ADV microclimate zones and their associated geomorphic processes is helping to provide a quantitative framework for assessing the evolution of climate on Mars.     

Interferometric millimeter observations of water vapor on Mars and comparison with Mars Express measurements

We present interferometric mapping of the 225.9-GHz HDO and 203.4-GHz lines on Mars obtained with the IRAM Plateau de Bure facility (PdBI). The observations were performed during martian year 28 (MY28), at L_s=320.3° for the HDO line, and at L_s=324.3° for the line. The HDO line is detected at the eastern (morning) and western (evening) limbs of the northern hemisphere, corresponding to a water column density in the range 3-6 pr.-μm. The line is not detected, which is compatible with the column densities derived from the HDO line. Quasi-simultaneous far infrared measurements obtained by the Planetary Fourier Spectrometer (PFS) onboard the Mars Express spacecraft confirm our PdBI results, yielding a 5±1 pr.-μm meridionally constant water column abundance.Such a low water abundance during the southern mid-autumn of MY28 does not correspond to the standard martian climatology as observed during the previous years. It was however already retrieved from near-infrared observations performed by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) onboard the Mars Reconnaissance Orbiter spacecraft [Smith, M.D., Wolff, M.J., Clancy, R.T., Murchie, S.L. 2009. CRISM observations of water vapor and carbon monoxide. J. Geophys. Res. 114, doi: 10.1029/2008JE003288]. Our observations thus confirm that the planet-encircling dust storm that occurred during MY28 significantly affected the martian water cycle. Our observations also demonstrate the usefulness of interferometric submillimeter observations to survey the martian water cycle from ground-based facilities.     

The nature of coarse-grained crystalline hematite and its implications for the early environment of Mars

The Thermal Emission Spectrometer (TES) on the Mars Global Surveyor spacecraft has detected deposits of coarse-grained, gray crystalline hematite in Sinus Meridiani, Aram Chaos, and Vallis Marineris. We argue that the key to the origin of gray hematite is that it requires crystallization at temperatures in excess of about 100 °C. We discuss thermal crystallization (1) as diagenesis at a depth of a few kilometers of sediments originally formed in low-temperature waters, or (2) as precipitation from hydrothermal solution. In Aram Chaos, a combination of TES data, Mars Orbiter Camera images, and Mars Orbiter Laser Altimeter (MOLA) topography suggests that high concentrations of hematite were formed in planar strata and have since been exposed by erosion of an overlying light-toned, caprock. Lesser concentrations of hematite are found adjacent to these strata at lower elevations, which we interpret as perhaps due to accumulation from physical weathering. The topography and the collapsed nature of the chaotic terrain favor a hydrothermally charged aquifer as the original setting where the hematite formed. Concentration of iron into such an ore-like body would be chemically favored by saline, Cl-rich hydrothermal fluids. An alternative sedimentary origin requires post-depositional burial to a depth of ∼3-5 km to induce thermally driven recrystallization of fine-grained iron oxides to coarse-grained hematite. This depth of burial and re-exposure is difficult to reconcile with commonly inferred martian geological processes. However, shallow burial accompanied by post-burial hydrothermal activity remains plausible. When the hematite regions originally formed, redox balance requires that much hydrogen must have been evolved to complement the extensive oxidation. Finally, we suggest that the coexistence of several factors required to form the gray hematite deposits would have produced a favorable environment for primitive life on early Mars, if it ever existed. These factors include liquid water, abundant electron donors in the form of H₂, and abundant electron acceptors in the form of Fe³⁺.     

A lake in Uzboi Vallis and implications for Late Noachian-Early Hesperian climate on Mars

Uzboi Vallis (centered at ∼28°S, 323°E) is ∼400 km long and comprises the southernmost segment of the northward-draining Uzboi-Ladon-Morava (ULM) meso-scale outflow system that emerges from Argyre basin. Bond and Holden craters blocked the valley to the south and north, respectively, forming a Late Noachian-to-Hesperian paleolake basin that exceeded 4000 km³. Limited CRISM data suggest lake deposits in Uzboi and underlying basin floor incorporate relatively more Mg-clays and more Fe-clays, respectively. The short-lived lake overflowed and breached Holden crater’s rim at an elevation of −350 m and rapidly drained into the crater. Fan deltas in Holden extend 25 km from the breach and incorporate meter-sized blocks, and longitudinal grooves along the Uzboi basin floor are hundreds of meters long and average 60 m wide, suggesting high-discharge drainage of the lake. Precipitation-derived runoff rather than regional groundwater or overflow from Argyre dominated contributions to the Uzboi lake, although the failure of most tributaries to respond to a lowering of base level indicates their incision largely ended when the lake drained. The Uzboi lake may have coincided with alluvial and/or lacustrine activity in Holden, Eberswalde, and other craters in southern Margaritifer Terra, where fluvial/lacustrine activity may have required widespread, synoptic precipitation (rain or snow), perhaps associated with an ephemeral, global hydrologic system during the Late Noachian into the Hesperian on Mars.     

Keys to gully formation processes on Mars: Relation to climate cycles and sources of meltwater

Advances in dating gullies on Mars using superposition relationships and a stratigraphic marker horizon link gully chronostratigraphy to recent climate cycles. New observations of gully morphology show the close association of gully source regions, channels, and fan deposits with well-documented ice-rich latitude-dependent mantle deposits, the deposition of which is interpreted to be coincident with recent ice ages. On the basis of these close correlations, we interpret the formative processes for mid-latitude gullies to involve melting of these ice-rich mantling deposits and the generation of an aqueous phase leading to fluvial activity. Continued monitoring of gullies by spacecraft in the current “interglacial” climate period (∼0.4 Ma to the present) will permit assessment of changing rates and styles of gully activity in the now largely depleted source areas.     

Hydrogen peroxide on Mars: evidence for spatial and seasonal variations

Hydrogen peroxide (H₂O₂) has been suggested as a possible oxidizer of the martian surface. Photochemical models predict a mean column density in the range of 10¹⁵-10¹⁶ cm⁻². However, a stringent upper limit of the H₂O₂ abundance on Mars (9×10¹⁴ cm⁻²) was derived in February 2001 from ground-based infrared spectroscopy, at a time corresponding to a maximum water vapor abundance in the northern summer (30 pr. μm, Ls=112°). Here we report the detection of H₂O₂ on Mars in June 2003, and its mapping over the martian disk using the same technique, during the southern spring (Ls=206°) when the global water vapor abundance was ∼10 pr. μm. The spatial distribution of H₂O₂ shows a maximum in the morning around the sub-solar latitude. The mean H₂O₂ column density (6×10¹⁵ cm⁻²) is significantly greater than our previous upper limit, pointing to seasonal variations. Our new result is globally consistent with the predictions of photochemical models, and also with submillimeter ground-based measurements obtained in September 2003 (Ls=254°), averaged over the martian disk (Clancy et al., 2004, Icarus 168, 116-121).     

Evidence for weathering on early Mars from a comparison with terrestrial weathering profiles

Phyllosilicates on Mars are widespread in the ancient crust suggesting the presence of liquid water at the martian surface and therefore warmer conditions during its early history. However, the role of the ancient climate in the alteration process, which produced these phyllosilicates, remains under debate, because similar mineral assemblages can be produced by hydrothermal alteration at depth. This paper focuses on the origin of coincident outcrops of Fe/Mg bearing phyllosilicates and Al-bearing phyllosilicates, which are observed in several regions of Mars. We performed a detailed mineralogical comparison between a section in Nili Fossae, Mars, and a weathering profile located at Murrin Murrin, Western Australia. The Murrin Murrin profile is developed in Archaean serpentinized peridotite massifs over a ∼40 m thick sequence. It has three alteration zones: the serpentine mineral saprolite is found at the bottom, immediately overlain by Fe/Mg-bearing smectites and then Al-bearing phyllosilicates (kaolinite) mixed with iron hydroxides. This example illustrates how Al-dominated minerals can derive from the alteration of initially Al-poor ultramafic rocks by the intense leaching of Mg²⁺. This mineralogical sequence is very similar to that detected locally in Nili Fossae by orbital spectroscopy. By analogy, we propose that the mineral assemblage detected on Mars is the result of long-term weathering, and thus could be the best evidence of past weathering as a direct result of a climate significantly warmer than at present.     

Residual south polar cap of Mars: Stratigraphy, history, and implications of recent changes

The residual south polar cap (RSPC) of Mars includes a group of different depositional units of CO₂ ice undergoing a variety of erosional processes. Complete summer coverage of the RSPC by ∼6-m/pixel data of the Context Imager (CTX) on Mars Reconnaissance Orbiter (MRO) has allowed mapping and inventory of the units in the RSPC. Unit maps and estimated thicknesses indicate the total volume of the RSPC is currently <380 km³, and represents less than 3% of the total mass of the current Mars atmosphere. Scarp retreat rates in the CO₂ ice derived from comparison of High Resolution Imaging Science Experiment (HiRISE) data with earlier images are comparable to those obtained for periods up to 3 Mars years earlier. These rates, combined with sizes of depressions suggest that the oldest materials were deposited more than 125 Mars years ago. Most current erosion is by backwasting of scarps 1-12 m in height. This backwasting is initiated by a series of scarp-parallel fractures. In the older, thicker unit these fractures form about every Mars year; in thinner, younger materials they form less frequently. Some areas of the older, thicker unit are lost by downwasting rather than by the scarp retreat. A surprising finding from the HiRISE data is the scarcity of visible layering of RSPC materials, a result quite distinct from previous interpretations of layers in lower resolution images. Layers ∼0.1 m thick are exposed on the upper surfaces of some areas, but their timescale of deposition is not known. Late summer albedo changes mapped by the CTX images indicate local recycling of ice, although the amounts may be morphologically insignificant. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) data show that the primary material of all the different forms of the RSPC is CO₂ ice with only small admixtures of water ice and dust.     

Adsorptive fractionation of HDO on JSC MARS-1 during sublimation with implications for the regolith of Mars

A chamber was constructed to simulate the boundary between the ice table, regolith and atmosphere of Mars and to examine fractionation between H₂O and HDO during sublimation under realistic martian conditions of temperature and pressure. Thirteen experimental runs were conducted with regolith overlying the ice. The thickness and characteristic grain size of the regolith layer as well as the temperature of the underlying ice was varied. From these runs, values for the effective diffusivity, taking into account the effects of adsorption, of the regolith were derived. These effective diffusivities ranged from 1.8 × 10⁻⁴ m² s⁻¹ to 2.2 × 10⁻³ m² s⁻¹ for bare ice and from 2.4 × 10⁻¹¹ m² s⁻¹ to 2.0 × 10⁻⁹ m² s⁻¹ with an adsorptive layer present. From these, latent heats of adsorption of 8.6 ± 2.6 kJ mol⁻¹ and 9.3 ± 2.8 kJ mol⁻¹ were derived at ice-surface temperatures above 223 ± 8 K and 96 ± 28 kJ mol⁻¹ and 104 ± 31 kJ mol⁻¹ respectively for H₂O and HDO were derived at colder temperatures. For temperatures below 223 K, the effective diffusivity of HDO was found to be lower than the diffusivity of H₂O by 40% on average, suggesting that the regolith was adsorptively fractionating the sublimating gas with a fractionation factor of 1.96 ± 0.74. Applying these values to Mars predicts that adsorbed water on the regolith is enriched in HDO compared to the atmosphere, particularly where the regolith is colder. Based on current observations, the D/H ratio of the regolith may be as high as 21 ± 8 times VSMOW at 12°S and L_S = 357° if the regolith is hydrated primarily by the atmosphere, neglecting any hydration from subsurface ice.     

Seasonal variations of photochemical tracers at low and middle latitudes on Mars: Observations and models

Mars Express observations give ozone abundances that are smaller than those from the ground-based infrared heterodyne and HST observations at low and middle latitudes. Both ground-based and Mars Express observations of the O₂ dayglow at 1.27 μm, which originates from photolysis of ozone, are in mutual agreement after correction for the local time variability. Therefore a problem appears: whether the MEX ozone data are compatible with (1) the observed O₂ dayglow intensities and (2) the photochemical model by Krasnopolsky [Krasnopolsky, V.A., 2006. Icarus 185, 153-170] within uncertainties of its reaction rate coefficients. That model involves heterogeneous loss of H₂O₂ on water ice and agrees with the observations of the O₂ dayglow, H₂O₂, and the ground-based and HST ozone. The answers are ‘yes’ to both questions. A version of the model is given that fits the MEX ozone as well as the observed O₂ dayglow and H₂O₂. Laboratory studies of two reaction rate coefficients could indicate a preferable version of the model and a preferable set of the ozone data (MEX versus the ground-based and HST). The predicted seasonal behavior of H₂O₂ is different from that in the model by Lefevre et al. [Lefevre, F., Bertaux, J.L., Clancy, R.T., Encrenaz, T., Fast, K., Forget, F., Lebonnois, S., Montmessin, F., Perrier, S., 2008. Nature 454, 971-975], and future observations may help to choose between the models.