On the HCN and CO2 abundance and distribution in Jupiter's stratosphere

Observations of Jupiter by Cassini/CIRS, acquired during the December 2000 flyby, provide the latitudinal distribution of HCN and CO₂ in Jupiter's stratosphere with unprecedented spatial resolution and coverage. Following up on a preliminary study by Kunde et al. [Kunde, V.G., and 41 colleagues, 2004. Science 305, 1582-1587], the analysis of these observations leads to two unexpected results (i) the total HCN mass in Jupiter's stratosphere in 2000 was (6.0±1.5)×¹⁰¹³ g, i.e., at least three times larger than measured immediately after the Shoemaker-Levy 9 (SL9) impacts in July 1994 and (ii) the latitudinal distributions of HCN and CO₂ are strikingly different: while HCN exhibits a maximum at 45° S and a sharp decrease towards high Southern latitudes, the CO₂ column densities peak over the South Pole. The total CO₂ mass is (2.9±1.2)×¹⁰¹³ g. A possible cause for the HCN mass increase is its production from the photolysis of NH₃, although a problem remains because, while millimeter-wave observations clearly indicate that HCN is currently restricted to submillibar (∼0.3 mbar) levels, immediate post-impact infrared observations have suggested that most of the ammonia was present in the lower stratosphere near 20 mbar. HCN appears to be a good atmospheric tracer, with negligible chemical losses. Based on 1-dimensional (latitude) transport models, the HCN distribution is best interpreted as resulting from the combination of a sharp decrease (over an order of magnitude in Kyy) of wave-induced eddy mixing poleward of 40° and an equatorward transport with velocity. The CO₂ distribution was investigated by coupling the transport model with an elementary chemical model, in which CO₂ is produced from the conversion of water originating either from SL9 or from auroral input. The auroral source does not appear adequate to reproduce the CO₂ peak over the South Pole, as required fluxes are unrealistically high and the shape of the CO₂ bulge is not properly matched. In contrast, the CO₂ distribution can be fit by invoking poleward transport with a velocity and vigorous eddy mixing (). While the vertical distribution of CO₂ is not measured, the combined HCN and CO₂ results imply that the two species reside at different stratospheric levels. Comparing with the circulation regimes predicted by earlier radiative-dynamical models of Jupiter's stratosphere, and with inferences from the ethane and acetylene stratospheric latitudinal distribution, we suggest that CO₂ lies in the middle stratosphere near or below the 5-mbar level.     

Cassini CIRS retrievals of ammonia in Jupiter's upper troposphere

The zonal mean ammonia abundance on Jupiter between the 400- and 500-mbar pressure levels is inferred as a function of latitude from Cassini Composite Infrared Spectrometer data. Near the Great Red Spot, the ammonia abundance is mapped as a function of latitude and longitude. The Equatorial Zone is rich in ammonia, with a relative humidity near unity. The North and South Equatorial Belts are depleted relative to the Equatorial Zone by an order of magnitude. The Great Red Spot shows a local maximum in the ammonia abundance. Ammonia abundance is highly correlated with temperature perturbations at the same altitude. Under the assumption that anomalies in ammonia and temperature are both perturbed from equilibrium by vertical motion, we find that the adjustment time constant for ammonia equilibration is about one third of the radiative time constant.     

Wind variations in Jupiter's equatorial atmosphere: A QQO counterpart?

Jupiter's equatorial atmosphere, much like the Earth's, is known to show quasi-periodic variations in temperature, particularly in the stratosphere, but variations in other jovian atmospheric tracers have not been studied for any correlations to these oscillations. Data taken at NASA's Infrared Telescope Facility (IRTF) from 1979 to 2000 were used to obtain temperatures at two levels in the atmosphere, corresponding to the upper troposphere (250 mbar) and to the stratosphere (20 mbar). We find that the data show periodic signals at latitudes corresponding to the troposphere zonal wind jets, with periods ranging from 4.4 (stratosphere, 95% confidence at 4° S planetographic latitude) to 7.7 years (troposphere, 97% confidence at 6° N). We also discuss evidence that at some latitudes the troposphere temperature variations are out of phase from the stratosphere variations, even where no periodicity is evident. Hubble Space Telescope images were used, in conjunction with Voyager and Cassini data, to track small changes in the troposphere zonal winds from 20° N to 20° S latitude over the 1994-2000 time period. Oscillations with a period of 4.5 years are found near 7°-8° S, with 80-85% significance. Further, the strongest evidence for a QQO-induced tropospheric wind change tied to stratospheric temperature change occurs near these latitudes, though tropospheric temperatures show little periodicity here. Comparison of thermal winds and measured zonal winds for three dates indicate that cloud features at other latitudes are likely tracked at pressures that can vary by up to a few hundred millibar, but the cloud altitude change required is too large to explain the wind changes measured at 7° S.     

Jupiter's White Oval turns red

Jupiter's remaining White Oval changed color in late 2005 and became noticeably red in early 2006, as reported by amateur observers. We present wind and color analyses from high spatial resolution images taken with the Hubble Space Telescope Advanced Camera for Surveys in April 2006. These images suggest that the recent color change was tied to a strengthening of this storm, as implied by increased vorticity, causing it to become more like the Great Red Spot. From a historical perspective, the current activity may be consistent with the generation of new anticyclones at this latitude in the coming months and years.     

A new model of the hydrogen and helium-broadened microwave opacity of ammonia based on extensive laboratory measurements

Close to 2000 laboratory measurements of the microwave opacity and refractivity of gaseous NH₃ in an H₂/He atmosphere have been conducted in the 1.1-20 cm wavelength range (1.5-27 GHz) at pressures from 30 mbar to 12 bar and at temperatures from 184 to 450 K. The mole fraction of NH₃ ranged from 0.06 to 6% with some additional measurements of pure NH₃. The high accuracy of these results have enabled development of a new model for the opacity of NH₃ in a H₂/He atmosphere under jovian conditions. The model employs the Ben-Reuven lineshape applied to the published inversion line center frequencies and intensities of NH₃ (JPL Catalog—[Pickett, H.M., Poynter, R.L., Cohen, E.A., Delitsky, M.L., Pearson, J.C., Müller, H.S.P., 1998. J. Quant. Spectrosc. Radiat. Trans. 60, 883-890]) with empirically-fitted line parameters for H₂ and He broadening, and for the self-broadening of some previously unmeasured ammonia inversion lines. The new model for ammonia opacity will provide reliable results for temperatures from 150 to 500 K, at pressures up to 50 bar and at frequencies up to 40 GHz. These results directly impact the retrieval of jovian atmospheric constituent abundances from the Galileo Probe radio signal absorption measurements, from microwave emission measurements conducted with Earth-based radio telescopes and with the future NASA Juno mission, and studies of Saturn's atmosphere conducted with the Cassini Radio Science Experiment and the Cassini RADAR 2.1 cm passive radiometer.     

Transport of nonmethane hydrocarbons to Jupiter's troposphere by descent of smog particles

Ethane and other C₂ and C₃ nonmethane hydrocarbons were observed by the Galileo Probe Mass Spectrometer to have a deep minimum in mixing ratio near and below the tropopause, rising to much larger values at and below the 15 bar level. This minimum requires that these hydrocarbons condense on smog particles at low temperatures. The large amounts at deeper levels were produced in the pumping system of the instrument and any contribution from the ambient atmosphere cannot be resolved, although evaporation from the smog particles is proposed and incorporated in a model. In the stratosphere some of the ethane is released by photon-stimulated desorption. The other light nonmethane hydrocarbons are not modeled, but can be expected to show the same behavior as ethane.     

Gravity waves in Jupiter's equatorial clouds observed by the Galileo orbiter

A reanalysis of Galileo images of Jupiter's Equatorial Zone obtained in 1999 and 2001 reveals the presence of trains of cloud bands, probably generated by gravity waves, similar to those seen in Voyager 1 and 2 (1979) and New Horizons (2007) images. No such waves have been found in a similar analysis of the Cassini flyby (2000) dataset. We present the properties of these waves and discuss them in the context of previously proposed models and observations.     

EPIC simulations of the merger of Jupiter's White Ovals BE and FA: altitude-dependent behavior

Observations of the merger of Jupiter's White Ovals BE and FA show altitude-dependent behavior that we seek to capture in numerical simulations. In particular, it was observed that the upper portions of the vortices orbited each other before merging, but the lower portions translated into each other without orbiting, a phenomenon we term the pair-orbit vertical dichotomy. To reproduce this dichotomy in the EPIC model, it is sufficient to have (i) a decrease with altitude of the background zonal winds above the cloud level with a scale height of ∼2.4, (ii) a height scale of the winds inside the vortices that is the same or larger, and (iii) a maximum tangential velocity in each vortex of ∼100 m s⁻¹ or larger. Condition (i) is expected from thermal-wind analyses, (ii) is consistent with thermal-wind and Shoemaker-Levy 9 debris-trajectory analyses, and (iii) is consistent with cloud-top wind tracking. The model generally does not reproduce the dichotomy for vortices with smaller vertical extent or weaker circulations. Our simulated mergers correctly reproduce the observed ∼9° separation at which vortices start to orbit in the upper layers before they merge and the ∼70% area ratio of the final vortex BA to the sum of BE and FA.     

Velocity and vorticity measurements of Jupiter's Great Red Spot using automated cloud feature tracking

We have produced mosaics of the Great Red Spot (GRS) using images taken by the Galileo spacecraft in May 2000, and have measured the winds of the GRS using an automated algorithm that does not require manual cloud tracking. Our technique yields a high-density, regular grid of wind velocity vectors that is advantageous over a limited number of scattered wind vectors that result from manual cloud tracking. The high-velocity collar of the GRS is clearly seen from our velocity vector map, and highest wind velocities are measured to be around 170 m s⁻¹. The high resolution of the mosaics has also enabled us to map turbulent eddies inside the chaotic central region of the GRS, similar to those mapped by Sada et al. [Sada, P.V., Beebe, R.F., Conrath, B.J., 1996. Icarus 119, 311-335]. Using the wind velocity measurements, we computed particle trajectories around the GRS as well as maps of relative and absolute vorticities. We have discovered a narrow ring of cyclonic vorticity that surrounds the main anti-cyclonic high-velocity collar. This narrow ring appears to correspond to a ring surrounding the GRS that is bright in 5 μm [Terrile, R.J., Beebe, R.F., 1979. Science 204, 948-951]. It appears that this cyclonic ring is not a transient feature of the GRS, as we have discovered it in a re-analysis of Galileo data taken in 1996 first analyzed by Vasavada et al. [Vasavada, A.R., and 13 colleagues, 1998. Icarus 135, 265-275]. We also calculate how absolute vorticity changes as a function of latitude along a trajectory around the GRS and compare these measurements to similar ones performed by Dowling and Ingersoll [Dowling, T.E., Ingersoll, A.P., 1988. J. Atmos. Sci. 45, 1380-1396] using Voyager data. We show no dramatic evolution in the structure of the GRS since the Voyager era except for additional evidence for a counter-rotating GRS core, an increase in velocity in the main velocity collar, and an overall decrease in the length of the GRS.     

Jupiter's 24° N highest speed jet: Vertical structure deduced from nonlinear simulations of a large-amplitude natural disturbance

The evolution of a large-amplitude disturbance at cloud level in Jupiter's 24° N jet stream in 1990 is used to constrain the vertical structure of a realistic atmospheric model down to the 6 bar pressure level. We use the EPIC model (Dowling et al., 1998, The explicit planetary isentropic-coordinate (EPIC) atmospheric model, Icarus 132, 221-238) to perform long-term, three-dimensional, nonlinear simulations with a series of systematic variations in vertical structure and find that the details of the 1990 disturbance combine with the characteristics of the 24° N jet, the fastest on Jupiter, to yield a tight constraint on the solution space. The most important free parameters are the vertical dependence of the zonal-wind profile, and the thermal structure, below the cloud tops (p>0.7 bar) at the jet's central latitude. The temporal evolution of the disturbed cloud patterns, which spans more than 2 years, can be reproduced if the jet peak reaches ∼180 ms⁻¹ at the cloud level and increases to ∼210 ms⁻¹ at 1 bar and up to ∼240 ms⁻¹ at 6 bar; the observations were not reproduced for other configurations investigated. This trend is consistent with that measured by the Galileo Probe at 7° N; the implication is that this jovian jet extends well below the solar radiation penetration level situated near the 2 bar level.     

Jupiter's atmospheric temperatures: From Voyager IRIS to Cassini CIRS

Retrievals performed on Cassini Composite Infrared Spectrometer data obtained during the distant Jupiter flyby in 2000/2001 have been used to generate global temperature maps of the planet in the troposphere and stratosphere, but to higher latitudes than were shown previously by Flasar et al. [Flasar, F.M., 39 colleagues, 2004a. Nature 427, 132-135; Flasar, F.M., 44 colleagues, 2004b. Space Sci. Rev. 115, 169-297]. Similar retrievals were performed on Voyager 1 IRIS data to provide the first detailed IRIS map of the stratosphere, and high latitudes in the troposphere. Thermal winds were calculated for each data set and show strong vertical shears in the zonal winds at low latitudes, and meridional temperature gradients indicate the presence of circumpolar jets, as well. The temperatures retrieved from the two spacecraft were also compared with yearly ground-based data obtained over the intervening two decades. Tropospheric temperatures reveal gradual changes at low latitudes, with little obvious seasonal or short-term variation [Orton et al., 1994. Science 265, 625-631]. Stratospheric temperatures show much more complicated behavior over short timescales, consistent with quasi-quadrennial oscillations at low latitudes, as suggested in prior analyses of shorter intervals of ground-based data [Orton et al., 1991. Science 252, 537-542; Friedson, A.J., 1999. Icarus 137, 34-55]. A scaling analysis indicates that meridional motions, mechanically forced by wave or eddy convergence, play an important role in modulating the temperatures and winds in the upper troposphere and stratosphere on seasonal and shorter timescales. At latitudes away from the equator, the mechanical forcing can be derived simply from a temporal record of temperature and its vertical derivative. Ground-based observations with improved vertical resolution and/or long-term monitoring from spacecraft are required for this purpose, though the Voyager and Cassini data given indications that the magnitude of the forcing is very small.     

Interaction between eddies and mean flow in Jupiter's atmosphere: Analysis of Cassini imaging data

Beebe et al. [Beebe, R.F., et al., 1980. Geophys. Res. Lett. 17, 1-4] and Ingersoll et al. [Ingersoll, A.P., et al., 1981. J. Geophys. Res. 86, 8733-8743] used images from Voyagers 1 and 2 to analyze the interaction between zonal winds and eddies in Jupiter's atmosphere. They reported a high positive correlation between Jupiter's eddy momentum flux, , and the variation of zonal velocity with latitude, . This correlation implied a surprisingly high rate of conversion of energy from eddies to zonal flow: , a value more than 10% of Jupiter's thermal flux emission. However, Sromovsky et al. [Sromovsky, L.A., et al., 1982. J. Atmos. Sci. 39, 1413-1432] argued that possible biases in the analysis could have caused an artificially high correlation. In addition, significant differences in the derived eddy flux between datasets put into question the robustness of any one result. We return to this long-standing puzzle using images of Jupiter from the Cassini flyby of December 2000. Our method is similar to previous analyses, but utilizes an automatic feature tracker instead of the human eye. The number of velocity vectors used in this analysis is over 200,000, compared to the 14,000 vectors used by Ingersoll et al. We also find a positive correlation between and and derive a global average power per unit mass, , ranging from . Utilizing Ingersoll et al.'s estimate of the mass per unit area involved in the transport, this would imply a rate of energy conversion of . We discuss the implications of this result and employ several tests to demonstrate its robustness.     

Brightness power spectral distribution and waves in Jupiter's upper cloud and hazes

In this work we analyze the spatial structure of Jupiter's cloud reflectivity field in order to determine brightness periodicities and power spectra characteristics together with their relationship with Jupiter's dynamics and turbulence. The research is based on images obtained in the near-infrared (∼950 nm), blue (∼430 nm) and near-ultraviolet (∼260 nm) wavelengths with the Hubble Space Telescope in 1995 and the Cassini spacecraft Imaging Science Subsystem in 2000. Zonal reflectivity scans were analyzed by means of spatial periodograms and power spectra. The periodograms have been used to search for waves as a function of latitude. We present the values of the dominant wavenumbers for latitude bands between 32° N and 42° S. The brightness power spectra analysis has been performed in the meridional and zonal directions. The meridional analysis of albedo profiles are close to a k⁻⁵ law similarly to the wind profiles at blue and infrared wavelengths, although results differ from that in the ultraviolet. The zonal albedo analysis results in two distributions characterized by different slopes. In the near infrared and blue wavelengths, average spectral slopes are n₁=−1.3±0.4 for shorter wavenumbers (k<80), and n₂=−2.5±0.7 for greater wavenumbers, whereas for the ultraviolet n₁=−1.9±0.4 and n₂=−0.7±0.4, possibly showing a different dynamical regime. We find a turning point in the spectra between both regimes at wavenumber k∼80 (corresponding to L∼1000 km) for all wavelengths.     

Waves in Jupiter's atmosphere observed by the Cassini ISS and CIRS instruments

The Cassini Imaging Science Subsystem (ISS) and Composite Infrared Spectrometer (CIRS) reported a North Equatorial Belt (NEB) wave in Jupiter's atmosphere from optical images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] and thermal maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135], respectively. The connection between the two waves remained uncertain because the two observations were not simultaneous. Here we report on simultaneous ISS images and CIRS thermal maps that confirm that the NEB wave shown in the ISS ultraviolet (UV1) and strong methane band (MT3) images is correlated with the thermal wave in the CIRS temperature maps, with low temperatures in the CIRS maps (upwelling) corresponding to dark regions in the UV1 images (UV-absorbing particles) and bright regions in the MT3 images (high clouds and haze). The long period of the NEB wave suggests that it is a planetary (Rossby) wave. The combined observations from the ISS and CIRS are utilized to discuss the vertical and meridional propagation of the NEB wave, which offers a possible explanation for why the NEB wave is confined to specific latitudes and altitudes. Further, the ISS UV1 images reveal a circumpolar wave centered at 48.5° S (planetocentric) and probably located in the stratosphere, as suggested by the ISS and CIRS observations. The simultaneous comparison between the ISS and CIRS also implies that the large dark oval in the polar stratosphere of Jupiter discovered in the ISS UV1 images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] is the same feature as the warm regions at high northern latitudes in the CIRS 1-mbar temperature maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135]. This comparison supports a previous suggestion that the dark oval in the ISS UV1 images is linked to auroral precipitation and heating [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547].     

Modeling Jupiter's cloud bands and decks: 2. Distribution and motion of condensates

A simple jovian cloud scheme has been developed for the Oxford Planetary Unified model System (OPUS). NH₃-ice, NH₄SH-solid, H₂O-ice and H₂O-liquid clouds have been modeled in Southern hemisphere limited area simulations of Jupiter. We found that either three or four of the condensates existed in the model. For a deep atmospheric water abundance close to solar composition, an NH₃-ice deck above 0.7 bar, an NH₄SH-solid deck above 2.5 bar and a H₂O-liquid deck with a base at about 7.5 bar and frozen cloud tops formed. If a depleted deep water abundance is assumed, however, a very compact cloud structure develops, where an H₂O-ice cloud forms by direct sublimation above 3 bar. The condensates constitute good tracers of atmospheric motion, and we have confirmed that zonal velocities determined from manual feature tracking in the modeled cloud layers agree reasonably well with the modeled zonal velocities. Dense and elevated clouds form over latitudes with strong atmospheric upwelling and depleted clouds exist over areas with strong downwelling. In the NH₃-ice deck this leads to elevated cloud bands over the zones in the domain and thin clouds over the belts, which is consistent with the observationally deduced distribution. Due to changes in the vertical velocity pattern in the deeper atmosphere, the NH₄SH-solid and water cloud decks are more uniform. This modeled cloud structure thus includes the possibility of more frequent water cloud observations in belts, as this deeper deck could be more easily detected under areas with thin NH₃-ice clouds. Large scale vortices appeared spontaneously in the model and were characterized by elevated NH₃-ice clouds, as expected from observations. These eddies leave the most discernible imprint on the lighter condensate particles of the uppermost layer.     

Jupiter's polar clouds and waves from Cassini and HST images: 1993-2006

For a variety of reasons, Jupiter's polar areas are probably the less observed regions of the planet. To study the dynamics and cloud vertical structure in the polar regions of the planet (latitudes 50° to 80° in both hemispheres) we have used images of Jupiter obtained from the ultraviolet to near infrared (258 to 939 nm) by the Cassini Imagining Science Subsystem (ISS) in December 2000. The temporal coverage was complemented with archived images from the Hubble Space Telescope (1993-2006) in a similar spectral range. The zonal wind velocities have been measured at three Cassini ISS wavelengths (CB2, MT3 and UV1, corresponding to 750, 890 and 258 nm) sounding different altitude levels. The three eastward jets detected in CB2 images (lower cloud) go to zero velocity when measured in the UV1 filter (upper haze). A radiative transfer analysis has been performed to characterize the vertical structure of cloud and hazes distribution at the poles. We also present a characterization (phase speed, amplitude and zonal wavenumber) of the previously detected circumpolar waves at 67° N and S at 890 nm and at about 50° N and −57° S at 258 nm that are a permanent phenomenon in Jupiter with some variability in its structure during the analyzed period. From the ensemble of data analyzed we propose the waves are Rossby waves whose dynamic behavior constrains plausible values for their meridional and vertical wavenumbers. This work demonstrates the long-term nature of Jupiter's polar waves, providing a dynamical and vertical characterization which supports a detailed analysis of these phenomena in terms of a Rossby wave model.     

Modeling Jupiter's cloud bands and decks: 1. Jet scale meridional circulations

We have investigated the formation of jet scale meridional circulation cells on Jupiter in response to radiative and zonal momentum forcing. In the framework of semi-geostrophic theory, the meridional streamfunction is described by an elliptic equation with a source term dependent on the sum of the latitudinal derivative of the radiative forcing and the vertical derivative of the zonal momentum forcing. Using this equation with analytic terms similar to the assumed forcing on Jupiter, we obtained two set of atmospheric circulations cells, a stratospheric and a tropospheric one. A possible shift in the overturning circulation of the high and deep atmosphere can be induced by breaking the latitudinal alignment of radiative heating with the enforced belt and zones. A series of numerical simulations was conducted with the Jovian GCM OPUS, which was initiated with observational data obtained from the Cassini CIRS temperature cross-section and a corresponding geostrophic zonal wind field. Newtonian forcing of potential temperature as well as zonal momentum was applied respectively towards latitudinally and vertically uniform equilibrium fields. In accordance with the analytic illustrations two rows of jet scale circulation cells were created. The stratospheric circulation showed the distribution of upwelling over zones and downwelling over belts, consistent with cloud observations. The tropospheric cells featured a partial reversal of the downward vertical velocity over the belts and a considerable reduction of the upward movement over the zones in the domain, consistent with recent detections of high water clouds and lightning in belts. We also used the modeled new forcing fields as source terms for the semi-geostrophic Poisson equation to attribute the origin of the modeled secondary circulation. In this analysis, the stratospheric circulation cells observed in the model are primarily generated in response to radiative forcing, while momentum forcing induces the shifted configurations in the deep atmosphere.     

Microwave remote sensing of Jupiter's atmosphere from an orbiting spacecraft

Microwave remote sounding from a spacecraft flying by or in orbit around Jupiter offers new possibilities for retrieving important and presently poorly understood properties of its atmosphere. In particular, we show that precise measurements of relative brightness temperature as a function of off-nadir emission angles, combined with absolute brightness temperature measurements, can allow us to determine the global abundances of water and ammonia and study the dynamics and deep circulations of the atmosphere in the altitude range from the ammonia cloud region to depths greater than 30 bars in a manner which would not be achievable with ground-based telescopes.     

Meridional variations of C2H2 and C2H6 in Jupiter's atmosphere from Cassini CIRS infrared spectra

Hydrocarbons such as acetylene (C₂H₂) and ethane (C₂H₆) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm⁻¹ (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm⁻¹) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν₄ band of CH₄, and in the troposphere at 150-400 mbar, via the H₂ absorption at 600-800 cm⁻¹. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C₂H₂ and C₂H₆ by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C₂H₂ν₅ and C₂H₆ν₉ bands, and also emission of the acetylene (ν₄+ν₅)−ν₄ hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼3×¹⁰⁻⁹. Additionally, the abundance gradient of C₂H₂ between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C₂H₂ and C₂H₆ by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C₂H₆ in the stratosphere (3×¹⁰¹⁰ s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5-50×¹⁰⁸ s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C₂H₂, the opposite occurs, with the relatively short photochemical lifetime (3×¹⁰⁷ s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible.