Alkali and Chlorine Photochemistry in a Volcanically Driven Atmosphere on Io

Observations of the Io plasma torus and neutral clouds indicate that the extended ionian atmosphere must contain sodium, potassium, and chlorine in atomic and/or molecular form. Models that consider sublimation of pure sulfur dioxide frost as the sole mechanism for generating an atmosphere on Io cannot explain the presence of alkali and halogen species in the atmosphere—active volcanoes or surface sputtering must also be considered, or the alkali and halide species must be discharged along with the SO₂ as the frost sublimates. To determine how volcanic outgassing can affect the chemistry of Io's atmosphere, we have developed a one-dimensional photochemical model in which active volcanoes release a rich suite of S-, O-, Na-, K-, and Cl-bearing vapor and in which photolysis, chemical reactions, condensation, and vertical eddy and molecular diffusion affect the subsequent evolution of the volcanic gases. Observations of Pele plume constituents, along with thermochemical equilibrium calculations of the composition of volcanic gases exsolved from high-temperature silicate magmas on Io, are used to constrain the composition of the volcanic vapor. We find that NaCl, Na, Cl, KCl, and K will be the dominant alkali and chlorine gases in atmospheres generated from Pele-like plume eruptions on Io. Although the relative abundances of these species will depend on uncertain model parameters and initial conditions, these five species remain dominant for a wide variety of realistic conditions. Other sodium and chlorine molecules such as NaS, NaO, Na₂, NaS₂, NaO₂, NaOS, NaSO₂, SCl, ClO, Cl₂, S₂Cl, and SO₂Cl₂ will be only minor constituents in the ionian atmosphere because of their low volcanic emission rates and their efficient photochemical destruction mechanisms. Our modeling has implications for the general appearance, properties, and variability of the neutral sodium clouds and jets observed near Io. The neutral NaCl molecules present at high altitudes in atmosph eres generated by active volcanoes might provide the NaX⁺ ion needed to help explain the morphology of the high-velocity sodium “stream” feature observed near Io.     

Silicon tetrafluoride on Io

Silicon tetrafluoride (SiF₄) is observed in terrestrial volcanic gases and is predicted to be the major F-bearing species in low-temperature volcanic gases on Io [Schaefer, L., Fegley Jr., B., 2005b. Alkali and halogen chemistry in volcanic gases on Io. Icarus 173, 454-468]. SiF₄ gas is also a potential indicator of silica-rich crust on Io. We used F/S ratios in terrestrial and extraterrestrial basalts, and gas/lava enrichment factors for F and S measured at terrestrial volcanoes to calculate equilibrium SiF₄/SO₂ ratios in volcanic gases on Io. We conclude that SiF₄ can be produced at levels comparable to the observed NaCl/SO₂ gas ratio. We also considered potential loss processes for SiF₄ in volcanic plumes and in Io's atmosphere including ion-molecule reactions, electron chemistry, photochemistry, reactions with the major atmospheric constituents, and condensation. Photochemical destruction (t_chem ∼266 days) and/or condensation as Na₂SiF₆ (s) appear to be the major sinks for SiF₄. We recommend searching for SiF₄ with infrared spectroscopy using its 9.7 μm band as done on Earth.     

Alkali (Rb/K) abundances in Allende barred-olivine chondrules: Implications for the melting conditions of chondrules

Abstract— In order to study abundances of alkali metals in chondrules, 25 petrographically characterized chondrules, including 18 barred olivine (BO) chondrules from the Allende (CV3) meteorite, were analyzed for alkalis (K and Rb) and alkaline earths (Sr, Ba, Ca and Mg) by mass spectrometric isotope dilution. Most BO chondrules with higher alkalis (>CI level) have nearly CI-chondritic Rb/K ratios, while those with lower alkalis clearly show higher Rb/K ratios than the CI-chondritic. In general, BO chondrules with higher Rb/K exhibit more depletion of alkalis relative to Ca. The mean olivine Fa for individual chondrules positively correlates with bulk alkali concentrations in BO type but not in porphyritic type chondrules. These observations suggest that some BO chondrules formed from more reducing assemblages of precursor minerals, which experienced more intensive vaporization losses of alkalis, accompanied by Rb/K fractionation, during the chondrule-formation melting.     

A thermodynamic model of high temperature lava vaporization on Io

We modified the MAGMA chemical equilibrium code developed by Fegley and Cameron (1987, Earth Planet. Sci. Lett. 82, 207-222) and used it to model vaporization of high temperature silicate lavas on Io. The MAGMA code computes chemical equilibria in a melt, between melt and its equilibrium vapor, and in the gas phase. The good agreement of MAGMA code results with experimental data and with other computer codes is demonstrated. The temperature-dependent pressure and composition of vapor in equilibrium with lava is calculated from 1700 to 2400 K for 109 different silicate lavas in the ONaKFeSiMgCaAlTi system. Results for five lavas (tholeiitic basalt, alkali basalt, Barberton komatiite, dunite, and a molten type B1 Ca, Al-rich inclusion) are discussed in detail. The effects of continuous fractional vaporization on chemistry of these lavas and their equilibrium vapor are presented. The predicted abundances (relative to Na) of K, Fe, Si, Al, Ca, and Ti in the vapor equilibrated with lavas at 1900 K are lower than published upper limits for Io's atmosphere (which do not include Mg). We predict evaporative loss of alkalis, Fe, and Si during volcanic eruptions. Sodium is more volatile than K, and the Na/K ratio in the gas is decreased by fractional vaporization. This process can match Io's atmospheric Na/K ratio of 10±3 reported by Brown (2001, Icarus 151, 190-195). Silicon monoxide is an abundant species in the vapor above lavas. Spectroscopic searches are recommended for SiO at IR and mm wavelengths. Reactions of metallic vapors with S- and Cl-bearing volcanic gases may form other unusual gases including MgCl₂, MgS, MgCl, FeCl₂, FeS, FeCl, and SiS.     

REE abundances in the matrix of the Allende (CV) meteorite: Implications for matrix origin

Abstract— The trace element distributions in the matrix of primitive chondrites were examined using four least‐contaminated matrix specimens from the polished sections of the Allende (CV) meteorite. Analysis of rare earth element (REE), Ba, Sr, Rb, and K abundances by isotope dilution mass spectrometry revealed that the elemental abundances of lithophile elements except for alkali metals (K, Rb) in the specimens of the Allende matrix studied here are nearly CI (carbonaceous Orgueil) chondritic (～1 × CI). Compared to refractory elements, all the matrix samples exhibited systematic depletion of the moderately volatile elements K and Rb (0.1–0.5 × CI). We suggest that the matrix precursor material did not carry significant amounts of alkali metals or that the alkalis were removed from the matrix precursor material during the parent body process and/or before matrix formation and accretion. The matrix specimens displayed slightly fractionated REE abundance patterns with positive Ce anomalies (CI‐normalized La/Yb ratio = 1.32–1.65; Ce/Ce* = 1.16–1.28; Eu/Eu* = 0.98–1.10). The REE features of the Allende matrix do not indicate a direct relationship with chondrules or calcium‐aluminum‐rich inclusions (CAIs), which in turn suggests that the matrix was not formed from materials produced by the breakage and disaggregation of the chondrules or CAIs. Therefore, we infer that the Allende matrix retains the REE features acquired during the condensation process in the nebula gas.     

Energy Distributions for Desorption of Sodium and Potassium from Ice: The Na/K Ratio at Europa

The sputtering and decomposition of the surface of Europa by fast ions and electrons lead to the production of an atomosphere containing sodium and potassium atoms. Here time-of-flight energy distributions are measured for Na and K sputtered from a vapor-deposited ice by 200-eV electrons. These data are then used in a Monte Carlo simulation for alkalis in Europa's atmosphere. Na/K ratios versus distance from Europa are calculated and compared to the recent observations in the range 6 to 18 Europan radii from the surface. Normalizing to the observations, the Na/K ratio for the loss rates is ∼27 and the ratio for the average surface source rates is ∼20. These ratios are very different from the Na/K ratio at Io and are larger than the Na/K ratio suggested for Europa's putative subsurface ocean, consistent with fractionation on freezing and upwelling of ocean material.     

Alkali elements in the Earth's core: Evidence from enstatite meteorites

Abstract— The abundances of alkali elements in the Earth's core are predicted by assuming that accretion of the Earth started from material similar in composition to enstatite chondrites and that enstatite achondrites (aubrites) provide a natural laboratory to study core-mantle differentiation under extremely reducing conditions. If core formation on the aubrite parent body is comparable with core formation on the early Earth, it is found that 2600 (±1000) ppm Na, 550 (±260) ppm K, 3.4 (±2.1) ppm Rb, and 0.31 (±0.24) ppm Cs can reside in the Earth's core. The alkali-element abundances are consistent with those predicted by independent estimates based on nebula condensation calculations and heat flow data.     

Spectral reflectance change and luminescence of selected salts during 2–10 KeV proton bombardment: Implications for Io

Radiation damage and luminescence, caused by magnetospheric charged particles, have been suggested by several authors as mechanisms for explaining some of the peculiar spectral/albedo features of Io. We have pursued this possibility by measuring the uv-visual spectral reflectance and luminescent efficiency of several proposed Io surface constituents during 2 to 10-keV proton irradiation at room temperature and at low temperature (120 < T < 140°K). The spectral reflectance of NaCl and KCl during proton irradiation exhibits the well-known F-center absorption bands at 4580 and 5560 Å. Na₂SO₄ shows a generalized darkening which increases toward longer wavelengths. NaNO₃ shows a spectral reflectance change indicative of the partial alteration of NaNo₃ to NaNo₂. NaNO₂ shows no change. The luminescent efficiencies of NaCl and KCl are ～10^?4 at 300°K and increase by one-half order of magnitude at ～130°K. The efficiencies of K₂CO₃, Na₂CO₃, Na₂SO₄, and NaNO₃ are 10^?4, 10^?4, 10^?5 and 10^?6, respectively, at 300°K and they all decrease by one-half order of magnitude at ～130°K. These results indicate that magnetospheric proton irradiation of Io could cause spectral features in its observed ultraviolet and visible reflection spectrum if salts such as those studied here are present on its surface. However, because the magnitude of these spectral effects is dependent on competing factors such as surface temperature, incident particle energy flux, solar bleaching effects, and trace element abundance, we are unable at this time to make a quantitative estimate of the strength of these spectral effects on Io. The luminescent efficiencies of pure samples that we have studied in the laboratory suggest that charged-particle induced luminescence from Io's surface might be observable by a spacecraft such as Voyager when viewing Io's dark side.     

Thermal history of the Jovian satellite Io

The discovery of large volcanic eruptions on Io suggests that Io is one of the most geologically active planetary bodies. The energy source of this geologic activity is believed to be tidal heating induced by Jupiter. A number of thermal history calculations were done to investigate the effect of tidal heating on the thermal history of Io taking into account solid state convection and advective heat transfer. These simulations show that the total tidal heating energy in Io is almost equal to the advectively transferred heat, indicating that the observed heat flow from Io is nearly equal to the total tidal heating energy. Since total tidal heating energy is dependent on the radius of the liquid mantle and the internal dissipation factor (Q), the radius of the liquid mantle can be estimated for a given value of Q. Some reasonable thermal history models of Io were obtained using a model with Q ≈ 25–50 in which the magma source of Ionian volcanism is at a depth of 100–300 km. The models satisfy the heat flow data and the existence of a thick lithosphere. Using a model with Q = 25 and L = 300 km (thickness of the advective region) as the standard model (model II), we then studied the effect of convective heat transfer and the initial temperature distribution on the Ionian thermal history. In these calculations, the other parameters are the same as in the standard model (model II). These calculations show that although the temperature distribution in the central region reflects the difference in the efficiency of convective heat transfer and initial temperature distribution, the temperature distribution in the outer region does not changes appreciably.     

Photochemistry of a Volcanically Driven Atmosphere on Io: Sulfur and Oxygen Species from a Pele-Type Eruption

To determine how active volcanism might affect the standard picture of sulfur dioxide photochemistry on Io, we have developed a one-dimensional atmospheric model in which a variety of sulfur-, oxygen-, sodium-, potassium-, and chlorine-bearing volatiles are volcanically outgassed at Io's surface and then evolve due to photolysis, chemical kinetics, and diffusion. Thermochemical equilibrium calculations in combination with recent observations of gases in the Pele plume are used to help constrain the composition and physical properties of the exsolved volcanic vapors. Both thermochemical equilibrium calculations (Zolotov and Fegley 1999, Icarus141, 40-52) and the Pele plume observations of Spencer et al. (2000; Science288, 1208-1210) suggest that S₂ may be a common gas emitted in volcanic eruptions on Io. If so, our photochemical models indicate that the composition of Io's atmosphere could differ significantly from the case of an atmosphere in equilibrium with SO₂ frost. The major differences as they relate to oxygen and sulfur species are an increased abundance of S, S₂, S₃, S₄, SO, and S₂O and a decreased abundance of O and O₂ in the Pele-type volcanic models as compared with frost sublimation models. The high observed SO/SO₂ ratio on Io might reflect the importance of a contribution from volcanic SO rather than indicate low eddy diffusion coefficients in Io's atmosphere or low SO “sticking” probabilities at Io's surface; in that case, the SO/SO₂ ratio could be temporally and/or spatially variable as volcanic activity fluctuates. Many of the interesting volcanic species (e.g., S₂, S₃, S₄, and S₂O) are short lived and will be rapidly destroyed once the volcanic plumes shut off; condensation of these species near the source vent is also likely. The diffuse red deposits associated with active volcanic centers on Io may be caused by S₄ radicals that are created and temporarily preserved when sulfur vapor (predominantly S₂) condenses around the volcanic vent. Condensation of SO across the surface and, in particular, in the polar regions might also affect the surface spectral properties. We predict that the S/O ratio in the torus and neutral clouds might be correlated with volcanic activity—during periods when volcanic outgassing of S₂ (or other molecular sulfur vapors) is prevalent, we would expect the escape of sulfur to be enhanced relative to that of oxygen, and the S/O ratio in the torus and neutral clouds could be correspondingly increased.     

Io: Volcanic thermal sources and global heat flow

We have examined thermal emission from 240 active or recently-active volcanic features on Io and quantified the magnitude and distribution of their volcanic heat flow during the Galileo epoch. We use spacecraft data and a geological map of Io to derive an estimate of the maximum possible contribution from small dark areas not detected as thermally active but which nevertheless appear to be sites of recent volcanic activity. We utilize a trend analysis to extrapolate from the smallest detectable volcanic heat sources to these smallest mapped dark areas. Including the additional heat from estimates for “outburst” eruptions and for a multitude of very small (“myriad”) hot spots, we account for ～62 × 10¹² W (～59 ± 7% of Io’s total thermal emission). Loki Patera contributes, on average, 9.6 × 10¹² W (～9.1 ± 1%). All dark paterae contribute 45.3 × 10¹² W (～43 ± 5%). Although dark flow fields cover a much larger area than dark paterae, they contribute only 5.6 × 10¹² W (～5.3 ± 0.6%). Bright paterae contribute ～2.6 × 10¹² W (～2.5 ± 0.3%). Outburst eruption phases and very small hot spots contribute no more than ～4% of Io’s total thermal emission: this is probably a maximum value. About 50% of Io’s volcanic heat flow emanates from only 1.2% of Io’s surface. Of Io’s heat flow, 41 ± 7.0% remains unaccounted for in terms of identified sources. Globally, volcanic heat flow is not uniformly distributed. Power output per unit surface area is slightly biased towards mid-latitudes, although there is a stronger bias toward the northern hemisphere when Loki Patera is included. There is a slight favoring of the northern hemisphere for outbursts where locations were well constrained. Globally, we find peaks in thermal emission at ～315°W and ～105°W (using 30° bins). There is a minimum in thermal emission at around 200°W (almost at the anti-jovian longitude) which is a significant regional difference. These peaks and troughs suggest a shift to the east from predicted global heat flow patterns resulting from tidal heating in an asthenosphere. Global volcanic heat flow is dominated by thermal emission from paterae, especially from Loki Patera (312°W, 12°N). Thermal emission from dark flows maximises between 165°W and 225°W. Finally, it is possible that a multitude of very small hot spots, smaller than the present angular resolution detection limits, and/or cooler, secondary volcanic processes involving sulphurous compounds, may be responsible for at least part of the heat flow that is not associated with known sources. Such activity should be sought out during the next mission to Io.     

Io: Heat flow from dark volcanic fields

Dark flow fields on the jovian satellite Io are evidence of current or recent volcanic activity. We have examined the darkest volcanic fields and quantified their thermal emission in order to assess their contribution to Io’s total heat flow. Loki Patera, the largest single source of heat flow on Io, is a convenient point of reference. We find that dark volcanic fields are more common in the hemisphere opposite Loki Patera and this large scale concentration is manifested as a maximum in the longitudinal distribution (near ∼200 °W), consistent with USGS global geologic mapping results. In spite of their relatively cool temperatures, dark volcanic fields contribute almost as much to Io’s heat flow as Loki Patera itself because of their larger areal extent. As a group, dark volcanic fields provide an asymmetric component of ∼5% of Io’s global heat flow or ∼5 × 10¹² W.     

Sulfur flows of Ra Patera,Io

Voyager 1 imaging data have been used to investigate the color and morphology of several radial flow-like features at Ra Patera, a broad volcanic structure at approximately 8° latitude and 325° longitude on the Galilean satellite Io (J1). It was found that downstream progressions of flow color and morphology are consistent with lava of a predominately sulfur composition cooling radiatively and erupting in the range of 470 to 520°K at effusion rates at 10¹⁰ to 10¹¹ cm³/sec. This implies global resurfacing rates by volcanic flows on Io of the order of 1 cm/year. Calculated energy content and effusion rates for flows at Ra Patera, using the physical parameters of sulfur, are of the order of the largest known terrestial basaltic eruptions and are consistent with calculations of globally available energy.     

Composition of jovian dust stream particles

The Cassini spacecraft encountered Jupiter in late 2000. Within more than 1 AU of the gas giant the Cosmic Dust Analyser onboard the spacecraft recorded the first ever mass spectra of jovian stream particles. To determine the chemical composition of particles, a comprehensive statistical analysis of the dataset was performed. Our results imply that the vast majority (>95%) of the observed stream particles originate from the volcanic active jovian satellite Io from where they are sprinkled out far into the Solar System. Sodium chloride (NaCl) was identified as the major particle constituent, accompanied by sulphurous as well as potassium bearing components. This is in contrast to observations of gas in the ionian atmosphere, its co-rotating plasma torus, and the neutral cloud, where sulphur species are dominant while alkali and chlorine species are only minor components. Io has the largest active volcanoes of the Solar System with plumes reaching heights of more than 400 km above the moons surface. Our in situ measurements indicate that alkaline salt condensation of volcanic gases inside those plumes could be the dominant formation process for particles reaching the ionian exosphere.     

Io: Thermal models and chemical evolution

A combined thermal and chemical evolution model of Io is presented, outlining limits on the possible starting materials, heating history, chemical history, and present state of Io. Our best scenario starts with Io being accreted from material in a proto-Jovian nebula which condensed between 400–600°K. Radionuclides and tidal heating would lead to large-scale convection within Io and chemical reactions leading to the outgassing of water and methane. Reactions between Fe⁰FeS and water, at least near the surface, go to completion, resulting in all Fe being oxidized with elemental sulfur producing a low-conductivity crust. In the deep interior, these reactions may not completely exhaust Fe metal, and an FeS-rich core may be formed.     

Optical properties of solid and liquid sulfur at visible and infrared wavelengths

Knowledge of the optical constants of elemental sulfur has potential applications to Venus, Jupiter, Io, Amalthea, and the Earth. The real part, n, of the index of refraction of liquid sulfur (at 133°C) and of solid orthorhombic sulfur (at 25°C) for the wavelength range 0.4–2.0 μm were measured ellipsometrically. The imaginary part, k, of the refractive index of liquid sulfur was obtained by transmittance measurements at the same temperature and wavelength range. The reflectance of semi-infinite slabs of solid and liquid sulfur is calculated using the measured n and k values. We confirm that sulfur melts on Io would be classified as “black” by the Voyager imaging system.     

Io's 4-μm band and the role of adsorbed SO2

The role of adsorbed SO₂ on Io's surface particles in producing the observed spectral absorption band near 4 μm in Io's reflectance spectrum is explored. Calculations show that a modest 50% monolayer coating of adsorbed SO₂ molecules on submicron grains of sulfur of alkali sulfide, assumed to make up Io's uppermost optical surface (“radialith”), will result in a ν₁ + ν₃ absorption band near 4 μm with depth ～30% below the adjacent continuum, consistent with the observed strength of the Io band. The precise wavelength position of the ν₁ + ν₃ band of SO₂ in different phase states such as frost, ice, adsorbate, and gas are summarized from the experimental literature and compared with the available telescopic measurements of the Io band position. The results suggest that the 4-μm band in Io's full disk spectrum can best be explained by the presence on Io's surface of widespread SO₂ in the form of adsorbate rather than ice or frost.     

Mid-infrared detection of large longitudinal asymmetries in Io's SO2 atmosphere

We have observed about 16 absorption lines of the ν₂ SO₂ vibrational band on Io, in disk-integrated 19-μm spectra taken with the TEXES high spectral resolution mid-infrared spectrograph at the NASA Infrared Telescope Facility in November 2001, December 2002, and January 2004. These are the first ground-based infrared observations of Io's sunlit atmosphere, and provide a new window on the atmosphere that allows better longitudinal and temporal monitoring than previous techniques. Dramatic variations in band strength with longitude are seen that are stable over at least a 2 year period. The depth of the strongest feature, a blend of lines centered at 530.42 cm⁻¹, varies from about 7% near longitude 180° to about 1% near longitude 315° W, as measured at a spectral resolution of 57,000. Interpretation of the spectra requires modeling of surface temperatures and atmospheric density across Io's disk, and the variation in non-LTE ν₂ vibrational temperature with altitude, and depends on the assumed atmospheric and surface temperature structure. About half of Io's 19-μm radiation comes from the Sun-heated surface, and half from volcanic hot spots with temperatures primarily between 150 and 200 K, which occupy about 8% of the surface. The observations are thus weighted towards the atmosphere over these low-temperature hot spots. If we assume that the atmosphere over the hot spots is representative of the atmosphere elsewhere, and that the atmospheric density is a function of latitude, the most plausible interpretation of the data is that the equatorial atmospheric column density varies from about 1.5×¹⁰¹⁷ cm⁻² near longitude 180° W to about 1.5×¹⁰¹⁶ cm⁻² near longitude 300° W, roughly consistent with HST UV spectroscopy and Lyman-α imaging. The inferred atmospheric kinetic temperature is less than about 150 K, at least on the anti-Jupiter hemisphere where the bands are strongest, somewhat colder than inferred from HST UV spectroscopy and millimeter-wavelength spectroscopy. This longitudinal variability in atmospheric density correlates with the longitudinal variability in the abundance of optically thick, near-UV bright SO₂ frost. However it is not clear whether the correlation results from volcanic control (regions of large frost abundance result from greater condensation of atmospheric gases supported by more vigorous volcanic activity in these regions) or sublimation control (regions of large frost abundance produce a more extensive atmosphere due to more extensive sublimation). Comparison of data taken in 2001, 2002, and 2004 shows that with the possible exception of longitudes near 180° W between 2001 and 2002, Io's atmospheric density does not appear to decrease as Io recedes from the Sun, as would be expected if the atmosphere were supported by the sublimation of surface frost, suggesting that the atmosphere is dominantly supported by direct volcanic supply rather than by frost sublimation. However, other evidence such as the smooth variation in atmospheric abundance with latitude, and atmospheric changes during eclipse, suggest that sublimation support is more important than volcanic support, leaving the question of the dominant atmospheric support mechanism still unresolved.     

The surface of Io: Geologic units,morphology, and tectonics

A prelimanary geologic map, representing 26.5% of the surface of Io, has been compiled using best-resolution (0.5 to 5 km/line pair) Voyager 1 images and (as a base) a preliminary pictorial map of Io. Nine volcanic units are identified, including materials of mountains (1.9% of total area), plains (49.6%), flows (31.1%), cones (0.1%), and crater vents (4.0%), in addition to seven types of structural features. Photogeologic evidence indicates a dominantly silicate composition for the mountain material, which supports heights of at least 9 ± 1 km. Sulfur flows of diverse viscosity and sulfur-silicate mixtures are thought to compose the pervasive plains. Pit crater and shield crater vent wall scarps reach heights of 2 km and layered plains boundary scarps have estimated heights of 150 to 1700 m; such scarps indicate a material with considerable strenght. A cumulative, volcanic crater size-frequency distribution plot has been prepared using 170 mapped Ionian vents with diameters > 14 km; the shape and slope of the curve are like those for impact craters on other bodies in the solar system, attesting to a similar nonrandom distribution to crater diameters and a surplus of small craters. Io's equatorial zone has six times the number of vents per unit area as the south polar zone. No craters of unequivocal impact origin have been identified on Io to date. A total of 151 lineaments and grabens are recognized with four dominant azimuthal trends forming two nearly orthogonal sets spaces 110° apart (N 85° E, N 25° W and N 45° E, N 55°W). The mapped area lies within the longitudinal zone (250 to 323°) of least-abundant SO₂ frost, indicating that other sulfurous components dominate the upper surface layers in this area.     

Temporal behavior of the SO 1.707 μm ro-vibronic emission band in Io's atmosphere

We report observations of the ro-vibronic a¹Δ→X³Σ⁻ transition of SO at 1.707 μm on Io. These data were taken while Io was eclipsed by Jupiter, on four nights between July 2000 and March 2003. We analyze these results in conjunction with a previously published night to investigate the temporal behavior of these emissions. The observations were all conducted using the near-infrared spectrometer NIRSPEC on the W.M. Keck II telescope. The integrated emitted intensity for this band varies from 0.8×¹⁰²⁷ to 2.4×¹⁰²⁷ photons/s, with a possible link to variations in Loki's infrared brightness. The band-shapes imply rotational temperatures of 550-1000 K for the emitting gas, lending further evidence to a volcanic origin for sulfur monoxide. An attempt to detect the B¹Σ→X³Σ⁻ transition of SO at 0.97 μm was unsuccessful; simultaneous detection with the 1.707 μm band would permit determination of the SO column abundance.